KR20180111853A - 코어-쉘 전극 물질 입자 및 전기 화학 전지에서의 이들의 사용 - Google Patents
코어-쉘 전극 물질 입자 및 전기 화학 전지에서의 이들의 사용 Download PDFInfo
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- KR20180111853A KR20180111853A KR1020187023685A KR20187023685A KR20180111853A KR 20180111853 A KR20180111853 A KR 20180111853A KR 1020187023685 A KR1020187023685 A KR 1020187023685A KR 20187023685 A KR20187023685 A KR 20187023685A KR 20180111853 A KR20180111853 A KR 20180111853A
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- Prior art keywords
- polymer
- monomer
- hydrophobic
- particles
- active material
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- 239000002245 particle Substances 0.000 title claims abstract description 148
- 239000007772 electrode material Substances 0.000 title claims abstract description 41
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- 229920000642 polymer Polymers 0.000 claims abstract description 153
- 238000000034 method Methods 0.000 claims abstract description 131
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- -1 alkyl methacrylates Chemical class 0.000 claims description 50
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 49
- GQHTUMJGOHRCHB-UHFFFAOYSA-N 2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine Chemical group C1CCCCN2CCCN=C21 GQHTUMJGOHRCHB-UHFFFAOYSA-N 0.000 claims description 44
- 229910052748 manganese Inorganic materials 0.000 claims description 42
- 229910052759 nickel Inorganic materials 0.000 claims description 42
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- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 28
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- 238000010526 radical polymerization reaction Methods 0.000 claims description 19
- 238000006116 polymerization reaction Methods 0.000 claims description 18
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims description 17
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 14
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- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
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- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 8
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- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 7
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/003—Titanates
- C01G23/005—Alkali titanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
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- C—CHEMISTRY; METALLURGY
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CN107892090B (zh) * | 2017-11-01 | 2019-05-03 | 浙江时进包装有限公司 | 一种铝箔基复合包装材料及其制备方法 |
DE102018209416A1 (de) | 2018-06-13 | 2019-12-19 | Robert Bosch Gmbh | Verfahren zur Herstellung eines Kompositmaterials |
KR102118468B1 (ko) * | 2018-08-08 | 2020-06-03 | 성균관대학교산학협력단 | 무기 미립자 및 탄소를 포함하는 코어-쉘 구조체 및 이의 제조 방법 |
DE102018221609A1 (de) | 2018-12-13 | 2020-06-18 | Robert Bosch Gmbh | Verfahren zur Herstellung eines Elektrodenfilms für einen Energiespeicher |
CN109728278B (zh) * | 2018-12-29 | 2021-04-20 | 蜂巢能源科技有限公司 | 正极活性材料及其制备方法和锂离子电池 |
WO2021108760A1 (en) * | 2019-11-26 | 2021-06-03 | Virginia Commonwealth University | Slug-flow manufacturing of uniform and controllable microparticles for battery cathodes |
CN111785960B (zh) * | 2020-09-03 | 2020-11-20 | 中南大学 | 五氧化二钒/rGO包覆镍钴锰酸锂正极材料及制备方法 |
CN112259736A (zh) * | 2020-10-27 | 2021-01-22 | 成都新柯力化工科技有限公司 | 一种锂电池缓解胀气的钛酸锂负极及制备方法 |
WO2022126253A1 (fr) * | 2020-12-14 | 2022-06-23 | HYDRO-QUéBEC | Matériaux d'électrode comprenant un oxyde lamellaire de métaux enrobé d'un oxyde de métaux de type tunnel, électrodes les comprenant et leur utilisation en électrochimie |
CN112599755B (zh) * | 2021-01-09 | 2022-05-17 | 福州大学 | 一种硅-二氧化锡链状和枝状核壳结构锂离子电池负极材料及其制备方法 |
CN112844489B (zh) * | 2021-02-02 | 2022-05-13 | 湖北大学 | 一种三相异质结光催化剂及其制备方法和应用、复合光催化剂及其制备方法和应用 |
CN113149143B (zh) * | 2021-02-10 | 2023-01-03 | 中国石油大学(北京) | 基于层级疏水/亲水电极同步除盐和有机物的方法、装置 |
CN113140715B (zh) * | 2021-04-12 | 2022-08-26 | 广东佳纳能源科技有限公司 | 复合正极材料及其制备方法以及锂离子电池 |
CN114094085B (zh) * | 2021-11-24 | 2023-07-21 | 蜂巢能源科技有限公司 | 一种正极材料及其制备方法和应用 |
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WO2010078649A2 (en) * | 2009-01-08 | 2010-07-15 | The University Of Western Ontario | Self-cleaning coatings |
CN102792498B (zh) * | 2010-03-11 | 2015-09-02 | 株式会社Lg化学 | 聚合物-硅复合粒子、其制备方法以及包含所述聚合物-硅复合粒子的负极和锂二次电池 |
JP5717461B2 (ja) | 2011-02-17 | 2015-05-13 | 株式会社東芝 | 電池用電極及びその製造方法、非水電解質電池、電池パック及び活物質 |
JP5985975B2 (ja) * | 2012-02-15 | 2016-09-06 | 日立マクセル株式会社 | リチウムイオン二次電池およびリチウムイオン二次電池用正極活物質の製造方法 |
JP2014099291A (ja) | 2012-11-13 | 2014-05-29 | Kaneka Corp | 負極活物質及びその製造方法並びに非水電解質二次電池 |
CN103474666B (zh) * | 2013-07-23 | 2016-03-02 | 江苏华东锂电技术研究院有限公司 | 锂离子电池负极活性材料的制备方法 |
CN105762334B (zh) | 2014-12-16 | 2018-08-10 | 北京有色金属研究总院 | 适合水性粘结剂体系的纳米磷酸铁锂复合正极材料及其制备方法 |
WO2017111131A1 (ja) | 2015-12-25 | 2017-06-29 | 富士フイルム株式会社 | 全固体二次電池、全固体二次電池用粒子、全固体二次電池用固体電解質組成物および全固体二次電池用電極シートならびにこれらの製造方法 |
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