KR900018336A - 사우어(sour)탄화수소 스트림의 무가성 스위트닝법 - Google Patents

사우어(sour)탄화수소 스트림의 무가성 스위트닝법 Download PDF

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KR900018336A
KR900018336A KR1019900006538A KR900006538A KR900018336A KR 900018336 A KR900018336 A KR 900018336A KR 1019900006538 A KR1019900006538 A KR 1019900006538A KR 900006538 A KR900006538 A KR 900006538A KR 900018336 A KR900018336 A KR 900018336A
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compound
group
carbon atoms
alkaryl
aryl
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KR1019900006538A
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KR930010567B1 (ko
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알. 프레임 로버트
씨. 브리커 제퍼리
오. 스틴 로오렌스
에이. 베락티트 토마스
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토마스 케이. 맥브라이드
유오피
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Priority claimed from US07/349,013 external-priority patent/US4908122A/en
Priority claimed from US07/348,620 external-priority patent/US4913802A/en
Application filed by 토마스 케이. 맥브라이드, 유오피 filed Critical 토마스 케이. 맥브라이드
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/06—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of alkaline solutions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0254—Nitrogen containing compounds on mineral substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/10—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/025—Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Gas Separation By Absorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

내용 없음

Description

사우어(sour)탄화수소 스트림의 무가성 스위트닝법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 산화제, 수산화암모늄 수용액 및 다음 구조식을 가지는 사급 암모늄 화합물의 존재 중에서, 탄화수소 분류물을 메르갑탄을 이황화무로 산화시키는데 유효한 흡착성 지지체 상에 분산시킨 금속 킬레이트로 된 촉매 조성물과 접촉시키는 것으로 되는 메르캅탄 함유 사우어(sour)탄화수소 분류물을 스위트닝(sweetening)시키는 방법.
    상기식에서, R은 최대로 탄소수 20을 가지는 탄화수소기로서, 알킬, 시클로알킬, 아릴, 알카릴, 및 아랄킬로 구성되는 군으로부터 선택되며, R1은 탄소수 5내지 20을 가지는 직쇄 알킬기이고, R2는 아릴, 알카릴 및 아랄킬로 구성되는 군으로부터 선택된 탄화수소기이며, X는 히드록시드, 할라이드, 니트레이트, 니트리트, 설페이트, 포스페이트, 아세테이트, 시트레이트 및 타르타레이트로 구성되는 군으로부터 선택된 음이온이다.
  2. 제1항에 있어서, 수산화암모늄이 탄화수소 분류물에 대해 0.1 내지 20wppm 농도로 존재하는 방법.
  3. 제1항에 있어서, 금속 킬레이트가 금속 프탈로시아닌인 방법.
  4. 제1항에 있어서, 사급 암모늄 화합물이 수산화물 또는 할로겐화물이며, 탄화수소 분류물에 대해 0.05 내지 500wppm 양으로 존재하는 방법.
  5. 제1항에 있어서, 촉매 조성물이 또한 일반식[R'(R)yM]+X-[여기서, R은 최대로 탄소수 20을 가지는 탄화수소기로서, 알킬, 시클로알킬, 아릴, 알카릴 및 아랄킬로 구성되는 군으로부터 선택되며, R'는 탄소수 5내지 20을 가지는 직쇄 알킬기이고, M은 인(포스포늄 화합물), 질소(암모늄 화합물), 비소(아르소늄 화합물), 안티몬(스티보늄 화합물), 산소(옥소늄 화합물)또는 황(술포늄 화합물)이고, X는 히드록시드이고, M이 산소 또는 황일 때 y는 2이고, M이 인, 질소, 비소 또는 안티몬일 때 y는 3임]을 가지는 오늄 화합물인 방법.
  6. 제5항에 있어서, 오늄 화합물이 암모늄 화합물인 방법.
  7. 제1항에 있어서, 수용액이 메탄올을 함유하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900006538A 1989-05-08 1990-05-07 사우어 탄화수소 스트림의 무가성 스위트닝법 KR930010567B1 (ko)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US348620 1982-02-12
US349,013 1989-05-08
US348,620 1989-05-08
US07/349,013 US4908122A (en) 1989-05-08 1989-05-08 Process for sweetening a sour hydrocarbon fraction
US349013 1989-05-08
US07/348,620 US4913802A (en) 1989-05-08 1989-05-08 Process for sweetening a sour hydrocarbon fraction

Publications (2)

Publication Number Publication Date
KR900018336A true KR900018336A (ko) 1990-12-21
KR930010567B1 KR930010567B1 (ko) 1993-10-28

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JP (1) JPH0643587B2 (ko)
KR (1) KR930010567B1 (ko)
CN (1) CN1026121C (ko)
AR (1) AR246758A1 (ko)
AT (1) ATE86651T1 (ko)
AU (1) AU618886B2 (ko)
BR (1) BR9002096A (ko)
CA (1) CA2015160C (ko)
CS (1) CS275150B2 (ko)
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NO (1) NO179216C (ko)
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RU (1) RU1826987C (ko)
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CN1074313C (zh) * 1997-06-04 2001-11-07 中国石油化工总公司 一种负载型酞菁钴硫醇氧化催化剂
CN1072035C (zh) * 1997-06-04 2001-10-03 中国石油化工总公司 一种负载型金属配合物催化剂及其制备
CN1072034C (zh) * 1997-06-04 2001-10-03 中国石油化工总公司 一种硫醇氧化催化剂及其制备
CN100406540C (zh) * 2005-05-31 2008-07-30 中国科学院大连化学物理研究所 一种用于轻质油氧化脱臭的催化剂及制备方法
CN103031141B (zh) * 2011-09-29 2015-11-25 中国石油化工股份有限公司 一种脱除轻质石油产品中硫醇的方法
DE102012202622A1 (de) * 2012-02-21 2013-08-22 Wacker Chemie Ag Katalysator zur Carbonylierung carbonylierbarer Verbindungen in der Gasphase
CN103450924B (zh) * 2012-05-29 2015-06-24 北京安耐吉能源工程技术有限公司 一种油品非加氢脱硫醇的方法
MY178884A (en) 2013-12-11 2020-10-21 Evonik Operations Gmbh A catalyst for oxidation reactions, a method for its preparation and the use thereof
CN105567302B (zh) * 2014-10-17 2018-06-19 中国石油化工股份有限公司 一种不使用无机碱的油品脱臭方法
CN111072442B (zh) * 2019-12-27 2022-09-06 江苏盈天化学有限公司 一种带恶臭味的甲苯溶剂的回收方法

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US3294517A (en) * 1963-02-11 1966-12-27 Owens Illinois Inc Forehearth construction
DE2461700C3 (de) * 1974-12-27 1978-11-23 Sorg - Gmbh & Co Kg, 8771 Pflochsbach Verfahren und Vorrichtung zur Beheizung von glasführenden Kanälen, Speisern und Speiserköpfen
ZA7740B (en) * 1976-01-14 1977-11-30 Uop Inc Improved process for sweetening sour hydrocarbon distillates
US4124493A (en) * 1978-02-24 1978-11-07 Uop Inc. Catalytic oxidation of mercaptan in petroleum distillate including alkaline reagent and substituted ammonium halide
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DE3528332A1 (de) * 1985-08-07 1987-02-12 Sorg Gmbh & Co Kg Verfahren zur elektrischen beheizung von glasfuehrenden kanaelen, speiserrinnen und speiserkoepfen von glasspeisern, sowie vorrichtung zur durchfuehrung des verfahrens
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EG18957A (en) 1994-06-30
DE69001039D1 (de) 1993-04-15
PT93980B (pt) 1996-11-29
ATE86651T1 (de) 1993-03-15
JPH0643587B2 (ja) 1994-06-08
CA2015160C (en) 1997-06-24
CN1048543A (zh) 1991-01-16
AU5226790A (en) 1990-11-08
RU1826987C (ru) 1993-07-07
YU84490A (en) 1992-05-28
CN1026121C (zh) 1994-10-05
AU618886B2 (en) 1992-01-09
JPH03115392A (ja) 1991-05-16
KR930010567B1 (ko) 1993-10-28
ES2038857T3 (es) 1993-08-01
HU207699B (en) 1993-05-28
MX166657B (es) 1993-01-26
FI902285A0 (fi) 1990-05-07
GR3007380T3 (ko) 1993-07-30
FI100664B (fi) 1998-01-30
CS9002251A3 (en) 1992-02-19
NO179216C (no) 1996-08-28
HUT54334A (en) 1991-02-28
TR26234A (tr) 1995-02-15
DK0396934T3 (da) 1993-04-13
NO902016L (no) 1990-11-09
MY105560A (en) 1994-10-31
NO902016D0 (no) 1990-05-07
NZ233124A (en) 1991-04-26
CA2015160A1 (en) 1990-11-08
CS275150B2 (en) 1992-02-19
BR9002096A (pt) 1991-08-13
DE69001039T2 (de) 1993-06-17
EP0396934B1 (en) 1993-03-10
PT93980A (pt) 1991-01-08
HU902696D0 (en) 1990-09-28
AR246758A1 (es) 1994-09-30
NO179216B (no) 1996-05-20
EP0396934A1 (en) 1990-11-14

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