FR2606771B1 - Procede d'hydroformylation utilisant des ligands phosphiniques peu volatils - Google Patents

Procede d'hydroformylation utilisant des ligands phosphiniques peu volatils

Info

Publication number
FR2606771B1
FR2606771B1 FR878715930A FR8715930A FR2606771B1 FR 2606771 B1 FR2606771 B1 FR 2606771B1 FR 878715930 A FR878715930 A FR 878715930A FR 8715930 A FR8715930 A FR 8715930A FR 2606771 B1 FR2606771 B1 FR 2606771B1
Authority
FR
France
Prior art keywords
hydroformylation process
low volatile
phosphinic
ligands
phosphinic ligands
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR878715930A
Other languages
English (en)
Other versions
FR2606771A1 (fr
Inventor
Anthony George Abatjoglou
David Robert Bryant
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of FR2606771A1 publication Critical patent/FR2606771A1/fr
Application granted granted Critical
Publication of FR2606771B1 publication Critical patent/FR2606771B1/fr
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00Compounds having —CHO groups
    • C07C47/52Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
    • C07C47/55Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing halogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00Compounds having —CHO groups
    • C07C47/02Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
FR878715930A 1986-11-18 1987-11-18 Procede d'hydroformylation utilisant des ligands phosphiniques peu volatils Expired FR2606771B1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/932,002 US4731486A (en) 1986-11-18 1986-11-18 Hydroformylation using low volatile phosphine ligands

Publications (2)

Publication Number Publication Date
FR2606771A1 FR2606771A1 (fr) 1988-05-20
FR2606771B1 true FR2606771B1 (fr) 1989-11-03

Family

ID=25461633

Family Applications (1)

Application Number Title Priority Date Filing Date
FR878715930A Expired FR2606771B1 (fr) 1986-11-18 1987-11-18 Procede d'hydroformylation utilisant des ligands phosphiniques peu volatils

Country Status (28)

Country Link
US (1) US4731486A (fr)
EP (1) EP0268268B1 (fr)
JP (1) JPH0667868B2 (fr)
KR (1) KR920003556B1 (fr)
CN (1) CN1017145B (fr)
AR (1) AR248390A1 (fr)
AT (1) ATE77075T1 (fr)
AU (1) AU611867B2 (fr)
BE (1) BE1000619A5 (fr)
BR (1) BR8706223A (fr)
CA (1) CA1307296C (fr)
DE (2) DE3739064A1 (fr)
DK (1) DK605887A (fr)
ES (3) ES2009221A6 (fr)
FI (1) FI90858C (fr)
FR (1) FR2606771B1 (fr)
GB (1) GB2197867B (fr)
HU (1) HU202177B (fr)
IN (1) IN170369B (fr)
IT (1) IT1223147B (fr)
MX (1) MX166784B (fr)
NL (1) NL8702752A (fr)
NO (1) NO166440C (fr)
PL (1) PL153062B1 (fr)
RU (1) RU2002728C1 (fr)
SE (1) SE8704533L (fr)
YU (1) YU45074B (fr)
ZA (1) ZA878638B (fr)

Families Citing this family (81)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2059651T3 (es) * 1988-07-14 1994-11-16 Union Carbide Chem Plastic Procedimiento para separar un catalizador y un producto aldehidico.
PT91161A (pt) * 1988-07-14 1990-02-08 Union Carbide Chem Plastic Processo aperfeicoado para a producao de alcoois e aldeidos
US5180854A (en) * 1988-07-14 1993-01-19 Union Carbide Chemicals & Plastics Technology Corporation Process for catalyst aldehyde product separation
US5059710A (en) * 1988-08-05 1991-10-22 Union Carbide Chemicals And Plastics Technology Corporation Ionic phosphites and their use in homogeneous transition metal catalyzed processes
US5113022A (en) * 1988-08-05 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Ionic phosphites used in homogeneous transition metal catalyzed processes
US4965404A (en) * 1989-03-09 1990-10-23 Kuraray Company, Ltd. Process for the preparation of lithium diphenylphosphinobenzene-m-monosulfonate
DE3942954A1 (de) * 1989-12-23 1991-06-27 Hoechst Ag Verfahren zur herstellung von aldehyden
EP0545997B1 (fr) * 1990-08-31 1995-11-02 The Governors Of The University Of Alberta Carbonylation de methanol utilisant un nouveau precurseur catalytique de metal de transition
US5087763A (en) * 1990-11-09 1992-02-11 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
US5288818A (en) * 1991-08-20 1994-02-22 Exxon Chemical Patents Inc. Method for separating a water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction
US5215667A (en) * 1991-08-20 1993-06-01 Exxon Chemical Patents Inc. Method for separating water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction
US5196596A (en) * 1991-12-26 1993-03-23 Union Carbide Chemicals & Plastics Technology Corporation Higher aldehyde separation process
US5300617A (en) * 1993-01-21 1994-04-05 Exxon Chemical Patents Inc. Potassium para-diphenyl phosphino benzene sulfonate ligand
US6143211A (en) 1995-07-21 2000-11-07 Brown University Foundation Process for preparing microparticles through phase inversion phenomena
DE19532393A1 (de) * 1995-09-02 1997-03-06 Hoechst Ag Verfahren zur Hydroformylierung olefinisch ungesättigter Verbindungen
CA2204133C (fr) * 1995-09-26 2003-08-12 Toshihiro Omatsu Procede d'hydroformylation
DE19700804C1 (de) * 1997-01-13 1998-08-06 Hoechst Ag Verfahren zur Herstellung von Aldehyden durch Hydroformylierung olefinischer Verbindungen mit 6 bis 16 Kohlenstoffatomen in Anwesenheit einer Rhodium und sulfonierte Triarylphosphine als Katalysator enthaltenden wäßrigen Phase
DE19700805C1 (de) * 1997-01-13 1998-08-06 Hoechst Ag Verfahren zur Herstellung von Aldehyden durch Hydroformylierung olefinischer Verbindungen mit 3 bis 5 Kohlenstoffatomen in Anwesenheit einer Rhodium und sulfonierte Triarylphosphine als Katalysator enthhaltenden wäßrigen Phase
DE19742305A1 (de) * 1997-09-25 1999-04-01 Hoechst Ag Verfahren zur Herstellung von Aldehyden durch Hydroformylierung in Gegenwart von Kronenether
FI20002807A0 (fi) * 2000-09-05 2000-12-20 Neste Chemicals Oy Menetelmä alkeenien hydroformyloimiseksi
CA2447730A1 (fr) * 2001-06-07 2002-12-19 Kuraray Co., Ltd. P-diarylphosphinobenzenesulfonates de lithium, procede de preparation et utilisation de ces composes
US6746635B2 (en) * 2001-08-08 2004-06-08 Brown University Research Foundation Methods for micronization of hydrophobic drugs
EP1460897A4 (fr) * 2001-12-10 2006-09-13 Spherics Inc Procedes et produits utiles dans la formation et l'isolation de microparticules
ATE468318T1 (de) * 2003-04-25 2010-06-15 Dow Global Technologies Inc Von samenölen abgeleitete aldehyd- und alkoholzusammensetzungen
KR100547587B1 (ko) * 2004-06-12 2006-01-31 주식회사 엘지화학 인을 포함하는 촉매 조성물 및 이를 이용한히드로포르밀화 방법
MX2007004991A (es) * 2004-10-25 2007-06-14 Dow Global Technologies Inc Poliuretanos hechos de acidos grasos conteniendo hidroxi-metilo o esteres de alquilo de tales acidos grasos.
ES2352455T3 (es) * 2004-10-25 2011-02-18 Dow Global Technologies Inc. Polímeros polioles y dispersiones de polímeros obtenidas a partir de materiales que contienen hidroxilo basados en aceites vegetales.
JP5000523B2 (ja) * 2004-10-25 2012-08-15 ダウ グローバル テクノロジーズ エルエルシー 脂肪酸に由来するヒドロキシメチル含有ポリエステルポリオールから製造されたプレポリマー
US7053253B1 (en) * 2005-05-02 2006-05-30 3M Innovative Properties Company Process for purifying hexafluoropropene dimers
BRPI0617017B1 (pt) * 2005-09-15 2016-03-15 Dow Global Technologies Inc processo para preparar monossulfonato de fosfina aromática na forma zwiteriônica, processo para preparar sal metálico alcalino de monossulfonato de diciclohexilfenilfosfina, e monossulfonato de fosfina aromática na forma zwiteriônica
CN100526279C (zh) * 2006-04-11 2009-08-12 中国科学院兰州化学物理研究所 连续制备正戊醛的工艺过程
CA2652016C (fr) 2006-05-15 2015-02-03 Dow Global Technologies Inc. Processus d'hydroformylation et separation de produit avec recuperation amelioree de rhodium
JP5371760B2 (ja) * 2006-09-21 2013-12-18 ダウ グローバル テクノロジーズ エルエルシー 高い通気量を有する粘弾性フォーム
EP1918247A1 (fr) * 2006-10-18 2008-05-07 Ecole Polytechnique Fédérale de Lausanne (EPFL) Production d'hydrogène à partir d'acide formique
JP2010523797A (ja) * 2007-04-09 2010-07-15 ダウ グローバル テクノロジーズ インコーポレイティド キャップ化ポリエステルポリオール潤滑剤組成物
WO2008134217A1 (fr) 2007-04-27 2008-11-06 Dow Global Technologies Inc. Revêtements, adhésifs et liants peu volatiles obtenus à partir d'une huile renouvelable
JP5628024B2 (ja) * 2007-05-15 2014-11-19 ダウ グローバル テクノロジーズ エルエルシー 高弾性発泡体
EP2167454A2 (fr) * 2007-06-13 2010-03-31 Dow Global Technologies Inc. Procede d'extraction pour une separation de produit d'aldehyde et une recuperation de catalyseur
CN101802046B (zh) * 2007-07-12 2014-06-18 陶氏环球技术有限责任公司 室温可固化聚合物及其前体
BRPI0812637A2 (pt) * 2007-07-12 2015-02-24 Dow Global Technologies Inc "pré-polímero, elastômero, processo para formar um pré-polímero ou elastômero, artigo, composição de revestimento de poliuretano termoplástico"
BRPI0813064A2 (pt) * 2007-08-01 2018-07-10 Dow Brasil Sudeste Ind Ltda "processo para produzir um laminado ou estrutura composta, laminado ou estrutura composta e artigo" processo para produzir um laminado ou estrutura composta, laminado ou estrutura composta e artigo
EP2242760B1 (fr) * 2008-01-15 2014-03-05 Dow Global Technologies LLC Composés d'organophosphine sulfonée et leur utilisation dans les processus d'hydroformylation
BRPI0905699A2 (pt) * 2008-01-15 2015-07-14 Dow Global Technologies Inc Composição, catalisador complexo ou composição de precursor de catalisador complexo, solução de catalisador complexo ou solução de percursor de catalisador complexo e processo de hidroformilação
WO2009091670A1 (fr) * 2008-01-15 2009-07-23 Dow Global Technologies Inc. Composés d'organophosphine sulfonée et leur utilisation dans des procédés d'hydroformylation
BRPI0908697A2 (pt) * 2008-05-09 2019-02-26 Dow Global Technologies Inc mistura de poliol à base de óleo natural, espuma de poliuretano flexível e método para produzir uma espuma de poliuretano
CN102639586A (zh) 2009-07-22 2012-08-15 陶氏环球技术有限责任公司 基于天然油的聚氨酯泡沫体
CN102791666A (zh) 2009-12-03 2012-11-21 陶氏环球技术有限责任公司 多元醇的脱色
EP2510031B1 (fr) 2009-12-08 2013-10-30 Dow Global Technologies LLC Procédé pour préparer des mousses à alvéoles ouvertes fabriquées avec des polyols à base d'huile naturelle et des polyols de poly(oxyde de propylène)
WO2011078922A1 (fr) 2009-12-21 2011-06-30 Dow Global Technologies Llc Produit d'étanchéité à base de polyuréthane destiné à des unités de verre isolant
PL2722325T5 (pl) * 2009-12-22 2019-07-31 Dow Technology Investments Llc Regulowanie stosunku aldehyd normalny : izoaldehyd w procesie hydroformylowania z mieszanymi ligandami przez regulowanie ciśnienia cząsteczkowego gazu syntezowego
US20130202891A1 (en) 2010-03-12 2013-08-08 Dow Global Technologies Llc Elastomer binding materials made with natural oil based polyols
US20130005900A1 (en) 2010-03-12 2013-01-03 Dow Global Technologies Llc Gels and soft elastomers made with natural oil based polyols
EP2552990B1 (fr) 2010-03-31 2017-04-19 Dow Global Technologies LLC Elastomères de polyuréthane/polyurée à pulvériser
KR101820988B1 (ko) 2010-04-14 2018-03-08 다우 글로벌 테크놀로지스 엘엘씨 폴리카르보네이트 폴리올 및 그로부터 제조된 폴리우레탄
US20130096251A1 (en) 2010-06-22 2013-04-18 Dow Global Technologies Llc Curable silyl polymers
CN103080173B (zh) 2010-06-30 2015-05-27 陶氏环球技术有限责任公司 甲硅烷基封端的聚合物
ITMI20101380A1 (it) 2010-07-27 2012-01-28 Dow Global Technologies Inc Pannello composito poliuretanico a basso impatto ambientale
RU2572611C2 (ru) 2010-11-11 2016-01-20 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Полиуретансодержащий герметик для изоляционного стеклопакета
KR20140043334A (ko) 2011-03-31 2014-04-09 다우 글로벌 테크놀로지스 엘엘씨 폴리우레탄용 소수성 폴리에스테르 폴리카르보네이트 폴리올
CN102826974B (zh) * 2011-06-17 2015-11-25 中国石油化工股份有限公司 一种丙烯氢甲酰化反应制备丁醛的方法
WO2013003051A2 (fr) 2011-06-30 2013-01-03 Dow Global Technologies Llc Copolymères polycarbonate-polyester terminés par un silane pour des applications de revêtements, d'adhésifs, de matériaux d'étanchéité et d'élastomères
WO2014047256A1 (fr) * 2012-09-24 2014-03-27 Exxonmobil Chemical Patents Inc. Hydroformylation catalytique de polyoléfines terminées par un vinyle
WO2014047531A1 (fr) 2012-09-24 2014-03-27 Exxonmobil Chemical Patents Inc. Hydroamination de macromonomères contenant un aldéhyde
EP2900724B1 (fr) 2012-09-26 2018-01-10 Dow Global Technologies LLC Produit d'étanchéité à base de polyuréthane pour du verre, isolé
CN104045532B (zh) 2013-03-15 2018-05-25 陶氏技术投资有限责任公司 加氢甲酰化方法
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RU2561171C1 (ru) * 2014-09-12 2015-08-27 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ непрерывного двухступенчатого гидроформилирования олефинов с3, с4 и технологическая установка для его осуществления
CA3018072A1 (fr) 2016-03-18 2017-09-21 Dow Technology Investments Llc Procede d'hydroformylation
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GB202404300D0 (en) 2024-03-26 2024-05-08 Johnson Matthey Davy Technologies Ltd Process for the production of 2-alkylalkanol

Family Cites Families (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US31812A (en) * 1861-03-26 Stump-extractor
US3527809A (en) * 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
BE758502A (fr) * 1969-11-06 1971-05-05 Basf Ag Preparation d'alcools et d'aldehydes
NL7106084A (fr) * 1970-05-06 1971-11-09
US3968136A (en) * 1974-07-12 1976-07-06 Union Carbide Corporation Catalytic process for polyhydric alcohols and derivatives
US4159999A (en) * 1974-11-22 1979-07-03 Celanese Corporation Hydroformylation of olefins
US4148830A (en) * 1975-03-07 1979-04-10 Union Carbide Corporation Hydroformylation of olefins
US3984478A (en) * 1975-05-27 1976-10-05 Universal Oil Products Company Hydroformylation process
US4248802A (en) * 1975-06-20 1981-02-03 Rhone-Poulenc Industries Catalytic hydroformylation of olefins
US4247486A (en) * 1977-03-11 1981-01-27 Union Carbide Corporation Cyclic hydroformylation process
FR2351077A1 (fr) * 1976-05-13 1977-12-09 Celanese Corp Procede perfectionne d'hydroformylation des olefines avec un catalyseur complexe au rhodium
US4162261A (en) * 1976-09-29 1979-07-24 Union Carbide Corporation Novel solvents for the catalytic process for making polyhydric alcohols
ZA78146B (en) * 1977-01-25 1978-12-27 Union Carbide Corp Improved hydroformylation process
US4211719A (en) * 1978-02-13 1980-07-08 Union Carbide Corporation Catalytic process for polyhydric alcohols and derivatives
US4306084A (en) * 1978-12-06 1981-12-15 The University Of Texas Alcohol and aldehyde production using ruthenium carbonyl catalysts
DE3022025A1 (de) * 1979-06-18 1981-01-08 Celanese Corp Verfahren zur hydroformylierung von olefinen
US4329511A (en) * 1979-06-18 1982-05-11 Celanese Corporation Hydroformylation process improved by choice of reaction solvent and control of product stripping parameters
US4283562A (en) * 1979-10-26 1981-08-11 Union Carbide Corporation Hydroformylation process using stable rhodium catalyst
FR2478078A2 (fr) * 1980-03-12 1981-09-18 Rhone Poulenc Ind Procede d'hydroformylation des olefines
US4302547A (en) * 1980-06-30 1981-11-24 Union Carbide Corporation Novel solvents for the catalytic process for producing polyhydric alcohols
GB2085874B (en) * 1980-09-04 1984-08-08 Johnson Matthey Plc Hydroformylation of olefins
DE3046355A1 (de) * 1980-12-09 1982-07-15 Basf Ag, 6700 Ludwigshafen Verfahren zur hydroformylierung von olefinisch ungesaettigten verbindungen
US4400548A (en) * 1981-08-17 1983-08-23 Union Carbide Corporation Hydroformylation process using bisphosphine monooxide ligands
JPS58157739A (ja) * 1982-03-12 1983-09-19 Kuraray Co Ltd 1,9−ノナンジア−ルの製造方法
US4453022A (en) * 1982-04-21 1984-06-05 Union Carbide Corporation Process for preparing nonionic surfactants-oxyalkylation with calcium and/or strontium catalysts
FR2532318B1 (fr) * 1982-08-31 1985-06-14 Rhone Poulenc Chim Base Procede de preparation de triarylphosphines sulfonees
DE3234701A1 (de) * 1982-09-18 1984-04-05 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
DE3235030A1 (de) * 1982-09-22 1984-03-22 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von sulfonierten arylphosphinen
DE3235029A1 (de) * 1982-09-22 1984-03-22 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur rueckgewinnung von wasserloeslichen, rhodium enthaltenden hydroformylierungskatalysatoren
US4480138A (en) * 1982-10-12 1984-10-30 Celanese Corporation Hydroformylation process
DE3245883A1 (de) * 1982-12-11 1984-06-14 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur hydroformylierung von olefinen
FR2550202B1 (fr) * 1983-08-03 1986-03-21 Rhone Poulenc Rech Procede de preparation de tri(m-sulfophenyl) phosphine
DE3341035A1 (de) * 1983-11-12 1985-05-23 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
DE3347406A1 (de) * 1983-12-29 1985-07-11 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur abtrennung und wiedergewinnung von rhodium aus den produkten der oxosynthese
DE3412335A1 (de) * 1984-04-03 1985-10-10 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
DE3411034A1 (de) * 1984-03-26 1985-09-26 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur rueckgewinnung von rhodium aus reaktionsprodukten der oxosynthese
FR2561650B1 (fr) * 1984-03-26 1987-10-23 Rhone Poulenc Rech Perfectionnement au procede de preparation de tri(m-sulfophenyl)phosphine par hydrolyse et dilution controlees du sulfonat
DE3413427A1 (de) * 1984-04-10 1985-10-17 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
DE3415968A1 (de) * 1984-04-28 1985-10-31 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
DE3420491A1 (de) * 1984-06-01 1985-12-05 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
DE3420493A1 (de) * 1984-06-01 1985-12-05 Ruhrchemie Ag, 4200 Oberhausen Quartaere ammoniumsalze sulfonierter triarylphosphine
US4578523A (en) * 1985-05-29 1986-03-25 Ruhrchemie Aktiengesellschaft Process for the preparation of aldehydes
DE3534314A1 (de) * 1985-09-26 1987-04-02 Ruhrchemie Ag Verfahren zur herstellung von aldehyden
US4633021A (en) * 1985-11-29 1986-12-30 National Distillers And Chemical Corporation Olefin hydroformylation
US4716250A (en) * 1986-07-10 1987-12-29 Union Carbide Corporation Hydroformylation using low volatile/organic soluble phosphine ligands

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GB2197867A (en) 1988-06-02
YU209187A (en) 1988-12-31
FI875087A0 (fi) 1987-11-18
NO874810L (no) 1988-05-19
NO874810D0 (no) 1987-11-18
IN170369B (fr) 1992-03-21
IT1223147B (it) 1990-09-12
ES2009221A6 (es) 1989-09-16
IT8722675A0 (it) 1987-11-18
ES2012719A6 (es) 1990-04-01
ES2012718A6 (es) 1990-04-01
DE3739064C2 (fr) 1990-12-20
EP0268268B1 (fr) 1992-06-10
GB2197867B (en) 1991-05-29
ZA878638B (en) 1988-07-27
KR920003556B1 (ko) 1992-05-04
GB8727013D0 (en) 1987-12-23
HUT45729A (en) 1988-08-29
PL153062B1 (en) 1991-02-28
SE8704533D0 (sv) 1987-11-18
DK605887D0 (da) 1987-11-18
NO166440C (no) 1991-07-24
FI90858B (fi) 1993-12-31
BR8706223A (pt) 1988-06-21
MX166784B (es) 1993-02-04
BE1000619A5 (fr) 1989-02-21
FI875087A (fi) 1988-05-19
EP0268268A3 (en) 1988-10-26
CN1017145B (zh) 1992-06-24
AR248390A1 (es) 1995-08-18
KR880006155A (ko) 1988-07-21
DK605887A (da) 1988-05-19
AU8128087A (en) 1988-05-19
NO166440B (no) 1991-04-15
HU202177B (en) 1991-02-28
YU45074B (en) 1991-08-31
DE3739064A1 (de) 1988-05-26
EP0268268A2 (fr) 1988-05-25
CA1307296C (fr) 1992-09-08
RU2002728C1 (ru) 1993-11-15
JPH0667868B2 (ja) 1994-08-31
PL268876A1 (en) 1988-08-04
AU611867B2 (en) 1991-06-27
CN87101178A (zh) 1988-07-06
SE8704533L (sv) 1988-05-19
DE3779725D1 (de) 1992-07-16
FR2606771A1 (fr) 1988-05-20
JPS63190844A (ja) 1988-08-08
FI90858C (fi) 1994-04-11
ATE77075T1 (de) 1992-06-15
US4731486A (en) 1988-03-15
NL8702752A (nl) 1988-06-16

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