KR830002698A - 제초제 및 화학중간체 제조방법 - Google Patents

제초제 및 화학중간체 제조방법 Download PDF

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KR830002698A
KR830002698A KR1019800001833A KR800001833A KR830002698A KR 830002698 A KR830002698 A KR 830002698A KR 1019800001833 A KR1019800001833 A KR 1019800001833A KR 800001833 A KR800001833 A KR 800001833A KR 830002698 A KR830002698 A KR 830002698A
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키이스 크라스 데니스
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로오즈 엠 페코라
피이 피이 지이 인더스트리이즈 인코포레이팃드
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Abstract

내용 없음

Description

제초제 및 화학중간체 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (46)

  1. (1)화학식(Ⅲ)의 옥심과 화학식 X-CH2(R1)-CO-OR2(R2:알킬기)의 카르복실레이트와 반응시키며, 필요에 따라서는 화학식(Ⅰ)의 화합물(R2:알킬기)을 가수분해시켜 상응하는 화합물(R2:수소)로 전환시키던지, 필요에 따라서는 화학식(Ⅰ)의 화합물(R2:수소)과 가용성 이온 R2을 가지는 염기와 반응시켜 상응하는 염을 제조함을 특징으로 하는 화학실(Ⅰ)을 가지는 화합물 제조방법.
  2. 단, 화학식(Ⅰ)과 화학식(Ⅲ)에 있어서
  3. X : 니트로기 (-NO2), 할로겐 또는 시아노기(-CN),
  4. Y: 수소 또는 염소(Cl)
  5. Z: Y가 염소일때는 염소
  6. Y사 염소 또는 수소일때는 수소
  7. R: 수소 또는 탄수원자수가 3까지인 알킬기.
  8. R1: 수소 또는 메틸기
  9. R2: 수소, 탄소원자수가 10까지인 알킬기 또는 가용성 염이온.
  10. (2) 화학식(Ⅱ)의 화합물(X:수소)를 할로겐화반응 또는 니트로화반응시켜 화학식(Ⅱ)를 가지는 상응하는 화합물(X:할로겐 또는 니트로기)로 제조하여 필요에 따라서는 X를 시아노기로 하는 화합물로 제조하고 화학식(Ⅱ)의 화합물(X:니트로기)을 환원시켜 X를 아미노기로 하는 상응하는 화합물로 제조하여 CuCN으로 처리하여 디아조화반응을 시켜 화학식(Ⅱ)의 화합물을 제조하는 방법.
  11. 단, 화학식(Ⅱ)에 있어서,
  12. X: 니트로기(-NO2), 할로겐 또는 시아노기(-CN),
  13. Y: 수소 또는 염소
  14. Z: ① Y가 염소일때는 염소
  15. ② Y가 염소 또는 수소일 때는 수소
  16. R: 수소 또는 탄소원자수가 3까지인 알킬기.
  17. (3) 청구범위 (2)의 화학식(Ⅱ)을 가지는 화합물과 히드록실아민 또는 산부가염을 반응시킴을 특징으로하는 화학식(Ⅲ)의 화합물 제조방법.
  18. 단, 화학식(Ⅱ)는 청구범위 ②와 같고, 화학식(Ⅲ)에 있어서는
  19. X: 니트로기(-NO2), 할로겐 또는 시아노기(-CN0),
  20. Y: 수소 또는 염소
  21. Z: ① Y가 염소일때는 염소
  22. ② Y가 염소 또는 수소일 때는 수소
  23. R: 수소 또는 탄소원자수가 3까지인 알킬기.
  24. (4) 화학식(Ⅰ), (Ⅱ) 또는 (Ⅲ)을 가지는 최소한 한가지 화합물을 제초유효량 만큼 사용함을 특징으로한 제초 조성물.
  25. 단, 화학식(Ⅰ), (Ⅱ) 또는 (Ⅲ)에 있어서
  26. X : 니트로기 (-NO2), 할로겐 또는 시아노기(-CN),
  27. Y: 수소 또는 염소(Cl)
  28. Z: ① Y가 염소일때는 염소
  29. ② Y사 염소 또는 수소일때는 수소
  30. R: 수소 또는 탄수원자수가 3까지인 알킬기.
  31. R1: 수소 또는 메틸기
  32. R2: 수소, 탄소원자수가 10까지인 알킬기 또는 가용성 염이온.
  33. (5) 화학식(I)을 가지는 화합물을 제초유효량 사용하여 잡초에 접촉시킴을 특징으로 하는 잡초방제방법.
  34. 단, 화학식(Ⅰ)에 있어서
  35. X : 니트로기 (-NO2), 할로겐 또는 시아노기(-CN),
  36. Y: 수소 또는 염소(Cl)
  37. Z: ① Y가 염소일때는 염소
  38. ② Y사 염소 또는 수소일때는 수소
  39. R: 수소 또는 탄수원자수가 3까지인 알킬기.
  40. R1: 수소 또는 메틸기
  41. R2: 수소, 탄소원자수가 10까지인 알킬기 또는 가용성 염이온.
  42. (6) 화학식(I)에 있어서 R을 수소 또는 메틸기로 함을 특징으로 하는 청구범위 1-5항에 기재된 조성물 또는 그의 제조방법.
  43. (7) 화학식(I)에 있어서 R2를 수소, 탄소원자수가 4까지인 알킬기, 나트륨이온, 칼륨이온 또는 암모늄 이온으로 함을 특징으로 하는 청구범위 제 6항에 기재된 조성물 또는 그의 제조방법.
  44. (8) 화학식(I)에 있어서Z를 수소로 하고 Y를 클로로(-Cl )로 함을 특징으로 하는 청구범위 제 1-7항에 기재된 조성물 또는 그의 제조방법.
  45. (9) 화학식(I)을 가지는 화합물로서는 5-(2-클로로-4-트리플루오로메틸페녹시)-2-클로로벤즈알도옥심-0-(아세트산, 메틸에스테르), 5-(2-클로로-4-트리플루오로메틸페녹시)-2-클로로벤즈알도옥심-0-(2-프로피온산, 메틸에스테르), 5-(2-클로로-4-트리플루오로메틸페녹시)-2-클로로아세토페논옥심-0-(아세트산, 메틸에스테르), 5-(2-클로로-4-트리플루오로메틸페녹시)-2-클로로아세토페논옥심-0-(2-프로피온산, 메틸에스테르), 5-(2-클로로-4-트리플루오로메틸페녹시)-2-시아노벤즈알도옥심-0-(아세트산, 메틸에스테르), 5-(2-클로로-4-트리플루오로메틸페녹시)-2-시아노벤즈알도옥심-0-(2-프로피온산, 메틸에스레르), 5-(2-클로로-4-트리플루오로메틸페녹시)-2-시아노아세토페논옥심-0-(아세트산, 메틸에스레르), 5-(2-클로로-4-트리플루오로메틸페녹시)-2-시아노아세토페논옥심-0-(2-프로피온산, 메틸에스레르) 같은 것과 5-(2-클로로-4-트리플루오로메틸페녹시)-2-니트로아세토페논옥심-0-(2-프로피온산) 또는 5-(2-클로로-4-트리플루오로메틸페녹시)-2-니트로아세토페논옥심-o-아세토페논의 나트륨염 ; 칼륨염 또는 암모늄염 같은 가용성염의 형태를 특징으로 하는 청구범위 제 1-5항에 기재된 제조방법 또는 그의 조성물.
  46. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019800001833A 1979-05-11 1980-05-09 옥심 유도체의 제조방법 KR840001968B1 (ko)

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US3804379A 1979-05-11 1979-05-11
US38043 1979-05-11
US136171 1980-04-15
US06/136,171 US4344789A (en) 1979-05-11 1980-04-15 Acids and esters of 5-(2-optionally substituted-4-trifluoromethyl-6-optionally substituted phenoxy)-2-nitro, -halo, or-cyano alpha substituted phenyl carboxy oximes, and method of controlling weeds with them

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DK203980A (da) 1980-11-12
FR2456088B1 (ko) 1983-02-25
EG14625A (en) 1985-03-31
IE800961L (en) 1980-11-11
PL224072A1 (ko) 1981-02-13
DE3017795C2 (ko) 1988-11-24
NL8002681A (nl) 1980-11-13
SU1005656A3 (ru) 1983-03-15
RO79871A (ro) 1983-02-01
FR2456085A1 (fr) 1980-12-05
DE3051060C2 (ko) 1988-08-18
GB2049695A (en) 1980-12-31
AU526031B2 (en) 1982-12-16
IL59958A0 (en) 1980-06-30
HU183134B (en) 1984-04-28
FI71731B (fi) 1986-10-31
FR2456087B1 (ko) 1983-02-25
YU42506B (en) 1988-10-31
GB2049695B (en) 1983-07-20
CH644588A5 (fr) 1984-08-15
FR2456088A1 (fr) 1980-12-05
AU5826880A (en) 1980-11-13
SE8003512L (sv) 1980-11-12
NL181430C (nl) 1987-08-17
AR230986A1 (es) 1984-08-31
FI801303A (fi) 1980-11-12
NO149587C (no) 1984-05-16
ES491327A0 (es) 1981-04-16
BG38333A3 (en) 1985-11-15
NL181430B (nl) 1987-03-16
DD151861A5 (de) 1981-11-11
CA1236851C (en) 1988-05-17
CS221909B2 (en) 1983-04-29
LU82433A1 (fr) 1980-12-16
PT71222A (en) 1980-06-01
CH652385A5 (fr) 1985-11-15
RO79871B (ro) 1983-01-30
BR8002850A (pt) 1980-12-23
FI71731C (fi) 1987-02-09
PL134026B1 (en) 1985-07-31
DE3017795A1 (de) 1980-11-13
ES8104212A1 (es) 1981-04-16
FR2456087A1 (fr) 1980-12-05
GR67695B (ko) 1981-09-07
YU121080A (en) 1983-12-31
KR840001968B1 (ko) 1984-10-26
IT1133087B (it) 1986-07-09
IT8067734A0 (it) 1980-05-09
AT366883B (de) 1982-05-10
NO149587B (no) 1984-02-06
GB2120233A (en) 1983-11-30
IE49793B1 (en) 1985-12-11
ATA248480A (de) 1981-10-15
PH16450A (en) 1983-10-12
GB2120233B (en) 1984-05-02
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US4344789A (en) 1982-08-17
GB8300942D0 (en) 1983-02-16

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