KR101749431B1 - 디엔계 고무 라텍스의 제조방법 및 이를 포함하는 아크릴로니트릴-부타디엔-스티렌 그라프트 공중합체 - Google Patents

디엔계 고무 라텍스의 제조방법 및 이를 포함하는 아크릴로니트릴-부타디엔-스티렌 그라프트 공중합체 Download PDF

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KR101749431B1
KR101749431B1 KR1020150186080A KR20150186080A KR101749431B1 KR 101749431 B1 KR101749431 B1 KR 101749431B1 KR 1020150186080 A KR1020150186080 A KR 1020150186080A KR 20150186080 A KR20150186080 A KR 20150186080A KR 101749431 B1 KR101749431 B1 KR 101749431B1
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South Korea
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weight
emulsifier
rubber latex
polymerization
diene rubber
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KR1020150186080A
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Korean (ko)
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KR20160078288A (ko
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이진형
김영민
한수정
김유빈
정영환
정선행
석재민
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주식회사 엘지화학
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Priority to JP2017521097A priority Critical patent/JP6398003B2/ja
Priority to PCT/KR2015/014285 priority patent/WO2016105171A1/ko
Priority to US15/519,111 priority patent/US10508159B2/en
Publication of KR20160078288A publication Critical patent/KR20160078288A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00—Gloves
    • A41D19/0055—Plastic or rubber gloves
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/42—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using short-stopping agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0025—Crosslinking or vulcanising agents; including accelerators
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C08L25/12—Copolymers of styrene with unsaturated nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/10—Latex
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
KR1020150186080A 2014-12-24 2015-12-24 디엔계 고무 라텍스의 제조방법 및 이를 포함하는 아크릴로니트릴-부타디엔-스티렌 그라프트 공중합체 KR101749431B1 (ko)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2017521097A JP6398003B2 (ja) 2014-12-24 2015-12-24 ジエン系ゴムラテックスの製造方法、及びこれを含むアクリロニトリル−ブタジエン−スチレングラフト共重合体
PCT/KR2015/014285 WO2016105171A1 (ko) 2014-12-24 2015-12-24 디엔계 고무 라텍스의 제조방법 및 이를 포함하는 아크릴로니트릴-부타디엔-스티렌 그라프트 공중합체
US15/519,111 US10508159B2 (en) 2014-12-24 2015-12-24 Method for preparing diene-based rubber latex and acrylonitrile-butadiene-styrene graft copolymer comprising the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020140187763 2014-12-24
KR20140187763 2014-12-24

Publications (2)

Publication Number Publication Date
KR20160078288A KR20160078288A (ko) 2016-07-04
KR101749431B1 true KR101749431B1 (ko) 2017-06-21

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US (1) US10508159B2 (de)
EP (1) EP3239198B1 (de)
JP (1) JP6398003B2 (de)
KR (1) KR101749431B1 (de)
CN (1) CN107075039B (de)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102049890B1 (ko) * 2016-11-01 2019-11-28 주식회사 엘지화학 충격강도가 향상된 abs계 그라프트 공중합체의 제조방법 및 이를 포함하는 abs계 사출성형품의 제조방법
KR102013184B1 (ko) * 2016-11-01 2019-08-22 주식회사 엘지화학 디엔계 고무 라텍스의 제조방법, 이를 포함하는 abs계 그라프트 공중합체의 제조방법 및 abs계 사출성형품의 제조방법
WO2018084407A1 (ko) * 2016-11-01 2018-05-11 (주) 엘지화학 디엔계 고무 라텍스의 제조방법, 이를 포함하는 abs계 그라프트 공중합체의 제조방법 및 abs계 사출성형품의 제조방법
KR102068166B1 (ko) * 2016-11-04 2020-01-20 주식회사 엘지화학 열가소성 수지의 제조 방법
KR102157627B1 (ko) * 2016-12-22 2020-09-18 주식회사 엘지화학 Abs계 그라프트 공중합체, 이의 제조방법, 이를 포함하여 제조되는 abs계 수지 조성물 및 사출 성형품
KR102146369B1 (ko) * 2017-09-25 2020-08-20 주식회사 엘지화학 그라프트 공중합체의 제조방법, 그라프트 공중합체 및 열가소성 수지 성형품
WO2019059664A1 (ko) * 2017-09-25 2019-03-28 주식회사 엘지화학 그라프트 공중합체의 제조방법, 그라프트 공중합체 및 열가소성 수지 성형품
KR102154046B1 (ko) * 2017-10-26 2020-09-09 주식회사 엘지화학 연속식 중합에 의한 공액디엔계 중합체의 제조방법
KR102354836B1 (ko) * 2018-02-09 2022-01-25 주식회사 엘지화학 공액 디엔계 중합체의 제조방법 및 이를 포함하는 그라프트 공중합체의 제조방법
KR20200077384A (ko) 2018-12-20 2020-06-30 주식회사 엘지화학 디엔계 고무 라텍스, 이의 제조방법 및 이를 포함하는 코어-쉘 구조의 그라프트 공중합체
KR102511428B1 (ko) * 2019-09-20 2023-03-20 주식회사 엘지화학 디엔계 고무질 중합체의 제조방법 및 이를 포함하는 그라프트 중합체의 제조방법
EP4036128A4 (de) * 2019-09-27 2022-11-30 Lg Chem, Ltd. Verfahren zur herstellung von konjugiertem dienbasiertem polymer
WO2022172696A1 (ja) * 2021-02-09 2022-08-18 日本ゼオン株式会社 成形体の製造方法
CN113121740B (zh) * 2021-04-09 2022-11-04 万华化学(四川)有限公司 一种用于制备高白度abs树脂的聚丁二烯胶乳及其制备方法和用途
CN113072660A (zh) * 2021-04-13 2021-07-06 长春工业大学 一种大粒径聚丁二烯胶乳的制备方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH482740A (de) 1964-10-07 1969-12-15 Bayer Ag Verfahren zur Herstellung von thermoplastisch-elastischen Formmassen
JPS581683B2 (ja) * 1978-04-07 1983-01-12 ジェイエスアール株式会社 耐衝撃性樹脂の製造方法
KR920005670B1 (ko) 1989-01-31 1992-07-13 주식회사 럭키 내충격성이 우수한 열가소성 수지 제조에 적합한 고무 라텍스의 제조법
JPH0649147A (ja) * 1992-07-28 1994-02-22 Monsant Kasei Kk 耐衝撃性樹脂の製造法およびその組成物
KR950009734B1 (ko) 1992-10-13 1995-08-26 주식회사미원유화 메틸메타크릴레이트-부타디엔-스티렌 수지용 고무 라텍스의 제조방법
KR950011450B1 (ko) 1992-12-16 1995-10-04 주식회사미원유화 열가소성 수지 조성물 및 그의 제조방법
KR100484720B1 (ko) * 2001-11-20 2005-04-20 주식회사 엘지화학 열가소성 수지 및 그 제조방법
US7812073B2 (en) * 2004-10-12 2010-10-12 China National Petroleum Corporation Preparation method of small particle sized polybutadiene latex used for the production of ABS
CN100526352C (zh) * 2006-08-17 2009-08-12 中国石油天然气集团公司 一种小粒径聚丁二烯胶乳的制备方法
CN100513430C (zh) * 2007-03-28 2009-07-15 北京化工大学 一种用于橡胶增强的核壳型乳胶粒子乳液的制备方法
KR100871318B1 (ko) * 2007-05-29 2008-12-01 이봉규 콘크리트 개질제용 카르복실레이트 스티렌 부타디엔합성라텍스의 제조방법
KR101233587B1 (ko) * 2008-10-06 2013-02-15 주식회사 엘지화학 폴리카보네이트용 코어-쉘 구조의 부타디엔계 충격보강제 및 이를 이용한 열가소성 수지 조성물
KR101288752B1 (ko) * 2009-12-09 2013-07-23 주식회사 엘지화학 고무질 중합체 라텍스, 이의 제조 방법, 이를 포함하는 ａｂｓ 그라프트 공중합체
KR101450379B1 (ko) 2011-11-23 2014-10-14 주식회사 엘지화학 그라프트 공중합체의 제조방법

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JP6398003B2 (ja) 2018-09-26
CN107075039B (zh) 2019-06-21
JP2017538799A (ja) 2017-12-28
CN107075039A (zh) 2017-08-18
US10508159B2 (en) 2019-12-17
KR20160078288A (ko) 2016-07-04
EP3239198A4 (de) 2018-01-03
EP3239198A1 (de) 2017-11-01
US20170226236A1 (en) 2017-08-10
EP3239198B1 (de) 2019-03-06

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