JPWO2019130829A1 - 農産容器 - Google Patents
農産容器 Download PDFInfo
- Publication number
- JPWO2019130829A1 JPWO2019130829A1 JP2019562811A JP2019562811A JPWO2019130829A1 JP WO2019130829 A1 JPWO2019130829 A1 JP WO2019130829A1 JP 2019562811 A JP2019562811 A JP 2019562811A JP 2019562811 A JP2019562811 A JP 2019562811A JP WO2019130829 A1 JPWO2019130829 A1 JP WO2019130829A1
- Authority
- JP
- Japan
- Prior art keywords
- film
- acid
- porous film
- agricultural product
- cellulose acylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 239000011148 porous material Substances 0.000 claims abstract description 41
- 125000002252 acyl group Chemical group 0.000 claims abstract description 29
- 238000006467 substitution reaction Methods 0.000 claims abstract description 23
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- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims description 9
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Abstract
Description
収容部材51にCAフィルム11を貼り付けることにより包装箱50をつくり、実施例1〜実施例9とした。面積S11と底板52の収容空間側の面積とは8cm×17.5cm(=140cm2)であり、包装箱50の収容空間の高さは5.5cmであった。側板53a及び側板53cには、径が8mmの開口56をパンチングにより形成し、開口56を覆う状態に多孔フィルム12を側板53a及び側板53cに貼り付けた。なお、面積S12は、形成する開口56の個数で調節した。
固形分の第1成分 100質量部
固形分の第2成分 15質量部
固形分の第3成分 1.3質量部
ジクロロメタン(溶媒の第1成分) 635質量部
メタノール(溶媒の第2成分) 125質量部
A;富士フイルム(株)製ミクロフィルタ アストロポア(登録商標) PSS03のカートリッジに組み込まれている平均孔径0.030μmのフィルタ
B;富士フイルム(株)製ミクロフィルタ アストロポア(登録商標) PSEカートリッジの孔径2μm品に組み込まれている平均孔径0.20μmのフィルタ
C;富士フイルム(株)製ミクロフィルタ アストロポア(登録商標) PSEカートリッジの孔径1.2μm品に組み込まれている平均孔径1.2μmのフィルタ
D;メルク(株)製VITIPORE(登録商標)IIカートリッジに組み込まれている平均孔径0.65μmのフィルタ
E;富士フイルム(株)製アストロポア(登録商標)PPEカートリッジUXLに組み込まれている平均孔径4.5μmのフィルタ(ポリプロピレン不織布)、
F:ポール(株)製スーポア(登録商標)カートリッジに組み込まれている平均孔径0.20μmのフィルタ(ポリエーテルスルホン)
上記5日間の静置後、包装箱50内の結露の程度を目視で観察した。評価の基準は以下の通りである。A,Bは合格、Cは不合格である。各評価結果は表1の「結露」欄に示す。
A:結露が認められない。
B:結露は認められるものの、薄く曇っている程度である。
C:水滴が認められる。
包装箱50の内部の側板53dに、(株)T&D社製の二酸化炭素、温度、湿度データロガーおんどとり(登録商標)TR−76Uiを設け、二酸化炭素濃度を測定した。二酸化炭素の濃度は空気全体に対する体積割合である。二酸化炭素の濃度は、一定となった時点の値を表1に示している。
上記5日間の静置後、(株)食品微生物センターにおいて細菌検査として一般生菌の検査を実施した。評価の基準は以下の通りである。A,Bは合格、Cは不合格である。各評価結果は表1の「細菌」欄に示す。
A:一般生菌として1000未満であった。
B:一般生菌として1000以上10000未満であった。
C:一般生菌10000以上であった。
実施例2の多孔フィルム12を用いずに、側板53a及び側板53cの開口56をポリプロピレン製の板により塞いだ状態でベビーリーフを保管し、比較例1とした。実施例2のCAフィルム11の代わりにポリエチレンテレフタレート製のフィルムを用い、かつ、多孔フィルム12を用いずに開口56をポリプロピレン製の板により塞いだ状態で、ベビーリーフを保管し、比較例2とした。比較例2の上記ポリエチレンテレフタレート製のフィルムは、全面積において、直径300μmの穿孔を、面積1cm2あたり20個程度で形成したフィルムであり、厚みは100μmであった。実施例2のCAフィルム11の代わりに、ポリエチレンテレフタレート製のフィルムを用い、比較例3とした。比較例3のポリエチレンテレフタレート製のフィルムには上記の穿孔は形成しておらず、厚みは100μmであった。これら比較例のその他の条件は実施例2と同じである。なお、用いたポリエチレンテレフタレート製のフィルムの厚みは、表1の「CAフィルム」の「厚み」欄に記載している。
包装箱50をつくり、実施例10〜実施例18とした。包装袋10をつくり、実施例19とした。包装袋30をつくり、実施例20〜実施例21とした。表2の「農産容器」欄には、包装箱50の場合には「箱」と記載し、包装袋10と包装袋30との各場合には「袋」と記載する。
上記冷蔵下で静置した後のブロッコリの質量を測定した。その測定値をMB(単位はg)とする。農産容器に包装される前のブロッコリの質量(200g)を基準にし、減少した質量の割合を{(200−MB)/200}×100の算出式により百分率で求めた。求めた結果は、表2の「重量減少」欄に示す。
冷蔵静置後のブロッコリの花蕾と茎の切り口とを目視で観察することにより変色の程度を評価した。評価の基準は以下の通りである。A,Bは合格、Cは不合格である。各評価結果は表1の「変色」欄に示す。
A:包装開始時と色が変わっていない。
B:少し変色は認められるものの、花蕾はわずかに黄色い程度、かつ、茎の切り口の変色もごくわずかな程度である。
C:花蕾が黄色く、茎の切り口が茶色である。
上記14日間の冷蔵静置後、冷蔵庫から農産容器を取り出し、農産容器における変形と変形が進行することにより見えるしわとを以下の基準で評価した。変形については箱50については天面に配置したCAフィルム11のたるみ及び全体的な変形、袋10、30についてはCAフィルム11自体及びその接合部10aの変形を評価した。しわは箱50、袋10、30においてCAフィルム11が青果物と接触している部分でおきる変形を評価した。5,4,3は合格、2,1は不合格である。各評価結果は表1の「変形及びしわ」欄に示す。
5:農産容器に変形がまったく認められない。
4:農産容器の一部に変形及び/またはしわがわずかに認められる程度である。
3:農産容器の一部に変形としわとが認められるものの、実用上問題無い。
2:農産容器の全体に変形としわとが認められる。
1:農産容器の全体に変形としわとの両方が強く認められる。
多孔フィルム12を用いずに、側板53a及び側板53cの開口56を開放した状態の包装箱をつくり、その他の条件は実施例18と同様な条件とし、比較例4とした。実施例10のCAフィルム11を、アシル基置換度が1.00であるセルロースアシレートから形成したCAフィルムに置き換え、比較例5とした。実施例10のCAフィルム11をフタムラ化学(株)製の普通セロハンPL#500に置き換え、比較例6とした。農産容器として、住友ベークライト(株)製のP−プラス(登録商標)(ジッパー付き、サイズはM,295mm×220mm,厚み40μm)を用いた場合を比較例7とした。東洋紡(株)製のF&G(登録商標)防曇フィルム11号(サイズ200mm×300mm、厚み25μm)を用いた場合を比較例8とした。比較例8においてはブロッコリを入れた袋の1辺を接着テープで密封した状態で、冷蔵庫に静置した。農産容器を用いずに、ブロッコリを包装しない状態(非包装状態)で冷蔵保存し、比較例9とした。その他の条件は実施例10〜実施例21と同様である。なお、比較例4〜比較例8で用いた上記素材の厚みは、表2のCAフィルムの「厚み」欄に示す。
育苗装置69により、小松菜の苗を育てた。育苗箱70の収容空間側のサイズは、20cm×20cm×20cmとした。育苗箱70のその他の諸条件、及び、育てた苗の本数は表3に示す。なお、生育後の小松菜の1本あたりの質量は概ね10gであり、1本あたりの葉の面積は30cm2であった。なお、表3のCAフィルムの透湿度(単位はg/m2・day)は、40℃、相対湿度90%での値である。
苗床74として、水耕栽培用スポンジ・ウレタン培地を用い、これに水を含ませた。小松菜の種を置き苗床74に置き、室温(21℃以上24℃以下の範囲)にて4日間栽培し、その後苗床74とともに育苗箱70に入れ、2日後の苗75について生育評価を行った。育苗箱75に入れる前との苗75の大きさの比較、葉の大きさ及び葉の状態について以下に評価した。A,Bは合格、Cは不合格である。
A;苗は育苗箱に入れる前と同等の大きさ。葉は広く、しおれはなかった。
B;苗は育苗箱に入れる前と同等の大きさ。葉は広く、少ししおれがあった。
C;苗は育苗箱に入れる前より小さい。葉は小さく、しおれがあった。
多孔フィルム12を用いずに、側板53a及び側板53cの開口56をポリプロピレン製の板で塞いだ状態の包装箱をつくり、その他の条件は実施例22と同様な条件とし、比較例10とした。
10a 接合部
10b 開口
11 CAフィルム
12 多孔フィルム
15,15a〜15h 孔
31 PPフィルム
50 包装箱
51 収容部材
52 底板
53,53a〜53d 側板
56 開口
69 育苗装置
70 育苗箱
71 光源ユニット
74 苗床
75 苗
76 容器
77 水
81 光源
82 支持板
83 コントローラ
86 温湿度調節機
S11 CAフィルムの面積
S12 多孔フィルムの面積
S31 PPフィルムの面積
S51 収容部材の面積
SA 隔壁の全表面積
SR11 CAフィルムの面積割合
SR12 多孔フィルムの面積割合
Claims (9)
- 被収容物を収容する収容空間と外部空間とを隔てる隔壁の少なくとも一部がフィルムである農産容器において、
アシル基置換度が2.00以上2.97以下の範囲内であるセルロースアシレートを含むセルロースアシレートフィルムと、
0.0050μm以上5.0μm以下の範囲内の平均孔径をもつ複数の孔が厚み方向に貫通した状態に形成されている多孔フィルムと、
を備える農産容器。 - 前記セルロースアシレートはアセチル基を有する請求項1に記載の農産容器。
- 前記セルロースアシレートフィルムの面積割合が少なくとも10.0%である請求項1または2に記載の農産容器。
- 前記多孔フィルムの面積割合が0.1%以上20.0%以下の範囲内である請求項1ないし3のいずれか1項に記載の農産容器。
- 前記多孔フィルムは、厚み方向において複数の前記孔が連通している請求項1ないし4のいずれか1項に記載の農産容器。
- 前記被収容物は苗床と種苗とであり、
前記多孔フィルムは、前記苗床に対して起立した姿勢の側面に配されている請求項1ないし5のいずれか1項に記載の農産容器。 - 前記多孔フィルムは、互いに対向した第1の前記側面と第2の前記側面とのそれぞれに配されている請求項6に記載の農産容器。
- 前記セルロースアシレートフィルムは、天面に配されている請求項6または7に記載の農産容器。
- 前記被収容物を入れる開口が形成された袋である請求項1ないし5のいずれか1項に記載の農産容器。
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