JP6524630B2

JP6524630B2 - 樹脂組成物、及び樹脂成形体

樹脂組成物、及び樹脂成形体 Download PDF

Info

Publication number: JP6524630B2
Authority: JP; Japan
Prior art keywords: resin; resin composition; cellulose ester; less; group
Prior art date: 2014-09-26
Legal status : Expired - Fee Related

Application number

JP2014197378A

Other languages

English (en)

Japanese (ja)

Other versions

JP2016069422A (ja

JP2016069422A5 (enExample

Inventor

八百　健二

健二八百

正洋森山

学川島

雅也生野

Current Assignee

Fujifilm Business Innovation Corp

Original Assignee

Fuji Xerox Co Ltd

Fujifilm Business Innovation Corp

Priority date

2014-09-26

Filing date

2014-09-26

Publication date

2019-06-05

2014-09-26 Application filed by Fuji Xerox Co Ltd, Fujifilm Business Innovation Corp filed Critical Fuji Xerox Co Ltd

2014-09-26 Priority to JP2014197378A priority Critical patent/JP6524630B2/ja

2015-02-02 Priority to US14/611,665 priority patent/US9441096B2/en

2015-03-13 Priority to CN201510111793.9A priority patent/CN106032414B/zh

2016-04-28 Priority to US15/140,810 priority patent/US9605137B2/en

2016-04-28 Priority to US15/140,601 priority patent/US9605136B2/en

2016-04-28 Priority to US15/140,873 priority patent/US9605138B2/en

2016-04-28 Priority to US15/140,966 priority patent/US9605139B2/en

2016-05-09 Publication of JP2016069422A publication Critical patent/JP2016069422A/ja

2017-11-02 Publication of JP2016069422A5 publication Critical patent/JP2016069422A5/ja

2019-06-05 Application granted granted Critical

2019-06-05 Publication of JP6524630B2 publication Critical patent/JP6524630B2/ja

Status Expired - Fee Related legal-status Critical Current

2034-09-26 Anticipated expiration legal-status Critical

Links

229920005989 resin Polymers 0.000 title claims description 152
239000011347 resin Substances 0.000 title claims description 152
239000011342 resin composition Substances 0.000 title claims description 115
229920002678 cellulose Polymers 0.000 claims description 78
-1 ester compound Chemical class 0.000 claims description 70
238000000465 moulding Methods 0.000 claims description 69
239000004721 Polyphenylene oxide Substances 0.000 claims description 53
229920000570 polyether Polymers 0.000 claims description 53
125000004432 carbon atom Chemical group C* 0.000 claims description 34
150000001875 compounds Chemical group 0.000 claims description 34
125000002947 alkylene group Chemical group 0.000 claims description 26
229920005672 polyolefin resin Polymers 0.000 claims description 24
125000003710 aryl alkyl group Chemical group 0.000 claims description 14
125000002252 acyl group Chemical group 0.000 claims description 13
125000003118 aryl group Chemical group 0.000 claims description 13
238000006467 substitution reaction Methods 0.000 claims description 13
125000000217 alkyl group Chemical group 0.000 claims description 8
125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims description 7
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
229910000831 Steel Inorganic materials 0.000 description 38
239000010959 steel Substances 0.000 description 38
239000000047 product Substances 0.000 description 22
239000004014 plasticizer Substances 0.000 description 12
238000001746 injection moulding Methods 0.000 description 10
239000000203 mixture Substances 0.000 description 10
238000000034 method Methods 0.000 description 8
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 8
238000007493 shaping process Methods 0.000 description 6
229920002554 vinyl polymer Polymers 0.000 description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
229910052799 carbon Inorganic materials 0.000 description 5
229920006026 co-polymeric resin Polymers 0.000 description 5
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 5
239000000463 material Substances 0.000 description 4
230000001629 suppression Effects 0.000 description 4
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical group CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
150000001336 alkenes Chemical class 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
125000004122 cyclic group Chemical group 0.000 description 3
239000011521 glass Substances 0.000 description 3
238000004898 kneading Methods 0.000 description 3
239000008188 pellet Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
239000001913 cellulose Substances 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
238000002425 crystallisation Methods 0.000 description 2
230000008025 crystallization Effects 0.000 description 2
LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
238000011156 evaluation Methods 0.000 description 2
230000008020 evaporation Effects 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
238000005259 measurement Methods 0.000 description 2
239000000155 melt Substances 0.000 description 2
CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
229920006324 polyoxymethylene Polymers 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
239000002904 solvent Substances 0.000 description 2
238000012360 testing method Methods 0.000 description 2
229920005992 thermoplastic resin Polymers 0.000 description 2
UAOUIVVJBYDFKD-XKCDOFEDSA-N (1R,9R,10S,11R,12R,15S,18S,21R)-10,11,21-trihydroxy-8,8-dimethyl-14-methylidene-4-(prop-2-enylamino)-20-oxa-5-thia-3-azahexacyclo[9.7.2.112,15.01,9.02,6.012,18]henicosa-2(6),3-dien-13-one Chemical compound C([C@@H]1[C@@H](O)[C@@]23C(C1=C)=O)C[C@H]2[C@]12C(N=C(NCC=C)S4)=C4CC(C)(C)[C@H]1[C@H](O)[C@]3(O)OC2 UAOUIVVJBYDFKD-XKCDOFEDSA-N 0.000 description 1
DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
PCBPVYHMZBWMAZ-UHFFFAOYSA-N 5-methylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C)CC1C=C2 PCBPVYHMZBWMAZ-UHFFFAOYSA-N 0.000 description 1
229910052582 BN Inorganic materials 0.000 description 1
PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
229920000049 Carbon (fiber) Polymers 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
125000003535 D-glucopyranosyl group Chemical group [H]OC([H])([H])[C@@]1([H])OC([H])(*)[C@]([H])(O[H])[C@@]([H])(O[H])[C@]1([H])O[H] 0.000 description 1
229920002943 EPDM rubber Polymers 0.000 description 1
239000004696 Poly ether ether ketone Substances 0.000 description 1
229930182556 Polyacetal Natural products 0.000 description 1
239000004693 Polybenzimidazole Substances 0.000 description 1
239000004697 Polyetherimide Substances 0.000 description 1
239000004734 Polyphenylene sulfide Substances 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
229910052581 Si3N4 Inorganic materials 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
LJOOWESTVASNOG-UFJKPHDISA-N [(1s,3r,4ar,7s,8s,8as)-3-hydroxy-8-[2-[(4r)-4-hydroxy-6-oxooxan-2-yl]ethyl]-7-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-yl] (2s)-2-methylbutanoate Chemical compound C([C@H]1[C@@H](C)C=C[C@H]2C[C@@H](O)C[C@@H]([C@H]12)OC(=O)[C@@H](C)CC)CC1C[C@@H](O)CC(=O)O1 LJOOWESTVASNOG-UFJKPHDISA-N 0.000 description 1
230000002159 abnormal effect Effects 0.000 description 1
239000011354 acetal resin Substances 0.000 description 1
239000002253 acid Substances 0.000 description 1
125000005396 acrylic acid ester group Chemical group 0.000 description 1
150000008360 acrylonitriles Chemical class 0.000 description 1
230000010933 acylation Effects 0.000 description 1
238000005917 acylation reaction Methods 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
239000011324 bead Substances 0.000 description 1
235000013361 beverage Nutrition 0.000 description 1
230000000740 bleeding effect Effects 0.000 description 1
238000000071 blow moulding Methods 0.000 description 1
125000004063 butyryl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000011088 calibration curve Methods 0.000 description 1
239000004917 carbon fiber Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
229910052570 clay Inorganic materials 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000003086 colorant Substances 0.000 description 1
229940127204 compound 29 Drugs 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
238000005336 cracking Methods 0.000 description 1
229910002026 crystalline silica Inorganic materials 0.000 description 1
ZXIJMRYMVAMXQP-UHFFFAOYSA-N cycloheptene Chemical compound C1CCC=CCC1 ZXIJMRYMVAMXQP-UHFFFAOYSA-N 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
125000006182 dimethyl benzyl group Chemical group 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
230000002708 enhancing effect Effects 0.000 description 1
LDLDYFCCDKENPD-UHFFFAOYSA-N ethenylcyclohexane Chemical compound C=CC1CCCCC1 LDLDYFCCDKENPD-UHFFFAOYSA-N 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000003063 flame retardant Substances 0.000 description 1
239000003365 glass fiber Substances 0.000 description 1
238000004128 high performance liquid chromatography Methods 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000004973 liquid crystal related substance Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
125000005397 methacrylic acid ester group Chemical group 0.000 description 1
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
125000006178 methyl benzyl group Chemical group 0.000 description 1
239000010445 mica Substances 0.000 description 1
229910052618 mica group Inorganic materials 0.000 description 1
239000003607 modifier Substances 0.000 description 1
239000006082 mold release agent Substances 0.000 description 1
239000000178 monomer Substances 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
125000001624 naphthyl group Chemical group 0.000 description 1
150000004767 nitrides Chemical class 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
125000004344 phenylpropyl group Chemical group 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920001643 poly(ether ketone) Polymers 0.000 description 1
229920002492 poly(sulfone) Polymers 0.000 description 1
229920000412 polyarylene Polymers 0.000 description 1
229920002480 polybenzimidazole Polymers 0.000 description 1
229920005668 polycarbonate resin Polymers 0.000 description 1
239000004431 polycarbonate resin Substances 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920001225 polyester resin Polymers 0.000 description 1
239000004645 polyester resin Substances 0.000 description 1
229920002530 polyetherether ketone Polymers 0.000 description 1
229920001601 polyetherimide Polymers 0.000 description 1
229920001470 polyketone Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229920001955 polyphenylene ether Polymers 0.000 description 1
229920000069 polyphenylene sulfide Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 1
239000012744 reinforcing agent Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
238000003860 storage Methods 0.000 description 1
150000003457 sulfones Chemical class 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
XBFJAVXCNXDMBH-UHFFFAOYSA-N tetracyclo[6.2.1.1(3,6).0(2,7)]dodec-4-ene Chemical compound C1C(C23)C=CC1C3C1CC2CC1 XBFJAVXCNXDMBH-UHFFFAOYSA-N 0.000 description 1
AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 1
125000003944 tolyl group Chemical group 0.000 description 1
238000001721 transfer moulding Methods 0.000 description 1
XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
238000005303 weighing Methods 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1