NO174813B - Ekstruderbar silanfornettbar etylenkopolymerblanding - Google Patents
Ekstruderbar silanfornettbar etylenkopolymerblanding Download PDFInfo
- Publication number
- NO174813B NO174813B NO860651A NO860651A NO174813B NO 174813 B NO174813 B NO 174813B NO 860651 A NO860651 A NO 860651A NO 860651 A NO860651 A NO 860651A NO 174813 B NO174813 B NO 174813B
- Authority
- NO
- Norway
- Prior art keywords
- weight
- parts
- silane compound
- ethylene
- organic group
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 23
- 229910000077 silane Inorganic materials 0.000 title claims abstract description 21
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 title claims abstract description 10
- 229920001038 ethylene copolymer Polymers 0.000 title description 14
- -1 unsaturated silane compound Chemical class 0.000 claims abstract description 32
- 229920001577 copolymer Polymers 0.000 claims abstract description 16
- 125000000962 organic group Chemical group 0.000 claims abstract description 15
- 239000005977 Ethylene Substances 0.000 claims abstract description 13
- 239000000178 monomer Substances 0.000 claims abstract description 13
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003054 catalyst Substances 0.000 claims abstract description 12
- 238000009833 condensation Methods 0.000 claims abstract description 11
- 230000005494 condensation Effects 0.000 claims abstract description 10
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000010526 radical polymerization reaction Methods 0.000 claims abstract description 4
- 238000001125 extrusion Methods 0.000 claims description 7
- 150000004756 silanes Chemical class 0.000 claims description 7
- 239000007870 radical polymerization initiator Substances 0.000 claims description 5
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 4
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 4
- 239000012986 chain transfer agent Substances 0.000 claims description 3
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 238000004132 cross linking Methods 0.000 description 14
- 238000000034 method Methods 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 5
- 238000004898 kneading Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 150000001451 organic peroxides Chemical class 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- AYMDJPGTQFHDSA-UHFFFAOYSA-N 1-(2-ethenoxyethoxy)-2-ethoxyethane Chemical compound CCOCCOCCOC=C AYMDJPGTQFHDSA-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- 239000012975 dibutyltin dilaurate Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011133 lead Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 150000007530 organic bases Chemical class 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- WDYVUKGVKRZQNM-UHFFFAOYSA-N 6-phosphonohexylphosphonic acid Chemical compound OP(O)(=O)CCCCCCP(O)(O)=O WDYVUKGVKRZQNM-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- NBJODVYWAQLZOC-UHFFFAOYSA-L [dibutyl(octanoyloxy)stannyl] octanoate Chemical compound CCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCC NBJODVYWAQLZOC-UHFFFAOYSA-L 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000001769 aryl amino group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 125000004369 butenyl group Chemical group C(=CCC)* 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001734 carboxylic acid salts Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- PNOXNTGLSKTMQO-UHFFFAOYSA-L diacetyloxytin Chemical compound CC(=O)O[Sn]OC(C)=O PNOXNTGLSKTMQO-UHFFFAOYSA-L 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- NHOGGUYTANYCGQ-UHFFFAOYSA-N ethenoxybenzene Chemical compound C=COC1=CC=CC=C1 NHOGGUYTANYCGQ-UHFFFAOYSA-N 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 125000000555 isopropenyl group Chemical group [H]\C([H])=C(\*)C([H])([H])[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical compound [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 description 1
- PLYIPBIZXSTXCW-UHFFFAOYSA-N octanoic acid;tin Chemical compound [Sn].CCCCCCCC(O)=O PLYIPBIZXSTXCW-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- KOPQZJAYZFAPBC-UHFFFAOYSA-N propanoyl propaneperoxoate Chemical compound CCC(=O)OOC(=O)CC KOPQZJAYZFAPBC-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L43/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Compositions of derivatives of such polymers
- C08L43/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Organic Insulating Materials (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60036004A JPH0615644B2 (ja) | 1985-02-25 | 1985-02-25 | シラン架橋性共重合体組成物 |
Publications (3)
Publication Number | Publication Date |
---|---|
NO860651L NO860651L (no) | 1986-08-26 |
NO174813B true NO174813B (no) | 1994-04-05 |
NO174813C NO174813C (fr) | 1994-07-13 |
Family
ID=12457627
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO860651A NO174813B (no) | 1985-02-25 | 1986-02-21 | Ekstruderbar silanfornettbar etylenkopolymerblanding |
Country Status (7)
Country | Link |
---|---|
US (2) | US4689369A (fr) |
EP (1) | EP0193317B2 (fr) |
JP (1) | JPH0615644B2 (fr) |
DE (1) | DE3673837D1 (fr) |
DK (1) | DK169078B1 (fr) |
FI (1) | FI86876C (fr) |
NO (1) | NO174813B (fr) |
Families Citing this family (52)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0169536B1 (fr) * | 1984-07-26 | 1994-05-18 | Kanegafuchi Chemical Industry Co., Ltd. | Composition de polymère réticulable |
EP0245938A3 (fr) * | 1986-04-03 | 1987-11-25 | BP Chemicals Limited | Composition polymère |
US4822864A (en) * | 1987-06-18 | 1989-04-18 | Ocular Technologies, Inc. | Gas permeable contact lens and method and materials for its manufacture |
JP2609256B2 (ja) * | 1987-07-21 | 1997-05-14 | 鐘淵化学工業株式会社 | 硬化性組成物 |
CA1312166C (fr) * | 1987-12-16 | 1992-12-29 | Mitsui Chemicals, Incorporated | Composition de resine de polyolefine |
KR920005671B1 (ko) * | 1987-12-16 | 1992-07-13 | 미쯔이도오아쯔가가꾸 가부시끼가이샤 | 함규소 폴리머의 제조방법 |
GB8816657D0 (en) * | 1988-07-13 | 1988-08-17 | Bp Chem Int Ltd | Crosslinkable silyl polymer composition |
GB8816658D0 (en) * | 1988-07-13 | 1988-08-17 | Bp Chem Int Ltd | Crosslinkable silyl polymer composition |
JP2565753B2 (ja) * | 1988-09-19 | 1996-12-18 | 住友化学工業株式会社 | ポリプロピレン成形品 |
SE462752B (sv) * | 1988-12-23 | 1990-08-27 | Neste Oy | Silanfoernaetningsbar polymerkomposition innehaallande en silanfoerening som motverkar foer tidig haerdning |
US5204404A (en) * | 1989-03-21 | 1993-04-20 | E. I. Du Pont De Nemours And Company | Waterbased acrylic silane and polyurethane containing coating composition |
EP0601219B1 (fr) * | 1990-08-16 | 1997-09-10 | E.I. Du Pont De Nemours And Company | Composition de revêtement aqueuse contenant d'acrylsilan et de polyurethane |
US5036139A (en) * | 1989-09-29 | 1991-07-30 | E. I. Du Pont De Nemours And Company | Hybrid acrylic star polymers with polysiloxane cores |
US5004474A (en) * | 1989-11-28 | 1991-04-02 | Baxter International Inc. | Prosthetic anterior cruciate ligament design |
SE465165B (sv) * | 1989-12-13 | 1991-08-05 | Neste Oy | Foernaetningsbar polymerkomposition innehaallande hydrolyserbara silangrupper och en syraanhydrid som katalysator |
US5854356A (en) * | 1990-10-29 | 1998-12-29 | Neste Oy | Polymers for release films on surfaces containing pressure-sensitive adhesives |
US5153382A (en) * | 1991-04-18 | 1992-10-06 | Union Carbide Chemicals & Plastics Technology Corporation | Extrusion of thermoplastic copolymers |
US5338609A (en) * | 1991-10-30 | 1994-08-16 | Quantum Chemical Corporation | Fractional melt flow rate polymer powders and process for their preparation |
DE4244517A1 (en) * | 1992-12-30 | 1993-05-19 | Kathrin Weise | Photochemical crosslinking of persistent silicon carbide ceramic precursors - by UV-irradiation of poly-silane(s) in presence of special bis:azide(s), e.g. 2,6-bis-(4-azido:benzylidene)-4-methyl-cyclohexanone |
SE502171C2 (sv) * | 1993-12-20 | 1995-09-04 | Borealis Holding As | Polyetenkompatibla sulfonsyror som silanförnätningskatalysatorer |
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US6165387A (en) * | 1997-02-04 | 2000-12-26 | Borealis A/S | Composition for electric cables |
SE9703798D0 (sv) | 1997-10-20 | 1997-10-20 | Borealis As | Electric cable and a method an composition for the production thereof |
SE513362C2 (sv) | 1997-11-18 | 2000-09-04 | Borealis As | Förfarande för minskning av reaktornedsmutsning |
SE9802087D0 (sv) | 1998-06-12 | 1998-06-12 | Borealis Polymers Oy | An insulating composition for communication cables |
SE9802386D0 (sv) | 1998-07-03 | 1998-07-03 | Borealis As | Composition for elektric cables |
SE9804323D0 (sv) * | 1998-12-15 | 1998-12-15 | Borealis As | A power cable insulating layer, a process for the preparation thereof, and a composition therefor |
SE9804407D0 (sv) | 1998-12-18 | 1998-12-18 | Borealis Polymers Oy | A multimodal polymer composition |
SE515726C2 (sv) | 1999-05-05 | 2001-10-01 | Borealis As | Elektrisk kabel |
SE9901619D0 (sv) * | 1999-05-05 | 1999-05-05 | Borealis As | Elastomeric polymer composition |
DE10016518B4 (de) * | 2000-04-03 | 2009-07-02 | Maschinenfabrik Niehoff Gmbh & Co Kg | Verfahren und Vorrichtung zur Herstellung eines isolierten Kabels |
CN100481524C (zh) * | 2003-09-10 | 2009-04-22 | 大日本印刷株式会社 | 太阳能电池组件用填充材料层、太阳能电池组件 |
EP1923404B1 (fr) * | 2006-11-16 | 2009-10-14 | Borealis Technology Oy | Procédé pour la préparation d'un copolymère comprenant de l'éthylène et du silane |
CN103122096B (zh) * | 2007-06-27 | 2017-04-12 | 陶氏环球技术有限责任公司 | 用于挠性提高的电缆绝缘层的聚烯烃弹性体与硅烷共聚物的可交联共混物 |
EP2075281A1 (fr) * | 2007-12-03 | 2009-07-01 | Borealis Technology OY | Composition polyoléfinique comprenant une polyoléfine réticulable avec des groupes silanes, un catalyseur de condensation au silanol et un composé contenant du silicium |
EP2367878A1 (fr) * | 2008-12-23 | 2011-09-28 | Dow Global Technologies LLC | Système catalytique pour durcissement à l'humidité de copolymères d'éthylène-vinylsilane |
WO2010130458A1 (fr) * | 2009-05-14 | 2010-11-18 | Borealis Ag | Composition de polyoléfine pouvant être réticulée comprenant des groupes silane formant un acide ou une base après hydrolyse |
ES2697528T3 (es) * | 2009-05-14 | 2019-01-24 | Borealis Ag | Composición de poliolefina reticulable que comprende grupos silano que forman un ácido o una base por hidrolización |
DE102009028353A1 (de) * | 2009-08-07 | 2011-04-14 | Wacker Chemie Ag | Bindemittel auf der Basis von silangruppenhaltigen hochverzweigten Polyolefinen |
EP2508558B1 (fr) | 2011-04-07 | 2014-05-21 | Borealis AG | Composition de polymère réticulable au silane |
EP2508566B1 (fr) | 2011-04-07 | 2014-05-28 | Borealis AG | Composition de polymère réticulable au silane |
EP2738774A1 (fr) | 2012-11-30 | 2014-06-04 | Borealis AG | Construction de câble |
EP2746296B1 (fr) | 2012-12-21 | 2016-03-02 | Borealis AG | Procédé de fabrication d'un article en polyéthylène réticulé |
PL3182422T3 (pl) | 2015-12-18 | 2020-01-31 | Borealis Ag | Sposób wytwarzania kabla energetycznego i kabel energetyczny otrzymywany według sposobu |
EP3182418A1 (fr) | 2015-12-18 | 2017-06-21 | Borealis AG | Composition de gaine de câble, gaine de câble et câble, par exemple câble de puissance ou câble de communication |
CN108359038B (zh) * | 2017-01-26 | 2020-10-23 | 中国石油化工股份有限公司 | 一种乙烯与端烯基硅烷/硅氧烷的共聚方法 |
KR20210090663A (ko) | 2018-11-12 | 2021-07-20 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌 및 가수분해성 실란의 수분 가교성 공중합체 |
CN113508156B (zh) | 2019-03-26 | 2024-05-03 | 陶氏环球技术有限责任公司 | 可快速湿固化的聚乙烯配制物 |
CA3150251C (fr) | 2019-09-06 | 2023-12-19 | Jari-Jussi Ruskeeniemi | Procede d'amelioration de la stabilite au stockage et/ou de la stabilite au transport d'un polymere |
EP4023712A1 (fr) | 2020-12-29 | 2022-07-06 | Borealis AG | Compositions de polyéthylène à résistance élevée à la dégradation pour des applications de fils et de câbles |
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SU633870A1 (ru) * | 1968-04-09 | 1978-11-25 | Институт Нефтехимического Синтеза Имени А.В.Топчиева | Способ получени эластомерных блок-сополимеров |
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US3776977A (en) * | 1971-06-18 | 1973-12-04 | Stauffer Chemical Co | Method of curing organic siloxane polymers and copolymers |
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JPS591423B2 (ja) * | 1977-12-29 | 1984-01-12 | 鐘淵化学工業株式会社 | 室温硬化性組成物 |
JPS559611A (en) * | 1978-07-05 | 1980-01-23 | Mitsubishi Petrochem Co Ltd | Cross-linkable polyethylene resin composition |
US4157321A (en) * | 1978-07-18 | 1979-06-05 | Union Carbide Corporation | Stabilized polymeric organosilane compositions |
JPS5566809A (en) * | 1978-11-13 | 1980-05-20 | Mitsubishi Petrochemical Co | Method of manufacturing crosslinked polyethylene resinncoated wire |
CH631289A5 (fr) * | 1979-04-03 | 1982-07-30 | Maillefer Sa | Procede de fabrication d'un conducteur electrique, isole par un revetement en matiere plastique reticulee, et conducteur electrique isole obtenu selon le procede. |
JPS5648944A (en) * | 1979-09-17 | 1981-05-02 | Mitsubishi Petrochemical Co | Bridged polyethylene hollow molding vessel |
JPS57153004A (en) * | 1981-03-19 | 1982-09-21 | Nippon Oil Co Ltd | Production of silane-crosslinked polyolefin |
JPS57207632A (en) * | 1981-06-16 | 1982-12-20 | Mitsubishi Petrochem Co Ltd | Crosslinkable polyethylene resin composition |
JPS608345A (ja) * | 1983-06-28 | 1985-01-17 | Sekisui Chem Co Ltd | ポリオレフイン系樹脂組成物 |
-
1985
- 1985-02-25 JP JP60036004A patent/JPH0615644B2/ja not_active Expired - Lifetime
-
1986
- 1986-02-05 US US06/826,301 patent/US4689369A/en not_active Expired - Lifetime
- 1986-02-14 DE DE8686301046T patent/DE3673837D1/de not_active Expired - Lifetime
- 1986-02-14 EP EP86301046A patent/EP0193317B2/fr not_active Expired - Lifetime
- 1986-02-21 NO NO860651A patent/NO174813B/no unknown
- 1986-02-24 DK DK084686A patent/DK169078B1/da not_active IP Right Cessation
- 1986-02-24 FI FI860795A patent/FI86876C/fi not_active IP Right Cessation
-
1989
- 1989-02-27 US US07/316,525 patent/US4983675A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0193317B1 (fr) | 1990-09-05 |
US4983675A (en) | 1991-01-08 |
JPS61195141A (ja) | 1986-08-29 |
FI86876C (fi) | 1992-10-26 |
EP0193317A3 (en) | 1987-11-11 |
EP0193317B2 (fr) | 1993-01-27 |
US4689369A (en) | 1987-08-25 |
DE3673837D1 (de) | 1990-10-11 |
DK84686D0 (da) | 1986-02-24 |
FI860795A0 (fi) | 1986-02-24 |
DK169078B1 (da) | 1994-08-08 |
JPH0615644B2 (ja) | 1994-03-02 |
NO174813C (fr) | 1994-07-13 |
FI86876B (fi) | 1992-07-15 |
NO860651L (no) | 1986-08-26 |
FI860795A (fi) | 1986-08-26 |
DK84686A (da) | 1986-08-26 |
EP0193317A2 (fr) | 1986-09-03 |
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