KR101347005B1 - 리튬 이온 배터리용 합금 조성물 - Google Patents
리튬 이온 배터리용 합금 조성물 Download PDFInfo
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- KR101347005B1 KR101347005B1 KR1020087002053A KR20087002053A KR101347005B1 KR 101347005 B1 KR101347005 B1 KR 101347005B1 KR 1020087002053 A KR1020087002053 A KR 1020087002053A KR 20087002053 A KR20087002053 A KR 20087002053A KR 101347005 B1 KR101347005 B1 KR 101347005B1
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- 239000000203 mixture Substances 0.000 title claims abstract description 140
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 130
- 239000000956 alloy Substances 0.000 title claims abstract description 130
- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 36
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 32
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 55
- 229910052718 tin Inorganic materials 0.000 claims abstract description 53
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- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims abstract description 48
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- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 13
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- 229910018077 Li 15 Si 4 Inorganic materials 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
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- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 3
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M4/02—Electrodes composed of, or comprising, active material
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/40—Alloys based on alkali metals
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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| US11/387,219 | 2006-03-23 | ||
| PCT/US2006/028336 WO2007014016A1 (en) | 2005-07-25 | 2006-07-21 | Alloy composition for lithium ion batteries |
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Families Citing this family (59)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN100517856C (zh) * | 2004-04-01 | 2009-07-22 | 3M创新有限公司 | 用于可再充电锂离子电池中过放电保护的氧化还原对 |
| WO2005099024A2 (en) * | 2004-04-01 | 2005-10-20 | 3M Innovative Properties Company | Redox shuttle for rechargeable lithium-ion cell |
| US7851085B2 (en) * | 2005-07-25 | 2010-12-14 | 3M Innovative Properties Company | Alloy compositions for lithium ion batteries |
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| US7906238B2 (en) * | 2005-12-23 | 2011-03-15 | 3M Innovative Properties Company | Silicon-containing alloys useful as electrodes for lithium-ion batteries |
| US7875388B2 (en) * | 2007-02-06 | 2011-01-25 | 3M Innovative Properties Company | Electrodes including polyacrylate binders and methods of making and using the same |
| US20080206641A1 (en) * | 2007-02-27 | 2008-08-28 | 3M Innovative Properties Company | Electrode compositions and electrodes made therefrom |
| US20080206631A1 (en) * | 2007-02-27 | 2008-08-28 | 3M Innovative Properties Company | Electrolytes, electrode compositions and electrochemical cells made therefrom |
| US20080248386A1 (en) * | 2007-04-05 | 2008-10-09 | Obrovac Mark N | Electrodes with raised patterns |
| JP5932220B2 (ja) * | 2008-02-12 | 2016-06-08 | スリーエム イノベイティブ プロパティズ カンパニー | 高電圧用カソードのためのレドックスシャトル |
| US8277974B2 (en) * | 2008-04-25 | 2012-10-02 | Envia Systems, Inc. | High energy lithium ion batteries with particular negative electrode compositions |
| US20100028784A1 (en) * | 2008-07-29 | 2010-02-04 | 3M Innovative Properties Company | Electrolyte composition, lithium-containing electrochemical cell, battery pack, and device including the same |
| US9012073B2 (en) * | 2008-11-11 | 2015-04-21 | Envia Systems, Inc. | Composite compositions, negative electrodes with composite compositions and corresponding batteries |
| US20100288077A1 (en) | 2009-05-14 | 2010-11-18 | 3M Innovative Properties Company | Method of making an alloy |
| US8287772B2 (en) * | 2009-05-14 | 2012-10-16 | 3M Innovative Properties Company | Low energy milling method, low crystallinity alloy, and negative electrode composition |
| EP2441106A4 (en) * | 2009-06-09 | 2014-06-11 | 3M Innovative Properties Co | THIN-FILM ALLOY ELECTRODES |
| US8257864B2 (en) | 2009-06-29 | 2012-09-04 | 3M Innovative Properties Company | Method of making tin-based alloys for negative electrode compositions |
| WO2011024909A1 (ja) * | 2009-08-28 | 2011-03-03 | 古河電気工業株式会社 | スパッタリングターゲット用銅材料およびその製造方法 |
| US8137841B2 (en) * | 2009-08-31 | 2012-03-20 | 3M Innovative Properties Company | Cathode compositions for lithium-ion electrochemical cells |
| JP5487388B2 (ja) * | 2009-10-02 | 2014-05-07 | 国立大学法人東北大学 | 多結晶繊維状シリコンの製造方法および多結晶繊維状シリコン |
| KR20120128125A (ko) | 2009-11-03 | 2012-11-26 | 엔비아 시스템즈 인코포레이티드 | 리튬 이온 전지용 고용량 아노드 물질 |
| US8962188B2 (en) * | 2010-01-07 | 2015-02-24 | Nanotek Instruments, Inc. | Anode compositions for lithium secondary batteries |
| US20110183209A1 (en) * | 2010-01-27 | 2011-07-28 | 3M Innovative Properties Company | High capacity lithium-ion electrochemical cells |
| US20130216910A1 (en) | 2010-11-09 | 2013-08-22 | 3M Innovative Properties Company | High capacity alloy anodes and lithium-ion electrochemical cells containing same |
| US20120127632A1 (en) * | 2010-11-19 | 2012-05-24 | Evans Capacitor Company | Extended life capacitors |
| JP6063397B2 (ja) | 2011-02-18 | 2017-01-18 | スリーエム イノベイティブ プロパティズ カンパニー | 複合粒子、その製造方法、及びそれを含む物品 |
| US9601228B2 (en) | 2011-05-16 | 2017-03-21 | Envia Systems, Inc. | Silicon oxide based high capacity anode materials for lithium ion batteries |
| CN103563155B (zh) | 2011-06-07 | 2017-07-21 | 3M创新有限公司 | 包含碳氟化合物电解质添加剂的锂离子电化学电池 |
| EP2751030B1 (en) | 2011-08-31 | 2017-04-26 | 3M Innovative Properties Company | High capacity positive electrodes for use in lithium-ion electrochemical cells and methods of making the same |
| JP5621753B2 (ja) * | 2011-11-15 | 2014-11-12 | 信越化学工業株式会社 | リチウムイオン電池用負極材 |
| US9139441B2 (en) | 2012-01-19 | 2015-09-22 | Envia Systems, Inc. | Porous silicon based anode material formed using metal reduction |
| US9780358B2 (en) | 2012-05-04 | 2017-10-03 | Zenlabs Energy, Inc. | Battery designs with high capacity anode materials and cathode materials |
| US10553871B2 (en) | 2012-05-04 | 2020-02-04 | Zenlabs Energy, Inc. | Battery cell engineering and design to reach high energy |
| US8673493B2 (en) | 2012-05-29 | 2014-03-18 | Toyota Motor Engineering & Manufacturing North America, Inc. | Indium-tin binary anodes for rechargeable magnesium-ion batteries |
| US8647770B2 (en) | 2012-05-30 | 2014-02-11 | Toyota Motor Engineering & Manufacturing North America, Inc. | Bismuth-tin binary anodes for rechargeable magnesium-ion batteries |
| US20140063219A1 (en) | 2012-08-28 | 2014-03-06 | General Electric Company | System and method including a portable user profile for medical imaging systems |
| JP5831407B2 (ja) * | 2012-09-06 | 2015-12-09 | 信越化学工業株式会社 | リチウムイオン電池用負極材 |
| TW201421771A (zh) * | 2012-11-16 | 2014-06-01 | Quan An Resource Co Ltd | 矽材料之製備方法及其應用 |
| US10020491B2 (en) | 2013-04-16 | 2018-07-10 | Zenlabs Energy, Inc. | Silicon-based active materials for lithium ion batteries and synthesis with solution processing |
| US10886526B2 (en) | 2013-06-13 | 2021-01-05 | Zenlabs Energy, Inc. | Silicon-silicon oxide-carbon composites for lithium battery electrodes and methods for forming the composites |
| US11476494B2 (en) | 2013-08-16 | 2022-10-18 | Zenlabs Energy, Inc. | Lithium ion batteries with high capacity anode active material and good cycling for consumer electronics |
| TWI689127B (zh) | 2014-12-01 | 2020-03-21 | 英商強生麥特公司 | 用於鋰離子電池組的陽極材料以及製造與使用其之方法 |
| CN104835652A (zh) * | 2015-03-24 | 2015-08-12 | 中航锂电(洛阳)有限公司 | 锂超级电容电池用嵌锂负极片及制备方法、锂超级电容电池 |
| KR102479726B1 (ko) | 2015-10-22 | 2022-12-21 | 삼성전자주식회사 | 전극 활물질, 이를 포함하는 전극 및 이차전지, 및 상기 전극 활물질의 제조방법 |
| US10707491B2 (en) | 2016-02-10 | 2020-07-07 | Nec Corporation | Binder for secondary battery |
| CN106099079A (zh) * | 2016-08-26 | 2016-11-09 | 宁德时代新能源科技股份有限公司 | 二次电池负极材料,其制备方法及含有该负极材料的电池 |
| US10847780B2 (en) * | 2016-09-16 | 2020-11-24 | Pacesetter, Inc. | Battery electrode and methods of making |
| US11495792B2 (en) * | 2017-02-16 | 2022-11-08 | Global Graphene Group, Inc. | Method of manufacturing a lithium secondary battery having a protected high-capacity anode active material |
| US11742475B2 (en) | 2017-04-03 | 2023-08-29 | Global Graphene Group, Inc. | Encapsulated anode active material particles, lithium secondary batteries containing same, and method of manufacturing |
| KR102488677B1 (ko) * | 2017-05-12 | 2023-01-16 | 주식회사 엘지에너지솔루션 | 리튬 이차전지의 제조방법 |
| KR102617865B1 (ko) * | 2017-05-12 | 2023-12-26 | 주식회사 엘지에너지솔루션 | 리튬 이차전지용 음극의 제조방법 |
| DE102017211086A1 (de) | 2017-06-29 | 2019-01-03 | Sgl Carbon Se | Neuartiges Kompositmaterial |
| US11094925B2 (en) | 2017-12-22 | 2021-08-17 | Zenlabs Energy, Inc. | Electrodes with silicon oxide active materials for lithium ion cells achieving high capacity, high energy density and long cycle life performance |
| US20210126254A1 (en) * | 2018-04-12 | 2021-04-29 | Johnson Matthey Public Limited Company | Anode materials for and methods of making and using same |
| US12218346B2 (en) | 2018-06-21 | 2025-02-04 | Honeycomb Battery Company | Method of extending cycle-life of a lithium metal secondary battery |
| US11223049B2 (en) | 2018-08-24 | 2022-01-11 | Global Graphene Group, Inc. | Method of producing protected particles of cathode active materials for lithium batteries |
| CN110474043B (zh) * | 2019-08-13 | 2022-09-02 | 青岛大学 | 一种锂离子电池的电极材料及其制备方法 |
| TWI713246B (zh) * | 2019-12-27 | 2020-12-11 | 國立臺灣大學 | 鋰離子電池之陽極材料及其製備方法 |
| US11637291B2 (en) | 2020-11-04 | 2023-04-25 | Global Graphene Group, Inc. | Lithium-protecting polymer layer for an anode-less lithium metal secondary battery and manufacturing method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030134198A1 (en) | 2001-09-28 | 2003-07-17 | Kabushiki Kaisha Toshiba | Negative electrode material, negative electrode, nonaqueous electrolyte battery and method of manufacturing a negative electrode material |
| US20040241548A1 (en) | 2003-04-02 | 2004-12-02 | Takayuki Nakamoto | Negative electrode active material and non-aqueous electrolyte rechargeable battery using the same |
| US20040248011A1 (en) | 2003-03-26 | 2004-12-09 | Canon Kabushiki Kaisha | Electrode material for lithium secondary battery, electrode structure comprising the electrode material and secondary battery comprising the electrode structure |
Family Cites Families (62)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2755178A (en) * | 1952-07-30 | 1956-07-17 | Robert T C Rasmussen | Electric smelting process for production of silicon-aluminum alloys |
| JPS6166369A (ja) | 1984-09-08 | 1986-04-05 | Hitachi Maxell Ltd | リチウム二次電池 |
| NO175543C (no) | 1992-11-18 | 1994-10-26 | Elkem As | Silisiumbasert legering, fremgangsmåte til fremstilling av slik legering samt fremgangsmåte for fremstilling av konsoliderte produkter fra silisiumbasert legering |
| US5504128A (en) * | 1993-06-30 | 1996-04-02 | New Japan Chemical Co., Ltd. | Thermoplastic resin composition and a method of molding the same |
| US5536599A (en) * | 1994-05-16 | 1996-07-16 | Eic Laboratories Inc. | Solid polymer electrolyte batteries containing metallocenes |
| JP3493873B2 (ja) * | 1995-04-28 | 2004-02-03 | ソニー株式会社 | 非水電解液二次電池 |
| JP3669024B2 (ja) * | 1995-05-26 | 2005-07-06 | ソニー株式会社 | 非水電解液二次電池 |
| JP3354402B2 (ja) | 1996-08-05 | 2002-12-09 | 日立粉末冶金株式会社 | 耐食性に優れた内燃機関のバルブシート用耐摩耗性焼結合金およびその製造方法 |
| US5858573A (en) * | 1996-08-23 | 1999-01-12 | Eic Laboratories, Inc. | Chemical overcharge protection of lithium and lithium-ion secondary batteries |
| US6506524B1 (en) * | 1996-10-03 | 2003-01-14 | National Research Council Of Canada | Electrolyte comprising fluoro-ethylene carbonate and propylene carbonate, for alkali metal-ion secondary battery |
| JPH10188992A (ja) * | 1996-12-24 | 1998-07-21 | Sony Corp | 非水電解液電池 |
| US5882812A (en) * | 1997-01-14 | 1999-03-16 | Polyplus Battery Company, Inc. | Overcharge protection systems for rechargeable batteries |
| JPH10208741A (ja) | 1997-01-22 | 1998-08-07 | Hitachi Ltd | リチウム二次電池 |
| EP0855752B1 (en) * | 1997-01-28 | 2006-11-29 | Canon Kabushiki Kaisha | Electrode structural body, rechargeable battery provided with said electrode structural body, and process for the production of said electrode structural body and said rechargeable battery |
| EP0883199B1 (en) | 1997-06-03 | 2003-05-07 | Matsushita Electric Industrial Co., Ltd. | Negative electrode materials for non-aqueous electrolyte secondary batteries and said batteries employing the same materials |
| GB9717220D0 (en) * | 1997-08-15 | 1997-10-22 | Aea Technology Plc | Eklectrolyte for a rechargeable cell |
| US6004698A (en) * | 1997-08-21 | 1999-12-21 | The United States Of America As Represented By The United States Department Of Energy | Solid polymer electrolyte electrochemical storage cell containing a redox shuttle additive for overcharge protection |
| US5900385A (en) * | 1997-10-15 | 1999-05-04 | Minnesota Mining And Manufacturing Company | Nickel--containing compounds useful as electrodes and method for preparing same |
| US6045952A (en) * | 1998-03-23 | 2000-04-04 | The United States Of America As Represented By The United States Department Of Energy | Electrochemical storage cell containing a substituted anisole or di-anisole redox shuttle additive for overcharge protection and suitable for use in liquid organic and solid polymer electrolytes |
| US6203944B1 (en) * | 1998-03-26 | 2001-03-20 | 3M Innovative Properties Company | Electrode for a lithium battery |
| US6235427B1 (en) * | 1998-05-13 | 2001-05-22 | Fuji Photo Film Co., Ltd. | Nonaqueous secondary battery containing silicic material |
| KR100366978B1 (ko) | 1998-09-08 | 2003-01-09 | 마츠시타 덴끼 산교 가부시키가이샤 | 비수전해질 이차전지용 음극재료와 그 제조방법 |
| PT1033767E (pt) * | 1998-09-18 | 2010-07-13 | Canon Kk | MATERIAL DE ELECTRODO PARA PËLO NEGATIVO DE CéLULA SECUNDáRIA DE LTIO, ESTRUTURA DE ELéCTRODO QUE UTILIZA O REFERIDO MATERIAL DE ELéCTRODO, CéLULA SECUNDáRIA DE LTIO QUE UTILIZA A REFERIDA ESTRUTURA DE ELéCTRODO, E PROCESSO PARA FABRICAÃO DA REFER |
| JP3620703B2 (ja) * | 1998-09-18 | 2005-02-16 | キヤノン株式会社 | 二次電池用負極電極材、電極構造体、二次電池、及びこれらの製造方法 |
| JP2000113912A (ja) | 1998-10-01 | 2000-04-21 | Alps Electric Co Ltd | 電池の電路遮断機構 |
| DE69938822D1 (de) | 1998-12-02 | 2008-07-10 | Matsushita Electric Industrial Co Ltd | Sekundärzelle mit nichtwässrigem elektrolyten und vefahren zu dessen aufladung |
| ATE430636T1 (de) * | 1998-12-28 | 2009-05-15 | Ultraclad Corp | Verfahren zur herstellung eines silizium/aluminiumsputtertargets |
| JP4457429B2 (ja) * | 1999-03-31 | 2010-04-28 | パナソニック株式会社 | 非水電解質二次電池とその負極 |
| US6428933B1 (en) * | 1999-04-01 | 2002-08-06 | 3M Innovative Properties Company | Lithium ion batteries with improved resistance to sustained self-heating |
| JP2001015102A (ja) | 1999-07-01 | 2001-01-19 | Matsushita Electric Ind Co Ltd | 非水電解質二次電池およびその製造法 |
| JP4147442B2 (ja) * | 1999-09-30 | 2008-09-10 | ソニー株式会社 | 非水電解液型二次電池 |
| WO2001029920A1 (en) | 1999-10-18 | 2001-04-26 | The Regents Of The University Of California | Shutdown and redox shuttle additives for batteries |
| US6664004B2 (en) * | 2000-01-13 | 2003-12-16 | 3M Innovative Properties Company | Electrode compositions having improved cycling behavior |
| US6699336B2 (en) | 2000-01-13 | 2004-03-02 | 3M Innovative Properties Company | Amorphous electrode compositions |
| JP3546798B2 (ja) | 2000-03-09 | 2004-07-28 | 松下電器産業株式会社 | 非水電解質二次電池と該電池用合金およびその製造方法 |
| JP2001332255A (ja) * | 2000-03-16 | 2001-11-30 | Sanyo Electric Co Ltd | リチウム二次電池用負極 |
| JP2001291512A (ja) * | 2000-04-05 | 2001-10-19 | Matsushita Electric Ind Co Ltd | 非水電解質二次電池 |
| JP2001297757A (ja) | 2000-04-14 | 2001-10-26 | Sumitomo Metal Ind Ltd | 非水電解質二次電池用負極材料およびその製造方法 |
| US20020037452A1 (en) | 2000-06-23 | 2002-03-28 | Schmidt David G. | Novel compositions for use in batteries, capacitors, fuel cells and similar devices and for hydrogen production |
| JP3890185B2 (ja) * | 2000-07-27 | 2007-03-07 | 松下電器産業株式会社 | 正極活物質およびこれを含む非水電解質二次電池 |
| JP2002075351A (ja) | 2000-09-04 | 2002-03-15 | Sumitomo Metal Ind Ltd | 非水電解質二次電池負極用合金粉末とその製造方法 |
| US6964828B2 (en) * | 2001-04-27 | 2005-11-15 | 3M Innovative Properties Company | Cathode compositions for lithium-ion batteries |
| US6680145B2 (en) * | 2001-08-07 | 2004-01-20 | 3M Innovative Properties Company | Lithium-ion batteries |
| JP4955193B2 (ja) * | 2001-08-07 | 2012-06-20 | スリーエム イノベイティブ プロパティズ カンパニー | リチウムイオンバッテリー用の改良されたカソード組成物 |
| JP2004006206A (ja) * | 2001-09-28 | 2004-01-08 | Toshiba Corp | 非水電解質電池用負極材料、負極、非水電解質電池及び非水電解質電池用負極材料の製造方法 |
| JP4097127B2 (ja) | 2002-05-24 | 2008-06-11 | 株式会社三徳 | リチウムイオン二次電池用負極材料、その製造法、リチウムイオン二次電池用負極及びリチウムイオン二次電池 |
| US7341804B2 (en) * | 2002-09-20 | 2008-03-11 | 3M Innovative Properties Company | Anode compositions having an elastomeric binder and an adhesion promoter |
| JP2004193005A (ja) | 2002-12-12 | 2004-07-08 | Toshiba Corp | 非水電解質電池用電極材料、電極及び非水電解質電池 |
| US20040121234A1 (en) * | 2002-12-23 | 2004-06-24 | 3M Innovative Properties Company | Cathode composition for rechargeable lithium battery |
| US7169328B2 (en) * | 2003-01-17 | 2007-01-30 | T/J Technologies, Inc. | Multiphase nanocomposite material and method for its manufacture |
| US7556655B2 (en) * | 2003-03-14 | 2009-07-07 | 3M Innovative Properties Company | Method of producing lithium ion cathode materials |
| EP2302720B1 (en) | 2003-03-26 | 2012-06-27 | Canon Kabushiki Kaisha | Electrode material for lithium secondary battery and electrode structure including the same |
| US20050130043A1 (en) | 2003-07-29 | 2005-06-16 | Yuan Gao | Lithium metal dispersion in electrodes |
| US7211237B2 (en) * | 2003-11-26 | 2007-05-01 | 3M Innovative Properties Company | Solid state synthesis of lithium ion battery cathode material |
| KR100953544B1 (ko) * | 2004-01-02 | 2010-04-21 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 금속 합금계 음극, 이의 제조 방법 및이를 포함한 전지 |
| WO2005099024A2 (en) * | 2004-04-01 | 2005-10-20 | 3M Innovative Properties Company | Redox shuttle for rechargeable lithium-ion cell |
| US20060046144A1 (en) | 2004-09-01 | 2006-03-02 | 3M Innovative Properties Company | Anode composition for lithium ion battery |
| WO2006052313A1 (en) * | 2004-11-08 | 2006-05-18 | 3M Innovative Properties Company | Polyimide electrode binders |
| US20060147802A1 (en) * | 2005-01-05 | 2006-07-06 | Kiyotaka Yasuda | Anode for nonaqueous secondary battery, process of producing the anode, and nonaqueous secondary battery |
| US7615317B2 (en) * | 2005-05-17 | 2009-11-10 | 3M Innovative Properties Company | N-oxide redox shuttles for rechargeable lithium-ion cell |
| US7615312B2 (en) * | 2005-05-17 | 2009-11-10 | 3M Innovative Properties Company | Substituted phenothiazine redox shuttles for rechargeable lithium-ion cell |
| US7851085B2 (en) * | 2005-07-25 | 2010-12-14 | 3M Innovative Properties Company | Alloy compositions for lithium ion batteries |
-
2006
- 2006-03-23 US US11/387,219 patent/US7871727B2/en active Active
- 2006-07-21 CN CN2006800273144A patent/CN101233631B/zh active Active
- 2006-07-21 JP JP2008523993A patent/JP5345844B2/ja active Active
- 2006-07-21 WO PCT/US2006/028336 patent/WO2007014016A1/en not_active Ceased
- 2006-07-21 EP EP06788087.2A patent/EP1908138B1/en not_active Not-in-force
- 2006-07-21 KR KR1020087002053A patent/KR101347005B1/ko active Active
- 2006-07-24 TW TW095127004A patent/TWI389370B/zh not_active IP Right Cessation
-
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030134198A1 (en) | 2001-09-28 | 2003-07-17 | Kabushiki Kaisha Toshiba | Negative electrode material, negative electrode, nonaqueous electrolyte battery and method of manufacturing a negative electrode material |
| US20040248011A1 (en) | 2003-03-26 | 2004-12-09 | Canon Kabushiki Kaisha | Electrode material for lithium secondary battery, electrode structure comprising the electrode material and secondary battery comprising the electrode structure |
| US20040241548A1 (en) | 2003-04-02 | 2004-12-02 | Takayuki Nakamoto | Negative electrode active material and non-aqueous electrolyte rechargeable battery using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| TW200711206A (en) | 2007-03-16 |
| CN101233631B (zh) | 2010-10-13 |
| EP1908138B1 (en) | 2015-10-21 |
| US20070020522A1 (en) | 2007-01-25 |
| JP2013065569A (ja) | 2013-04-11 |
| WO2007014016A1 (en) | 2007-02-01 |
| KR20080031322A (ko) | 2008-04-08 |
| US7871727B2 (en) | 2011-01-18 |
| JP5345844B2 (ja) | 2013-11-20 |
| CN101233631A (zh) | 2008-07-30 |
| TWI389370B (zh) | 2013-03-11 |
| EP1908138A1 (en) | 2008-04-09 |
| JP2009503787A (ja) | 2009-01-29 |
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