KR100452673B1 - 에틸렌옥사이드제조용은촉매,그제조방법및에틸렌옥사이드의제조방법 - Google Patents

에틸렌옥사이드제조용은촉매,그제조방법및에틸렌옥사이드의제조방법 Download PDF

Info

Publication number
KR100452673B1
KR100452673B1 KR19980058841A KR19980058841A KR100452673B1 KR 100452673 B1 KR100452673 B1 KR 100452673B1 KR 19980058841 A KR19980058841 A KR 19980058841A KR 19980058841 A KR19980058841 A KR 19980058841A KR 100452673 B1 KR100452673 B1 KR 100452673B1
Authority
KR
South Korea
Prior art keywords
silver
ethylene oxide
catalyst
carrier
producing ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR19980058841A
Other languages
English (en)
Korean (ko)
Other versions
KR19990063490A (ko
Inventor
마사히데 시마
히토시 다카다
Original Assignee
니폰 쇼쿠바이 컴파니 리미티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 니폰 쇼쿠바이 컴파니 리미티드 filed Critical 니폰 쇼쿠바이 컴파니 리미티드
Publication of KR19990063490A publication Critical patent/KR19990063490A/ko
Application granted granted Critical
Publication of KR100452673B1 publication Critical patent/KR100452673B1/ko
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
KR19980058841A 1997-12-25 1998-12-26 에틸렌옥사이드제조용은촉매,그제조방법및에틸렌옥사이드의제조방법 Expired - Fee Related KR100452673B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP35730997 1997-12-25
JP9-357309 1997-12-25

Publications (2)

Publication Number Publication Date
KR19990063490A KR19990063490A (ko) 1999-07-26
KR100452673B1 true KR100452673B1 (ko) 2005-01-31

Family

ID=18453468

Family Applications (1)

Application Number Title Priority Date Filing Date
KR19980058841A Expired - Fee Related KR100452673B1 (ko) 1997-12-25 1998-12-26 에틸렌옥사이드제조용은촉매,그제조방법및에틸렌옥사이드의제조방법

Country Status (12)

Country Link
US (2) US6153556A (enExample)
EP (1) EP0927575B1 (enExample)
KR (1) KR100452673B1 (enExample)
CN (1) CN1117618C (enExample)
AT (1) ATE236721T1 (enExample)
BR (1) BR9807867A (enExample)
CA (1) CA2257039A1 (enExample)
DE (1) DE69813170T2 (enExample)
ID (1) ID21608A (enExample)
IN (1) IN194403B (enExample)
SG (1) SG76583A1 (enExample)
TW (1) TW426545B (enExample)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000015333A1 (en) * 1998-09-14 2000-03-23 Shell Internationale Research Maatschappij B.V. Process for removing ionizable species from catalyst surface to improve catalytic properties
EP1086743B1 (en) * 1999-09-21 2006-08-16 Nippon Shokubai Co., Ltd. Catalyst for production of epoxides and methods for production thereof and epoxides
US6576588B2 (en) * 2000-04-07 2003-06-10 Catalytic Distillation Technologies Process for selective hydrogenation of alkynes and catalyst therefor
US6831037B2 (en) 2002-02-25 2004-12-14 Saint-Gobain Norpro Corporation Catalyst carriers
DE10300526A1 (de) * 2003-01-09 2004-07-22 Hte Ag The High Throughput Experimentation Company Silberhaltige Katalysatoren zur Umsetzung von Substraten mit C-C-Doppelbindungen
JP4870561B2 (ja) * 2003-08-22 2012-02-08 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー アルキレンオキサイドの製造用の改良されたアルミナ担体及び銀系触媒
US7208646B2 (en) * 2004-05-14 2007-04-24 Catalytic Distillation Technologies Selective hydrogenation of butadiene
US20060036105A1 (en) * 2004-08-12 2006-02-16 Shell Oil Company Method of preparing a shaped catalyst, the catalyst, and use of the catalyst
EP1786797B1 (en) * 2004-08-12 2014-11-26 Velocys, Inc. Process for converting ethylene to ethylene oxide using microchannel process technology
US20060173224A1 (en) * 2005-02-01 2006-08-03 Catalytic Distillation Technologies Process and catalyst for selective hydrogenation of dienes and acetylenes
US7759284B2 (en) * 2005-05-09 2010-07-20 Scientific Design Company, Inc. Calcination in an inert gas in the presence of a small concentration of an oxidizing component
WO2006133187A2 (en) * 2005-06-07 2006-12-14 Saint-Gobain Ceramics & Plastics, Inc. A catalyst carrier and a process for preparing the catalyst carrier
RU2007149318A (ru) 2005-06-07 2009-07-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Кктализатор, способ приготовления катализатора и способ получения оксида олефина, 1, 2-диола, эфира 1, 2-диола или алканоламина
WO2007021742A1 (en) * 2005-08-11 2007-02-22 Shell Internationale Research Maatschappij B.V. A method of preparing a shaped catalyst, the catalyst, and use of the catalyst
WO2007129649A1 (ja) * 2006-05-02 2007-11-15 Nippon Shokubai Co., Ltd. オレフィンの部分酸化用触媒、その製造方法およびアルキレンオキサイドの製造方法
US8097557B2 (en) * 2006-08-08 2012-01-17 Sd Lizenverwertungsgesellschaft Mbh & Co. Kg Two-stage calcination for catalyst production
EP2062641A4 (en) * 2006-09-15 2013-07-17 Nippon Catalytic Chem Ind CATALYST FOR THE PREPARATION OF ALKYLENE OXIDES, METHOD FOR THE PRODUCTION OF THE CATALYST AND METHOD FOR THE PRODUCTION OF ALKYLENE OXIDES WITH THE CATALYST
WO2009119416A1 (ja) * 2008-03-26 2009-10-01 株式会社日本触媒 エチレンオキシド製造用触媒および該触媒を用いたエチレンオキシドの製造方法
WO2009134839A1 (en) * 2008-04-30 2009-11-05 Dow Technology Investments, Llc Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same
US20110059843A1 (en) * 2008-04-30 2011-03-10 Howard Kevin E Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same
WO2009134843A1 (en) * 2008-04-30 2009-11-05 Dow Technology Investments, Llc Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same
CN102099346A (zh) * 2008-07-14 2011-06-15 巴斯夫欧洲公司 制备环氧乙烷的方法
US8349765B2 (en) * 2008-07-18 2013-01-08 Scientific Design Company, Inc. Mullite-containing carrier for ethylene oxide catalysts
US8524927B2 (en) * 2009-07-13 2013-09-03 Velocys, Inc. Process for making ethylene oxide using microchannel process technology
US8883678B2 (en) 2010-06-04 2014-11-11 Scientific Design Company, Inc. Carrier for ethylene oxide catalysts
US8586769B2 (en) * 2010-06-04 2013-11-19 Scientific Design Company, Inc. Carrier for ethylene oxide catalysts
CN104707664B (zh) * 2013-12-13 2017-11-07 中国石油化工股份有限公司 一种用于银催化剂的α‑氧化铝载体的制备方法
US8975424B1 (en) * 2013-12-30 2015-03-10 Scientific Design Company, Inc. Zinc-promoted catalysts for epoxidation of ethylene
CN111068714B (zh) * 2019-12-16 2021-05-04 北京化工大学 一种负载型银基多组分纳米催化剂的制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55145677A (en) * 1979-05-02 1980-11-13 Mitsubishi Petrochem Co Ltd Preparation of ethylene oxide
KR830001028A (ko) * 1978-12-20 1983-04-29 리차아드 버언즈 메그리 입상 플라스틱 및 중합체 가공방법 및 장치
US4410453A (en) * 1980-08-25 1983-10-18 Norton Co. Ethylene oxide catalyst

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2294383A (en) * 1942-09-01 Process for the preparation of
GB1491447A (en) * 1973-12-05 1977-11-09 Ici Ltd Alkylene oxide production and catalysts therefor
FR2412538A1 (fr) * 1977-12-22 1979-07-20 Ugine Kuhlmann Catalyseurs a base d'argent pour la production d'oxyde d'ethylene
BG37835A3 (en) * 1982-06-30 1985-08-15 Hoechst Aktiengesellschaft Method for preparing silver catalyst
US4575494A (en) * 1984-02-08 1986-03-11 The Dow Chemical Company Alumina compositions useful as catalyst supports for ethylene oxidation
AU586048B2 (en) * 1985-11-12 1989-06-29 Nippon Shokubai Kagaku Kogyo Co. Ltd. Silver catalyst for production of ethylene oxide and method for manufacture thereof
FR2597098B1 (fr) * 1986-04-11 1989-01-13 Atochem Catalyseurs a base d'argent pour la fabrication d'oxyde d'ethylene
GB8610441D0 (en) * 1986-04-29 1986-06-04 Shell Int Research Preparation of silver-containing catalyst
JP2561678B2 (ja) * 1987-11-06 1996-12-11 三菱化学株式会社 エチレンオキシド製造用銀触媒
JP2637537B2 (ja) * 1989-01-24 1997-08-06 株式会社日本触媒 エチレンオキシド製造用銀触媒およびその製造方法
CA1337722C (en) * 1989-04-18 1995-12-12 Madan Mohan Bhasin Alkylene oxide catalysts having enhanced activity and/or stability
JP3312916B2 (ja) * 1991-06-06 2002-08-12 三菱化学株式会社 酸化エチレン製造用銀触媒
CA2089510C (en) * 1992-02-27 1998-09-01 Shinichi Nagase Silver catalyst for production of ethylene oxide and method for production of the catalyst
US5380697A (en) * 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
US5504052A (en) * 1994-12-02 1996-04-02 Scientific Design Company, Inc. Silver catalyst preparation
US5611829A (en) * 1995-06-20 1997-03-18 Minnesota Mining And Manufacturing Company Alpha alumina-based abrasive grain containing silica and iron oxide

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR830001028A (ko) * 1978-12-20 1983-04-29 리차아드 버언즈 메그리 입상 플라스틱 및 중합체 가공방법 및 장치
JPS55145677A (en) * 1979-05-02 1980-11-13 Mitsubishi Petrochem Co Ltd Preparation of ethylene oxide
US4410453A (en) * 1980-08-25 1983-10-18 Norton Co. Ethylene oxide catalyst

Also Published As

Publication number Publication date
CN1117618C (zh) 2003-08-13
DE69813170D1 (de) 2003-05-15
ID21608A (id) 1999-07-01
ATE236721T1 (de) 2003-04-15
IN194403B (enExample) 2004-10-30
EP0927575A1 (en) 1999-07-07
KR19990063490A (ko) 1999-07-26
BR9807867A (pt) 2000-08-15
EP0927575B1 (en) 2003-04-09
SG76583A1 (en) 2000-11-21
US6153556A (en) 2000-11-28
TW426545B (en) 2001-03-21
US6281370B1 (en) 2001-08-28
CN1223900A (zh) 1999-07-28
CA2257039A1 (en) 1999-06-25
DE69813170T2 (de) 2003-12-18

Similar Documents

Publication Publication Date Title
KR100452673B1 (ko) 에틸렌옥사이드제조용은촉매,그제조방법및에틸렌옥사이드의제조방법
AU754631B2 (en) Carrier for catalyst for use in production of ethylene oxide, catalyst for use in production of ethylene oxide, and method for production of ethylene oxide
CA2171213C (en) Epoxidation catalyst and process
JP3302387B2 (ja) 酸化エチレン触媒および方法
US6103916A (en) Silver catalyst for production of ethylene oxide, method for production thereof, and method for production of ethylene oxide
KR101711108B1 (ko) 쌍봉 분포의 기공 크기 분포를 가지는 촉매 및 그의 용도
US5063195A (en) High efficiency silver catalyst for the production of ethylene oxide via ethylene oxidation
EP0496386B1 (en) Catalyst carrier, composition and process for making same
RU2495715C2 (ru) Носитель, содержащий муллит, для катализаторов для получения этиленоксида
JP5232642B2 (ja) 触媒担体およびその触媒担体の調製方法
CA2697818C (en) Process for the epoxidation of an olefin using a supported catalyst
JP2637537B2 (ja) エチレンオキシド製造用銀触媒およびその製造方法
US5177260A (en) Method for production of acrylic acid
KR101861259B1 (ko) 에틸렌 옥사이드 촉매용 담체
US20030092922A1 (en) Catalyst for production of ethylene oxide, method for production thereof, and method for production of ethylene oxide by the use of the catalyst
KR20100061698A (ko) 산화올레핀 촉매용 담체
US4417000A (en) Dimethyl ether process
JP3313164B2 (ja) エチレンオキシド製造用銀触媒およびその製造方法
RU2169040C2 (ru) Серебряный катализатор для получения оксида этилена, способ его приготовления и способ получения оксида этилена
JP3636912B2 (ja) エチレンオキシド製造用触媒の製造方法
JP4210255B2 (ja) エチレンオキシド製造用銀触媒およびエチレンオキシドの製造方法
JP2000044331A (ja) α―アルミナ触媒担体、その製造方法、該触媒担体を用いた触媒
JP4588183B2 (ja) セラミックス体、触媒用担体、それらの製造方法、該担体を用いてなる酸化エチレン製造用触媒、その製造方法および酸化エチレンの製造方法
JP4726349B2 (ja) 酸化エチレン製造用触媒、その製造方法および当該触媒による酸化エチレンの製造方法
JP4354060B2 (ja) 酸化エチレン製造用触媒の担体、酸化エチレン製造用触媒および酸化エチレンの製造方法

Legal Events

Date Code Title Description
PA0109 Patent application

St.27 status event code: A-0-1-A10-A12-nap-PA0109

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

A201 Request for examination
P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

D13-X000 Search requested

St.27 status event code: A-1-2-D10-D13-srh-X000

D14-X000 Search report completed

St.27 status event code: A-1-2-D10-D14-srh-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U11-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

FPAY Annual fee payment

Payment date: 20070920

Year of fee payment: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

LAPS Lapse due to unpaid annual fee
PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20081005

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20081005

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000