KR890004065B1 - 스틸렌 중합체의 제조방법 - Google Patents

스틸렌 중합체의 제조방법 Download PDF

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Publication number
KR890004065B1
KR890004065B1 KR1019860009480A KR860009480A KR890004065B1 KR 890004065 B1 KR890004065 B1 KR 890004065B1 KR 1019860009480 A KR1019860009480 A KR 1019860009480A KR 860009480 A KR860009480 A KR 860009480A KR 890004065 B1 KR890004065 B1 KR 890004065B1
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South Korea
Prior art keywords
polymer
titanium
styrene
weight
group
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Expired
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KR1019860009480A
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English (en)
Korean (ko)
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KR870011157A (ko
Inventor
노부히데 이시하라
마사히꼬 구라모도
미지다께 우오이
Original Assignee
이데미쓰 고산가부시기가이샤
이데미쓰 쇼스게
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Publication of KR870011157A publication Critical patent/KR870011157A/ko
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Publication of KR890004065B1 publication Critical patent/KR890004065B1/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
KR1019860009480A 1985-11-11 1986-11-11 스틸렌 중합체의 제조방법 Expired KR890004065B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP25253185 1985-11-11
JP60-252531 1985-11-11
JP61-101927 1986-05-06
JP61101927A JPS62187708A (ja) 1985-11-11 1986-05-06 スチレン系重合体の製造法

Publications (2)

Publication Number Publication Date
KR870011157A KR870011157A (ko) 1987-12-21
KR890004065B1 true KR890004065B1 (ko) 1989-10-18

Family

ID=26442695

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019860009480A Expired KR890004065B1 (ko) 1985-11-11 1986-11-11 스틸렌 중합체의 제조방법

Country Status (6)

Country Link
US (1) US4680353A (https=)
EP (1) EP0224097B1 (https=)
JP (1) JPS62187708A (https=)
KR (1) KR890004065B1 (https=)
CA (1) CA1250697A (https=)
DE (1) DE3677333D1 (https=)

Families Citing this family (159)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5252693A (en) * 1986-07-18 1993-10-12 Idemitsu Kosan Company Limited Syndiotactic styrene polymers
JP2531583B2 (ja) * 1987-01-28 1996-09-04 出光興産株式会社 スチレン系共重合体およびその製造方法
US5189125A (en) * 1985-07-29 1993-02-23 Idemitsu Kosan Co., Ltd. Process for producing syndiotactic styrene copolymer
US5280000A (en) * 1985-10-11 1994-01-18 Sumitomo Chemical Company, Limited Catalyst for olefin polymerization and process for producing olefin polymer using the catalyst
US5891951A (en) * 1987-09-14 1999-04-06 Idemitsu Kosan Co., Ltd. Styrene-based resin composition
US5166238A (en) * 1986-09-22 1992-11-24 Idemitsu Kosan Co., Ltd. Styrene-based resin composition
US5395890A (en) * 1987-09-14 1995-03-07 Idemitsu Kosan Co., Ltd. Styrene-based resin composition
JPH06104337B2 (ja) * 1987-12-04 1994-12-21 出光興産株式会社 スチレン系樹脂延伸フィルム及びその製造方法
JP2707446B2 (ja) * 1988-01-14 1998-01-28 出光興産 株式会社 スチレン系重合体繊維状成形品
JPH082925B2 (ja) * 1986-11-10 1996-01-17 出光興産株式会社 スチレン系重合体の製造方法
IL84800A (en) * 1986-12-15 1991-09-16 Montedison Spa Production of crystalline vinyl aromatic polymers having mainly a syndiotactic structure
IT1201715B (it) * 1986-12-15 1989-02-02 Montedison Spa Polimeri stirenici cristallini essenzialmente sindiotattici e procedimento per la loro preparazione
WO1988008432A1 (fr) * 1987-04-20 1988-11-03 Mitsui Petrochemical Industries, Ltd. Catalyseur et procede de polymerisation d'olefines
JPH085929B2 (ja) * 1987-01-22 1996-01-24 出光興産株式会社 スチレン系重合体の製造法
US6013726A (en) * 1987-04-12 2000-01-11 Idemitsu Kosan Co., Ltd. Composition of styrene resin, thermoplastic resin and rubber
US5206199A (en) * 1987-04-20 1993-04-27 Mitsui Petrochemical Industries, Ltd. Catalyst for polymerizing an olefin and process for polymerizing an olefin
US4774301A (en) * 1987-06-08 1988-09-27 The Dow Chemical Company Zirconium containing catalysts and method of use
US5045517A (en) * 1987-06-17 1991-09-03 The Dow Chemical Company Catalyst and process for preparation of syndiotactic polystyrene
US5196490A (en) * 1987-06-17 1993-03-23 The Dow Chemical Company Process for preparation of syndiotactic polystyrene
ATE91691T1 (de) * 1987-06-17 1993-08-15 Dow Chemical Co Katalysator und verfahren zur herstellung syndiotaktischer polystyrene.
JP2566889B2 (ja) * 1987-07-13 1996-12-25 出光興産株式会社 オレフィン系重合体またはスチレン系重合体の製造方法
US6046275A (en) * 1987-09-14 2000-04-04 Idemitsu Kosan Co., Ltd. Styrene resin with rubber polymer particles
US6087435A (en) * 1987-09-14 2000-07-11 Idemitsu Kosan Co., Ltd. Composition of styrene resin, thermoplastic resin and rubber particles
US6093768A (en) * 1987-09-14 2000-07-25 Idemitsu Kosan Co., Ltd. Syndiotactic styrene resin, thermoplastic resin and rubber
US6008293A (en) * 1987-09-14 1999-12-28 Idemitsu Kosan Co., Ltd. Syndiotactic polystyrene and polycarbonate resin compositions
DE3780635T2 (de) * 1987-09-15 1992-12-10 Idemitsu Kosan Co Harzzusammensetzung auf der basis von polystyrol.
US5212232A (en) * 1987-09-28 1993-05-18 Idemitsu Kosan Co., Ltd. Process for production of styrene-based polymers
JPH0822884B2 (ja) * 1987-09-28 1996-03-06 出光興産株式会社 スチレン系重合体の製造方法
KR890701646A (ko) * 1987-09-28 1989-12-21 이소미쓰 쇼스께 스티렌계 중합체의 제조방법
JPH0822885B2 (ja) * 1987-10-02 1996-03-06 出光興産株式会社 スチレン系重合体組成物の製造方法
KR940000789B1 (ko) * 1987-10-08 1994-01-31 이데미쓰 고산 가부시끼가이샤 스티렌계 중합체 및 그 제조방법
KR940004093B1 (ko) * 1987-10-20 1994-05-13 이데미쓰 고산 가부시끼가이샤 스티렌계 수지조성물과 성형품의 제조방법
IT1223326B (it) * 1987-10-28 1990-09-19 Montedipe Spa Composizioni termoplastiche a base di polimeri sindiotattici dello stirene e polifenileneteri
DE3789390T2 (de) * 1987-11-06 1994-10-20 Idemitsu Kosan Co Verfahren zur herstellung von styrenpolymeren und verfahren zum giessen.
JP2698085B2 (ja) * 1988-01-19 1998-01-19 出光興産株式会社 スチレン系重合体の製造方法とその触媒
JPH0813851B2 (ja) * 1988-03-19 1996-02-14 出光興産株式会社 スチレン系重合体の製造方法とその触媒
JPH0819175B2 (ja) * 1988-02-13 1996-02-28 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
JPH0813853B2 (ja) * 1988-03-19 1996-02-14 出光興産株式会社 スチレン系重合体の製造方法とその触媒
US4978730A (en) * 1987-12-24 1990-12-18 Idemitsu Kosan Company Limited Process for producing styrene-based polymers and catalyst for use therein
JP2768483B2 (ja) * 1988-01-13 1998-06-25 出光興産株式会社 熱可塑性樹脂組成物
US5270442A (en) * 1988-01-13 1993-12-14 Idemitsu Kosan Co., Ltd. Styrene-based polymer moldings
JPH07119306B2 (ja) * 1988-01-13 1995-12-20 出光興産株式会社 熱可塑性樹脂発泡体とその製造方法
JP2710324B2 (ja) * 1988-01-13 1998-02-10 出光興産株式会社 スチレン系重合体成形品とその製造方法
US5200454A (en) * 1988-01-14 1993-04-06 Idemitsu Kosan Company Limited Flame-retardant resin composition
US4959435A (en) * 1988-02-04 1990-09-25 The Dow Chemical Company Oriented optically transparent crystalline syndiotatic vinylaromatic polymer
US4859339A (en) * 1988-02-11 1989-08-22 The Dow Chemical Company Microporous membranes of syndiotactic vinylaromatic polymers
US5340786A (en) * 1988-02-12 1994-08-23 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for the polymerization of olefins
JP2700189B2 (ja) * 1988-02-13 1998-01-19 出光石油化学株式会社 スチレン系重合体の製造方法
AU611758B2 (en) * 1988-02-13 1991-06-20 Idemitsu Petrochemical Co., Ltd. Process for producing styrene-based polymers and apparatus for producing said polymers
JP2571254B2 (ja) * 1988-02-24 1997-01-16 旭化成工業株式会社 シンジオタクチックポリスチレン
JPH0813852B2 (ja) * 1988-03-19 1996-02-14 出光興産株式会社 スチレン系重合体の製造方法とその触媒
JPH0791327B2 (ja) * 1988-03-24 1995-10-04 出光興産株式会社 スチレン系重合体の製造方法とその触媒
JP2501865B2 (ja) * 1988-04-09 1996-05-29 三井石油化学工業株式会社 アルミノオキサン化合物の炭化水素溶液
US5004649A (en) * 1988-04-13 1991-04-02 Idemitsu Kosan Co., Ltd. Resin laminates and a process for production thereof
US5156797A (en) * 1988-06-30 1992-10-20 Idemitsu Kosan Co., Ltd. Nonwoven fabrics
JP2597392B2 (ja) * 1988-06-30 1997-04-02 出光興産株式会社 不織布
US5071917A (en) * 1988-07-22 1991-12-10 The Dow Chemical Company High strength fibers of stereoregular polystrene
US5286762A (en) * 1988-07-23 1994-02-15 Idemitsu Kosan Company Limited Styrene-based polymer moldings and process for production thereof
US5109068A (en) * 1988-08-31 1992-04-28 Idemitsu Kosan Co., Ltd. Styrene-based polymer composition, stretched molding thereof and process for producing the same
JP2824067B2 (ja) * 1988-09-30 1998-11-11 出光興産株式会社 難燃性樹脂組成物
JP2765863B2 (ja) * 1988-08-31 1998-06-18 出光興産株式会社 スチレン系樹脂組成物
US5006296A (en) * 1988-09-01 1991-04-09 The Dow Chemical Company Process for the preparation of fibers of stereoregular polystyrene
US5169893A (en) * 1988-09-01 1992-12-08 The Dow Chemical Company Mixtures containing stereoregular polystyrene
EP0358135B1 (en) * 1988-09-07 1996-01-31 Idemitsu Kosan Company Limited Polyarylene sulfide resin composition
US4950724A (en) * 1988-09-27 1990-08-21 The Dow Chemical Company Suspension polymerization of vinyl aromatic monomers to polymer having high syndiotacticity
JPH0637534B2 (ja) * 1988-09-28 1994-05-18 出光石油化学株式会社 スチレン系重合体の製造方法
JP2744254B2 (ja) * 1988-09-30 1998-04-28 出光興産株式会社 難燃性樹脂組成物
US5089353A (en) * 1988-10-14 1992-02-18 Kuraray Co., Ltd. Multi-layer material having gas barrier properties
US5082717A (en) * 1988-12-16 1992-01-21 Idemitsu Petrochemical Co., Ltd. Styrene-based resin composite material
US5273830A (en) * 1988-12-16 1993-12-28 Idemitsu Petrochemical Co., Ltd. Magnetic recording medium comprising a syndiotactic styrene-based polymer substrate, a magnetic layer and a backcoat lubricating layer each layer containing a curable phosphazine compound
JP2735596B2 (ja) * 1989-01-20 1998-04-02 出光石油化学株式会社 スチレン系重合体の製造方法
US5321107A (en) * 1989-01-31 1994-06-14 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for the polymerization of olefins
JP2812972B2 (ja) * 1989-02-02 1998-10-22 出光興産株式会社 スチレン系樹脂組成物と成形品の製造方法
US5270353A (en) * 1989-02-10 1993-12-14 Idemitsu Kosan Co., Ltd. Resin composition
US5260394A (en) * 1989-03-20 1993-11-09 Idemitsu Kosan Co., Ltd. Styrene copolymer and process for production thereof
JPH02252706A (ja) * 1989-03-28 1990-10-11 Idemitsu Kosan Co Ltd スチレン系重合体の製造方法
JPH02255708A (ja) * 1989-03-30 1990-10-16 Idemitsu Petrochem Co Ltd スチレン系重合体の製造方法
JP2752695B2 (ja) * 1989-05-25 1998-05-18 出光興産株式会社 アルミノキサンの乾燥方法およびポリマーの製造方法
JP2858786B2 (ja) * 1989-05-31 1999-02-17 出光興産株式会社 スチレン系重合体成形品およびその製造方法
US5187250A (en) * 1989-06-05 1993-02-16 Mitsui Toatsu Chemicals, Incorporated Poly-α-olefins
US5015275A (en) * 1989-07-14 1991-05-14 The Dow Chemical Company Isotropic microporous syndiotactic polystyrene membranes and processes for preparing the same
US4980101A (en) * 1989-07-14 1990-12-25 The Dow Chemical Company Anisotropic microporous syndiotactic polystyrene membranes and a process for preparing the same
US4927535A (en) * 1989-07-14 1990-05-22 The Dow Chemical Company Microporous membranes from isotactic polystyrene and syndiotactic polystyrene
US4976901A (en) * 1989-07-14 1990-12-11 The Dow Chemical Company Microporous membranes from isotactic polystyrene and syndiotactic polystyrene
JP2820964B2 (ja) * 1989-07-28 1998-11-05 出光興産株式会社 スチレン系重合体の精製方法
AU628194B2 (en) * 1989-07-28 1992-09-10 Idemitsu Kosan Co. Ltd Process for producing styrene polymers
CA2022255A1 (en) * 1989-08-01 1991-02-02 Tadanao Kohara Catalyst for polymerization of olefins
US6686488B2 (en) 1989-08-31 2004-02-03 The Dow Chemical Company Constrained geometry addition polymerization catalysts
US6025448A (en) * 1989-08-31 2000-02-15 The Dow Chemical Company Gas phase polymerization of olefins
US6075077A (en) * 1989-08-31 2000-06-13 The Dow Chemical Company Asphalt, bitumen, and adhesive compositions
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
CA2039161A1 (en) * 1989-08-31 1991-03-01 Keisuke Funaki Magnetic recording medium
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
EP0417724B1 (en) * 1989-09-14 1996-05-15 The Dow Chemical Company Coordination polymerization of styrene monomer
US5064918A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Ziegler-Natta polymerization of styrene monomer
US5340892A (en) * 1989-09-29 1994-08-23 Idemitsu Kosan Co., Ltd. Process for producing styrene polymers
US5077367A (en) * 1989-09-29 1991-12-31 The Dow Chemical Company Crystalline syndiotactic copolymers from arylcyclobutene functional monomers and vinyl aromatic monomers
CA2024830A1 (en) * 1989-09-29 1991-03-30 Richard E. Campbell, Jr. Process for preparation of syndiotactic vinyl aromatic polymers
JP2911501B2 (ja) * 1989-09-29 1999-06-23 出光興産株式会社 スチレン系重合体の製造方法
JP2996472B2 (ja) * 1989-10-09 1999-12-27 出光興産株式会社 電気絶縁用フィルム及びコンデンサ
US5247020A (en) * 1990-01-30 1993-09-21 Idemitsu Kosan Co., Ltd. Process for producing a styrene polymer composition
JPH07100723B2 (ja) * 1990-03-27 1995-11-01 三井東圧化学株式会社 シンジオタクチックビニルシクロヘキサン重合体
US6538080B1 (en) 1990-07-03 2003-03-25 Bp Chemicals Limited Gas phase polymerization of olefins
BR9104067A (pt) * 1990-09-20 1992-05-26 Dow Chemical Co Composto,processo para preparacao de compostos cataliticos e processo para polimerizacao de um ou mais monomeros
JP2866751B2 (ja) * 1991-01-10 1999-03-08 出光石油化学株式会社 積層体及び粘着テープ
JP2939354B2 (ja) * 1991-03-26 1999-08-25 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
DE69219932T2 (de) * 1991-03-29 1997-09-11 Idemitsu Kosan Co Verfahren zur Herstellung eines Homo- oder Copolymerisates des Styrols
JPH04366109A (ja) * 1991-06-12 1992-12-18 Idemitsu Kosan Co Ltd スチレン系重合体の製造方法及びその触媒
ATE153680T1 (de) * 1992-03-03 1997-06-15 Idemitsu Kosan Co Pfropfcopolymer, verfahren zu seiner herstellung und harzzusammensetzung, worin es enthalten ist
US5391603A (en) * 1992-03-09 1995-02-21 The Dow Chemical Company Impact modified syndiotactic vinyl aromatic polymers
JP3534421B2 (ja) * 1992-03-30 2004-06-07 出光興産株式会社 スチレン系樹脂積層体及びその成形体
JPH0693151A (ja) * 1992-09-10 1994-04-05 Idemitsu Kosan Co Ltd ポリスチレン系樹脂組成物
US7316833B1 (en) 1993-06-24 2008-01-08 Penchiney Emballage Flexible Europe Multi-layer thermoplastic films and packages made therefrom
AU701139B2 (en) * 1993-06-24 1999-01-21 Bemis Company, Inc. Improved structures of polymers made from single site catalysts
US5446117A (en) * 1993-08-19 1995-08-29 Queen's University At Kingston Process for producing amorphous syndiotactic polystyrene
US5428120A (en) * 1993-10-08 1995-06-27 The Dow Chemical Company Process for preparation of syndiotactic vinylidene aromatic polymers using chain transfer agent
US5453474A (en) * 1993-10-08 1995-09-26 The Dow Chemical Company Process for preparation of syndiotactic vinylidene aromatic polymers using reduced metal cationic catalysts
EP0722466B1 (en) * 1993-10-08 1997-07-09 The Dow Chemical Company Process for preparation of syndiotactic vinyl aromatic polymers using reduced metal catalyst
USRE37064E1 (en) * 1994-03-31 2001-02-20 Idemitsu Kosan Co., Ltd. Process for producing styrenic polymer
US5756612A (en) * 1995-03-30 1998-05-26 Idemitsu Kosan Co., Ltd. Process for producing styrenic polymer
US5569428A (en) * 1995-03-13 1996-10-29 The Dow Chemical Company Process for the preparation of fibers of syndiotactic vinylaromatic polymers
US5751388A (en) 1995-04-07 1998-05-12 Honeywell Inc. High efficiency polarized display
US5610455A (en) * 1995-06-29 1997-03-11 Minnesota Mining And Manufacturing Company Electret containing syndiotactic vinyl aromatic polymer
DE19546095A1 (de) * 1995-12-11 1997-06-12 Basf Ag Verfahren zur Herstellung von Copolymerisaten von vinylaromatischen Verbindungen in einer Stufe unter Verwendung von Doppelschneckenextrudern
DE69721505T2 (de) 1996-02-29 2003-11-20 Minnesota Mining And Manufacturing Company, St. Paul Film zur helligkeitserhoehung
US5825543A (en) 1996-02-29 1998-10-20 Minnesota Mining And Manufacturing Company Diffusely reflecting polarizing element including a first birefringent phase and a second phase
US5867316A (en) * 1996-02-29 1999-02-02 Minnesota Mining And Manufacturing Company Multilayer film having a continuous and disperse phase
BR9707766A (pt) * 1996-02-29 1999-07-27 Minnesota Mining & Mfg Corpo ótico
US5869154A (en) * 1996-03-21 1999-02-09 Fort James Corporation Resin composition having special colors and decoration added thereto
IT1283282B1 (it) * 1996-03-21 1998-04-16 Enichem Spa Procedimento per la preparazione di polimeri vinilaromatici cristallini a struttura predominantemente sindiotattica
CA2248365A1 (en) * 1996-05-07 1997-11-13 The Dow Chemical Company Improved syndiotactic vinylidene aromatic polymerization process
US6191197B1 (en) 1996-09-23 2001-02-20 Bridgestone Corporation Extended polymer compostion derived from blends of elastomers and syndiotactic polystyrene
US6329459B1 (en) 1996-09-23 2001-12-11 Bridgestone Corporation Extended syndiotactic polystyrene-elastomeric block copolymers
DE69925594T2 (de) 1998-04-07 2006-04-27 Dow Global Technologies, Inc., Midland Syndiotaktisches vinylaromatisches polymerisationsverfahren
US6005713A (en) * 1998-08-21 1999-12-21 3M Innovative Properties Company Multilayer polarizer having a continuous and disperse phase
US6274221B2 (en) 1999-01-29 2001-08-14 3M Innovative Properties Company Angular brightness microprismatic retroreflective film or sheeting incorporating a syndiotactic vinyl aromatic polymer
US6623824B1 (en) 1999-01-29 2003-09-23 3M Innovative Properties Company Method for making a microreplicated article using a substrate comprising a syndiotactic vinyl aromatic polymer
TW567192B (en) * 1999-04-14 2003-12-21 Idemitsu Petrochemical Co Styrene polymer and molded object obtained by molding the polymer
KR100349071B1 (ko) 2000-02-02 2002-08-14 삼성종합화학주식회사 생성물 순환 방식을 이용한 신디오탁틱 스티렌계 중합체의제조방법
US7026406B1 (en) 2000-02-10 2006-04-11 National Institute Of Advanced Industrial Science And Technology Syndiotactic styrene polymers and process for the production thereof
US6894102B2 (en) * 2002-05-20 2005-05-17 General Electric Syndiotactic polystyrene blends
US20040164434A1 (en) * 2002-10-24 2004-08-26 Tabar Ronald J. Methods of making high gain optical devices having a continuous and dispersive phase
US6818737B2 (en) * 2003-02-28 2004-11-16 Dow Global Technologies Inc. Method of producing articles from syndiotactic vinyl aromatic polymers
WO2005033206A1 (de) * 2003-09-13 2005-04-14 Rehau Ag + Co Polymerzusammensetzung
WO2006004068A1 (ja) 2004-07-02 2006-01-12 Riken メタロセン錯体を含む重合触媒組成物、およびそれを用いて製造される重合体
US7863343B2 (en) * 2005-01-25 2011-01-04 Jsp Corporation Expandable polylactic acid resin particles, expanded polylactic acid resin beads and molded article obtained from expanded polylactic acid resin beads
EP1777239B1 (en) 2005-10-19 2014-09-10 LG Chem Ltd. Half-metallocene catalyst and process for preparing syndiotactic styrene polymer using the same
US7592404B2 (en) * 2005-11-08 2009-09-22 Lg Chem, Ltd. Half metallocene catalyst and process for preparing syndiotactic styren polymer using the same
KR101821408B1 (ko) 2008-03-26 2018-01-23 데이진 가부시키가이샤 고체 고분자형 연료 전지의 전해질막 보강용 필름
JP5801532B2 (ja) 2009-11-30 2015-10-28 帝人株式会社 高絶縁性フィルム
CN102858877B (zh) 2010-03-08 2015-04-29 宇部兴产株式会社 聚酰胺树脂组合物
WO2012066016A1 (en) 2010-11-18 2012-05-24 Total Petrochemicals Research Feluy Process to make diblock polystyrene materials comprising syndiotactic and atactic blocks.
EP2712883B1 (en) 2011-04-26 2016-02-24 Teijin Limited High-insulating film
KR102001977B1 (ko) * 2012-03-15 2019-07-19 니폰 제온 가부시키가이샤 유기 el 표시 장치
EP2746319B1 (en) 2012-12-21 2015-09-09 Materialise N.V. Method for manufacturing objects by selective sintering
JP6275961B2 (ja) 2013-06-26 2018-02-07 富士フイルム株式会社 光学フィルム及び表示装置
WO2016043124A1 (ja) 2014-09-17 2016-03-24 日本ゼオン株式会社 円偏光板、広帯域λ／４板、及び、有機エレクトロルミネッセンス表示装置
CN118922491A (zh) 2022-03-25 2024-11-08 东洋纺株式会社 间规聚苯乙烯低介电片材成形体
TW202442445A (zh) 2023-04-24 2024-11-01 美商羅傑斯公司 多層導體、其製造方法及包含多層導體之組件

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3414553A (en) * 1955-03-31 1968-12-03 Monsanto Co Polymerization of styrene
BE555268A (https=) * 1956-02-24
GB826483A (en) * 1956-06-14 1960-01-06 Petrochemicals Ltd Improvements in or relating to polymeric compositions
US3049524A (en) * 1958-10-24 1962-08-14 Sun Oil Co Polymerization of styrene
US3069407A (en) * 1960-03-31 1962-12-18 Borden Co Method for preparation of crystalline polystyrene
BE606002A (https=) * 1960-07-11
US3489737A (en) * 1965-09-27 1970-01-13 Montedison Spa Crystalline isotactic copolymers of styrene derivatives prepared with ionic coordination catalysts
US4246134A (en) * 1978-11-27 1981-01-20 Uvarov Boris A Catalyst for di-, oligo-, co- and poly- merization of vinyl monomers
JPS5835602A (ja) * 1981-08-25 1983-03-02 Omron Tateisi Electronics Co プログラマブル・コントロ−ラ
JPS6026011A (ja) * 1983-07-21 1985-02-08 Idemitsu Kosan Co Ltd プロピレン・スチレン共重合体の製造方法
CA1276748C (en) * 1985-07-29 1990-11-20 Michitake Uoi Styrene polymers

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