KR850001145A - 알콜 제조방법 - Google Patents

알콜 제조방법 Download PDF

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Publication number
KR850001145A
KR850001145A KR1019840004110A KR840004110A KR850001145A KR 850001145 A KR850001145 A KR 850001145A KR 1019840004110 A KR1019840004110 A KR 1019840004110A KR 840004110 A KR840004110 A KR 840004110A KR 850001145 A KR850001145 A KR 850001145A
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fifteen
catalyst
fifteenth
copper
carrier
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KR1019840004110A
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KR910006901B1 (ko
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이네껑 에르베
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줴. 마띠유,쥐. 멜로뜨
올리오피나 쏘시에떼 아노뉨
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Publication of KR850001145A publication Critical patent/KR850001145A/ko
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Publication of KR910006901B1 publication Critical patent/KR910006901B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/42—Singly bound oxygen atoms
    • C07D307/44—Furfuryl alcohol

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

Abstract

내용 없음

Description

알콜 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (22)

  1. 약 20 내지 100bar의 수소압력과 150 내지 300℃의 온도와 Cu-Cr 혼합물과 구리부착 담체로 구성되는 촉매의 존재하에서 산, 에스테르 또는 알데히드 작용기를 가지는 딩해수의 탄소원자 화합물을 수소화함으로써 알콜을 제조하는 방법.
  2. 제1항에 있어서, 약 25 내지 100bar의 수소압력과 150˚ 내지 300℃의 온도에서 Cu-Cr 혼합물과 구리부착 담체로 구성되는 촉매의 존재하에서 당해 지방산 또는 알킬에스테르를 수소화하여 6내지 24 단소원자를 갖는 지방알콜을 제조하는 방법.
  3. 제2항에 있어서, 수소화가 약 30 내지 80bar의 수소압력하에 수행되는 방법.
  4. 제1항에 있어서, 20 내지 35bar의 수소압력과 150 내지 250℃의 온도에서 Cu-Cr 혼합물과 구리부착 담체로 구성되는 촉매의 존재하에서 푸푸릴 알레히드를 수소화하여 푸푸릴알콜을 제조하는 방법.
  5. 제4항에 있어서, 수소화가 약 170℃ 내지 250℃의 온도에서 수행되는 방법.
  6. 제2항에 있어서, 지방산알킬에스테르의 알킬라디칼이 1내지 25 탄소원자를 포함하는 지방산알킬에스테르의 수소화에 의한 지방알콜의 제조방법.
  7. 제6항에 있어서, 알킬라디칼이 메틸라디칼인 방법.
  8. 제1항에 있어서, 산화물로서 구리의 약 20 내지 40 중량%를 함유하는 구리와 크롬의 혼합물을 일차성분으로서 약 5 내지 45중량%에 해당하는 양의 구리 부착담체를 이차성분으로서 함유하는 촉매의 존재하에서 수소화를 수행하는 알콜의 제조방법.
  9. 제8항에 있어서, 촉매의 일차성분이 구리의 약 30 내지 40중량%를 함유하는 방법.
  10. 제8항에 있어서, 촉매의 이차성분이 구리의 약 20 내지 40중량%를 함유하는 방법.
  11. 제8항에 있어서, 촉매의 일차성분이 환원매질에서 제조되는 방법.
  12. 제11항에 있어서, 포름알데히드가 환원매질로 사용되는 방법.
  13. 제12항에 있어서, 촉매의 이차성분의 구리가 담체상의 분무로 부착되는 방법.
  14. 제8항에 있어서, 구리가 부착된 담체가 알카리금속 실리케이트인 방법.
  15. 제8항에 있어서, 구리가 부착된 담체가 알카리금속 알루미네이트인 방법.
  16. 제1항에 있어서, Cu-Cr 혼합물/담체상의 Cu의 중량비율이 약1:15 내지 1:0.75를 포함하는 촉매 존재하에서 지방산 또는 지방산 알킬에스테르의 수소화가 수행되는 방법.
  17. 제4항에 있어서, Cu-Cr 혼합물/담체상의 Cu의 중량비율이 1:0.2 내지 1:0.4를 포함하는 촉매 존재하에서 푸푸알데히드의 수소화가 수행되는 방법.
  18. 제1항에 있어서, 공급원료의 중량을 기준하여 약 0.1내지 5중량%에 해당하는 양으로 Cu-Cr 혼합물/담체상의 Cu의 촉매존재하에 수소화가 베취내에서 수행되는 방법.
  19. 제18항에 있어서, 촉매의 양이 공급원료를 기준하여 0.2 내지 1중량%로 함유되는 방법.
  20. 제1항에 있어서, 약0.1 내지 5의 LHSV에서 수소화가 연속 수행되는 방법.
  21. 제1,2,3,6,7,8,9,10,11,12,13,14,15,16,18,19,20항에서, 설명된 방법에 의해 제조되는 방법.
  22. 제1,4,5,8,9,10,11,12,13,14,15,17,18,19,20항에서 설명한 방법에 의해 제조되는 푸푸릴 알콜.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019840004110A 1983-07-14 1984-07-13 알콜의 제조방법 KR910006901B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
LU84912 1983-07-14
LU84912A LU84912A1 (fr) 1983-07-14 1983-07-14 Procede de production d'alcools

Publications (2)

Publication Number Publication Date
KR850001145A true KR850001145A (ko) 1985-03-16
KR910006901B1 KR910006901B1 (ko) 1991-09-10

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KR1019840004110A KR910006901B1 (ko) 1983-07-14 1984-07-13 알콜의 제조방법

Country Status (29)

Country Link
US (1) US4728671A (ko)
JP (1) JPS6038333A (ko)
KR (1) KR910006901B1 (ko)
AT (1) AT392065B (ko)
AU (1) AU566386B2 (ko)
BE (1) BE900118A (ko)
CA (1) CA1253512A (ko)
CZ (1) CZ278546B6 (ko)
DE (1) DE3425758C2 (ko)
DK (1) DK344284A (ko)
ES (1) ES8505913A1 (ko)
FR (1) FR2549056B1 (ko)
GB (1) GB2143524B (ko)
IE (1) IE57806B1 (ko)
IN (1) IN162883B (ko)
IT (1) IT1175574B (ko)
LU (1) LU84912A1 (ko)
MY (1) MY102507A (ko)
NL (1) NL8402172A (ko)
NO (1) NO157860C (ko)
NZ (1) NZ208904A (ko)
OA (1) OA07747A (ko)
PH (1) PH19887A (ko)
PL (1) PL143373B1 (ko)
PT (1) PT78904B (ko)
RO (1) RO89344A (ko)
SE (1) SE457080B (ko)
SU (2) SU1405698A3 (ko)
TR (1) TR21940A (ko)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3706658A1 (de) * 1987-03-02 1988-09-15 Henkel Kgaa Saeureresistenter katalysator fuer die fettsaeuredirekthydrierung zu fettalkoholen
DE3724254A1 (de) * 1987-07-22 1989-02-02 Henkel Kgaa Verfahren zur hydrierung von fettsaeuremethylestern im druckbereich von 20 bis 100 bar
WO1994006738A1 (en) * 1992-09-14 1994-03-31 Unichema Chemie B.V. Process for the production of alcohols
US5463143A (en) * 1994-11-07 1995-10-31 Shell Oil Company Process for the direct hydrogenation of wax esters
US5475160A (en) * 1994-11-07 1995-12-12 Shell Oil Company Process for the direct hydrogenation of triglycerides
US5475159A (en) * 1994-11-07 1995-12-12 Shell Oil Company Process for the direct hydrogenation of methyl esters
CN1051030C (zh) * 1995-01-16 2000-04-05 中国科学院山西煤炭化学研究所 相转移制由甲酸甲酯合成甲醇铜－铬催化剂的方法
EP0833808B1 (en) * 1995-06-20 2000-05-03 Kao Corporation Method for producing alcohol
US5536889A (en) * 1995-09-29 1996-07-16 Shell Oil Company Process for the two-stage hydrogenation of methyl esters
CN100438976C (zh) * 2005-12-07 2008-12-03 南化集团研究院 用于糠醛气相加氢制糠醇的催化剂及其制备方法
US7994347B2 (en) 2006-06-09 2011-08-09 Battelle Memorial Institute Hydroxymethylfurfural reduction methods and methods of producing furandimethanol
DE102008008872B4 (de) 2008-02-13 2010-04-29 Lurgi Gmbh Verfahren zum Herstellen von Fettalkoholen
DE102011012177A1 (de) 2011-02-23 2012-08-23 Lurgi Gmbh Verfahren zum Gewinnen von Fettalkoholen aus Abfallfetten oder Abfallölen
CN109328108A (zh) 2016-05-31 2019-02-12 Ptt全球化学股份有限公司 用于由糠醛制备糠醇的铜铝氧化物催化剂以及所述催化剂的制备

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DE639527C (de) * 1930-01-27 1936-12-07 Boehme Fettchemie Ges M B H Verfahren zur Herstellung hoeherer aliphatischer Alkohole
GB358869A (en) * 1930-07-18 1931-10-15 Bohme H Th Ag Process for the production of higher aliphatic alcohols
FR942332A (fr) * 1946-02-26 1949-02-04 Ici Ltd Fabrication d'alcool furfurylique
CH279628A (de) * 1949-02-21 1951-12-15 Ici Ltd Verfahren zur Herstellung von Furfurylalkohol.
US3180898A (en) * 1961-04-17 1965-04-27 Metallgesellschaft Ag Process for the production of fatty alcohols by catalytic hydrogenation of fatty acids and their derivatives
US3886219A (en) * 1969-01-14 1975-05-27 Huels Chemische Werke Ag Process for preparing saturated alcohols
JPS5343918B2 (ko) * 1973-02-02 1978-11-24
PL92724B1 (ko) * 1974-06-19 1977-04-30
US4112245A (en) * 1976-08-18 1978-09-05 Atlantic Richfield Company Process for the preparation of ethylene glycol
US4302397A (en) * 1979-02-26 1981-11-24 Ashland Oil, Inc. Preparation of furfuryl alcohol from furfural

Also Published As

Publication number Publication date
DE3425758C2 (de) 1994-06-23
DE3425758A1 (de) 1985-01-24
GB8416573D0 (en) 1984-08-01
NO157860B (no) 1988-02-22
ES534302A0 (es) 1985-07-01
PL143373B1 (en) 1988-02-29
DK344284D0 (da) 1984-07-13
GB2143524A (en) 1985-02-13
PL248689A1 (en) 1985-03-26
ES8505913A1 (es) 1985-07-01
PT78904A (en) 1984-08-01
SE8403636D0 (sv) 1984-07-09
BE900118A (fr) 1985-01-09
RO89344A (ro) 1986-05-30
MY102507A (en) 1992-07-31
GB2143524B (en) 1986-10-22
IT8421885A1 (it) 1986-01-13
LU84912A1 (fr) 1985-04-17
SE8403636L (sv) 1985-01-15
DK344284A (da) 1985-01-15
SU1517761A3 (ru) 1989-10-23
JPH0472810B2 (ko) 1992-11-19
SU1405698A3 (ru) 1988-06-23
PH19887A (en) 1986-08-13
NZ208904A (en) 1987-02-20
OA07747A (fr) 1985-08-30
AU566386B2 (en) 1987-10-15
AT392065B (de) 1991-01-25
CZ278546B6 (en) 1994-03-16
IT8421885A0 (it) 1984-07-13
NO842868L (no) 1985-01-15
NO157860C (no) 1988-06-01
ATA224084A (de) 1990-07-15
PT78904B (en) 1986-06-02
JPS6038333A (ja) 1985-02-27
IN162883B (ko) 1988-07-16
AU3001784A (en) 1985-01-17
US4728671A (en) 1988-03-01
IE57806B1 (en) 1993-04-21
FR2549056A1 (fr) 1985-01-18
CA1253512A (en) 1989-05-02
SE457080B (sv) 1988-11-28
IT1175574B (it) 1987-07-01
FR2549056B1 (fr) 1985-11-15
NL8402172A (nl) 1985-02-01
KR910006901B1 (ko) 1991-09-10
CZ541384A3 (en) 1994-01-19
IE841786L (en) 1985-01-14
TR21940A (tr) 1985-11-28

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