JPH11506476A - アニオンポリマーとケイ素−水素結合を有するトリアルコキシシランとのカップリング - Google Patents
アニオンポリマーとケイ素−水素結合を有するトリアルコキシシランとのカップリングInfo
- Publication number
- JPH11506476A JPH11506476A JP8531475A JP53147596A JPH11506476A JP H11506476 A JPH11506476 A JP H11506476A JP 8531475 A JP8531475 A JP 8531475A JP 53147596 A JP53147596 A JP 53147596A JP H11506476 A JPH11506476 A JP H11506476A
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- radial
- group
- initiator
- coupling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/25—Incorporating silicon atoms into the molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
- C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
- C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Sealing Material Composition (AREA)
- Paints Or Removers (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1. 金属開始剤を用いて、共役ジエン、モノビニル芳香族化合物またはその組 合せを重合させることによって金属末端線状アニオンポリマーを調製する工程、 ケイ素−水素結合を有するトリアルコキシシランを用いて、複数の線状アニオ ンポリマーをカップリングさせる工程を含む方法によって製造されるラジアルア ニオンポリマー。 2. 該トリアルコキシシランがトリメトキシシランである請求項1または2記 載のラジアルポリマー。 3. 該金属開始剤が一般式: [式中、A”はシクロヘキシル基または基−CR’R”−を表し、ここで、R’ は1ないし10個の炭素原子を有する線状アルキル基を表し、R”は水素原子ま たは1ないし10個の炭素原子を有する線状アルキル基を表す] の保護された機能性開始剤である請求項1または2記載のラジ アルポリマー。 4. 開始剤におけるA”が−CR’R”−であり、R”がメチルである請求項 3記載のラジアルポリマー。 5. R’がメチルである請求項4記載のラジアルポリマー。 6. 該ラジアルポリマーが重合した共役ジエンよりなるかまたはそれを含有し 、カップリング後に、更に重合した共役ジエンを水素化し、次いで、リチウム開 始剤からのトリメチルシリル基を水素で置き換えて、末端ヒドロキシル基を得る 化合物と反応させる請求項1ないし5のいずれか1項記載のラジアルポリマー。 7. 線状アニオンポリマーが500ないし200,000、最も好ましくは5 00ないし20,000の範囲の数平均分子量を有するホモポリイソプレンまた はホモポリブタジエンよりなる請求項6記載のラジアルポリマー。 8. 請求項1ないし7のいずれか1項記載の方法を含む、請求項1に記載のラ ジアルアニオンポリマーの製法。 9. 請求項1ないし7のいずれか1項記載のポリマーを含む接着剤、シーラン トおよびコーティング、フィルムおよび成形・押出した熱可塑性および熱硬化性 製品用の組成物。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US42483695A | 1995-04-19 | 1995-04-19 | |
US08/424,836 | 1995-04-19 | ||
PCT/EP1996/001637 WO1996033223A1 (en) | 1995-04-19 | 1996-04-17 | Coupling of anionic polymers with trialkoxysilanes having silicon-hydrogen bonds |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH11506476A true JPH11506476A (ja) | 1999-06-08 |
JP4057649B2 JP4057649B2 (ja) | 2008-03-05 |
Family
ID=23684065
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP53147596A Expired - Fee Related JP4057649B2 (ja) | 1995-04-19 | 1996-04-17 | アニオンポリマーとケイ素−水素結合を有するトリアルコキシシランとのカップリング |
Country Status (13)
Country | Link |
---|---|
US (1) | US5681895A (ja) |
EP (1) | EP0821699B1 (ja) |
JP (1) | JP4057649B2 (ja) |
KR (1) | KR100456245B1 (ja) |
CN (1) | CN1101824C (ja) |
AT (1) | ATE177435T1 (ja) |
BR (1) | BR9608184A (ja) |
CA (1) | CA2218290A1 (ja) |
DE (1) | DE69601704T2 (ja) |
ES (1) | ES2128858T3 (ja) |
TW (1) | TW390891B (ja) |
WO (1) | WO1996033223A1 (ja) |
ZA (1) | ZA963049B (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013513685A (ja) * | 2009-12-10 | 2013-04-22 | ダイナソル エラストメロス,ソシエダット アノニマ | アニオン重合によって合成された機能性ポリマーを含む機能性多分岐ポリマー、及びその使用 |
JP2013544302A (ja) * | 2010-11-16 | 2013-12-12 | ランクセス・ドイチュランド・ゲーエムベーハー | トリアルキルシリルオキシ末端化ポリマー |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6218478B1 (en) * | 1998-09-02 | 2001-04-17 | Shell Oil Company | Deprotection of polymers prepared with silyloxy protected functional initiators by reaction with hydride reducing agents |
US6225415B1 (en) | 1999-09-20 | 2001-05-01 | University Of North Carolina At Charlotte | Process to selectively place functional groups within polymer chain |
ES2307678T3 (es) * | 2001-03-26 | 2008-12-01 | Jsr Corporation | Polimero modificado hidrogenado, procedimiento para producir el mismo y composicion que contiene el mismo. |
EA007296B1 (ru) * | 2002-06-04 | 2006-08-25 | Кратон Полимерз Рисёч Б.В. | Композиция, содержащая сопряженный блок-сополимер, и способ ее получения |
US7001956B2 (en) | 2002-06-04 | 2006-02-21 | Kraton Polymers U.S. Llc | Articles prepared from hydrogenated block copolymers |
KR100830024B1 (ko) | 2004-03-03 | 2008-05-15 | 크레이튼 폴리머즈 리서치 비.브이. | 흐름성 및 탄성이 높은 블록 공중합체 |
US7241540B2 (en) * | 2004-04-27 | 2007-07-10 | Kraton Polymers U.S. Llc | Photocurable compositions and flexographic printing plates comprising the same |
US7569281B2 (en) * | 2005-07-25 | 2009-08-04 | Kraton Polymers U.S. Llc | Flexible packaging laminate films including a block copolymer layer |
KR100969106B1 (ko) | 2005-11-14 | 2010-07-09 | 크레이튼 폴리머즈 리서치 비.브이. | 역청질 결합제 조성물의 제조방법 |
CN100443514C (zh) * | 2006-08-17 | 2008-12-17 | 山东大学 | 端双羟基聚合物及其制备方法 |
US9115296B2 (en) | 2006-11-13 | 2015-08-25 | Kraton Polymers U.S. Llc | Bituminous emulsions |
WO2008137394A1 (en) | 2007-05-01 | 2008-11-13 | Kraton Polymers Us Llc | Bituminous binder composition and process for preparing the same |
US20110027803A1 (en) | 2007-12-17 | 2011-02-03 | Artin Moussavi | Compositions and Methods for Maintenance of Fluid Conducting and Containment Systems |
JP2011518244A (ja) | 2008-04-17 | 2011-06-23 | クレイトン・ポリマーズ・ユー・エス・エル・エル・シー | 路盤アスファルト舗装用途において用いるためのブロックコポリマーおよびポリマー改質瀝青バインダ組成物 |
CN101544762B (zh) * | 2009-04-30 | 2011-12-28 | 北京化工大学 | 一种端硅氢活性硅橡胶或氟硅橡胶的制备方法 |
US9790360B2 (en) | 2015-12-30 | 2017-10-17 | Kraton Polymers U.S. Llc | Oil gel for asphalt modification and rejuvenation |
JP7082580B2 (ja) | 2016-06-30 | 2022-06-08 | クレイトン・ポリマーズ・ユー・エス・エル・エル・シー | 改善された性能の高ビニルブロックコポリマー組成物及びその使用 |
US10793720B2 (en) | 2017-03-20 | 2020-10-06 | Kraton Polymers U.S. Llc | Reclaimed asphalt composition and methods of making and using same |
CN110183599B (zh) * | 2019-05-15 | 2021-07-09 | 大连理工大学 | 一类适用于硅氢加成化学反应的双硅氢功能化星形聚合物及其制备方法 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3244664A (en) * | 1960-10-24 | 1966-04-05 | Phillips Petroleum Co | Silicon-containing polymers |
USRE27145E (en) * | 1969-05-20 | 1971-06-22 | Side-chain | |
US3692874A (en) * | 1970-09-02 | 1972-09-19 | Ralph C Farrar | Process of coupling alkali metal-terminated polymers with silicic compound in presence of conjugated dienes |
US3840616A (en) * | 1972-10-12 | 1974-10-08 | Phillips Petroleum Co | Adjuvant in coupling of polyisoprene-alkali metal terminated polymers |
US3880954A (en) * | 1973-08-22 | 1975-04-29 | Phillips Petroleum Co | Methoxy silane coupling of block copolymer formed in cyclohexane |
GB1597500A (en) * | 1977-12-29 | 1981-09-09 | Shell Int Research | Polymers |
DE3129082A1 (de) * | 1981-07-23 | 1983-02-10 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von reaktive silylgruppen tragenden homo- oder copolymeren von 1,3-dienen |
GB9002804D0 (en) * | 1990-02-08 | 1990-04-04 | Secr Defence | Anionic polymerisation |
US5266649A (en) * | 1992-06-01 | 1993-11-30 | Shell Oil Company | Color stable coupled diene polymers and hot melt adhesives containing them |
US5266644A (en) * | 1992-11-02 | 1993-11-30 | Eastman Kodak Company | Process for preparing epoxy-terminated polymers |
US5391663A (en) * | 1993-11-22 | 1995-02-21 | Shell Oil Company | Protected functional initiators for making terminally functionalized polymers |
US5416168A (en) * | 1994-03-31 | 1995-05-16 | Shell Oil Company | Protected functional initiators for making terminally functionalized polymers |
-
1996
- 1996-04-17 CN CN96194003A patent/CN1101824C/zh not_active Expired - Lifetime
- 1996-04-17 ZA ZA963049A patent/ZA963049B/xx unknown
- 1996-04-17 KR KR1019970707354A patent/KR100456245B1/ko not_active IP Right Cessation
- 1996-04-17 BR BR9608184A patent/BR9608184A/pt not_active Application Discontinuation
- 1996-04-17 JP JP53147596A patent/JP4057649B2/ja not_active Expired - Fee Related
- 1996-04-17 CA CA002218290A patent/CA2218290A1/en not_active Abandoned
- 1996-04-17 ES ES96914950T patent/ES2128858T3/es not_active Expired - Lifetime
- 1996-04-17 DE DE69601704T patent/DE69601704T2/de not_active Expired - Lifetime
- 1996-04-17 WO PCT/EP1996/001637 patent/WO1996033223A1/en active IP Right Grant
- 1996-04-17 EP EP96914950A patent/EP0821699B1/en not_active Expired - Lifetime
- 1996-04-17 AT AT96914950T patent/ATE177435T1/de not_active IP Right Cessation
- 1996-05-14 TW TW085105692A patent/TW390891B/zh not_active IP Right Cessation
- 1996-08-29 US US08/705,032 patent/US5681895A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013513685A (ja) * | 2009-12-10 | 2013-04-22 | ダイナソル エラストメロス,ソシエダット アノニマ | アニオン重合によって合成された機能性ポリマーを含む機能性多分岐ポリマー、及びその使用 |
JP2013544302A (ja) * | 2010-11-16 | 2013-12-12 | ランクセス・ドイチュランド・ゲーエムベーハー | トリアルキルシリルオキシ末端化ポリマー |
Also Published As
Publication number | Publication date |
---|---|
CN1101824C (zh) | 2003-02-19 |
JP4057649B2 (ja) | 2008-03-05 |
ES2128858T3 (es) | 1999-05-16 |
KR19990007831A (ko) | 1999-01-25 |
MX9708019A (es) | 1997-11-29 |
CN1184485A (zh) | 1998-06-10 |
TW390891B (en) | 2000-05-21 |
EP0821699A1 (en) | 1998-02-04 |
KR100456245B1 (ko) | 2005-06-16 |
WO1996033223A1 (en) | 1996-10-24 |
BR9608184A (pt) | 1999-05-04 |
ATE177435T1 (de) | 1999-03-15 |
DE69601704T2 (de) | 1999-08-26 |
EP0821699B1 (en) | 1999-03-10 |
DE69601704D1 (de) | 1999-04-15 |
ZA963049B (en) | 1996-07-29 |
CA2218290A1 (en) | 1996-10-24 |
US5681895A (en) | 1997-10-28 |
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