KR101405781B1 - 합금화 용융 아연 도금 강판과 그 제조 방법 - Google Patents
합금화 용융 아연 도금 강판과 그 제조 방법 Download PDFInfo
- Publication number
- KR101405781B1 KR101405781B1 KR1020127010384A KR20127010384A KR101405781B1 KR 101405781 B1 KR101405781 B1 KR 101405781B1 KR 1020127010384 A KR1020127010384 A KR 1020127010384A KR 20127010384 A KR20127010384 A KR 20127010384A KR 101405781 B1 KR101405781 B1 KR 101405781B1
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- KR
- South Korea
- Prior art keywords
- less
- steel sheet
- composite oxide
- galvannealed
- oxide layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910001335 Galvanized steel Inorganic materials 0.000 title claims abstract description 73
- 239000008397 galvanized steel Substances 0.000 title claims abstract description 73
- 238000004519 manufacturing process Methods 0.000 title claims description 18
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 204
- 239000010959 steel Substances 0.000 claims abstract description 204
- 239000011572 manganese Substances 0.000 claims abstract description 164
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- 239000011701 zinc Substances 0.000 claims abstract description 130
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 112
- 238000007747 plating Methods 0.000 claims abstract description 102
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 95
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 87
- 150000001875 compounds Chemical class 0.000 claims abstract description 38
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000012535 impurity Substances 0.000 claims abstract description 14
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000005275 alloying Methods 0.000 claims description 50
- 230000003746 surface roughness Effects 0.000 claims description 49
- 238000000034 method Methods 0.000 claims description 38
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- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical group O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims description 10
- 229910045601 alloy Inorganic materials 0.000 claims description 8
- 239000000956 alloy Substances 0.000 claims description 8
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- 239000011863 silicon-based powder Substances 0.000 claims description 7
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- 239000010410 layer Substances 0.000 description 189
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
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- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 3
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- 241000920033 Eugenes Species 0.000 description 1
- HSNVNALJRSJDHT-UHFFFAOYSA-N P(=O)(=O)[Mo] Chemical compound P(=O)(=O)[Mo] HSNVNALJRSJDHT-UHFFFAOYSA-N 0.000 description 1
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- 229910052788 barium Inorganic materials 0.000 description 1
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- 239000004566 building material Substances 0.000 description 1
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- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- TVZISJTYELEYPI-UHFFFAOYSA-N hypodiphosphoric acid Chemical compound OP(O)(=O)P(O)(O)=O TVZISJTYELEYPI-UHFFFAOYSA-N 0.000 description 1
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- 125000002950 monocyclic group Chemical group 0.000 description 1
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- AMWVZPDSWLOFKA-UHFFFAOYSA-N phosphanylidynemolybdenum Chemical compound [Mo]#P AMWVZPDSWLOFKA-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
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- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
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- 238000005070 sampling Methods 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
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- 238000005204 segregation Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
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- 238000003466 welding Methods 0.000 description 1
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- 229910000859 α-Fe Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C18/00—Alloys based on zinc
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
- B32B15/013—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
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- C23C2/261—After-treatment in a gas atmosphere, e.g. inert or reducing atmosphere
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
- C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/40—Plates; Strips
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/18—Orthophosphates containing manganese cations
- C23C22/182—Orthophosphates containing manganese cations containing also zinc cations
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
- C23C28/321—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal alloy layer
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
- C23C28/345—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
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| Application Number | Priority Date | Filing Date | Title |
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| JP2009245871 | 2009-10-26 | ||
| JPJP-P-2009-245871 | 2009-10-26 | ||
| PCT/JP2010/061797 WO2011052269A1 (ja) | 2009-10-26 | 2010-07-12 | 合金化溶融亜鉛めっき鋼板とその製造方法 |
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| KR20120063530A KR20120063530A (ko) | 2012-06-15 |
| KR101405781B1 true KR101405781B1 (ko) | 2014-06-10 |
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| US (1) | US9133536B2 (enExample) |
| EP (1) | EP2495347B1 (enExample) |
| JP (1) | JP5146607B2 (enExample) |
| KR (1) | KR101405781B1 (enExample) |
| CN (1) | CN102575330B (enExample) |
| BR (1) | BRPI1011499B1 (enExample) |
| CA (1) | CA2775668C (enExample) |
| ES (1) | ES2696550T3 (enExample) |
| IN (1) | IN2012DN02681A (enExample) |
| MX (2) | MX2012004800A (enExample) |
| PL (1) | PL2495347T3 (enExample) |
| WO (1) | WO2011052269A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101665880B1 (ko) * | 2015-07-29 | 2016-10-13 | 주식회사 포스코 | 내식성이 우수한 합금화 아연도금강판 및 제조방법 |
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| ES2698392T3 (es) | 2010-07-09 | 2019-02-04 | Nippon Steel & Sumitomo Metal Corp | Chapa de acero galvanizado |
| WO2013160566A1 (fr) | 2012-04-25 | 2013-10-31 | Arcelormittal Investigacion Y Desarrollo, S.L. | Procédé de réalisation d'une tôle à revêtements znalmg huilés et tôle correspondante. |
| JP6187028B2 (ja) * | 2012-08-22 | 2017-08-30 | 新日鐵住金株式会社 | 生産性とプレス成形性に優れた合金化溶融亜鉛めっき鋼板およびその製造方法 |
| KR101568512B1 (ko) * | 2013-12-24 | 2015-11-11 | 주식회사 포스코 | 도금성이 우수한 용융아연강판의 제조방법 |
| JP5861806B1 (ja) * | 2014-02-20 | 2016-02-16 | 新日鐵住金株式会社 | メッキ鋼材 |
| KR101674771B1 (ko) * | 2014-12-24 | 2016-11-10 | 주식회사 포스코 | 가공성이 우수한 합금화 용융아연도금강판 및 그 제조방법 |
| EP3358041B1 (en) * | 2015-09-29 | 2021-03-24 | Nippon Steel Corporation | Grain-oriented electrical steel sheet and method for producing grain-oriented electrical steel sheet |
| CN108291312B (zh) * | 2015-12-28 | 2020-05-26 | 日本制铁株式会社 | 热浸镀锌钢板及其制造方法 |
| CN106191653A (zh) * | 2016-08-10 | 2016-12-07 | 安徽禹王铸业有限公司 | 一种耐磨耐腐轴承座 |
| CN107394741B (zh) * | 2017-06-29 | 2019-04-05 | 宁波乾豪金属制品有限公司 | 高压线线路导向架 |
| KR102346426B1 (ko) * | 2017-09-15 | 2022-01-04 | 닛폰세이테츠 가부시키가이샤 | 용융 도금 줄무늬 강판과 그의 제조 방법 |
| CN111989419B (zh) * | 2018-04-26 | 2022-09-30 | 日本制铁株式会社 | 热浸镀Sn-Zn系合金镀层钢板及其制造方法 |
| CN109385557A (zh) * | 2018-10-30 | 2019-02-26 | 云南东电线路器材有限公司 | 多元合金、其溶液制备方法以及铁塔塔材表面镀层工艺 |
| DE102019214135A1 (de) * | 2019-09-17 | 2021-03-18 | Thyssenkrupp Steel Europe Ag | Stahlblech mit einer deterministischen Oberflächenstruktur |
| DE102019215051B4 (de) * | 2019-09-30 | 2024-11-21 | Thyssenkrupp Steel Europe Ag | Stahlblech mit einer deterministischen Oberflächenstruktur und Verfahren zur Herstellung des Stahlblechs mit einer deterministischen Oberflächenstruktur |
| DE102020200326A1 (de) | 2020-01-13 | 2021-07-15 | Thyssenkrupp Steel Europe Ag | Verfahren zur Herstellung eines oberflächenveredelten und oberflächenkonditionierten Stahlblechs |
| JP7443635B2 (ja) | 2020-01-31 | 2024-03-06 | 株式会社神戸製鋼所 | ホットスタンプ用亜鉛めっき鋼板、ホットスタンプ部品及びホットスタンプ部品の製造方法 |
| CN112410768B (zh) * | 2020-10-30 | 2023-06-23 | 马鞍山钢铁股份有限公司 | 一种镀锌钢板表面处理剂、表面处理剂的制备方法及自润滑镀锌钢板、钢板的制备方法 |
| CN112522689B (zh) * | 2020-10-30 | 2023-06-23 | 马鞍山钢铁股份有限公司 | 一种合金化镀锌钢板表面处理剂、制备方法及合金化镀锌钢板、热成形零部件 |
| AU2024216754A1 (en) * | 2023-02-09 | 2025-07-17 | Nippon Steel Corporation | Zn-Al-Mg-BASED HOT-DIP PLATED STEEL MEMBER |
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| JP2002105657A (ja) | 2000-09-29 | 2002-04-10 | Kawasaki Steel Corp | プレス成形性および接着性に優れた表面処理鋼板およびその製造方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR101665880B1 (ko) * | 2015-07-29 | 2016-10-13 | 주식회사 포스코 | 내식성이 우수한 합금화 아연도금강판 및 제조방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| PL2495347T3 (pl) | 2019-05-31 |
| WO2011052269A1 (ja) | 2011-05-05 |
| CA2775668A1 (en) | 2011-05-05 |
| MX2012004800A (es) | 2012-06-08 |
| MX387392B (es) | 2025-03-18 |
| IN2012DN02681A (enExample) | 2015-09-04 |
| EP2495347A4 (en) | 2016-10-26 |
| ES2696550T3 (es) | 2019-01-16 |
| BRPI1011499B1 (pt) | 2020-05-19 |
| KR20120063530A (ko) | 2012-06-15 |
| CA2775668C (en) | 2013-09-17 |
| JP5146607B2 (ja) | 2013-02-20 |
| US20120211123A1 (en) | 2012-08-23 |
| CN102575330B (zh) | 2014-05-28 |
| CN102575330A (zh) | 2012-07-11 |
| EP2495347A1 (en) | 2012-09-05 |
| JPWO2011052269A1 (ja) | 2013-03-14 |
| BRPI1011499A2 (pt) | 2016-03-22 |
| EP2495347B1 (en) | 2018-10-10 |
| US9133536B2 (en) | 2015-09-15 |
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