JPH0548215B2 - - Google Patents

Info

Publication number
JPH0548215B2
JPH0548215B2 JP62503400A JP50340087A JPH0548215B2 JP H0548215 B2 JPH0548215 B2 JP H0548215B2 JP 62503400 A JP62503400 A JP 62503400A JP 50340087 A JP50340087 A JP 50340087A JP H0548215 B2 JPH0548215 B2 JP H0548215B2
Authority
JP
Japan
Prior art keywords
rhodium
hydroformylation
phosphite
group
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP62503400A
Other languages
English (en)
Japanese (ja)
Other versions
JPS63503385A (ja
Inventor
Jon Maikeru Maheru
Deibitsudo Robaato Buraianto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Chemicals and Plastics Technology LLC
Union Carbide Corp
Original Assignee
Union Carbide Chemicals and Plastics Technology LLC
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/865,061 external-priority patent/US4717775A/en
Application filed by Union Carbide Chemicals and Plastics Technology LLC, Union Carbide Corp filed Critical Union Carbide Chemicals and Plastics Technology LLC
Publication of JPS63503385A publication Critical patent/JPS63503385A/ja
Publication of JPH0548215B2 publication Critical patent/JPH0548215B2/ja
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP62503400A 1986-05-20 1987-05-19 改良遷移金属触媒反応 Granted JPS63503385A (ja)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US06/865,061 US4717775A (en) 1984-12-28 1986-05-20 Transition metal complex catalyzed reactions
US865061 1986-05-20
US07/046,821 US4774361A (en) 1986-05-20 1987-05-11 Transition metal complex catalyzed reactions
US46821 1987-05-11

Publications (2)

Publication Number Publication Date
JPS63503385A JPS63503385A (ja) 1988-12-08
JPH0548215B2 true JPH0548215B2 (enExample) 1993-07-20

Family

ID=26724327

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62503400A Granted JPS63503385A (ja) 1986-05-20 1987-05-19 改良遷移金属触媒反応

Country Status (12)

Country Link
US (1) US4774361A (enExample)
EP (1) EP0276231B1 (enExample)
JP (1) JPS63503385A (enExample)
CN (1) CN1010011B (enExample)
AU (1) AU613312B2 (enExample)
CA (1) CA1312094C (enExample)
DE (1) DE3773890D1 (enExample)
ES (1) ES2004935A6 (enExample)
IN (1) IN169727B (enExample)
MX (1) MX166107B (enExample)
NO (1) NO166583C (enExample)
WO (1) WO1987007261A2 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2453320A1 (en) 2000-06-27 2012-05-16 Dai Nippon Printing Co., Ltd. Multilayer volume hologram, and label for multilayer volume hologram fabrication

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US5210318A (en) * 1990-05-04 1993-05-11 Union Carbide Chemicals & Plastics Technology Corporation Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyldehydes
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JP2946790B2 (ja) * 1991-03-14 1999-09-06 三菱化学株式会社 アルデヒド類の製造法
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US5243099A (en) * 1991-12-06 1993-09-07 Union Carbide Chemicals & Plastics Technology Corporation Synthesis of alpha-substituted alkadienes
US5169981A (en) * 1991-12-06 1992-12-08 Union Carbide Chemicals & Plastics Technology Corporation Synthesis of alpha-substituted alkadienes
US5756855A (en) 1994-08-19 1998-05-26 Union Carbide Chemicals & Plastics Technology Corporation Stabilization of phosphite ligands in hydroformylation process
US5672766A (en) * 1994-12-12 1997-09-30 Mitsubishi Chemical Corporation Method for producing aldehydes
KR970703805A (ko) * 1995-05-01 1997-08-09 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크놀러지 코포레이션 막 분리방법(Membrane Separation)
US5739352A (en) * 1995-10-19 1998-04-14 United Carbide Chemicals & Plastics Technology Corporation Process for preparing carboxylic acids
DE19605435A1 (de) * 1996-02-14 1997-08-21 Basf Ag Verfahren zur Herstellung von Aldehyden durch Hydroformylierung mit einem Rhodiumkatalysator und Wiedergewinnung des Rhodiumkatalysators durch Extraktion
US6090987A (en) * 1998-07-06 2000-07-18 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
EP1312598B1 (en) * 1998-12-10 2005-02-16 Mitsubishi Chemical Corporation Process for producing aldehyde
JP3921853B2 (ja) * 1998-12-10 2007-05-30 三菱化学株式会社 アルデヒド類及びアルコール類の製造方法
GB9918229D0 (en) † 1999-08-04 1999-10-06 Ici Plc Improvements relating to metal-compound catalysed processes
DE19954510A1 (de) 1999-11-12 2001-05-17 Oxeno Olefinchemie Gmbh Verfahren zur katalytischen Herstellung von Aldehyden aus Olefinen unter Einsatz von Ligandenmischungen
EP1249441A1 (en) 2001-04-13 2002-10-16 Dsm N.V. Continuous hydroformylation process
DE10220801A1 (de) * 2002-05-10 2003-11-20 Oxeno Olefinchemie Gmbh Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste
RU2337090C2 (ru) * 2002-08-31 2008-10-27 Оксено Олефинхеми Гмбх Способ гидроформилирования олефиновых соединений в присутствии циклических эфиров угольной кислоты
BR0313814B1 (pt) * 2002-08-31 2012-11-27 processo para preparação de aldeìdos por hidroformilação de compostos olefinicamente insaturados, catalisado por complexos metálicos não modificados, na presença de ésteres de ácido carbÈnico cìclicos.
ES2345770T3 (es) * 2003-01-16 2010-10-01 Teijin Fibers Limited Hilo compuesto por filamentos combinados de poliester que tienen diferentes coeficientes de contraccion.
CN1997616B (zh) * 2003-07-03 2011-01-19 陶氏技术投资有限责任公司 配体降解产物的最小化,或其向有用的膦配体的转化
DE10349343A1 (de) * 2003-10-23 2005-06-02 Basf Ag Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden
EP1776328B2 (en) 2004-08-02 2025-03-26 Dow Technology Investments LLC Stabilization of a hydroformylation process
US7863487B2 (en) * 2007-03-20 2011-01-04 Dow Technology Investments Llc Hydroformylation process with improved control over product isomers
CN101681776B (zh) * 2007-04-09 2011-10-05 Lg化学株式会社 含有亚磷酸酯配体的催化剂组合物和使用该催化剂组合物的加氢甲酰化方法
WO2010003073A1 (en) 2008-07-03 2010-01-07 Dow Technology Investments Llc Process of controlling heavies in a recycle catalyst stream
CN102281948B (zh) 2008-11-14 2015-11-25 堪萨斯大学 聚合物负载的过渡金属催化剂络合物及使用方法
KR101706797B1 (ko) 2009-03-31 2017-02-15 다우 테크놀로지 인베스트먼츠 엘엘씨. 이중 개방 말단의 비스포스파이트 리간드를 사용한 하이드로포밀화 방법
US7928267B1 (en) * 2009-06-22 2011-04-19 Eastman Chemical Company Phosphite containing catalysts for hydroformylation processes
EP2488539B2 (en) 2009-10-16 2023-12-20 Dow Technology Investments LLC Gas phase hydroformylation process
JP2013515061A (ja) 2009-12-22 2013-05-02 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 混合リガンドヒドロホルミル化プロセスにおけるノルマル：イソアルデヒド比の制御
CN103951550B (zh) 2009-12-22 2016-06-01 陶氏技术投资有限责任公司 通过控制烯烃分压来控制混合配体加氢甲酰化工艺中的正构:异构醛比率
PL2516372T5 (pl) 2009-12-22 2020-08-10 Dow Technology Investments Llc Regulowanie stosunku aldehyd normalny : izoaldehyd w procesie hydroformowania z mieszanymi ligandami przez regulowanie ciśnienia cząsteczkowego gazu syntezowego
CN103153462B (zh) 2010-10-05 2016-06-01 陶氏技术投资有限责任公司 加氢甲酰基化方法
ES2719425T3 (es) 2010-11-12 2019-07-10 Dow Technology Investments Llc Mitigación de incrustación en procedimientos de hidroformilación mediante adición de agua
SA112330271B1 (ar) 2011-04-18 2015-02-09 داو تكنولوجى انفستمنتس ال ال سى تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء
EP2822921B1 (de) 2012-03-07 2018-06-20 Basf Se Verfahren zur wärmeintegration bei der hydrierung und destillation von c3-c20 aldehyden
MY172695A (en) 2012-04-12 2019-12-10 Basf Se Method for replenishing the catalyst in continuous hydroformylation
US8889917B2 (en) 2012-04-12 2014-11-18 Basf Se Method of supplementing the catalyst in continuous hydroformylation
JP6329136B2 (ja) 2012-06-04 2018-05-23 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセス
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CN104045532B (zh) 2013-03-15 2018-05-25 陶氏技术投资有限责任公司 加氢甲酰化方法
JP2016540780A (ja) 2013-12-19 2016-12-28 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセス
CN104725170B (zh) 2013-12-19 2019-08-23 陶氏技术投资有限责任公司 加氢甲酰化方法
US10131608B2 (en) 2014-03-31 2018-11-20 Dow Technology Investments Llc Hydroformylation process
CN106660915B (zh) 2014-05-14 2020-08-14 陶氏技术投资有限责任公司 稳定的有机磷化合物
MY184826A (en) * 2014-12-04 2021-04-24 Dow Technology Investments Llc Hydroformylation process
TWI709566B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
TWI709568B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
PL3374340T3 (pl) 2015-11-10 2022-04-11 Dow Technology Investments Llc Sposób wytwarzania aldehydów
EP3414220B1 (en) 2016-02-11 2021-10-13 Dow Technology Investments LLC Processes for converting olefins to alcohols, ethers, or combinations thereof
JP6889179B2 (ja) 2016-03-18 2021-06-18 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセス
TW201840362A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TW201840363A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 處理氫甲醯化催化劑溶液之方法
TWI758353B (zh) 2016-11-08 2022-03-21 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
US10981851B2 (en) 2017-10-25 2021-04-20 Dow Technology Investments Llc Hydroformylation process
JP7269238B2 (ja) 2017-11-13 2023-05-08 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセスからロジウムを回収するためのプロセス
TWI793216B (zh) * 2017-12-07 2023-02-21 美商陶氏科技投資公司 氫甲醯化方法
BR112020022070B1 (pt) 2018-05-30 2023-09-26 Dow Technology Investments Llc Método para controlar um processo de hidroformilação para produzir aldeídos
KR20210013703A (ko) 2018-05-30 2021-02-05 다우 테크놀로지 인베스트먼츠 엘엘씨. 모노포스핀, 테트라포스핀 리간드의 조합을 포함하는 촉매 조성물 및 이를 이용하는 하이드로포밀화 공정
CN120271422A (zh) 2018-05-30 2025-07-08 陶氏技术投资有限责任公司 在加氢甲酰化过程中减缓催化剂失活和/或减缓四膦配位体使用的方法
CN113179638B (zh) * 2018-11-29 2023-11-28 陶氏技术投资有限责任公司 加氢甲酰化工艺
KR20220024858A (ko) 2019-06-27 2022-03-03 다우 테크놀로지 인베스트먼츠 엘엘씨. 귀금속 회수를 위한 히드로포르밀화 공정으로부터 용액을 제조하는 공정
TWI874467B (zh) 2019-11-05 2025-03-01 美商陶氏科技投資有限公司 用於自ｃ６或更高碳數烯烴氫甲醯化製程之催化劑淨化流回收銠之方法
WO2021126421A1 (en) 2019-12-19 2021-06-24 Dow Technology Investments Llc Processes for preparing isoprene and mono-olefins comprising at least six carbon atoms
CN114478214B (zh) * 2020-10-23 2024-05-17 中国石油化工股份有限公司 一种氢甲酰化方法和一种氢甲酰化产物的分离方法
CA3201268A1 (en) 2020-12-14 2022-06-23 Michael A. Brammer Processes to improve catalytic metal accountability in hydroformylation processes
CN118103532A (zh) 2021-11-11 2024-05-28 陶氏技术投资有限责任公司 用于从加氢甲酰化过程中回收铑的方法
EP4448170B1 (en) 2021-12-16 2025-08-20 Dow Technology Investments LLC Compounds, transition metal complex hydroformylation catalyst precuror compositions comprising such compounds, and hydroformylation processes
WO2023114578A1 (en) 2021-12-16 2023-06-22 Dow Technology Investments Llc Transition metal complex hydroformylation catalyst precuror compositions comprising such compounds, and hydroformylation processes
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CN121194957A (zh) 2023-06-26 2025-12-23 陶氏技术投资有限责任公司 控制加氢甲酰化工艺的方法
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Also Published As

Publication number Publication date
WO1987007261A2 (en) 1987-12-03
EP0276231B1 (en) 1991-10-16
WO1987007261A3 (en) 1988-04-07
MX166107B (es) 1992-12-21
AU613312B2 (en) 1991-08-01
NO880207D0 (no) 1988-01-19
ES2004935A6 (es) 1989-02-16
CN87104311A (zh) 1988-06-08
CA1312094C (en) 1992-12-29
IN169727B (enExample) 1991-12-14
CN1010011B (zh) 1990-10-17
NO166583B (no) 1991-05-06
JPS63503385A (ja) 1988-12-08
AU7489887A (en) 1987-12-22
NO880207L (no) 1988-01-19
DE3773890D1 (de) 1991-11-21
EP0276231A1 (en) 1988-08-03
US4774361A (en) 1988-09-27
NO166583C (no) 1991-08-14

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