KR900016350A - 가소탄성 폴리프로필렌 조성물 - Google Patents

가소탄성 폴리프로필렌 조성물 Download PDF

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KR900016350A
KR900016350A KR1019900006052A KR900006052A KR900016350A KR 900016350 A KR900016350 A KR 900016350A KR 1019900006052 A KR1019900006052 A KR 1019900006052A KR 900006052 A KR900006052 A KR 900006052A KR 900016350 A KR900016350 A KR 900016350A
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ethylene
propylene
composition
weight
mpa
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KR1019900006052A
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KR0160511B1 (ko
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세친 지울리아노
구글리엘미 플로리아노
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원본미기재
히몬트 인코포레이티드
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • C08F297/086Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene the block polymer contains at least three blocks
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/02Heterophasic composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/10Peculiar tacticity
    • C08L2207/14Amorphous or atactic polypropylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815Copolymers of ethene with aliphatic 1-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00Chemical blending or stepwise polymerisation process with the same catalyst
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/909Polymerization characterized by particle size of product
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982Particulate matter [e.g., sphere, flake, etc.]

Abstract

내용 없음.

Description

가소탄성 폴리프로필렌 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 유연율 700MPa 미만, 75%에서의 잔류 신장율 60% 미만, 인장응력 6MPa 이상 및 -20℃ 및 -40℃에서의 놋치된 아이조드 탄성률 600J/m이상의, A)이소택틱 지수 90이상의 폴리프로필렌 단독중합체, 또는 85중량%이상의 프로필렌을 함유하며 85이상의 이소택틱 지수를 갖는 에틸렌 및/또는 CH2=CHR(여기에서, R은 탄소수 2∼6의 알킬기이다)올레핀과의 결정성 프로필렌 공중합체 10∼60중량부; B)실온에서 크실렌에 불용성인, 에틸렌을 함유하는 결정성 중합체 부분 10∼40중량부; C)소량의 디엔을 임의로 함유하며, 실온에서 크실렌에 용해되며 40∼70중량%의 에틸렌을 함유하는 무정형 에틸렌-프로필렌 공중합체 부분 30∼60중량부를 함유하는 폴리프로필렌 조성물.
  2. 제1항에 있어서, 중합되는 에틸렌의 총함량이 20∼60중량%인 조성물.
  3. 제1항 또는 제2항에 있어서, 유연율이 200∼500MPa이고, 잔류 신장율이 20∼50%이며, 인장용력이 8∼20MPa인 조성물.
  4. 제1항에 있어서, 평균 직경 500∼7000㎛, 유동성 30초 미만 및 탬프된 부피밀도(tamped bulk density) 0.4g/cc 이상의 구형 입자 형태인 조성물.
  5. Al-트리알킬 화합물, 및 표면적이 100m2/g미만이고, 다공성이 0.2∼0.4cc/g이며, 공극 부피 분포가 반경 100A이상의 공극 50%이상이고, X선 스펙트럼이 33.5°∼35°사이의 각도에서 최대 강도의 할로(halo)를 나타내고 14.95°에서 반사가 없음을 나타내는, 무수 염화 마그네슘상에 담지된 전자-공여 화합물 및 Ti의 할로겐화물이나 할로겐-알코올화물을 함유하는 고체 성분으로부터 수득된 촉매를 사용하여, 프로필렌 또는 그의 에틸렌 및/또는 알파올레핀과의 혼합물을 중합시켜 중합체상 A)를 생성하는 중합단계, 및 임의로는 디엔을 함유하는 에틸렌-프로필렌 혼합물을 중합시켜 중합체상 B) 및 C)를 생성하는 하나 이상의 중합단계(들)로 구성된, 제1항의 조성물의 제조방법.
  6. 제5항에 있어서, 프로필렌 중합단계를 액성 단량체 상태에서 실시하고, 에틸렌-프로필렌 공중합단계(들)을 기체상에서 실시하는 방법.
  7. 제5항에 있어서, 기체상에서 각 중합단계를 실시하는 방법.
  8. 제1항의 조성물로부터 수득되는 제품.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900006052A 1989-04-28 1990-04-28 가소탄성 폴리프로필렌 조성물 KR0160511B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IT8920328A IT1230133B (it) 1989-04-28 1989-04-28 Composizioni polipropileniche plasto-elastiche
IT20328A/89 1989-04-28
US20328A/89 1989-04-28

Publications (2)

Publication Number Publication Date
KR900016350A true KR900016350A (ko) 1990-11-13
KR0160511B1 KR0160511B1 (ko) 1999-01-15

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Country Link
US (1) US5302454A (ko)
EP (1) EP0400333B1 (ko)
JP (1) JP2950908B2 (ko)
KR (1) KR0160511B1 (ko)
CN (1) CN1067089C (ko)
AR (1) AR244740A1 (ko)
AT (1) ATE130014T1 (ko)
AU (1) AU634229B2 (ko)
BR (1) BR9001989A (ko)
CA (1) CA2015683C (ko)
CZ (1) CZ283097B6 (ko)
DD (1) DD294031A5 (ko)
DE (1) DE69023392T2 (ko)
ES (1) ES2081870T3 (ko)
FI (1) FI99016C (ko)
HU (1) HU218855B (ko)
IL (1) IL94153A (ko)
IT (1) IT1230133B (ko)
MX (1) MX20476A (ko)
MY (1) MY112377A (ko)
NO (1) NO176442C (ko)
PL (1) PL164127B1 (ko)
PT (1) PT93922B (ko)
RU (1) RU2092502C1 (ko)
SK (1) SK211090A3 (ko)
YU (1) YU82690A (ko)
ZA (1) ZA902972B (ko)

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FI99016C (fi) 1997-09-25
EP0400333B1 (en) 1995-11-08
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CA2015683A1 (en) 1990-10-28
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