MX166784B - Hidroformilacion usando grupos coordinadores de fosfina de baja volatilidad - Google Patents

Hidroformilacion usando grupos coordinadores de fosfina de baja volatilidad

Info

Publication number
MX166784B
MX166784B MX009383A MX938387A MX166784B MX 166784 B MX166784 B MX 166784B MX 009383 A MX009383 A MX 009383A MX 938387 A MX938387 A MX 938387A MX 166784 B MX166784 B MX 166784B
Authority
MX
Mexico
Prior art keywords
carbon monoxide
square centimeter
olefinically unsaturated
hydrogen
kilograms per
Prior art date
Application number
MX009383A
Other languages
English (en)
Inventor
Anthony George Abatjoglou
David Robert Bryant
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of MX166784B publication Critical patent/MX166784B/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
    • C07C47/55—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

La presente invención se refiere a un procedimiento de hidroformilación no acuoso para producir aldehídos, el cual comprende hacer reaccionar un compuesto orgánico olefínicamente insaturado que contiene de 2 a 20 átomos de carbono, con monóxido de carbono e hidrógeno, en un medio de reacción de hidroformilación no acuoso que contiene un compuesto orgánico olefínicamente insaturado, un producto de aldehído, un catalizador complejo de rodio solubilizado y un grupo coordinador de fósforo y un grupo coordinador de fósforo libre solubilizado y en donde las condiciones de reacción de hidroformilación comprenden una temperatura de reacción de aproximadamente 45 grados C a aproximadamente 200 grados C, una presión de gas total de hidrógeno, monóxido de carbono y el compuesto olefínicamente insaturado de menos de aproximadamente 35.15 kilogramos por centímetro cuadrado absoluta, una presión parcial de monóxido de carbono de desde aproximadamente 0.0703 a 8.44 kilogramos por centímetro cuadrado absoluta, una presión parcial de hidrógeno de aproximadamente 0.703 a 11.25 kilogramos por centímetro cuadrado absoluta y en donde el medio de reacción contiene por lo menos aproximadamente 2 moles del grupo coordinador de fósforo libre total por mol de rodio en el medio.
MX009383A 1986-11-18 1987-11-17 Hidroformilacion usando grupos coordinadores de fosfina de baja volatilidad MX166784B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/932,002 US4731486A (en) 1986-11-18 1986-11-18 Hydroformylation using low volatile phosphine ligands

Publications (1)

Publication Number Publication Date
MX166784B true MX166784B (es) 1993-02-04

Family

ID=25461633

Family Applications (1)

Application Number Title Priority Date Filing Date
MX009383A MX166784B (es) 1986-11-18 1987-11-17 Hidroformilacion usando grupos coordinadores de fosfina de baja volatilidad

Country Status (28)

Country Link
US (1) US4731486A (es)
EP (1) EP0268268B1 (es)
JP (1) JPH0667868B2 (es)
KR (1) KR920003556B1 (es)
CN (1) CN1017145B (es)
AR (1) AR248390A1 (es)
AT (1) ATE77075T1 (es)
AU (1) AU611867B2 (es)
BE (1) BE1000619A5 (es)
BR (1) BR8706223A (es)
CA (1) CA1307296C (es)
DE (2) DE3739064A1 (es)
DK (1) DK605887A (es)
ES (3) ES2009221A6 (es)
FI (1) FI90858C (es)
FR (1) FR2606771B1 (es)
GB (1) GB2197867B (es)
HU (1) HU202177B (es)
IN (1) IN170369B (es)
IT (1) IT1223147B (es)
MX (1) MX166784B (es)
NL (1) NL8702752A (es)
NO (1) NO166440C (es)
PL (1) PL153062B1 (es)
RU (1) RU2002728C1 (es)
SE (1) SE8704533L (es)
YU (1) YU45074B (es)
ZA (1) ZA878638B (es)

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DE3411034A1 (de) * 1984-03-26 1985-09-26 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur rueckgewinnung von rhodium aus reaktionsprodukten der oxosynthese
FR2561650B1 (fr) * 1984-03-26 1987-10-23 Rhone Poulenc Rech Perfectionnement au procede de preparation de tri(m-sulfophenyl)phosphine par hydrolyse et dilution controlees du sulfonat
DE3413427A1 (de) * 1984-04-10 1985-10-17 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
DE3415968A1 (de) * 1984-04-28 1985-10-31 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
DE3420491A1 (de) * 1984-06-01 1985-12-05 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
DE3420493A1 (de) * 1984-06-01 1985-12-05 Ruhrchemie Ag, 4200 Oberhausen Quartaere ammoniumsalze sulfonierter triarylphosphine
US4578523A (en) * 1985-05-29 1986-03-25 Ruhrchemie Aktiengesellschaft Process for the preparation of aldehydes
DE3534314A1 (de) * 1985-09-26 1987-04-02 Ruhrchemie Ag Verfahren zur herstellung von aldehyden
US4633021A (en) * 1985-11-29 1986-12-30 National Distillers And Chemical Corporation Olefin hydroformylation
US4716250A (en) * 1986-07-10 1987-12-29 Union Carbide Corporation Hydroformylation using low volatile/organic soluble phosphine ligands

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GB2197867A (en) 1988-06-02
YU209187A (en) 1988-12-31
FI875087A0 (fi) 1987-11-18
NO874810L (no) 1988-05-19
NO874810D0 (no) 1987-11-18
IN170369B (es) 1992-03-21
FR2606771B1 (fr) 1989-11-03
IT1223147B (it) 1990-09-12
ES2009221A6 (es) 1989-09-16
IT8722675A0 (it) 1987-11-18
ES2012719A6 (es) 1990-04-01
ES2012718A6 (es) 1990-04-01
DE3739064C2 (es) 1990-12-20
EP0268268B1 (en) 1992-06-10
GB2197867B (en) 1991-05-29
ZA878638B (en) 1988-07-27
KR920003556B1 (ko) 1992-05-04
GB8727013D0 (en) 1987-12-23
HUT45729A (en) 1988-08-29
PL153062B1 (en) 1991-02-28
SE8704533D0 (sv) 1987-11-18
DK605887D0 (da) 1987-11-18
NO166440C (no) 1991-07-24
FI90858B (fi) 1993-12-31
BR8706223A (pt) 1988-06-21
BE1000619A5 (fr) 1989-02-21
FI875087A (fi) 1988-05-19
EP0268268A3 (en) 1988-10-26
CN1017145B (zh) 1992-06-24
AR248390A1 (es) 1995-08-18
KR880006155A (ko) 1988-07-21
DK605887A (da) 1988-05-19
AU8128087A (en) 1988-05-19
NO166440B (no) 1991-04-15
HU202177B (en) 1991-02-28
YU45074B (en) 1991-08-31
DE3739064A1 (de) 1988-05-26
EP0268268A2 (en) 1988-05-25
CA1307296C (en) 1992-09-08
RU2002728C1 (ru) 1993-11-15
JPH0667868B2 (ja) 1994-08-31
PL268876A1 (en) 1988-08-04
AU611867B2 (en) 1991-06-27
CN87101178A (zh) 1988-07-06
SE8704533L (sv) 1988-05-19
DE3779725D1 (de) 1992-07-16
FR2606771A1 (fr) 1988-05-20
JPS63190844A (ja) 1988-08-08
FI90858C (fi) 1994-04-11
ATE77075T1 (de) 1992-06-15
US4731486A (en) 1988-03-15
NL8702752A (nl) 1988-06-16

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