JPS58104907A - 高剛性成形品用ポリプロピレンの製造方法 - Google Patents
高剛性成形品用ポリプロピレンの製造方法Info
- Publication number
- JPS58104907A JPS58104907A JP56204066A JP20406681A JPS58104907A JP S58104907 A JPS58104907 A JP S58104907A JP 56204066 A JP56204066 A JP 56204066A JP 20406681 A JP20406681 A JP 20406681A JP S58104907 A JPS58104907 A JP S58104907A
- Authority
- JP
- Japan
- Prior art keywords
- solid product
- polypropylene
- organoaluminum compound
- reacting
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 Polypropylene Polymers 0.000 title claims abstract description 76
- 239000004743 Polypropylene Substances 0.000 title claims description 42
- 229920001155 polypropylene Polymers 0.000 title claims description 42
- 238000002360 preparation method Methods 0.000 title description 4
- 239000012265 solid product Substances 0.000 claims abstract description 59
- 150000001875 compounds Chemical class 0.000 claims abstract description 34
- 239000003054 catalyst Substances 0.000 claims abstract description 32
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims abstract description 23
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 20
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 20
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 15
- 239000000047 product Substances 0.000 claims description 22
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 229910052782 aluminium Inorganic materials 0.000 claims description 16
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 16
- 239000004711 α-olefin Substances 0.000 claims description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 239000000370 acceptor Substances 0.000 claims 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract description 7
- 229920000642 polymer Polymers 0.000 abstract description 5
- 239000000654 additive Substances 0.000 abstract description 4
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 abstract description 4
- 230000000996 additive effect Effects 0.000 abstract description 2
- 229910003074 TiCl4 Inorganic materials 0.000 abstract 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 37
- 230000000052 comparative effect Effects 0.000 description 24
- 238000000034 method Methods 0.000 description 24
- 238000006243 chemical reaction Methods 0.000 description 20
- 239000002904 solvent Substances 0.000 description 19
- 150000001399 aluminium compounds Chemical class 0.000 description 13
- 238000006116 polymerization reaction Methods 0.000 description 13
- 239000000843 powder Substances 0.000 description 13
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 11
- 239000001257 hydrogen Substances 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- 239000007788 liquid Substances 0.000 description 11
- 230000000704 physical effect Effects 0.000 description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 239000011949 solid catalyst Substances 0.000 description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 8
- AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 6
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- FHUODBDRWMIBQP-UHFFFAOYSA-N Ethyl p-anisate Chemical compound CCOC(=O)C1=CC=C(OC)C=C1 FHUODBDRWMIBQP-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- XSIFPSYPOVKYCO-UHFFFAOYSA-N butyl benzoate Chemical compound CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 4
- 238000010908 decantation Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 238000012685 gas phase polymerization Methods 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 239000012760 heat stabilizer Substances 0.000 description 4
- DDIZAANNODHTRB-UHFFFAOYSA-N methyl p-anisate Chemical compound COC(=O)C1=CC=C(OC)C=C1 DDIZAANNODHTRB-UHFFFAOYSA-N 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 230000000379 polymerizing effect Effects 0.000 description 4
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 238000012662 bulk polymerization Methods 0.000 description 3
- YCURFOQQPNHZAO-UHFFFAOYSA-N butyl naphthalene-1-carboxylate Chemical compound C1=CC=C2C(C(=O)OCCCC)=CC=CC2=C1 YCURFOQQPNHZAO-UHFFFAOYSA-N 0.000 description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 3
- 239000008116 calcium stearate Substances 0.000 description 3
- 235000013539 calcium stearate Nutrition 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 238000009775 high-speed stirring Methods 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000006228 supernatant Substances 0.000 description 3
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- JLIDRDJNLAWIKT-UHFFFAOYSA-N 1,2-dimethyl-3h-benzo[e]indole Chemical compound C1=CC=CC2=C(C(=C(C)N3)C)C3=CC=C21 JLIDRDJNLAWIKT-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- RJTJVVYSTUQWNI-UHFFFAOYSA-N 2-ethylnaphthalene Chemical compound C1=CC=CC2=CC(CC)=CC=C21 RJTJVVYSTUQWNI-UHFFFAOYSA-N 0.000 description 2
- BSKHPKMHTQYZBB-UHFFFAOYSA-N 2-methylpyridine Chemical compound CC1=CC=CC=N1 BSKHPKMHTQYZBB-UHFFFAOYSA-N 0.000 description 2
- ZEYHEAKUIGZSGI-UHFFFAOYSA-N 4-methoxybenzoic acid Chemical compound COC1=CC=C(C(O)=O)C=C1 ZEYHEAKUIGZSGI-UHFFFAOYSA-N 0.000 description 2
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- KBEBGUQPQBELIU-CMDGGOBGSA-N Ethyl cinnamate Chemical compound CCOC(=O)\C=C\C1=CC=CC=C1 KBEBGUQPQBELIU-CMDGGOBGSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000005234 alkyl aluminium group Chemical group 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229940071248 anisate Drugs 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- DULCUDSUACXJJC-UHFFFAOYSA-N benzeneacetic acid ethyl ester Natural products CCOC(=O)CC1=CC=CC=C1 DULCUDSUACXJJC-UHFFFAOYSA-N 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- NMJJFJNHVMGPGM-UHFFFAOYSA-N butyl formate Chemical compound CCCCOC=O NMJJFJNHVMGPGM-UHFFFAOYSA-N 0.000 description 2
- 235000013877 carbamide Nutrition 0.000 description 2
- IZMHKHHRLNWLMK-UHFFFAOYSA-M chloridoaluminium Chemical compound Cl[Al] IZMHKHHRLNWLMK-UHFFFAOYSA-M 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- KBEBGUQPQBELIU-UHFFFAOYSA-N cinnamic acid ethyl ester Natural products CCOC(=O)C=CC1=CC=CC=C1 KBEBGUQPQBELIU-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- VJRUISVXILMZSL-UHFFFAOYSA-M dibutylalumanylium;chloride Chemical compound CCCC[Al](Cl)CCCC VJRUISVXILMZSL-UHFFFAOYSA-M 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- HJXBDPDUCXORKZ-UHFFFAOYSA-N diethylalumane Chemical compound CC[AlH]CC HJXBDPDUCXORKZ-UHFFFAOYSA-N 0.000 description 2
- PPQUYYAZSOKTQD-UHFFFAOYSA-M diethylalumanylium;iodide Chemical group CC[Al](I)CC PPQUYYAZSOKTQD-UHFFFAOYSA-M 0.000 description 2
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- SQNZJJAZBFDUTD-UHFFFAOYSA-N durene Chemical compound CC1=CC(C)=C(C)C=C1C SQNZJJAZBFDUTD-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical group 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- 229910003475 inorganic filler Inorganic materials 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- WVWZECQNFWFVFW-UHFFFAOYSA-N methyl 2-methylbenzoate Chemical compound COC(=O)C1=CC=CC=C1C WVWZECQNFWFVFW-UHFFFAOYSA-N 0.000 description 2
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
- 150000005673 monoalkenes Chemical class 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 239000002667 nucleating agent Substances 0.000 description 2
- IXQGCWUGDFDQMF-UHFFFAOYSA-N o-Hydroxyethylbenzene Natural products CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 description 2
- VECVSKFWRQYTAL-UHFFFAOYSA-N octyl benzoate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1 VECVSKFWRQYTAL-UHFFFAOYSA-N 0.000 description 2
- 125000002370 organoaluminium group Chemical group 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 238000004080 punching Methods 0.000 description 2
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- HNKJADCVZUBCPG-UHFFFAOYSA-N thioanisole Chemical compound CSC1=CC=CC=C1 HNKJADCVZUBCPG-UHFFFAOYSA-N 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 2
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 2
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- KMIOJWCYOHBUJS-HAKPAVFJSA-N vorolanib Chemical compound C1N(C(=O)N(C)C)CC[C@@H]1NC(=O)C1=C(C)NC(\C=C/2C3=CC(F)=CC=C3NC\2=O)=C1C KMIOJWCYOHBUJS-HAKPAVFJSA-N 0.000 description 2
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
- QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 1
- AVQQQNCBBIEMEU-UHFFFAOYSA-N 1,1,3,3-tetramethylurea Chemical compound CN(C)C(=O)N(C)C AVQQQNCBBIEMEU-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
- BPIUIOXAFBGMNB-UHFFFAOYSA-N 1-hexoxyhexane Chemical compound CCCCCCOCCCCCC BPIUIOXAFBGMNB-UHFFFAOYSA-N 0.000 description 1
- LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical class C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 description 1
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- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
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Landscapes
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56204066A JPS58104907A (ja) | 1981-12-17 | 1981-12-17 | 高剛性成形品用ポリプロピレンの製造方法 |
| GB08235201A GB2114581B (en) | 1981-12-17 | 1982-12-09 | Ziegler catalyst for producing polypropylene |
| DE19823246447 DE3246447A1 (de) | 1981-12-17 | 1982-12-15 | Polypropylen zur herstellung von hochsteifen formkoerpern und verfahren zur herstellung desselben |
| CA000417917A CA1193398A (en) | 1981-12-17 | 1982-12-16 | Polypropylene capable of producing high-rigidity molded products |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56204066A JPS58104907A (ja) | 1981-12-17 | 1981-12-17 | 高剛性成形品用ポリプロピレンの製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58104907A true JPS58104907A (ja) | 1983-06-22 |
| JPH0148922B2 JPH0148922B2 (enrdf_load_stackoverflow) | 1989-10-23 |
Family
ID=16484190
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56204066A Granted JPS58104907A (ja) | 1981-12-17 | 1981-12-17 | 高剛性成形品用ポリプロピレンの製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58104907A (enrdf_load_stackoverflow) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61155404A (ja) * | 1984-12-28 | 1986-07-15 | Idemitsu Petrochem Co Ltd | 結晶性ポリプロピレン |
| JPS62256803A (ja) * | 1986-04-30 | 1987-11-09 | Idemitsu Petrochem Co Ltd | プロピレン単独重合体およびその製造方法 |
| EP0269051A2 (en) | 1986-11-28 | 1988-06-01 | Chisso Corporation | Method for making nonwoven fabrics |
| EP0774489A1 (en) | 1995-11-17 | 1997-05-21 | Japan Polychem Corporation | Thermoplastic resin composition |
| US6586517B2 (en) | 2001-02-16 | 2003-07-01 | Mazda Motor Corporation | Long fiber-reinforced polypropylene resin composition |
| WO2007105344A1 (ja) | 2006-03-10 | 2007-09-20 | Mitsubishi Chemical Corporation | 樹脂分散体、塗料、積層体及びその製造方法 |
| WO2012036063A1 (ja) | 2010-09-14 | 2012-03-22 | 日本ポリプロ株式会社 | プロピレン系樹脂多層シートおよびそれを用いた加熱処理用包装体 |
| WO2012117823A1 (ja) | 2011-03-02 | 2012-09-07 | 株式会社Adeka | ラミネートフィルムおよび塗装部材用樹脂組成物の製造方法 |
| WO2013105552A1 (ja) * | 2012-01-11 | 2013-07-18 | 王子ホールディングス株式会社 | コンデンサー用２軸延伸ポリプロピレンフィルム |
| WO2013140905A1 (ja) | 2012-03-23 | 2013-09-26 | 株式会社Adeka | 家電材料用及び自動車内装材料用オレフィン樹脂組成物の製造方法 |
| WO2014088035A1 (ja) | 2012-12-07 | 2014-06-12 | 日本ポリプロ株式会社 | 繊維強化ポリプロピレン系樹脂組成物及びその成形体 |
| WO2015046526A1 (ja) | 2013-09-30 | 2015-04-02 | 積水化学工業株式会社 | 架橋ポリオレフィン系樹脂発泡シート |
| WO2015060257A1 (ja) | 2013-10-21 | 2015-04-30 | 株式会社Adeka | 安定化されたポリマーの製造方法 |
| EP3042990A1 (en) | 2010-11-16 | 2016-07-13 | Adeka Corporation | Method for stabilizing polymer for long term, method for producing nonwoven fabric, and method for producing elastomer composition |
| WO2017094723A1 (ja) | 2015-11-30 | 2017-06-08 | 積水化学工業株式会社 | ポリオレフィン系樹脂発泡シート及び粘着テープ |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0579510A3 (en) * | 1992-07-17 | 1994-08-24 | Mitsubishi Chem Ind | Propylene polymers and process for preparing the same |
| JPH07133388A (ja) * | 1993-11-09 | 1995-05-23 | Chisso Corp | 結晶性プロピレン重合体組成物 |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4734478A (enrdf_load_stackoverflow) * | 1971-03-23 | 1972-11-21 | ||
| JPS5124685A (ja) * | 1974-08-23 | 1976-02-28 | Sumitomo Chemical Co | Koketsushoseiorefuinjugotaino seizohoho |
| JPS5287490A (en) * | 1976-01-19 | 1977-07-21 | Mitsubishi Chem Ind Ltd | Production of of polyolefins |
| JPS533356A (en) * | 1976-06-30 | 1978-01-13 | Mitsubishi Heavy Ind Ltd | Laser interference |
| JPS54118486A (en) * | 1978-03-08 | 1979-09-13 | Sumitomo Chem Co Ltd | Preparation of propylene (co)polymer |
| JPS5592712A (en) * | 1978-12-29 | 1980-07-14 | Sumitomo Chem Co Ltd | Insulating polypropylene |
| JPS562307A (en) * | 1979-06-20 | 1981-01-12 | Sumitomo Chem Co Ltd | Preparation of highly crystalline olefin polymer |
| JPS56100806A (en) * | 1980-01-17 | 1981-08-13 | Chisso Corp | Preparation of alpha-olefin polymer |
| JPS56110707A (en) * | 1980-02-05 | 1981-09-02 | Chisso Corp | Production of alpha-olefin polymer |
| JPS56143207A (en) * | 1980-04-11 | 1981-11-07 | Chisso Corp | Production of ethylene/propylene/alpha-olefin terpolymer |
| JPS56155208A (en) * | 1980-05-02 | 1981-12-01 | Mitsubishi Chem Ind Ltd | Production of polyolefin |
-
1981
- 1981-12-17 JP JP56204066A patent/JPS58104907A/ja active Granted
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4734478A (enrdf_load_stackoverflow) * | 1971-03-23 | 1972-11-21 | ||
| JPS5124685A (ja) * | 1974-08-23 | 1976-02-28 | Sumitomo Chemical Co | Koketsushoseiorefuinjugotaino seizohoho |
| JPS5287490A (en) * | 1976-01-19 | 1977-07-21 | Mitsubishi Chem Ind Ltd | Production of of polyolefins |
| JPS533356A (en) * | 1976-06-30 | 1978-01-13 | Mitsubishi Heavy Ind Ltd | Laser interference |
| JPS54118486A (en) * | 1978-03-08 | 1979-09-13 | Sumitomo Chem Co Ltd | Preparation of propylene (co)polymer |
| JPS5592712A (en) * | 1978-12-29 | 1980-07-14 | Sumitomo Chem Co Ltd | Insulating polypropylene |
| JPS562307A (en) * | 1979-06-20 | 1981-01-12 | Sumitomo Chem Co Ltd | Preparation of highly crystalline olefin polymer |
| JPS56100806A (en) * | 1980-01-17 | 1981-08-13 | Chisso Corp | Preparation of alpha-olefin polymer |
| JPS56110707A (en) * | 1980-02-05 | 1981-09-02 | Chisso Corp | Production of alpha-olefin polymer |
| JPS56143207A (en) * | 1980-04-11 | 1981-11-07 | Chisso Corp | Production of ethylene/propylene/alpha-olefin terpolymer |
| JPS56155208A (en) * | 1980-05-02 | 1981-12-01 | Mitsubishi Chem Ind Ltd | Production of polyolefin |
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61155404A (ja) * | 1984-12-28 | 1986-07-15 | Idemitsu Petrochem Co Ltd | 結晶性ポリプロピレン |
| JPS62256803A (ja) * | 1986-04-30 | 1987-11-09 | Idemitsu Petrochem Co Ltd | プロピレン単独重合体およびその製造方法 |
| EP0269051A2 (en) | 1986-11-28 | 1988-06-01 | Chisso Corporation | Method for making nonwoven fabrics |
| EP0774489A1 (en) | 1995-11-17 | 1997-05-21 | Japan Polychem Corporation | Thermoplastic resin composition |
| US6586517B2 (en) | 2001-02-16 | 2003-07-01 | Mazda Motor Corporation | Long fiber-reinforced polypropylene resin composition |
| WO2007105344A1 (ja) | 2006-03-10 | 2007-09-20 | Mitsubishi Chemical Corporation | 樹脂分散体、塗料、積層体及びその製造方法 |
| WO2012036063A1 (ja) | 2010-09-14 | 2012-03-22 | 日本ポリプロ株式会社 | プロピレン系樹脂多層シートおよびそれを用いた加熱処理用包装体 |
| EP3042990A1 (en) | 2010-11-16 | 2016-07-13 | Adeka Corporation | Method for stabilizing polymer for long term, method for producing nonwoven fabric, and method for producing elastomer composition |
| WO2012117823A1 (ja) | 2011-03-02 | 2012-09-07 | 株式会社Adeka | ラミネートフィルムおよび塗装部材用樹脂組成物の製造方法 |
| EP2966095A1 (en) | 2011-03-02 | 2016-01-13 | Adeka Corporation | Process of producing resin composition for coating members |
| JPWO2013105552A1 (ja) * | 2012-01-11 | 2015-05-11 | 王子ホールディングス株式会社 | コンデンサー用２軸延伸ポリプロピレンフィルム |
| CN104054146A (zh) * | 2012-01-11 | 2014-09-17 | 王子控股株式会社 | 电容器用双轴拉伸聚丙烯薄膜 |
| KR20140119065A (ko) * | 2012-01-11 | 2014-10-08 | 오지 홀딩스 가부시키가이샤 | 콘덴서용 2축 연신 폴리프로필렌 필름 |
| US20150140266A1 (en) * | 2012-01-11 | 2015-05-21 | Oji Holdings Corporation | Biaxially stretched polypropylene film for capacitors |
| WO2013105552A1 (ja) * | 2012-01-11 | 2013-07-18 | 王子ホールディングス株式会社 | コンデンサー用２軸延伸ポリプロピレンフィルム |
| US9605093B2 (en) | 2012-01-11 | 2017-03-28 | Oji Holdings Corporation | Biaxially stretched polypropylene film for capacitors |
| WO2013140905A1 (ja) | 2012-03-23 | 2013-09-26 | 株式会社Adeka | 家電材料用及び自動車内装材料用オレフィン樹脂組成物の製造方法 |
| WO2014088035A1 (ja) | 2012-12-07 | 2014-06-12 | 日本ポリプロ株式会社 | 繊維強化ポリプロピレン系樹脂組成物及びその成形体 |
| WO2015046526A1 (ja) | 2013-09-30 | 2015-04-02 | 積水化学工業株式会社 | 架橋ポリオレフィン系樹脂発泡シート |
| WO2015060257A1 (ja) | 2013-10-21 | 2015-04-30 | 株式会社Adeka | 安定化されたポリマーの製造方法 |
| WO2017094723A1 (ja) | 2015-11-30 | 2017-06-08 | 積水化学工業株式会社 | ポリオレフィン系樹脂発泡シート及び粘着テープ |
| EP3753730A1 (en) | 2015-11-30 | 2020-12-23 | Sekisui Chemical Co., Ltd. | Polyolefin resin foam sheet and adhesive tape |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0148922B2 (enrdf_load_stackoverflow) | 1989-10-23 |
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