DE69813170D1 - Silberkatalysator, Verfahren zu dessen Herstellung und Verfahren zur Herstellung von Ethylenoxid - Google Patents

Silberkatalysator, Verfahren zu dessen Herstellung und Verfahren zur Herstellung von Ethylenoxid

Info

Publication number
DE69813170D1
DE69813170D1 DE69813170T DE69813170T DE69813170D1 DE 69813170 D1 DE69813170 D1 DE 69813170D1 DE 69813170 T DE69813170 T DE 69813170T DE 69813170 T DE69813170 T DE 69813170T DE 69813170 D1 DE69813170 D1 DE 69813170D1
Authority
DE
Germany
Prior art keywords
production
elements
ethylene oxide
carrier
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69813170T
Other languages
English (en)
Other versions
DE69813170T2 (de
Inventor
Masahide Shima
Hitoshi Takada
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Shokubai Co Ltd
Original Assignee
Nippon Shokubai Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Shokubai Co Ltd filed Critical Nippon Shokubai Co Ltd
Application granted granted Critical
Publication of DE69813170D1 publication Critical patent/DE69813170D1/de
Publication of DE69813170T2 publication Critical patent/DE69813170T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
DE69813170T 1997-12-25 1998-12-28 Silberkatalysator, Verfahren zu dessen Herstellung und Verfahren zur Herstellung von Ethylenoxid Expired - Fee Related DE69813170T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP35730997 1997-12-25

Publications (2)

Publication Number Publication Date
DE69813170D1 true DE69813170D1 (de) 2003-05-15
DE69813170T2 DE69813170T2 (de) 2003-12-18

Family

ID=18453468

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69813170T Expired - Fee Related DE69813170T2 (de) 1997-12-25 1998-12-28 Silberkatalysator, Verfahren zu dessen Herstellung und Verfahren zur Herstellung von Ethylenoxid

Country Status (12)

Country Link
US (2) US6153556A (de)
EP (1) EP0927575B1 (de)
KR (1) KR100452673B1 (de)
CN (1) CN1117618C (de)
AT (1) ATE236721T1 (de)
BR (1) BR9807867A (de)
CA (1) CA2257039A1 (de)
DE (1) DE69813170T2 (de)
ID (1) ID21608A (de)
IN (1) IN194403B (de)
SG (1) SG76583A1 (de)
TW (1) TW426545B (de)

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EP1086743B1 (de) 1999-09-21 2006-08-16 Nippon Shokubai Co., Ltd. Katalysator für die Herstellung von Epoxiden und Verfahren für die Bereitung derselben und die Herstellung von Epoxiden
US6576588B2 (en) * 2000-04-07 2003-06-10 Catalytic Distillation Technologies Process for selective hydrogenation of alkynes and catalyst therefor
US6831037B2 (en) 2002-02-25 2004-12-14 Saint-Gobain Norpro Corporation Catalyst carriers
DE10300526A1 (de) * 2003-01-09 2004-07-22 Hte Ag The High Throughput Experimentation Company Silberhaltige Katalysatoren zur Umsetzung von Substraten mit C-C-Doppelbindungen
RU2372342C2 (ru) * 2003-08-22 2009-11-10 Дау Текнолоджи Инвестментс Ллс. Улучшенные носители из оксида алюминия и катализаторы на основе серебра для получения алкиленоксидов
US7208646B2 (en) * 2004-05-14 2007-04-24 Catalytic Distillation Technologies Selective hydrogenation of butadiene
US20060036105A1 (en) * 2004-08-12 2006-02-16 Shell Oil Company Method of preparing a shaped catalyst, the catalyst, and use of the catalyst
WO2006020709A1 (en) * 2004-08-12 2006-02-23 Velocys Inc. Process for converting ethylene to ethylene oxide using microchannel process technology
US20060173224A1 (en) * 2005-02-01 2006-08-03 Catalytic Distillation Technologies Process and catalyst for selective hydrogenation of dienes and acetylenes
US7759284B2 (en) * 2005-05-09 2010-07-20 Scientific Design Company, Inc. Calcination in an inert gas in the presence of a small concentration of an oxidizing component
KR101369619B1 (ko) * 2005-06-07 2014-03-05 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 산화올레핀, 1,2-디올, 1,2-디올 에테르 또는 알칸올아민의제조방법, 이를 위한 촉매, 이 촉매의 제조방법
KR101072239B1 (ko) * 2005-06-07 2011-10-12 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 촉매 캐리어
RU2008109027A (ru) * 2005-08-11 2009-09-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Способ изготовления формованного катализатора, катализатор и использование такого катализатора
WO2007129649A1 (ja) * 2006-05-02 2007-11-15 Nippon Shokubai Co., Ltd. オレフィンの部分酸化用触媒、その製造方法およびアルキレンオキサイドの製造方法
US8097557B2 (en) * 2006-08-08 2012-01-17 Sd Lizenverwertungsgesellschaft Mbh & Co. Kg Two-stage calcination for catalyst production
JP5576607B2 (ja) * 2006-09-15 2014-08-20 株式会社日本触媒 アルキレンオキシド製造用触媒、その製造方法、および該触媒を用いたアルキレンオキシドの製造方法
WO2009119416A1 (ja) * 2008-03-26 2009-10-01 株式会社日本触媒 エチレンオキシド製造用触媒および該触媒を用いたエチレンオキシドの製造方法
CN102015095B (zh) * 2008-04-30 2013-05-08 陶氏技术投资有限公司 多孔体前体，成形多孔体，它们的制备方法和基于它们的终端产品
US8685883B2 (en) * 2008-04-30 2014-04-01 Dow Technology Investments Llc Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same
EP2282832A1 (de) * 2008-04-30 2011-02-16 Dow Technology Investments LLC Vorläufer von porösen körpern, poröse formkörper, herstellungverfahren dafür und endprodukte auf ihrer basis
WO2010007011A1 (en) * 2008-07-14 2010-01-21 Basf Se Process for making ethylene oxide
US8349765B2 (en) 2008-07-18 2013-01-08 Scientific Design Company, Inc. Mullite-containing carrier for ethylene oxide catalysts
US8524927B2 (en) * 2009-07-13 2013-09-03 Velocys, Inc. Process for making ethylene oxide using microchannel process technology
US8883678B2 (en) 2010-06-04 2014-11-11 Scientific Design Company, Inc. Carrier for ethylene oxide catalysts
US8586769B2 (en) * 2010-06-04 2013-11-19 Scientific Design Company, Inc. Carrier for ethylene oxide catalysts
CN104707664B (zh) * 2013-12-13 2017-11-07 中国石油化工股份有限公司 一种用于银催化剂的α‑氧化铝载体的制备方法
US8975424B1 (en) * 2013-12-30 2015-03-10 Scientific Design Company, Inc. Zinc-promoted catalysts for epoxidation of ethylene
CN111068714B (zh) * 2019-12-16 2021-05-04 北京化工大学 一种负载型银基多组分纳米催化剂的制备方法

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US2294383A (en) * 1942-09-01 Process for the preparation of
GB1491447A (en) * 1973-12-05 1977-11-09 Ici Ltd Alkylene oxide production and catalysts therefor
FR2412538A1 (fr) * 1977-12-22 1979-07-20 Ugine Kuhlmann Catalyseurs a base d'argent pour la production d'oxyde d'ethylene
CA1142319A (en) * 1978-12-20 1983-03-08 Peter Hold Process and apparatus for processing plastic and polymeric materials
JPS55145677A (en) * 1979-05-02 1980-11-13 Mitsubishi Petrochem Co Ltd Preparation of ethylene oxide
US4410453A (en) * 1980-08-25 1983-10-18 Norton Co. Ethylene oxide catalyst
BG37835A3 (en) * 1982-06-30 1985-08-15 Hoechst Ag,De Method for preparing silver catalyst
US4575494A (en) * 1984-02-08 1986-03-11 The Dow Chemical Company Alumina compositions useful as catalyst supports for ethylene oxidation
AU586048B2 (en) * 1985-11-12 1989-06-29 Nippon Shokubai Kagaku Kogyo Co. Ltd. Silver catalyst for production of ethylene oxide and method for manufacture thereof
FR2597098B1 (fr) * 1986-04-11 1989-01-13 Atochem Catalyseurs a base d'argent pour la fabrication d'oxyde d'ethylene
GB8610441D0 (en) * 1986-04-29 1986-06-04 Shell Int Research Preparation of silver-containing catalyst
JP2561678B2 (ja) * 1987-11-06 1996-12-11 三菱化学株式会社 エチレンオキシド製造用銀触媒
JP2637537B2 (ja) * 1989-01-24 1997-08-06 株式会社日本触媒 エチレンオキシド製造用銀触媒およびその製造方法
CA1337722C (en) * 1989-04-18 1995-12-12 Madan Mohan Bhasin Alkylene oxide catalysts having enhanced activity and/or stability
JP3312916B2 (ja) * 1991-06-06 2002-08-12 三菱化学株式会社 酸化エチレン製造用銀触媒
CA2089510C (en) * 1992-02-27 1998-09-01 Shinichi Nagase Silver catalyst for production of ethylene oxide and method for production of the catalyst
US5380697A (en) * 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
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Also Published As

Publication number Publication date
US6281370B1 (en) 2001-08-28
DE69813170T2 (de) 2003-12-18
US6153556A (en) 2000-11-28
BR9807867A (pt) 2000-08-15
KR100452673B1 (ko) 2005-01-31
EP0927575A1 (de) 1999-07-07
EP0927575B1 (de) 2003-04-09
TW426545B (en) 2001-03-21
ATE236721T1 (de) 2003-04-15
KR19990063490A (ko) 1999-07-26
SG76583A1 (en) 2000-11-21
CN1223900A (zh) 1999-07-28
CA2257039A1 (en) 1999-06-25
ID21608A (id) 1999-07-01
CN1117618C (zh) 2003-08-13
IN194403B (de) 2004-10-30

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Legal Events

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8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee