JPH0366325B2 - - Google Patents
Info
- Publication number
- JPH0366325B2 JPH0366325B2 JP57108454A JP10845482A JPH0366325B2 JP H0366325 B2 JPH0366325 B2 JP H0366325B2 JP 57108454 A JP57108454 A JP 57108454A JP 10845482 A JP10845482 A JP 10845482A JP H0366325 B2 JPH0366325 B2 JP H0366325B2
- Authority
- JP
- Japan
- Prior art keywords
- temperature
- ethylene
- copolymer
- melting point
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 61
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 58
- 239000013078 crystal Substances 0.000 claims description 55
- 238000002844 melting Methods 0.000 claims description 44
- 230000008018 melting Effects 0.000 claims description 44
- 229920001577 copolymer Polymers 0.000 claims description 43
- 238000000034 method Methods 0.000 claims description 40
- 229920000573 polyethylene Polymers 0.000 claims description 35
- 229920001038 ethylene copolymer Polymers 0.000 claims description 33
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 32
- 239000000460 chlorine Substances 0.000 claims description 32
- 229910052801 chlorine Inorganic materials 0.000 claims description 32
- 238000005660 chlorination reaction Methods 0.000 claims description 29
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 25
- 239000005977 Ethylene Substances 0.000 claims description 25
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims description 22
- 239000002994 raw material Substances 0.000 claims description 22
- 239000007900 aqueous suspension Substances 0.000 claims description 19
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 239000000155 melt Substances 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 241000694440 Colpidium aqueous Species 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 12
- 239000000047 product Substances 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 10
- 239000002245 particle Substances 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 230000004927 fusion Effects 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000011160 research Methods 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- 238000005054 agglomeration Methods 0.000 description 4
- 230000002776 aggregation Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000012467 final product Substances 0.000 description 4
- 239000004014 plasticizer Substances 0.000 description 4
- -1 polyethylene Polymers 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000004709 Chlorinated polyethylene Substances 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 229920001903 high density polyethylene Polymers 0.000 description 3
- 239000004700 high-density polyethylene Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- WZRRRFSJFQTGGB-UHFFFAOYSA-N 1,3,5-triazinane-2,4,6-trithione Chemical compound S=C1NC(=S)NC(=S)N1 WZRRRFSJFQTGGB-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- OBQXLKFNGBDSSQ-UHFFFAOYSA-N C1=CC=CC=C1.C[Si](O[Si](C)(C)C)(C)C Chemical class C1=CC=CC=C1.C[Si](O[Si](C)(C)C)(C)C OBQXLKFNGBDSSQ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 description 1
- 229920001875 Ebonite Polymers 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- GZETWZZNDACBTQ-UHFFFAOYSA-N [Cl].C=C Chemical group [Cl].C=C GZETWZZNDACBTQ-UHFFFAOYSA-N 0.000 description 1
- 239000000370 acceptor Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000001208 nuclear magnetic resonance pulse sequence Methods 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 238000004736 wide-angle X-ray diffraction Methods 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
- C08F8/22—Halogenation by reaction with free halogens
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57108454A JPS591512A (ja) | 1982-06-25 | 1982-06-25 | 後塩素化エチレン共重合体の製法 |
| US06/506,877 US4547554A (en) | 1982-06-25 | 1983-06-22 | After-chlorinated ethylene/butene-1 copolymer and process for its production |
| CA000430920A CA1207949A (fr) | 1982-06-25 | 1983-06-22 | Copolymere post-chlore d'ethylene et de butene-1; methode de preparation |
| KR1019830002844A KR900004670B1 (ko) | 1982-06-25 | 1983-06-24 | 후-염소화 에틸렌/부텐-1 공중합체의 제조방법 |
| IT21790/83A IT1169739B (it) | 1982-06-25 | 1983-06-24 | Copolimero etilene/butene-1 post-clorurato e procedimento per la sua produzione |
| GB08317241A GB2125049B (en) | 1982-06-25 | 1983-06-24 | Chlorinated ethylene/butene-1 copolymer |
| DE19833323151 DE3323151A1 (de) | 1982-06-25 | 1983-06-27 | Nachchloriertes aethylen/buten-1-copolymerisat und verfahren zu dessen herstellung |
| FR8310556A FR2529210B1 (fr) | 1982-06-25 | 1983-06-27 | Copolymere ethylene/butene-1 post-chlore et sa preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57108454A JPS591512A (ja) | 1982-06-25 | 1982-06-25 | 後塩素化エチレン共重合体の製法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS591512A JPS591512A (ja) | 1984-01-06 |
| JPH0366325B2 true JPH0366325B2 (fr) | 1991-10-17 |
Family
ID=14485181
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57108454A Granted JPS591512A (ja) | 1982-06-25 | 1982-06-25 | 後塩素化エチレン共重合体の製法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4547554A (fr) |
| JP (1) | JPS591512A (fr) |
| KR (1) | KR900004670B1 (fr) |
| CA (1) | CA1207949A (fr) |
| DE (1) | DE3323151A1 (fr) |
| FR (1) | FR2529210B1 (fr) |
| GB (1) | GB2125049B (fr) |
| IT (1) | IT1169739B (fr) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4593075A (en) * | 1983-07-15 | 1986-06-03 | Union Carbide Corporation | Preparation of elastomeric, chlorinated ethylene polymers |
| JPS60176755A (ja) * | 1984-02-23 | 1985-09-10 | 大阪曹達株式会社 | 樹脂被覆繊維製品 |
| JPH0641484B2 (ja) * | 1985-01-17 | 1994-06-01 | 三井石油化学工業株式会社 | 塩素化プロピレン系重合体，および塩素含有重合体用又は芳香族系重合体用接着剤 |
| JPS61209204A (ja) * | 1985-03-13 | 1986-09-17 | Nippon Oil Co Ltd | 塩素化された直鎖状超低密度ポリエチレンの製造方法 |
| CN1016429B (zh) * | 1986-11-18 | 1992-04-29 | 昭和电工株式会社 | 氯化乙烯-丙烯类共聚物的生产方法 |
| KR910008313B1 (ko) * | 1986-11-18 | 1991-10-12 | 소와 덴꼬 가부시끼가이샤 | 염화 에틸렌-프로필렌계 공중합체의 제조방법 |
| US5237010A (en) * | 1990-04-17 | 1993-08-17 | Mitsui Petrochemical Industries, Ltd. | Chlorinated ethylene-α-olefin copolymer rubber and composition |
| CA2040570A1 (fr) * | 1990-04-17 | 1991-10-18 | Tetsuo Tojo | Caoutchouc a base de copolymere d'ethylene-.alpha.-olefine chloree et composition ainsi obtenue |
| JPH0670086B2 (ja) * | 1990-06-29 | 1994-09-07 | 日本製紙株式会社 | 塩化ゴムの製造方法 |
| DE4203439B4 (de) * | 1992-02-06 | 2006-04-13 | Showa Denko K.K. | Verfahren zur Herstellung von chlorierten Polyolefinen |
| US5470919A (en) * | 1993-07-29 | 1995-11-28 | Mitsui Petrochemical Industries, Ltd. | Chlorinated ethylene/α-olefin copolymer rubber and composition containing the same |
| US20150086800A1 (en) * | 2013-09-04 | 2015-03-26 | Roderick Hughes | Stress-Resistant Extrudates |
| US10253207B2 (en) * | 2013-09-04 | 2019-04-09 | Roderick Hughes | Stress-resistant extrudates |
| CN104987436A (zh) * | 2015-08-07 | 2015-10-21 | 芜湖融汇化工有限公司 | 一种pvg整芯阻燃输送带用氯化聚乙烯、制备方法及其应用 |
| US10680256B2 (en) * | 2016-03-31 | 2020-06-09 | Sumitomo Riko Company Limited | Sealing member for a fuel cell |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL248355A (fr) * | 1960-02-12 | |||
| FR1316044A (fr) * | 1961-02-01 | 1963-01-25 | Allied Chem | Procédé d'halogénation de polymères d'hydrocarbures |
| GB1167460A (en) * | 1968-08-05 | 1969-10-15 | Allied Chem | Chlorinated Polyethylene and its Production |
| GB1299710A (en) * | 1970-11-03 | 1972-12-13 | Osaka Soda Co Ltd | Process for the preparation of chlorinated ethylene polymers and compositions thereof |
| US3867315A (en) * | 1973-02-12 | 1975-02-18 | Dow Chemical Co | Resinous compositions having high electroconductivity containing Cu and metal salts |
| US3874987A (en) * | 1974-03-13 | 1975-04-01 | Dow Chemical Co | Laminate of a moisture impervious polyethylene foam and a suspension chlorinated polyethylene sheet |
| US4104289A (en) * | 1976-09-20 | 1978-08-01 | The Dow Chemical Company | Filled thermoplastic resin compositions |
| NL7701599A (nl) * | 1977-02-16 | 1978-08-18 | Stamicarbon | Werkwijze voor het chloreren van etheen- polymeren. |
| JPS5767604A (en) * | 1980-10-16 | 1982-04-24 | Mitsui Petrochem Ind Ltd | Chorinated rubber |
-
1982
- 1982-06-25 JP JP57108454A patent/JPS591512A/ja active Granted
-
1983
- 1983-06-22 US US06/506,877 patent/US4547554A/en not_active Expired - Lifetime
- 1983-06-22 CA CA000430920A patent/CA1207949A/fr not_active Expired
- 1983-06-24 KR KR1019830002844A patent/KR900004670B1/ko not_active IP Right Cessation
- 1983-06-24 GB GB08317241A patent/GB2125049B/en not_active Expired
- 1983-06-24 IT IT21790/83A patent/IT1169739B/it active
- 1983-06-27 DE DE19833323151 patent/DE3323151A1/de active Granted
- 1983-06-27 FR FR8310556A patent/FR2529210B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB2125049A (en) | 1984-02-29 |
| GB2125049B (en) | 1985-10-16 |
| FR2529210B1 (fr) | 1985-08-23 |
| IT1169739B (it) | 1987-06-03 |
| KR900004670B1 (ko) | 1990-07-02 |
| DE3323151C2 (fr) | 1993-02-18 |
| GB8317241D0 (en) | 1983-07-27 |
| JPS591512A (ja) | 1984-01-06 |
| KR840005159A (ko) | 1984-11-05 |
| DE3323151A1 (de) | 1983-12-29 |
| US4547554A (en) | 1985-10-15 |
| IT8321790A0 (it) | 1983-06-24 |
| FR2529210A1 (fr) | 1983-12-30 |
| CA1207949A (fr) | 1986-07-15 |
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