JPH0366325B2 - - Google Patents
Info
- Publication number
- JPH0366325B2 JPH0366325B2 JP57108454A JP10845482A JPH0366325B2 JP H0366325 B2 JPH0366325 B2 JP H0366325B2 JP 57108454 A JP57108454 A JP 57108454A JP 10845482 A JP10845482 A JP 10845482A JP H0366325 B2 JPH0366325 B2 JP H0366325B2
- Authority
- JP
- Japan
- Prior art keywords
- temperature
- ethylene
- copolymer
- melting point
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 61
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 58
- 239000013078 crystal Substances 0.000 claims description 55
- 238000002844 melting Methods 0.000 claims description 44
- 230000008018 melting Effects 0.000 claims description 44
- 229920001577 copolymer Polymers 0.000 claims description 43
- 238000000034 method Methods 0.000 claims description 40
- 229920000573 polyethylene Polymers 0.000 claims description 35
- 229920001038 ethylene copolymer Polymers 0.000 claims description 33
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 32
- 239000000460 chlorine Substances 0.000 claims description 32
- 229910052801 chlorine Inorganic materials 0.000 claims description 32
- 238000005660 chlorination reaction Methods 0.000 claims description 29
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 25
- 239000005977 Ethylene Substances 0.000 claims description 25
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims description 22
- 239000002994 raw material Substances 0.000 claims description 22
- 239000007900 aqueous suspension Substances 0.000 claims description 19
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 239000000155 melt Substances 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 241000694440 Colpidium aqueous Species 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 12
- 239000000047 product Substances 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 10
- 239000002245 particle Substances 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 230000004927 fusion Effects 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000011160 research Methods 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- 238000005054 agglomeration Methods 0.000 description 4
- 230000002776 aggregation Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000012467 final product Substances 0.000 description 4
- 239000004014 plasticizer Substances 0.000 description 4
- -1 polyethylene Polymers 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000004709 Chlorinated polyethylene Substances 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 229920001903 high density polyethylene Polymers 0.000 description 3
- 239000004700 high-density polyethylene Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- WZRRRFSJFQTGGB-UHFFFAOYSA-N 1,3,5-triazinane-2,4,6-trithione Chemical compound S=C1NC(=S)NC(=S)N1 WZRRRFSJFQTGGB-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- OBQXLKFNGBDSSQ-UHFFFAOYSA-N C1=CC=CC=C1.C[Si](O[Si](C)(C)C)(C)C Chemical class C1=CC=CC=C1.C[Si](O[Si](C)(C)C)(C)C OBQXLKFNGBDSSQ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 description 1
- 229920001875 Ebonite Polymers 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- GZETWZZNDACBTQ-UHFFFAOYSA-N [Cl].C=C Chemical group [Cl].C=C GZETWZZNDACBTQ-UHFFFAOYSA-N 0.000 description 1
- 239000000370 acceptor Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000001208 nuclear magnetic resonance pulse sequence Methods 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 238000004736 wide-angle X-ray diffraction Methods 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
- C08F8/22—Halogenation by reaction with free halogens
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP57108454A JPS591512A (ja) | 1982-06-25 | 1982-06-25 | 後塩素化エチレン共重合体の製法 |
US06/506,877 US4547554A (en) | 1982-06-25 | 1983-06-22 | After-chlorinated ethylene/butene-1 copolymer and process for its production |
CA000430920A CA1207949A (fr) | 1982-06-25 | 1983-06-22 | Copolymere post-chlore d'ethylene et de butene-1; methode de preparation |
KR1019830002844A KR900004670B1 (ko) | 1982-06-25 | 1983-06-24 | 후-염소화 에틸렌/부텐-1 공중합체의 제조방법 |
IT21790/83A IT1169739B (it) | 1982-06-25 | 1983-06-24 | Copolimero etilene/butene-1 post-clorurato e procedimento per la sua produzione |
GB08317241A GB2125049B (en) | 1982-06-25 | 1983-06-24 | Chlorinated ethylene/butene-1 copolymer |
DE19833323151 DE3323151A1 (de) | 1982-06-25 | 1983-06-27 | Nachchloriertes aethylen/buten-1-copolymerisat und verfahren zu dessen herstellung |
FR8310556A FR2529210B1 (fr) | 1982-06-25 | 1983-06-27 | Copolymere ethylene/butene-1 post-chlore et sa preparation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP57108454A JPS591512A (ja) | 1982-06-25 | 1982-06-25 | 後塩素化エチレン共重合体の製法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS591512A JPS591512A (ja) | 1984-01-06 |
JPH0366325B2 true JPH0366325B2 (fr) | 1991-10-17 |
Family
ID=14485181
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP57108454A Granted JPS591512A (ja) | 1982-06-25 | 1982-06-25 | 後塩素化エチレン共重合体の製法 |
Country Status (8)
Country | Link |
---|---|
US (1) | US4547554A (fr) |
JP (1) | JPS591512A (fr) |
KR (1) | KR900004670B1 (fr) |
CA (1) | CA1207949A (fr) |
DE (1) | DE3323151A1 (fr) |
FR (1) | FR2529210B1 (fr) |
GB (1) | GB2125049B (fr) |
IT (1) | IT1169739B (fr) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4593075A (en) * | 1983-07-15 | 1986-06-03 | Union Carbide Corporation | Preparation of elastomeric, chlorinated ethylene polymers |
JPS60176755A (ja) * | 1984-02-23 | 1985-09-10 | 大阪曹達株式会社 | 樹脂被覆繊維製品 |
JPH0641484B2 (ja) * | 1985-01-17 | 1994-06-01 | 三井石油化学工業株式会社 | 塩素化プロピレン系重合体,および塩素含有重合体用又は芳香族系重合体用接着剤 |
JPS61209204A (ja) * | 1985-03-13 | 1986-09-17 | Nippon Oil Co Ltd | 塩素化された直鎖状超低密度ポリエチレンの製造方法 |
CN1016429B (zh) * | 1986-11-18 | 1992-04-29 | 昭和电工株式会社 | 氯化乙烯-丙烯类共聚物的生产方法 |
KR910008313B1 (ko) * | 1986-11-18 | 1991-10-12 | 소와 덴꼬 가부시끼가이샤 | 염화 에틸렌-프로필렌계 공중합체의 제조방법 |
US5237010A (en) * | 1990-04-17 | 1993-08-17 | Mitsui Petrochemical Industries, Ltd. | Chlorinated ethylene-α-olefin copolymer rubber and composition |
CA2040570A1 (fr) * | 1990-04-17 | 1991-10-18 | Tetsuo Tojo | Caoutchouc a base de copolymere d'ethylene-.alpha.-olefine chloree et composition ainsi obtenue |
JPH0670086B2 (ja) * | 1990-06-29 | 1994-09-07 | 日本製紙株式会社 | 塩化ゴムの製造方法 |
DE4203439B4 (de) * | 1992-02-06 | 2006-04-13 | Showa Denko K.K. | Verfahren zur Herstellung von chlorierten Polyolefinen |
US5470919A (en) * | 1993-07-29 | 1995-11-28 | Mitsui Petrochemical Industries, Ltd. | Chlorinated ethylene/α-olefin copolymer rubber and composition containing the same |
US20150086800A1 (en) * | 2013-09-04 | 2015-03-26 | Roderick Hughes | Stress-Resistant Extrudates |
US10253207B2 (en) * | 2013-09-04 | 2019-04-09 | Roderick Hughes | Stress-resistant extrudates |
CN104987436A (zh) * | 2015-08-07 | 2015-10-21 | 芜湖融汇化工有限公司 | 一种pvg整芯阻燃输送带用氯化聚乙烯、制备方法及其应用 |
US10680256B2 (en) * | 2016-03-31 | 2020-06-09 | Sumitomo Riko Company Limited | Sealing member for a fuel cell |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL248355A (fr) * | 1960-02-12 | |||
FR1316044A (fr) * | 1961-02-01 | 1963-01-25 | Allied Chem | Procédé d'halogénation de polymères d'hydrocarbures |
GB1167460A (en) * | 1968-08-05 | 1969-10-15 | Allied Chem | Chlorinated Polyethylene and its Production |
GB1299710A (en) * | 1970-11-03 | 1972-12-13 | Osaka Soda Co Ltd | Process for the preparation of chlorinated ethylene polymers and compositions thereof |
US3867315A (en) * | 1973-02-12 | 1975-02-18 | Dow Chemical Co | Resinous compositions having high electroconductivity containing Cu and metal salts |
US3874987A (en) * | 1974-03-13 | 1975-04-01 | Dow Chemical Co | Laminate of a moisture impervious polyethylene foam and a suspension chlorinated polyethylene sheet |
US4104289A (en) * | 1976-09-20 | 1978-08-01 | The Dow Chemical Company | Filled thermoplastic resin compositions |
NL7701599A (nl) * | 1977-02-16 | 1978-08-18 | Stamicarbon | Werkwijze voor het chloreren van etheen- polymeren. |
JPS5767604A (en) * | 1980-10-16 | 1982-04-24 | Mitsui Petrochem Ind Ltd | Chorinated rubber |
-
1982
- 1982-06-25 JP JP57108454A patent/JPS591512A/ja active Granted
-
1983
- 1983-06-22 US US06/506,877 patent/US4547554A/en not_active Expired - Lifetime
- 1983-06-22 CA CA000430920A patent/CA1207949A/fr not_active Expired
- 1983-06-24 KR KR1019830002844A patent/KR900004670B1/ko not_active IP Right Cessation
- 1983-06-24 GB GB08317241A patent/GB2125049B/en not_active Expired
- 1983-06-24 IT IT21790/83A patent/IT1169739B/it active
- 1983-06-27 DE DE19833323151 patent/DE3323151A1/de active Granted
- 1983-06-27 FR FR8310556A patent/FR2529210B1/fr not_active Expired
Also Published As
Publication number | Publication date |
---|---|
GB2125049A (en) | 1984-02-29 |
GB2125049B (en) | 1985-10-16 |
FR2529210B1 (fr) | 1985-08-23 |
IT1169739B (it) | 1987-06-03 |
KR900004670B1 (ko) | 1990-07-02 |
DE3323151C2 (fr) | 1993-02-18 |
GB8317241D0 (en) | 1983-07-27 |
JPS591512A (ja) | 1984-01-06 |
KR840005159A (ko) | 1984-11-05 |
DE3323151A1 (de) | 1983-12-29 |
US4547554A (en) | 1985-10-15 |
IT8321790A0 (it) | 1983-06-24 |
FR2529210A1 (fr) | 1983-12-30 |
CA1207949A (fr) | 1986-07-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPH0366325B2 (fr) | ||
US20050032959A1 (en) | Filled thermoplastic olefin composition | |
EP3201265B9 (fr) | Compositions polymères à base d'éthylène pouvant être soudées à haute fréquence présentant de bonnes propriétés ignifuges | |
US5055539A (en) | Molding made from a vinylidene fluoride copolymer and process for its production | |
AU7996298A (en) | Process for the manufacture of a composition comprising ethylene polymers | |
JPS59135242A (ja) | ポリオレフイン、イソブチレンを主鎖とするエラストマ−及びエチレンコポリマ−の熱可塑性ブレンド | |
JPH08512085A (ja) | Lldpeベースの高加工性ポリマー組成物 | |
JP2507778B2 (ja) | ポリ塩化ビニル、塩素化またはクロロスルフオン化されたポリエチレン及びエチレン含有三元重合体から成る配合物 | |
JPS6242921B2 (fr) | ||
JP2001510872A (ja) | 難燃性ポリオレフィン組成物 | |
JP2000511121A (ja) | フッ素含有ポリマーを含む多層組成物および物品 | |
EP2867013B1 (fr) | Article comprenant une mousse polymérique ignifuge | |
JPS60212403A (ja) | 塩素化されたエチレン共重合体の製法 | |
JP4748827B2 (ja) | ストレッチフィルム用軟質フィルム | |
JPH0517243B2 (fr) | ||
JPS6031503A (ja) | 成型性の良好な塩素化ポリエチレンゴムの製造法 | |
JP5886275B2 (ja) | 熱可塑性組成物およびそれにより形成した物品 | |
EP1539829B1 (fr) | Polyolefines chlorees et leur procede de production | |
JP2924188B2 (ja) | 塩素化ポリエチレンの製造方法 | |
JPH10306119A (ja) | カレンダー成型用ポリプロピレン系樹脂 | |
JP3800797B2 (ja) | 塩素化ポリオレフィン | |
JP3360862B2 (ja) | 軟質オレフィン系重合体組成物 | |
JPS58466B2 (ja) | ジユシソセイブツ | |
JP2002327095A (ja) | 難燃性ポリオレフィン系テープ基材用樹脂組成物およびそれから製造される難燃性テープ基材 | |
JPH03163146A (ja) | 塩素化ポリエチレンゴム組成物 |