JP6363072B2 - 低表面エネルギー基及びヒドロキシル基を含む添加剤、並びにコーティング組成物 - Google Patents
低表面エネルギー基及びヒドロキシル基を含む添加剤、並びにコーティング組成物 Download PDFInfo
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- JP6363072B2 JP6363072B2 JP2015518416A JP2015518416A JP6363072B2 JP 6363072 B2 JP6363072 B2 JP 6363072B2 JP 2015518416 A JP2015518416 A JP 2015518416A JP 2015518416 A JP2015518416 A JP 2015518416A JP 6363072 B2 JP6363072 B2 JP 6363072B2
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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| TWI624519B (zh) | 2012-12-20 | 2018-05-21 | 3M新設資產公司 | 包含具有吸收紫外線基團之寡聚物之氟聚合物組合物 |
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| CN106661365B (zh) * | 2014-06-25 | 2019-03-01 | 3M创新有限公司 | 包含至少一种低聚物的含氟聚合物组合物 |
| US11110689B2 (en) | 2014-06-25 | 2021-09-07 | 3M Innovative Properties Company | Pressure sensitive adhesive composition including ultraviolet light-absorbing oligomer |
| CN106661221B (zh) * | 2014-08-19 | 2018-11-30 | 3M创新有限公司 | 两亲性聚合物、涂料组合物以及方法 |
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| BE536477A (enExample) | 1954-03-15 | 1900-01-01 | ||
| US2803615A (en) | 1956-01-23 | 1957-08-20 | Minnesota Mining & Mfg | Fluorocarbon acrylate and methacrylate esters and polymers |
| US3220972A (en) | 1962-07-02 | 1965-11-30 | Gen Electric | Organosilicon process using a chloroplatinic acid reaction product as the catalyst |
| US3159662A (en) | 1962-07-02 | 1964-12-01 | Gen Electric | Addition reaction |
| US3250808A (en) | 1963-10-31 | 1966-05-10 | Du Pont | Fluorocarbon ethers derived from hexafluoropropylene epoxide |
| US3410886A (en) | 1965-10-23 | 1968-11-12 | Union Carbide Corp | Si-h to c=c or c=c addition in the presence of a nitrile-platinum (ii) halide complex |
| US3553179A (en) | 1968-05-06 | 1971-01-05 | Du Pont | Acrylate-type esters of perfluoropoly-oxa-alkaneamidoalkyl alcohols and their polymers |
| US3544537A (en) | 1968-05-31 | 1970-12-01 | Du Pont | Poly(perfluoroalkoxy)polyfluoroalkyl acrylate-type esters and their polymers |
| FR2067764A5 (enExample) | 1969-11-15 | 1971-08-20 | Raffinage Cie Francaise | |
| US4013615A (en) | 1973-05-14 | 1977-03-22 | Tekkosha Co., Ltd. | Electrostatic spray coating powder pigment composition and process for producing the same |
| US4262072A (en) | 1979-06-25 | 1981-04-14 | Minnesota Mining And Manufacturing Company | Poly(ethylenically unsaturated alkoxy) heterocyclic protective coatings |
| US4557751A (en) | 1981-03-10 | 1985-12-10 | Minnesota Mining And Manufacturing Company | Compositions containing surfactant and broadleaf foliar herbicide |
| US4654233A (en) | 1984-11-21 | 1987-03-31 | Minnesota Mining And Manufacturing Company | Radiation-curable thermoplastic coating |
| US4728571A (en) | 1985-07-19 | 1988-03-01 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafted copolymer release coating sheets and adhesive tapes |
| US4609574A (en) | 1985-10-03 | 1986-09-02 | Dow Corning Corporation | Silicone release coatings containing higher alkenyl functional siloxanes |
| US4855184A (en) | 1988-02-02 | 1989-08-08 | Minnesota Mining And Manufacturing Company | Radiation-curable protective coating composition |
| US5145886A (en) | 1988-05-19 | 1992-09-08 | Minnesota Mining And Manufacturing Company | Radiation activated hydrosilation reaction |
| US4916169A (en) | 1988-09-09 | 1990-04-10 | Minnesota Mining And Manufacturing Company | Visible radiation activated hydrosilation reaction |
| US5173363A (en) | 1990-11-01 | 1992-12-22 | Van Leer Metallized Products (Usa) Limited | Coating sheet which wicks away oil |
| US5882774A (en) | 1993-12-21 | 1999-03-16 | Minnesota Mining And Manufacturing Company | Optical film |
| JP3971455B2 (ja) | 1993-12-21 | 2007-09-05 | スリーエム カンパニー | 多層光学フィルム |
| US5648407A (en) | 1995-05-16 | 1997-07-15 | Minnesota Mining And Manufacturing Company | Curable resin sols and fiber-reinforced composites derived therefrom |
| US5677050A (en) | 1995-05-19 | 1997-10-14 | Minnesota Mining And Manufacturing Company | Retroreflective sheeting having an abrasion resistant ceramer coating |
| AU715827B2 (en) | 1995-06-22 | 2000-02-10 | Minnesota Mining And Manufacturing Company | Stable hydroalcoholic compositions |
| WO1997001440A1 (en) | 1995-06-26 | 1997-01-16 | Minnesota Mining And Manufacturing Company | Multilayer polymer film with additional coatings or layers |
| JP3048041B2 (ja) | 1995-09-04 | 2000-06-05 | 東亞合成株式会社 | 塗料用重合体の製造方法 |
| US5581905A (en) | 1995-09-18 | 1996-12-10 | Minnesota Mining And Manufacturing Company | Coated substrate drying system |
| US5694701A (en) | 1996-09-04 | 1997-12-09 | Minnesota Mining And Manufacturing Company | Coated substrate drying system |
| US5804625A (en) * | 1996-05-21 | 1998-09-08 | Minnesota Mining And Manufacturing Company | Fluorochemical and hydrocarbon surfactant blends as hydrophilic additives to thermoplastic polymers |
| US6019997A (en) | 1997-01-09 | 2000-02-01 | Minnesota Mining And Manufacturing | Hydroalcoholic compositions for transdermal penetration of pharmaceutical agents |
| AU2478499A (en) | 1998-01-28 | 1999-08-16 | Minnesota Mining And Manufacturing Company | Infrared interference filter |
| US7351470B2 (en) | 1998-02-19 | 2008-04-01 | 3M Innovative Properties Company | Removable antireflection film |
| US6134808A (en) | 1998-05-18 | 2000-10-24 | Minnesota Mining And Manufacturing Company | Gap drying with insulation layer between substrate and heated platen |
| US6224949B1 (en) | 1998-06-11 | 2001-05-01 | 3M Innovative Properties Company | Free radical polymerization method |
| JP2000144119A (ja) | 1998-08-31 | 2000-05-26 | Asahi Glass Co Ltd | 水系防汚加工剤組成物とその製造方法およびそれで処理された被処理物 |
| US6299799B1 (en) | 1999-05-27 | 2001-10-09 | 3M Innovative Properties Company | Ceramer compositions and antistatic abrasion resistant ceramers made therefrom |
| US6174964B1 (en) | 1999-09-24 | 2001-01-16 | 3M Innovative Properties Company | Fluorochemical oligomer and use thereof |
| JP4855616B2 (ja) | 1999-10-27 | 2012-01-18 | スリーエム イノベイティブ プロパティズ カンパニー | フルオロケミカルスルホンアミド界面活性剤 |
| US6376590B2 (en) | 1999-10-28 | 2002-04-23 | 3M Innovative Properties Company | Zirconia sol, process of making and composite material |
| JP2003514977A (ja) | 1999-11-22 | 2003-04-22 | スリーエム イノベイティブ プロパティズ カンパニー | 水をベースとするコーティング組成物 |
| DE60118576T2 (de) | 2000-08-18 | 2006-11-02 | 3M Innovative Properties Co., Saint Paul | Fluoro(meth)acrylatecopolymer-beschichtungsmassen |
| KR20020054756A (ko) | 2000-12-28 | 2002-07-08 | 정종순 | 전기아연도금강판 피복용 수용성 도료 조성물 |
| DE10221967A1 (de) | 2002-05-17 | 2003-11-27 | Behr Gmbh & Co | Wärmetauscher, insbesondere für eine Heizungs- oder Klimaanlage eines Kraftfahrzeuges |
| US6991695B2 (en) | 2002-05-21 | 2006-01-31 | 3M Innovative Properties Company | Method for subdividing multilayer optical film cleanly and rapidly |
| JP2005527677A (ja) | 2002-05-24 | 2005-09-15 | スリーエム イノベイティブ プロパティズ カンパニー | 弗素化ポリエーテルを含むフルオロケミカル組成物および該組成物による繊維基材の処理 |
| JP4216031B2 (ja) * | 2002-09-24 | 2009-01-28 | リンテック株式会社 | タッチパネル又はディスプレー用ハードコートフィルム |
| KR101014582B1 (ko) | 2002-11-13 | 2011-02-16 | 아사히 가라스 가부시키가이샤 | 활성 에너지선 경화형 피복용 조성물 및 그 조성물의경화물로 이루어지는 피막을 갖는 성형품 |
| US6965474B2 (en) | 2003-02-12 | 2005-11-15 | 3M Innovative Properties Company | Polymeric optical film |
| KR20040087534A (ko) | 2003-04-08 | 2004-10-14 | 주식회사 엘지화학 | 광디스크 표면처리용 조성물 |
| US6995222B2 (en) * | 2003-12-17 | 2006-02-07 | 3M Innovative Properties Company | Coating compositions with reactive fluorinated copolymers having pendant perfluoropolyether groups |
| JP4577481B2 (ja) | 2003-12-22 | 2010-11-10 | 日清紡ホールディングス株式会社 | 無機−有機複合機能性組成物 |
| JP4784723B2 (ja) * | 2003-12-24 | 2011-10-05 | Tdk株式会社 | ハードコート剤組成物及びこれを用いた光情報媒体 |
| JP4508635B2 (ja) | 2003-12-26 | 2010-07-21 | リンテック株式会社 | 画像表示装置用ハードコートフィルム |
| GB0406981D0 (en) | 2004-03-27 | 2004-04-28 | Eastman Kodak Co | Ink receiving material |
| US20050249940A1 (en) | 2004-05-07 | 2005-11-10 | 3M Innovative Properties Company | Fluoropolyether poly(meth)acryl compounds |
| US7342080B2 (en) | 2004-05-07 | 2008-03-11 | 3M Innovative Properties Company | Polymerizable compositions, methods of making the same, and composite articles therefrom |
| US7192795B2 (en) | 2004-11-18 | 2007-03-20 | 3M Innovative Properties Company | Method of making light emitting device with silicon-containing encapsulant |
| US7241437B2 (en) | 2004-12-30 | 2007-07-10 | 3M Innovative Properties Company | Zirconia particles |
| US20070125451A1 (en) | 2005-01-14 | 2007-06-07 | Smith Steven R | Stable, thin-film organic passivates |
| US20060216524A1 (en) | 2005-03-23 | 2006-09-28 | 3M Innovative Properties Company | Perfluoropolyether urethane additives having (meth)acryl groups and hard coats |
| JP2007108512A (ja) * | 2005-10-14 | 2007-04-26 | Fujifilm Corp | 反射防止フィルム、並びにそれを用いた偏光板及び画像表示装置 |
| JP5024591B2 (ja) | 2006-03-29 | 2012-09-12 | Dic株式会社 | コーティング組成物 |
| JP2008044979A (ja) * | 2006-08-11 | 2008-02-28 | Jsr Corp | 硬化性樹脂組成物及び反射防止膜 |
| US20080124555A1 (en) * | 2006-11-29 | 2008-05-29 | 3M Innovative Properties Company | Polymerizable composition comprising perfluoropolyether urethane having ethylene oxide repeat units |
| WO2008094236A1 (en) | 2007-01-30 | 2008-08-07 | Exxonmobil Upstream Research Company | Floating dispersant paste |
| WO2008154278A2 (en) | 2007-06-06 | 2008-12-18 | 3M Innovative Properties Company | Fluorinated compositions and surface treatments made therefrom |
| WO2009008512A1 (ja) * | 2007-07-11 | 2009-01-15 | Asahi Glass Company, Limited | 撥水撥油剤組成物の製造方法および物品 |
| JP2009040829A (ja) * | 2007-08-07 | 2009-02-26 | Dic Corp | フッ素系界面活性剤及びこれを用いる組成物 |
| WO2009029438A1 (en) | 2007-08-31 | 2009-03-05 | 3M Innovative Properties Company | Hardcoats |
| US20090064894A1 (en) | 2007-09-05 | 2009-03-12 | Ashland Licensing And Intellectual Property Llc | Water based hydrophobic self-cleaning coating compositions |
| JP2009083106A (ja) | 2007-09-27 | 2009-04-23 | Fujifilm Corp | 平版印刷版用版面保護剤及び平版印刷版の製版方法 |
| KR101043527B1 (ko) | 2007-12-05 | 2011-06-23 | 엘지전자 주식회사 | 내지문 코팅층을 갖는 가전제품의 스테인리스 스틸 외부 케이스 |
| JP5607540B2 (ja) | 2007-12-12 | 2014-10-15 | スリーエム イノベイティブ プロパティズ カンパニー | ポリ(アルキレンオキシド)反復単位を備えたペルフルオロポリエーテルポリマーを含むハードコート |
| CN101622283B (zh) | 2008-01-15 | 2012-03-28 | 木本股份有限公司 | 固化性组合物、固化物以及层叠体 |
| CN101983212B (zh) * | 2008-03-31 | 2013-04-17 | 大金工业株式会社 | 含氟共聚物、纸用处理剂和化妆品用被膜形成剂 |
| CN102099714A (zh) | 2008-06-03 | 2011-06-15 | 3M创新有限公司 | 包含聚烷基氮或磷鎓氟代烷基磺酰基盐的微结构 |
| JP5061298B2 (ja) | 2008-10-07 | 2012-10-31 | カナヱ塗料株式会社 | 防汚塗膜形成用コーティング剤組成物 |
| WO2010053729A1 (en) | 2008-11-04 | 2010-05-14 | Guiselin Olivier L | Coated abrasive article for polishing or lapping applications and system and method for producing the same |
| CN101392142B (zh) * | 2008-11-06 | 2011-11-16 | 同济大学 | 一种环保型防腐耐指纹金属表面漆的制备方法 |
| JP5659327B2 (ja) | 2009-04-08 | 2015-01-28 | サンノプコ株式会社 | 放射線硬化型コーティング組成物 |
| HUE027398T2 (en) | 2009-05-22 | 2016-10-28 | Novartis Ag | Proteolymers containing siloxane having actinically crosslinkable |
| JP5634398B2 (ja) | 2009-06-01 | 2014-12-03 | 株式会社ツジデン | 指紋消失性硬化膜、及び、その製造方法、並びに、それを用いたディスプレイ、タッチパネル、それらを用いた電子機器 |
| TWI424020B (zh) | 2009-07-14 | 2014-01-21 | Jsr Corp | Hardened composition and laminated film |
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| US8137807B2 (en) | 2010-03-26 | 2012-03-20 | 3M Innovative Properties Company | Pressure-sensitive adhesives derived from 2-alkyl alkanols |
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2013
- 2013-05-30 EP EP13728622.5A patent/EP2861677B1/en not_active Not-in-force
- 2013-05-30 WO PCT/US2013/043306 patent/WO2013191861A1/en not_active Ceased
- 2013-05-30 US US14/381,382 patent/US9441135B2/en not_active Expired - Fee Related
- 2013-05-30 CN CN201380032250.7A patent/CN104755562B/zh not_active Expired - Fee Related
- 2013-05-30 JP JP2015518416A patent/JP6363072B2/ja not_active Expired - Fee Related
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Also Published As
| Publication number | Publication date |
|---|---|
| US20160340457A1 (en) | 2016-11-24 |
| US9441135B2 (en) | 2016-09-13 |
| CN104755562A (zh) | 2015-07-01 |
| EP2861677A1 (en) | 2015-04-22 |
| US9803042B2 (en) | 2017-10-31 |
| EP2861677B1 (en) | 2020-11-11 |
| WO2013191861A1 (en) | 2013-12-27 |
| CN104755562B (zh) | 2017-05-17 |
| US20150126654A1 (en) | 2015-05-07 |
| JP2015520292A (ja) | 2015-07-16 |
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