MX2015013105A - Catalizador de etinilación novedoso y método para prepararlo. - Google Patents

Catalizador de etinilación novedoso y método para prepararlo.

Info

Publication number
MX2015013105A
MX2015013105A MX2015013105A MX2015013105A MX2015013105A MX 2015013105 A MX2015013105 A MX 2015013105A MX 2015013105 A MX2015013105 A MX 2015013105A MX 2015013105 A MX2015013105 A MX 2015013105A MX 2015013105 A MX2015013105 A MX 2015013105A
Authority
MX
Mexico
Prior art keywords
novel
making same
ethynylation
ethynylation catalyst
bismuth
Prior art date
Application number
MX2015013105A
Other languages
English (en)
Inventor
Rostam Madon
Peter Nagel
Scott Hedrick
Deepak Thakur
Original Assignee
Basf Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Corp filed Critical Basf Corp
Publication of MX2015013105A publication Critical patent/MX2015013105A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/843—Arsenic, antimony or bismuth
    • B01J23/8437—Bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10—Magnesium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/035—Precipitation on carriers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
    • C07C29/38—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones
    • C07C29/42—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones with compounds containing triple carbon-to-carbon bonds, e.g. with metal-alkynes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)

Abstract

Se forma un catalizador novedoso útil para la etinilación de formaldehído a butinediol mediante la precipitación de cobre y bismuto a partir de una solución de sal de dichos metales, utilizando un hidróxido de metal alcalino como agente de precipitación para depositar hidróxido de bismuto y cobre como un recubrimiento alrededor de una partícula de portador silíceo.
MX2015013105A 2013-03-15 2014-03-11 Catalizador de etinilación novedoso y método para prepararlo. MX2015013105A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361788851P 2013-03-15 2013-03-15
PCT/US2014/022961 WO2014150327A1 (en) 2013-03-15 2014-03-11 Novel ethynylation catalyst and method of making same

Publications (1)

Publication Number Publication Date
MX2015013105A true MX2015013105A (es) 2016-06-02

Family

ID=51530194

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015013105A MX2015013105A (es) 2013-03-15 2014-03-11 Catalizador de etinilación novedoso y método para prepararlo.

Country Status (7)

Country Link
US (2) US9006129B2 (es)
EP (1) EP2969208A4 (es)
CN (2) CN111330586A (es)
CA (1) CA2905005C (es)
MX (1) MX2015013105A (es)
MY (1) MY168975A (es)
WO (1) WO2014150327A1 (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2905005C (en) * 2013-03-15 2021-07-27 Basf Corporation Novel ethynylation catalyst and method of making same
CN105642301B (zh) * 2014-12-04 2018-02-09 中国石油化工股份有限公司 一种用于合成1,4‑丁炔二醇的铜铋催化剂的制备方法
CN105709757A (zh) * 2014-12-04 2016-06-29 中国石油化工股份有限公司 一种生产1,4-丁炔二醇催化剂的制备方法
CN105642303B (zh) * 2014-12-04 2018-02-09 中国石油化工股份有限公司 合成1,4‑丁炔二醇的铜铋催化剂及其制备方法
CN105709756B (zh) * 2014-12-04 2018-01-16 中国石油化工股份有限公司 一种生产1,4‑丁炔二醇催化剂及其制备方法和应用
CN105642300B (zh) * 2014-12-04 2018-04-10 中国石油化工股份有限公司 一种合成1,4‑丁炔二醇的铜铋催化剂制备方法
CN105709759B (zh) * 2014-12-04 2018-04-10 中国石油化工股份有限公司 一种用于合成1,4‑丁炔二醇的铜铋催化剂制备方法
CN105709758B (zh) * 2014-12-04 2018-02-09 中国石油化工股份有限公司 一种铜铋催化剂及其制备方法
CN107427816B (zh) * 2015-03-31 2021-03-05 巴斯夫公司 氢化和乙炔化催化剂
KR20180034668A (ko) * 2015-08-25 2018-04-04 바스프 코포레이션 분무-건조된 부틴디올 촉매
CN106669699A (zh) * 2015-11-09 2017-05-17 中国石油化工股份有限公司 制备1,4-丁炔二醇催化剂的方法
CN106669695A (zh) * 2015-11-09 2017-05-17 中国石油化工股份有限公司 一种铜铋硅催化剂的制备方法
CN106669694A (zh) * 2015-11-09 2017-05-17 中国石油化工股份有限公司 一种合成1,4-丁炔二醇催化剂的制备方法
CN106669696A (zh) * 2015-11-09 2017-05-17 中国石油化工股份有限公司 合成1,4-丁炔二醇催化剂及其制备方法和应用
CN106669700A (zh) * 2015-11-09 2017-05-17 中国石油化工股份有限公司 一种生产1,4-丁炔二醇催化剂的制备方法
CN106669692A (zh) * 2015-11-09 2017-05-17 中国石油化工股份有限公司 一种生产1,4-丁炔二醇催化剂及其制法和应用
CN106669701A (zh) * 2015-11-09 2017-05-17 中国石油化工股份有限公司 一种制备1,4-丁炔二醇催化剂的方法
CN106669689A (zh) * 2015-11-09 2017-05-17 中国石油化工股份有限公司 生产1,4-丁炔二醇催化剂的制备方法
CN106669688B (zh) * 2015-11-09 2018-06-19 中国石油化工股份有限公司 一种铜铋催化剂及其制备方法和应用
CN108067239B (zh) * 2016-11-11 2019-06-11 中国石油化工股份有限公司抚顺石油化工研究院 一种大颗粒铜铋催化剂及其制备方法和应用
KR20210096650A (ko) * 2018-12-03 2021-08-05 바스프 코포레이션 고활성 및 고선택성 구리 압출물 촉매
CN109821548B (zh) * 2019-04-03 2022-01-28 武汉轻工大学 一种复合金属催化剂的制备方法
CN112717945B (zh) * 2019-10-28 2023-05-26 中国石油化工股份有限公司 一种合成1,4-丁炔二醇催化剂及其制备方法和应用
CN113368886B (zh) * 2021-07-01 2023-01-24 河北瑞克新能源科技有限公司 一种用于制备1,4-丁炔二醇的催化剂
CN113813973B (zh) * 2021-09-17 2023-03-10 山西大学 纳米金限域铜基核壳结构催化剂及其制备方法和应用
WO2023227605A1 (en) 2022-05-24 2023-11-30 Basf Se Method for the preparation of a supported mixed metal oxide

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CN102658158B (zh) * 2012-05-20 2014-06-18 山西大学 一种铜铋催化剂及制备方法
CN102950002B (zh) * 2012-10-18 2014-06-18 大连瑞克科技有限公司 一种生产1,4-丁炔二醇的催化剂及其制备方法
CA2905005C (en) * 2013-03-15 2021-07-27 Basf Corporation Novel ethynylation catalyst and method of making same

Also Published As

Publication number Publication date
US9308522B2 (en) 2016-04-12
CA2905005C (en) 2021-07-27
WO2014150327A1 (en) 2014-09-25
CN111330586A (zh) 2020-06-26
CN105121016A (zh) 2015-12-02
US20140275639A1 (en) 2014-09-18
US9006129B2 (en) 2015-04-14
US20150258534A1 (en) 2015-09-17
CA2905005A1 (en) 2014-09-25
EP2969208A4 (en) 2016-11-16
MY168975A (en) 2019-01-29
EP2969208A1 (en) 2016-01-20

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