KR100561580B1 - 산화-환원 개시제 시스템을 가함으로써 액상 시스템 내잔류 단량체를 감소시키는 방법 - Google Patents
산화-환원 개시제 시스템을 가함으로써 액상 시스템 내잔류 단량체를 감소시키는 방법 Download PDFInfo
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- KR100561580B1 KR100561580B1 KR1020007002842A KR20007002842A KR100561580B1 KR 100561580 B1 KR100561580 B1 KR 100561580B1 KR 1020007002842 A KR1020007002842 A KR 1020007002842A KR 20007002842 A KR20007002842 A KR 20007002842A KR 100561580 B1 KR100561580 B1 KR 100561580B1
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- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 3
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- 238000004364 calculation method Methods 0.000 description 2
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- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- 238000011031 large-scale manufacturing process Methods 0.000 description 2
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- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
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- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
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- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 1
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- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000006887 Ullmann reaction Methods 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
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- 150000008064 anhydrides Chemical class 0.000 description 1
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- 230000009286 beneficial effect Effects 0.000 description 1
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- 230000015556 catabolic process Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
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- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
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- 125000002228 disulfide group Chemical group 0.000 description 1
- VFNGKCDDZUSWLR-UHFFFAOYSA-N disulfuric acid Chemical class OS(=O)(=O)OS(O)(=O)=O VFNGKCDDZUSWLR-UHFFFAOYSA-N 0.000 description 1
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
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- 150000002191 fatty alcohols Chemical class 0.000 description 1
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- 150000004688 heptahydrates Chemical class 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- SBGKURINHGJRFN-UHFFFAOYSA-N hydroxymethanesulfinic acid Chemical compound OCS(O)=O SBGKURINHGJRFN-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910000358 iron sulfate Inorganic materials 0.000 description 1
- 229940026239 isoascorbic acid Drugs 0.000 description 1
- FPCCSQOGAWCVBH-UHFFFAOYSA-N ketanserin Chemical compound C1=CC(F)=CC=C1C(=O)C1CCN(CCN2C(C3=CC=CC=C3NC2=O)=O)CC1 FPCCSQOGAWCVBH-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000012821 model calculation Methods 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 239000012257 stirred material Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/001—Removal of residual monomers by physical means
- C08F6/003—Removal of residual monomers by physical means from polymer solutions, suspensions, dispersions or emulsions without recovery of the polymer therefrom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/04—Acids, Metal salts or ammonium salts thereof
- C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/42—Nitriles
- C08F20/44—Acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/006—Removal of residual monomers by chemical reaction, e.g. scavenging
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/919—Catalyst injection technique in addition polymerization processes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19741184A DE19741184A1 (de) | 1997-09-18 | 1997-09-18 | Verfahren zur Verminderung von Restmonomeren in Flüssigsystemen unter Zugabe eines Redoxinitiatorsystems |
| DE19741184.3 | 1997-09-18 | ||
| PCT/EP1998/005927 WO1999014248A1 (de) | 1997-09-18 | 1998-09-17 | Verfahren zur verminderung von restmonomeren in flüssigsystemen unter zugabe eines redoxinitiatorsystems |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20010024093A KR20010024093A (ko) | 2001-03-26 |
| KR100561580B1 true KR100561580B1 (ko) | 2006-03-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| KR1020007002842A Expired - Lifetime KR100561580B1 (ko) | 1997-09-18 | 1998-09-17 | 산화-환원 개시제 시스템을 가함으로써 액상 시스템 내잔류 단량체를 감소시키는 방법 |
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| US (1) | US6462138B1 (https=) |
| EP (1) | EP1021468B1 (https=) |
| JP (1) | JP4824162B2 (https=) |
| KR (1) | KR100561580B1 (https=) |
| CN (1) | CN1113901C (https=) |
| AR (1) | AR018506A1 (https=) |
| AU (1) | AU9626398A (https=) |
| BR (1) | BR9812087A (https=) |
| DE (2) | DE19741184A1 (https=) |
| ID (1) | ID24215A (https=) |
| WO (1) | WO1999014248A1 (https=) |
Families Citing this family (123)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3464135B2 (ja) | 1998-01-30 | 2003-11-05 | 積水化成品工業株式会社 | （メタ）アクリル酸エステル系樹脂中の残存単量体の低減方法 |
| JP3434225B2 (ja) | 1998-11-27 | 2003-08-04 | 三菱レイヨン株式会社 | メタクリル系重合体の製造方法 |
| EP1024152B1 (en) * | 1999-06-18 | 2000-11-15 | National Starch and Chemical Investment Holding Corporation | Removal of volatile organic compounds from polymer latices/dispersions |
| EP1078936B1 (en) * | 1999-08-27 | 2004-11-10 | Rohm And Haas Company | Process for stripping polymer dispersions or solutions |
| DE19942776A1 (de) * | 1999-09-08 | 2001-03-15 | Basf Ag | Verfahren zur Verminderung der Restmonomerenmenge in wäßrigen Polymerisatdispersionen |
| JP4319779B2 (ja) * | 2000-12-15 | 2009-08-26 | 電気化学工業株式会社 | エチレン−酢酸ビニル系共重合体エマルジョンの製造方法及びそのエマルジョン並びに接着剤組成物 |
| DE10107044A1 (de) | 2001-02-13 | 2002-08-14 | Basf Ag | Verfahren zur Überführung wässriger Polymerisatdispersionen von einem Behälter in einen anderen Behälter |
| BR0210232A (pt) * | 2001-06-29 | 2004-04-06 | Dow Global Technologies Inc | Processo para a preparação de um polìmero absorvente de água, polìmero obtido e estrutura absorvente |
| JP4011415B2 (ja) * | 2002-06-20 | 2007-11-21 | 日本ペイント株式会社 | アクリル共重合体の製造方法 |
| DE102005028989A1 (de) * | 2005-06-21 | 2007-01-04 | Basf Ag | Verfahren zur Herstellung einer wässrigen Polymerdispersion |
| US7960477B2 (en) | 2006-12-13 | 2011-06-14 | Basf Se | Polyamides with acrylate rubbers |
| DE102008000269A1 (de) | 2007-02-13 | 2008-10-02 | Basf Se | Wässrige Polymerisatdispersionen |
| WO2008152017A1 (de) | 2007-06-11 | 2008-12-18 | Basf Se | Verfahren zur herstellung einer wässrigen polymerisatdispersion |
| WO2009153162A1 (de) | 2008-06-17 | 2009-12-23 | Basf Se | Verfahren zur herstellung einer wässrigen polymerisatdispersion |
| WO2011009838A2 (de) | 2009-07-22 | 2011-01-27 | Basf Se | Wässrige polymerisatdispersion und deren verwendung als bindemittel für die beschichtung von untergründen |
| CN102597023B (zh) | 2009-09-09 | 2015-09-16 | 巴斯夫欧洲公司 | 制备含水粘合剂分散体的方法 |
| WO2011039177A1 (de) | 2009-10-02 | 2011-04-07 | Basf Se | Gipsbauplatte enthaltend mikroverkapselte latentwärmespeichermaterialien |
| EP2507300A1 (de) | 2009-12-04 | 2012-10-10 | Basf Se | Verfahren zur herstellung einer polymerisatdispersion |
| US20110133110A1 (en) * | 2009-12-04 | 2011-06-09 | Basf Se | Process for producing a polymer dispersion |
| WO2011069891A1 (de) | 2009-12-08 | 2011-06-16 | Basf Se | Verfahren zur herstellung von ladungsstrukturierten beschichtungen |
| CN102666657B (zh) | 2009-12-17 | 2014-09-03 | 巴斯夫欧洲公司 | 水性涂料制剂 |
| US8629207B2 (en) | 2009-12-17 | 2014-01-14 | Basf Se | Aqueous coating formulation |
| JP5755249B2 (ja) | 2010-01-20 | 2015-07-29 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 水性重合体分散液の製造方法 |
| US8722796B2 (en) | 2010-01-20 | 2014-05-13 | Basf Se | Process for preparing an aqueous polymer dispersion |
| DE102011005638A1 (de) | 2010-03-19 | 2011-12-15 | Basf Se | Verfahren zur Herstellung eines Formkörpers aus körnigen und/oder faserförmigen Substraten |
| DE102011079112A1 (de) | 2010-08-09 | 2013-01-03 | Basf Se | Wässrige Beschichtungsformulierung |
| AU2011298374B2 (en) | 2010-09-01 | 2015-04-23 | Basf Se | Aqueous emulsion polymers, production of same and use thereof |
| US8722756B2 (en) | 2010-09-01 | 2014-05-13 | Basf Se | Aqueous emulsion polymers, their preparation and use |
| US8754151B2 (en) | 2010-12-21 | 2014-06-17 | Basf Se | Multistage polymer dispersions, processes for preparing them, and use thereof |
| AU2011347669B2 (en) | 2010-12-21 | 2016-03-17 | Basf Se | Multistage polymer dispersions, method for producing same, and use thereof |
| US20120225978A1 (en) | 2011-03-02 | 2012-09-06 | Basf Se | Aqueous binders for granular and/or fibrous substrates |
| EP2681271B1 (de) | 2011-03-02 | 2018-04-04 | Basf Se | Wässrige bindemittel für körnige und/oder faserförmige substrate |
| TR201904462T4 (tr) | 2011-03-30 | 2019-05-21 | Basf Se | Çok kademeli sulu polimer dispersiyonlarının üretimi için metot ve bunların zeminlerin kaplanması için bağ maddesi olarak kullanımı. |
| CN103582667B (zh) | 2011-04-04 | 2017-03-15 | 巴斯夫欧洲公司 | 用于颗粒状和/或纤维状基底的水性粘合剂 |
| US8877842B2 (en) | 2011-04-04 | 2014-11-04 | Basf Se | Aqueous binders for granular and/or fibrous substrates |
| EP2744837B1 (de) | 2011-08-18 | 2016-06-01 | Basf Se | Verfahren zur herstellung eines wässrigen bindemittelsystems |
| US8957174B2 (en) | 2011-09-28 | 2015-02-17 | Basf Se | Process for preparing an aqueous polymer dispersion |
| AU2012314726B2 (en) | 2011-09-28 | 2015-09-17 | Basf Se | Process for preparing an aqueous polymer dispersion |
| BR112014008235B8 (pt) | 2011-10-24 | 2020-07-14 | Dow Global Technologies Llc | método de redução de toxicidade e/ou odor, e, composição |
| BR112014018874B1 (pt) | 2012-02-08 | 2020-10-20 | Basf Se | dispersão aquosa livre de cimento, processos para preparar uma dispersão aquosa, e uma composição de polímero em pó, composição de polímero em pó, uso de uma dispersão aquosa, formulação aquosa de composições de fixação hidráulicas, e, composição de fixação hidráulica na forma de pó |
| US9023919B2 (en) | 2012-02-14 | 2015-05-05 | Basf Se | Aqueous binder composition |
| JP2015512967A (ja) | 2012-02-14 | 2015-04-30 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 水性バインダー組成物 |
| JP2015527413A (ja) | 2012-05-31 | 2015-09-17 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 結合剤 |
| AU2013273573B2 (en) | 2012-06-05 | 2016-05-26 | Basf Se | Use of multi-stage polymerizate dispersions to coat metal sheets |
| KR20150085525A (ko) | 2012-11-15 | 2015-07-23 | 바스프 에스이 | 색상 보유력을 개선하기 위한, 코팅제에서의 수성 중합체 분산액의 용도 |
| CN105073842A (zh) | 2013-03-18 | 2015-11-18 | 巴斯夫欧洲公司 | 制备可容易地再分散于水中的聚合物粉末的方法 |
| CN103289616B (zh) * | 2013-06-13 | 2015-09-02 | 廊坊三利木业有限公司 | 石材背网胶 |
| CN103555069A (zh) * | 2013-10-21 | 2014-02-05 | 扬州大学 | 一种水性日光荧光颜料色浆的制备方法 |
| CN104693636B (zh) * | 2013-12-06 | 2017-07-14 | 中国石油天然气股份有限公司 | 一种具有提高abs接枝共聚物转化率的聚合方法 |
| CA2937581A1 (en) | 2014-01-22 | 2015-07-30 | Basf Se | Binder composition |
| WO2015150213A1 (de) | 2014-04-04 | 2015-10-08 | Basf Se | Verfahren zur herstellung von formkörpern |
| US10544249B2 (en) | 2014-04-11 | 2020-01-28 | Basf Se | Method for preparing an aqueous polymer dispersion |
| WO2016005468A1 (de) | 2014-07-10 | 2016-01-14 | Basf Se | Verfahren zur herstellung gefrier-auftau-stabiler, waessriger dispersionen |
| DE202014005635U1 (de) | 2014-07-10 | 2014-07-29 | Basf Se | Gefrier-Auftau-stabile, wässrige Dispersion |
| JP2017526768A (ja) | 2014-07-15 | 2017-09-14 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 床材用接着剤のための結合剤 |
| MX2017001518A (es) | 2014-08-01 | 2017-05-08 | Basf Se | Procedimiento para la preparacion y el uso de dispersiones hibridas acuosas de poliuretano-poliacrilato, asi como su uso en agentes de revestimiento. |
| EP3018148B1 (de) | 2014-11-04 | 2017-06-28 | Basf Se | Verfahren zur Herstellung einer wässrigen Polymerdispersion |
| WO2016087240A1 (de) | 2014-12-03 | 2016-06-09 | Basf Se | Bindemittelsystem für hochglänzende anstriche |
| WO2016096816A1 (en) | 2014-12-16 | 2016-06-23 | Basf Se | Novel polymer compositions and use of these polymer compositions as viscosity modifiers |
| AU2016299778A1 (en) | 2015-07-29 | 2018-03-08 | Basf Se | Aqueous dispersion of an oxazoline group-containing polymer |
| JP6869245B2 (ja) | 2015-09-23 | 2021-05-12 | ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆ Ｓｅ | 二成分コーティング組成物 |
| JP2018538384A (ja) | 2015-10-20 | 2018-12-27 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 繊維セメント板を被覆するためのコーティング組成物 |
| US10604608B2 (en) | 2015-11-06 | 2020-03-31 | Basf Se | Method for producing an aqueous binder |
| WO2017081233A1 (de) | 2015-11-13 | 2017-05-18 | Basf Se | Wässrige zusammensetzungen auf basis von polyalkenameren |
| CN108368208A (zh) | 2015-12-11 | 2018-08-03 | 巴斯夫欧洲公司 | 聚合物水分散体的制备方法 |
| WO2017140520A1 (de) | 2016-02-15 | 2017-08-24 | Basf Se | Thermoverformbares polymer/faser-komposit |
| KR101939388B1 (ko) * | 2016-02-24 | 2019-01-16 | 주식회사 엘지화학 | 아크릴산계 중합체의 제조방법 |
| WO2017191167A1 (en) | 2016-05-04 | 2017-11-09 | Basf Se | Process for preparing an aqueous polymer latex |
| EP3263209A1 (en) | 2016-06-30 | 2018-01-03 | Basf Se | Membranes comprising polymeric particle layers |
| BR112018076908A2 (pt) | 2016-07-20 | 2019-04-02 | Basf Se | processo para produzir uma dispersão aquosa de polímero, dispersão aquosa de polímero, polímero em pó, usos de uma dispersão aquosa de polímero e de uma formulação aquosa, e, formulação aquosa. |
| AU2017339556B2 (en) | 2016-10-07 | 2021-09-09 | Basf Se | Latex paint containing titanium dioxide pigment |
| US20190241762A1 (en) | 2016-10-07 | 2019-08-08 | Basf Se | Latex paint containing titanium dioxide pigment |
| CN106905900A (zh) * | 2017-03-06 | 2017-06-30 | 佛山市亿达胶粘制品有限公司 | 一种粘胶剂的制备方法 |
| CN106883326A (zh) * | 2017-03-22 | 2017-06-23 | 美巢集团股份公司 | 一种降低聚醋酸乙烯酯乳液voc含量的方法 |
| WO2019043024A1 (en) | 2017-08-30 | 2019-03-07 | Basf Se | ETHYLENE-BASED POLYMER COMPOSITIONS FOR SOFT ROOF COVERINGS |
| WO2019091889A1 (de) | 2017-11-10 | 2019-05-16 | Basf Se | Wässrige polymerdispersionen |
| EP3713970A1 (en) | 2017-11-20 | 2020-09-30 | Basf Se | Aqueous acrylic polymer latexes and their use as binders |
| WO2019145265A1 (en) | 2018-01-23 | 2019-08-01 | Basf Se | Aqueous binder compositions |
| EP3765531B1 (de) | 2018-03-15 | 2024-08-28 | Basf Se | Wässrige bindemittel |
| ES2991465T3 (es) | 2018-07-05 | 2024-12-03 | Basf Se | Procedimiento para producir una dispersión polimérica acuosa |
| WO2020025383A1 (en) | 2018-08-02 | 2020-02-06 | Basf Se | Process for producing an aqueous polymer dispersion |
| EP3833522B1 (de) | 2018-08-10 | 2025-08-20 | Basf Se | Verfahren zur herstellung eines thermoverformbaren polymer/faser-komposits |
| DE102019217820A1 (de) | 2018-11-21 | 2020-05-28 | Basf Se | Verfahren zur Herstellung von Dekorbeschichtungen auf mineralischen Substraten |
| CN118255914A (zh) * | 2019-04-01 | 2024-06-28 | 陶氏东丽株式会社 | 具有碳硅氧烷树枝状大分子结构的共聚物、以及含有该共聚物的组合物、化妆料原料、成膜剂及化妆料 |
| WO2020221605A1 (en) | 2019-05-02 | 2020-11-05 | Basf Se | Aqueous binder composition |
| FI3966260T3 (fi) | 2019-05-08 | 2023-06-21 | Basf Se | Vesipitoinen polymeerilateksi |
| ES3040747T3 (en) | 2019-05-22 | 2025-11-04 | Basf Se | Fibre mouldings |
| CN114127135B (zh) | 2019-07-26 | 2024-05-31 | 巴斯夫欧洲公司 | 制备聚合物水分散体的方法 |
| FR3100249B1 (fr) | 2019-08-28 | 2021-10-29 | Arkema France | Procédé de traitement de dispersions polymères basé sur l’utilisation de peroxydes organiques spécifiques |
| EP4097183B1 (en) | 2020-01-30 | 2025-11-19 | Basf Se | Process of coating wood |
| CN111138599A (zh) * | 2020-02-03 | 2020-05-12 | 山东赛德丽新材料股份有限公司 | 一种耐候型真石漆乳液的制备方法 |
| EP4136130A1 (en) | 2020-04-17 | 2023-02-22 | Basf Se | Aqueous polymer dispersions |
| JP2023532812A (ja) | 2020-07-09 | 2023-07-31 | ベーアーエスエフ・エスエー | 接着剤配合物用の水性ポリマー分散液 |
| CN116134056B (zh) | 2020-07-20 | 2025-02-25 | 巴斯夫欧洲公司 | 适合作为水性涂料组合物中的粘合剂的成膜共聚物的水性聚合物胶乳 |
| ES3018708T3 (en) | 2020-11-26 | 2025-05-19 | Basf Se | Waterbased binder for two-component coating composition |
| EP4251665B1 (en) | 2020-11-30 | 2025-01-08 | Basf Se | Process of producing polymer dispersions |
| EP4255865A1 (en) | 2020-12-02 | 2023-10-11 | Basf Se | Composition for watertight coverings |
| CN112724322B (zh) * | 2020-12-28 | 2022-04-22 | 宜宾海丰和锐有限公司 | 一种pvc树脂的悬浮溶胀接枝改性方法 |
| WO2022161998A1 (en) | 2021-01-26 | 2022-08-04 | Basf Se | Aqueous polymer latex |
| CN117136203A (zh) | 2021-04-01 | 2023-11-28 | 巴斯夫欧洲公司 | 空心聚合物颗粒的水性聚合物分散体 |
| EP4326804A1 (en) | 2021-04-22 | 2024-02-28 | Basf Se | Process for preparing coated shaped bodies and their use |
| WO2023012213A1 (en) | 2021-08-04 | 2023-02-09 | Basf Se | Process for modifying an aqueous polymer latex |
| CN118055984A (zh) | 2021-10-04 | 2024-05-17 | 巴斯夫欧洲公司 | 水性聚合物组合物作为多孔材料的着色剂的用途 |
| WO2023117394A1 (de) | 2021-12-20 | 2023-06-29 | Basf Se | Verfahren zur herstellung eines thermoverformbaren polymer/faser-komposits |
| AU2022422307A1 (en) | 2021-12-23 | 2024-07-04 | Basf Se | Use of polymer dispersions in waterborne coating formulations and polymer dispersions therefor |
| WO2023209082A1 (en) | 2022-04-29 | 2023-11-02 | Basf Se | Combinations of an organic polymer and calcium silicate hydrate for producing mineral water-proofing membranes |
| WO2023232832A1 (en) | 2022-06-01 | 2023-12-07 | Basf Se | Composition for waterproofing membranes |
| CN119947876A (zh) | 2022-09-12 | 2025-05-06 | 巴斯夫欧洲公司 | 用于由有机废料生产水性聚合物分散体的方法 |
| CN120187764A (zh) | 2022-11-18 | 2025-06-20 | 巴斯夫欧洲公司 | 适合作为水性涂料组合物中的粘合剂的成膜共聚物的水性聚合物胶乳 |
| EP4389778A1 (en) | 2022-12-21 | 2024-06-26 | Basf Se | Aqueous polymer dispersion for coating compositions |
| TW202502831A (zh) | 2023-03-24 | 2025-01-16 | 德商巴斯夫歐洲公司 | 適合作為水性塗料組成物中黏合劑的成膜共聚物的水性聚合物膠乳 |
| AU2024256180A1 (en) | 2023-04-20 | 2025-10-30 | Basf Se | Polymer dispersions of polymers p |
| WO2024256160A1 (en) | 2023-06-14 | 2024-12-19 | Basf Se | Compositions for construction purposes |
| TW202509091A (zh) | 2023-08-16 | 2025-03-01 | 德商巴斯夫歐洲公司 | 適合作為水性塗料組成物中之黏合劑之共聚物之含水聚合物乳膠 |
| WO2025078362A1 (en) | 2023-10-09 | 2025-04-17 | Basf Se | Process for the manufacture of styrene acrylic copolymers having a renewably-sourced carbon content |
| WO2025093409A1 (en) | 2023-10-30 | 2025-05-08 | Basf Se | Two-component coating composition |
| WO2025103901A1 (en) | 2023-11-14 | 2025-05-22 | Basf Se | Polymer dispersions for coatings |
| TW202546015A (zh) | 2023-12-13 | 2025-12-01 | 德商巴斯夫歐洲公司 | 適合作為水性塗料組成物中之黏合劑之共聚物之水性聚合物乳膠 |
| WO2025125067A1 (de) | 2023-12-15 | 2025-06-19 | Basf Se | Schnellhärtende, wässrige, intumeszierende brandschutzzusammensetzung mit hoher anwendungsschichtdicke auf oberflächen beliebiger neigung |
| EP4570865A1 (de) | 2023-12-15 | 2025-06-18 | Hilti Aktiengesellschaft | Wässrige brandschutzzusammensetzung mit hoher anwendungsschichtdicke und brandschutzbeschichtung mit verbesserter widerstandsfähigkeit gegen schimmelbildung |
| WO2025132646A1 (en) | 2023-12-19 | 2025-06-26 | Basf Se | Waterborne coating compositions requiring reduced amounts of biocides |
| WO2025252549A1 (en) | 2024-06-07 | 2025-12-11 | Basf Se | Polyamide particle foam moldings with low oil uptake |
| WO2026052438A1 (en) | 2024-09-03 | 2026-03-12 | Basf Se | Two-component coating composition |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4277684A (en) | 1977-08-18 | 1981-07-07 | U.S. Philips Corporation | X-Ray collimator, particularly for use in computerized axial tomography apparatus |
| US4351875A (en) | 1978-09-25 | 1982-09-28 | Rohm And Haas Company | Heteropolymer acrylic latices and textiles treated therewith |
| US4289823A (en) | 1980-09-30 | 1981-09-15 | Rohm And Haas Company | Calenderable acrylic polymers and textiles treated therewith |
| US4529753A (en) | 1984-04-10 | 1985-07-16 | Polysar Limited | Chemical/steam stripping |
| US4966791A (en) | 1986-03-11 | 1990-10-30 | Union Oil Company Of California | Methods for manufacturing textile materials |
| US4908229A (en) | 1986-03-11 | 1990-03-13 | Union Oil Of California | Method for producing an article containing a radiation cross-linked polymer and the article produced thereby |
| US4900615A (en) | 1986-03-11 | 1990-02-13 | Union Oil Company Of California | Textile materials and compositions for use therein |
| US4758641A (en) | 1987-02-24 | 1988-07-19 | The B F Goodrich Company | Polycarboxylic acids with small amount of residual monomer |
| DE3803450A1 (de) | 1988-02-05 | 1989-08-17 | Hoechst Ag | Emissionsarme dispersionsfarben, anstrichmittel und kunststoffdispersionsputze sowie verfahren zu ihrer herstellung |
| US5055510A (en) | 1988-08-31 | 1991-10-08 | Union Oil Company Of California | Extended polymer compositions and textile materials manufactured therewith |
| US5264475A (en) | 1988-08-31 | 1993-11-23 | Rohm And Haas Company | Extended polymer compositions and textile materials manufactured therewith |
| US5270121A (en) | 1988-08-31 | 1993-12-14 | Rohm And Haas Company | Polymer-coated articles |
| US5230950A (en) | 1988-08-31 | 1993-07-27 | Rohm And Haas Company | Extended polymer compositions and textile materials manufactured therewith |
| US5059456A (en) | 1990-05-04 | 1991-10-22 | Rohm And Haas Company | Latex barrier tiecoat for use with mastic coatings |
| US5451432A (en) | 1990-08-31 | 1995-09-19 | Rohm And Haas Company | Treating flexible, porous substrates with formaldehyde free binder |
| DE69124354T3 (de) | 1990-12-21 | 2003-04-24 | Rohm And Haas Co., Philadelphia | Lufthärtende Polymerzusammensetzung |
| US5403894A (en) | 1991-07-11 | 1995-04-04 | Rohm And Haas Company | A redispersible core-shell polymer powder |
| US5430127A (en) | 1993-11-02 | 1995-07-04 | National Starch And Chemical Investment Holding Corporation | Process for minimizing residual monomers |
| JPH07278210A (ja) * | 1994-04-05 | 1995-10-24 | Mitsui Toatsu Chem Inc | エマルションの製造方法 |
| DE4419518A1 (de) | 1994-06-03 | 1995-12-07 | Basf Ag | Verfahren zur Herstellung einer wäßrigen Polymerisatdispersion |
| CN1120180C (zh) * | 1994-06-03 | 2003-09-03 | 巴斯福股份公司 | 聚合物水分散液的制备 |
| DE19529599A1 (de) | 1995-08-11 | 1997-02-13 | Basf Ag | Verfahren zur Herstellung einer wäßrigen Polymerisatdispersion |
| IT1276816B1 (it) | 1995-10-04 | 1997-11-03 | Atochem Elf Italia | Emulsione a basso voc |
| DE19711022A1 (de) | 1997-03-17 | 1998-09-24 | Basf Ag | Verwendung eines Mehrstufenrührers zur Herstellung von Polymerisaten |
-
1997
- 1997-09-18 DE DE19741184A patent/DE19741184A1/de not_active Withdrawn
-
1998
- 1998-09-17 JP JP2000511795A patent/JP4824162B2/ja not_active Expired - Lifetime
- 1998-09-17 KR KR1020007002842A patent/KR100561580B1/ko not_active Expired - Lifetime
- 1998-09-17 BR BR9812087-5A patent/BR9812087A/pt active IP Right Grant
- 1998-09-17 ID IDW20000486A patent/ID24215A/id unknown
- 1998-09-17 CN CN98809280A patent/CN1113901C/zh not_active Expired - Lifetime
- 1998-09-17 US US09/508,089 patent/US6462138B1/en not_active Expired - Lifetime
- 1998-09-17 EP EP98950047A patent/EP1021468B1/de not_active Expired - Lifetime
- 1998-09-17 DE DE59807759T patent/DE59807759D1/de not_active Expired - Lifetime
- 1998-09-17 WO PCT/EP1998/005927 patent/WO1999014248A1/de not_active Ceased
- 1998-09-17 AU AU96263/98A patent/AU9626398A/en not_active Abandoned
- 1998-09-17 AR ARP980104618A patent/AR018506A1/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1270600A (zh) | 2000-10-18 |
| KR20010024093A (ko) | 2001-03-26 |
| ID24215A (id) | 2000-07-13 |
| AU9626398A (en) | 1999-04-05 |
| JP4824162B2 (ja) | 2011-11-30 |
| AR018506A1 (es) | 2001-11-28 |
| EP1021468A1 (de) | 2000-07-26 |
| CN1113901C (zh) | 2003-07-09 |
| BR9812087A (pt) | 2000-09-26 |
| DE19741184A1 (de) | 1999-03-25 |
| EP1021468B1 (de) | 2003-04-02 |
| JP2001516774A (ja) | 2001-10-02 |
| US6462138B1 (en) | 2002-10-08 |
| WO1999014248A1 (de) | 1999-03-25 |
| DE59807759D1 (de) | 2003-05-08 |
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