KR890008059A - 다공성의 멤브레인 및 그 제조방법 - Google Patents

다공성의 멤브레인 및 그 제조방법 Download PDF

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KR890008059A
KR890008059A KR1019880014344A KR880014344A KR890008059A KR 890008059 A KR890008059 A KR 890008059A KR 1019880014344 A KR1019880014344 A KR 1019880014344A KR 880014344 A KR880014344 A KR 880014344A KR 890008059 A KR890008059 A KR 890008059A
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polymer
metal oxide
silica
nitrogen
dispersion
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KR1019880014344A
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English (en)
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케이.제인 무케시
케이.나드카르니 사다시브
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원본미기재
알칸 인토내셔날 리미티드
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Publication of KR890008059A publication Critical patent/KR890008059A/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0067—Inorganic membrane manufacture by carbonisation or pyrolysis
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01B—SOIL WORKING IN AGRICULTURE OR FORESTRY; PARTS, DETAILS, OR ACCESSORIES OF AGRICULTURAL MACHINES OR IMPLEMENTS, IN GENERAL
    • A01B1/00—Hand tools
    • A01B1/02—Spades; Shovels
    • A01B1/026—Spades; Shovels with auxiliary handles for facilitating lifting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0041—Inorganic membrane manufacture by agglomeration of particles in the dry state
    • B01D67/00411—Inorganic membrane manufacture by agglomeration of particles in the dry state by sintering
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/58—Fabrics or filaments
    • B01J35/59—Membranes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/0022—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof obtained by a chemical conversion or reaction other than those relating to the setting or hardening of cement-like material or to the formation of a sol or a gel, e.g. by carbonising or pyrolysing preformed cellular materials based on polymers, organo-metallic or organo-silicon precursors
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/12—Specific ratios of components used
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00793—Uses not provided for elsewhere in C04B2111/00 as filters or diaphragms
    • C04B2111/00801—Membranes; Diaphragms
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0081—Uses not provided for elsewhere in C04B2111/00 as catalysts or catalyst carriers

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Soil Sciences (AREA)
  • Environmental Sciences (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Ceramic Products (AREA)

Abstract

내용 없음

Description

다공성의 멤브레인 및 그 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제 1 도는 소결된 알루미나 튜브의 외부표면을 80배로 확대한 현미경 사진이다
제 2 도는 소결된 알루미나 튜브의 외부표면을 1000배로 확대한 현미경 사진이다
제 3 도는 상기 알루미나 튜브의 내부표면을 65배 확대한 사진이다
제 4 도는 제 1 도의 튜브벽의 단면을 400배로 확대한 현미경 사진이다

Claims (14)

  1. 사용된 실리카 또는 금속 산화물의 양이 그 다음의 가열단계에서 폴리머로부터 유도된 탄소와 반응하도록 된 과량으로 포함된, 금속 산화물, 실리카 및 혼합물로 그성된 그룹으로부터 선택된 물질의 분말을 유기 폴리머에 분산시키고; 그 분산물을 형성하여 원하는 얇은 형태로 만들고; 비산화성 분위기에서 가열함으로써 폴리머를 탄화시키고; 질소를 전혀 포함하지 않거나 또는 비다공성의 생성물이 형성되는 양보다 적은양의 질소를 포함한 비산화성 분위기에서 상기 생성물을 탄소가 산화물과 반응하는 한편 남은 미반응 산화물 입자가 같이 소결되는 온도로 가열하는 것으로 구성된 것을 특징으로 하는 실리카 또는 금속 산화물로 제조된 다공성의 멤브레인을 제조하는 방법
  2. 제 1 항에 있어서, 금속 산화물이 알루미나, 티타니아 지르코니아, 이트리아 또는 텅스텐 산화물로 구성된 그룹으로부터 선택된 것을 특징으로 하는 방법
  3. 제 1 항에 있어서, 폴리머가 포리아크릴로 니트릴 및 그코폴리머 및 터포리머, 셀풀로오즈 및 그 유도체, 포리비닐알콜 및 그코폴리머 및 터폴리머, 폴리에틸렌 글리콜, 폴리아릴에테르, 폴리아세나프틸렌 및 폴리악세틸렌인 것을 특징으로 하는 방법
  4. 제 1 항에 있어서, 유기 폴리머에서 분말의 분산이 적합한 용매속에 있는 폴리머 용액에 실린카 또는 금속 산화물을 첨가함으로서 형성되고 이어서 용매를 제거하는 것을 특징으로 하는 방법
  5. 제 4 항에 있어서, 용매가 이어서 용매 건조에 의해서 용액으로부터 제거되는 것을 특징으로하는 방법
  6. 제 1 항에서 3항 중 어느 한 항에 있어서, 탄화단계동안에 폴리머로부터 유도되는 탄소에 대한 실리카 또는 금속 산화물의 비가 몰비로 1:1보다 큰 것을 특징으로 하는 방법
  7. 제 1 항에서 3항중 어느 한 항에 있어서, 상기 가열단계가 10-20부피%의 질소를 포함하는 분위기에서 수행되는 것을 특징으로하는 방법
  8. 제 1 항에서 3항중 어느 한 항에 있어서, 상기 가열단계가 우선 질소를 포함하지 않은 분위기에서 수행되고 이어서 추가의 다공성의 형성을 방지하기 위하여 질소를 주입 하는 것을 특징으로 하는 방법
  9. 제 1 항에서 3항중 어느 한 항에 있어서, 금속 산화물이 알루미나 인 것을 특징으로 하는 방법
  10. 제 1 항에서 3항 중 어느 한 항에 있어서, 상기 물질의 입자가범위의 크기를 가진 것을 특징으로 하는 벙법
  11. 제 1 항에서 3항중 어느 한 항에 있어서, 상기 물질의 입자가보다 작은 크기를 가진 것을 특징으로 하는 방법
  12. 제 1 항에서 3항중 어느 한 항에 있어서, 분산물이 5mm이하의 두께를 가진 형태로 성형되는 것을 특징으로 하는 방법
  13. 제 1 항에서 3 항중 어느 한 항에 있어서, 분산물이 시이트, 판 및 튜브로 구성된 그룹으로부터 선택된 얇은 형태로 성형되는 것을 특징으로 하는 방법
  14. 제 1 항에서 3항중 어느 한 항에 따른 방법에 의해 제조되는 실리카 또는 내화성의 금속 산화물로 제조된 다공성의 멤브레인
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880014344A 1987-11-03 1988-11-01 다공성의 멤브레인 및 그 제조방법 KR890008059A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA000550959A CA1269404A (en) 1987-11-03 1987-11-03 Porous membrane of sinterable refractory metal oxides or silica
CA550959 1987-11-03

Publications (1)

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KR890008059A true KR890008059A (ko) 1989-07-08

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US (1) US4973435A (ko)
EP (1) EP0315453A3 (ko)
JP (1) JPH01261285A (ko)
KR (1) KR890008059A (ko)
CN (1) CN1032932A (ko)
AU (1) AU2458688A (ko)
BR (1) BR8805659A (ko)
CA (1) CA1269404A (ko)
DK (1) DK610188A (ko)
NO (1) NO884890L (ko)

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KR20210039070A (ko) * 2019-10-01 2021-04-09 한국화학연구원 입도제어 가능한 고속 순간 혼화방식 액상폴리머 용해장치

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101487107B1 (ko) * 2013-12-24 2015-01-28 오씨아이 주식회사 글리콜 에테르 탈수용 유-무기 복합막을 이용한 투과증발 시스템
KR20210039070A (ko) * 2019-10-01 2021-04-09 한국화학연구원 입도제어 가능한 고속 순간 혼화방식 액상폴리머 용해장치

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AU2458688A (en) 1989-05-04
DK610188D0 (da) 1988-11-02
CN1032932A (zh) 1989-05-17
NO884890L (no) 1989-05-05
JPH01261285A (ja) 1989-10-18
US4973435A (en) 1990-11-27
NO884890D0 (no) 1988-11-02
EP0315453A3 (en) 1991-01-30
CA1269404A (en) 1990-05-22
DK610188A (da) 1989-05-04
EP0315453A2 (en) 1989-05-10

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