KR950704563A - 무전해 도금된 아라미드 표면 및 이러한 표면의 제조방법(Electroless Plated Aramid Surfaces and a Process for Making Such Surfaces) - Google Patents

무전해 도금된 아라미드 표면 및 이러한 표면의 제조방법(Electroless Plated Aramid Surfaces and a Process for Making Such Surfaces) Download PDF

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KR950704563A
KR950704563A KR1019950702298A KR19950702298A KR950704563A KR 950704563 A KR950704563 A KR 950704563A KR 1019950702298 A KR1019950702298 A KR 1019950702298A KR 19950702298 A KR19950702298 A KR 19950702298A KR 950704563 A KR950704563 A KR 950704563A
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fibers
contacting
fiber
solution
drying
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KR1019950702298A
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KR100240852B1 (ko
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블로덱 가바라
헤-시옹 슈
에드워드 윌리암 토카르스키
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미리암 디. 메코너헤이
이. 아이. 듀폰 디 네모아 앤드 캄파니
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/22—Roughening, e.g. by etching
    • C23C18/24—Roughening, e.g. by etching using acid aqueous solutions

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemically Coating (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

본 발명은 내구성 및 고전도성 도금을 제공하는 금속 도금된 PPD-T 섬유의 제조 방법에 관한 것이다.

Description

무전해 도금된 아라미드 표면 및 이러한 표면의 제조방법(Electroless Plated Aramid Surfaces and a Process for Making Such Surfaces)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 도금된 구리 금속 부착량을 섬유의 산 처리시 사용되는 황산 농도의 함수로서 나타낸 그래프이고,
제2도는 본 발명의 구리 도금 섬유의 단면을 확대한 현미경 사진이고,
제3도는 본 발명의 방법으로 처리되지 않은 구리 도금 섬유의 단면을 확대한 현미경 사진이다.

Claims (11)

  1. 도금될 섬유를 활성화 용액과 접촉시키고, 섬유를 세정하고, 도금할 금속 양이온의 용액에 섬유를 첨지시키는 단계를 포함하는 아라미드 섬유를 내구성 금속 코팅으로 무전해 도금하는 방법에 있어서, 도금될 섬유를 증감액(增感液)과 접촉시키기 전에, (a) 아라미드 섬유를 80내지 90% 황산 용액 중에서 10내지 100℃의 온도에서 2내지 60초 동안 접촉시키는 단계 및 (b) 산 접촉된 섬유를 산이 실질적으로 전부 제거 될 때까지 물로 세척하는 단계를 포함하는 것을 특징으로 하는 방법.
  2. 제1항에 있어서, 세척된 섬유를 건조시키는 단계 (c)를 더 포함하는 방법.
  3. 제2항에 있어서, 상기 건조는 15내지 80℃에서 수행되는 것인 방법.
  4. 제1항에 있어서, 상기 내구성 금속은 구리인 것인 방법.
  5. 제4항에 있어서, 증감액은 주석-팔라듐 용액인 것인 방법.
  6. 제1항에 있어서, 상기 내구성 금속은 은인 것인 방법.
  7. 제6항에 있어서, 증감액은 제1주석 이온 함유 용액인 것인 방법.
  8. (a) 아라미드 섬유를 80내지 90% 황산 용액 중에서 10 내지 100℃의 온도에서 2내 60초 동안 접촉시키는 단계, (b)산 접촉된 섬유를 산이 실질적으로 전부 제거될 때까지 물로 세척하는 단계, (c)세척된 섬유를 증감액과 접촉시키는 단계, (d)섬유를 세정하여 부착하지 않은 증감액을 제거하는 단계, 및 (e)세정된 섬유를 도금 할 금속 양이온을 함유하는 수용액 중에 침지시키는 단계를 포함하는, 아라미드 섬유를 내구성 금속 코팅으로 도금시키는 방법.
  9. 제8항에 있어서, 상기 도금할 금속 양이온은 은, 구리, 니켈 및 코발트로 이루어진 군으로부터 선택되는 것인 방법.
  10. 제8항에 있어서, 단계(b)의 세척 및 단계(c)의 접촉을 수행한 후에 세척된 섬유를 건조시키는 단계를 더 포함하는 방법.
  11. 제10항에 있어서, 상기 건조는 15내지 80℃에서 수행되는 것인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950702298A 1992-12-08 1993-12-02 무전해 도금된 아라미드 표면 및 이러한 표면의 제조 방법 KR100240852B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US07/987,898 US5302415A (en) 1992-12-08 1992-12-08 Electroless plated aramid surfaces and a process for making such surfaces
US07/987898 1992-12-08
US7/987,898 1992-12-08
PCT/US1993/011522 WO1994013876A1 (en) 1992-12-08 1993-12-02 Electroless plated aramid surfaces and a process for making such surfaces

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KR950704563A true KR950704563A (ko) 1995-11-20
KR100240852B1 KR100240852B1 (ko) 2000-01-15

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US (2) US5302415A (ko)
EP (1) EP0673451B1 (ko)
JP (1) JP3296491B2 (ko)
KR (1) KR100240852B1 (ko)
CN (1) CN1040785C (ko)
DE (1) DE69305362T2 (ko)
TW (1) TW281704B (ko)
WO (1) WO1994013876A1 (ko)

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Also Published As

Publication number Publication date
EP0673451B1 (en) 1996-10-09
KR100240852B1 (ko) 2000-01-15
EP0673451A1 (en) 1995-09-27
DE69305362D1 (de) 1996-11-14
US5302415A (en) 1994-04-12
TW281704B (ko) 1996-07-21
JPH08504241A (ja) 1996-05-07
DE69305362T2 (de) 1997-03-06
CN1089309A (zh) 1994-07-13
JP3296491B2 (ja) 2002-07-02
US5422142A (en) 1995-06-06
CN1040785C (zh) 1998-11-18
WO1994013876A1 (en) 1994-06-23

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