JPS6096674A - ゴム補強用接着剤 - Google Patents
ゴム補強用接着剤Info
- Publication number
- JPS6096674A JPS6096674A JP58205537A JP20553783A JPS6096674A JP S6096674 A JPS6096674 A JP S6096674A JP 58205537 A JP58205537 A JP 58205537A JP 20553783 A JP20553783 A JP 20553783A JP S6096674 A JPS6096674 A JP S6096674A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- copolymer
- vinylpyridine
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 26
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 26
- 229920001971 elastomer Polymers 0.000 title claims abstract description 10
- 239000005060 rubber Substances 0.000 title claims abstract description 10
- 230000002787 reinforcement Effects 0.000 title 1
- 229920001577 copolymer Polymers 0.000 claims abstract description 29
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 22
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004816 latex Substances 0.000 claims abstract description 18
- 229920000126 latex Polymers 0.000 claims abstract description 18
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 claims abstract description 11
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 9
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002245 particle Substances 0.000 claims abstract description 3
- 230000003014 reinforcing effect Effects 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 239000000839 emulsion Substances 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 5
- 239000012783 reinforcing fiber Substances 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 abstract description 2
- 239000000178 monomer Substances 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000012790 adhesive layer Substances 0.000 description 6
- KVBYPTUGEKVEIJ-UHFFFAOYSA-N benzene-1,3-diol;formaldehyde Chemical compound O=C.OC1=CC=CC(O)=C1 KVBYPTUGEKVEIJ-UHFFFAOYSA-N 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical group CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical group C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical group CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- BYLSIPUARIZAHZ-UHFFFAOYSA-N 2,4,6-tris(1-phenylethyl)phenol Chemical compound C=1C(C(C)C=2C=CC=CC=2)=C(O)C(C(C)C=2C=CC=CC=2)=CC=1C(C)C1=CC=CC=C1 BYLSIPUARIZAHZ-UHFFFAOYSA-N 0.000 description 1
- YQUDMNIUBTXLSX-UHFFFAOYSA-N 2-ethenyl-5-ethylpyridine Chemical compound CCC1=CC=C(C=C)N=C1 YQUDMNIUBTXLSX-UHFFFAOYSA-N 0.000 description 1
- KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical compound C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 description 1
- VJOWMORERYNYON-UHFFFAOYSA-N 5-ethenyl-2-methylpyridine Chemical compound CC1=CC=C(C=C)C=N1 VJOWMORERYNYON-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000011297 pine tar Substances 0.000 description 1
- 229940068124 pine tar Drugs 0.000 description 1
- 235000015277 pork Nutrition 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 229960001755 resorcinol Drugs 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
Landscapes
- Reinforced Plastic Materials (AREA)
- Moulding By Coating Moulds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58205537A JPS6096674A (ja) | 1983-10-31 | 1983-10-31 | ゴム補強用接着剤 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58205537A JPS6096674A (ja) | 1983-10-31 | 1983-10-31 | ゴム補強用接着剤 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6096674A true JPS6096674A (ja) | 1985-05-30 |
| JPH0149308B2 JPH0149308B2 (enExample) | 1989-10-24 |
Family
ID=16508528
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58205537A Granted JPS6096674A (ja) | 1983-10-31 | 1983-10-31 | ゴム補強用接着剤 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6096674A (enExample) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6341581A (ja) * | 1986-08-07 | 1988-02-22 | Nippon Zeon Co Ltd | ゴム補強用ポリエステル繊維の製造方法 |
| JPS6357685A (ja) * | 1986-08-28 | 1988-03-12 | Sumitomo Naugatuck Co Ltd | ゴムと繊維との接着用接着剤組成物 |
| JP2007046210A (ja) * | 2005-08-12 | 2007-02-22 | Teijin Techno Products Ltd | ゴム補強用繊維の製造方法 |
| WO2010125992A1 (ja) | 2009-04-28 | 2010-11-04 | 株式会社ブリヂストン | 有機繊維コード用接着剤組成物、並びにそれを用いたゴム補強材、タイヤおよび接着方法 |
| JP2013512284A (ja) * | 2009-11-24 | 2013-04-11 | オムノバ ソリューソンズ インコーポレーティッド | 窒素含有モノマーを含むビニルピリジンラテックスポリマーを含むゴム接着剤組成物 |
| WO2021117521A1 (ja) | 2019-12-09 | 2021-06-17 | 株式会社ブリヂストン | 接着剤組成物、ゴム－有機繊維コード複合体及びタイヤ |
| WO2021256149A1 (ja) | 2020-06-19 | 2021-12-23 | デンカ株式会社 | 有機繊維コード用の接着剤組成物、ゴム補強材及びその製造方法、並びに、ゴム物品 |
| WO2022130879A1 (ja) | 2020-12-15 | 2022-06-23 | 株式会社ブリヂストン | 接着剤組成物、ゴム－有機繊維コード複合体及びタイヤ |
-
1983
- 1983-10-31 JP JP58205537A patent/JPS6096674A/ja active Granted
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6341581A (ja) * | 1986-08-07 | 1988-02-22 | Nippon Zeon Co Ltd | ゴム補強用ポリエステル繊維の製造方法 |
| JPS6357685A (ja) * | 1986-08-28 | 1988-03-12 | Sumitomo Naugatuck Co Ltd | ゴムと繊維との接着用接着剤組成物 |
| JP2007046210A (ja) * | 2005-08-12 | 2007-02-22 | Teijin Techno Products Ltd | ゴム補強用繊維の製造方法 |
| WO2010125992A1 (ja) | 2009-04-28 | 2010-11-04 | 株式会社ブリヂストン | 有機繊維コード用接着剤組成物、並びにそれを用いたゴム補強材、タイヤおよび接着方法 |
| KR20120023706A (ko) | 2009-04-28 | 2012-03-13 | 가부시키가이샤 브리지스톤 | 유기 섬유 코드용 접착제 조성물 및 그것을 사용한 고무 보강재, 타이어 및 접착 방법 |
| US9394647B2 (en) | 2009-04-28 | 2016-07-19 | Bridgestone Corporation | Adhesive composition for organic fiber cords, rubber-reinforcing material using same, tire and bonding method |
| JP2013512284A (ja) * | 2009-11-24 | 2013-04-11 | オムノバ ソリューソンズ インコーポレーティッド | 窒素含有モノマーを含むビニルピリジンラテックスポリマーを含むゴム接着剤組成物 |
| WO2021117521A1 (ja) | 2019-12-09 | 2021-06-17 | 株式会社ブリヂストン | 接着剤組成物、ゴム－有機繊維コード複合体及びタイヤ |
| WO2021256149A1 (ja) | 2020-06-19 | 2021-12-23 | デンカ株式会社 | 有機繊維コード用の接着剤組成物、ゴム補強材及びその製造方法、並びに、ゴム物品 |
| WO2022130879A1 (ja) | 2020-12-15 | 2022-06-23 | 株式会社ブリヂストン | 接着剤組成物、ゴム－有機繊維コード複合体及びタイヤ |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0149308B2 (enExample) | 1989-10-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |