JP5750375B2 - フッ素化イオノマーの分散微粒子を使用する水性重合により製造されるフルオロポリマー - Google Patents

フッ素化イオノマーの分散微粒子を使用する水性重合により製造されるフルオロポリマー Download PDF

Info

Publication number
JP5750375B2
JP5750375B2 JP2011543633A JP2011543633A JP5750375B2 JP 5750375 B2 JP5750375 B2 JP 5750375B2 JP 2011543633 A JP2011543633 A JP 2011543633A JP 2011543633 A JP2011543633 A JP 2011543633A JP 5750375 B2 JP5750375 B2 JP 5750375B2
Authority
JP
Japan
Prior art keywords
reactor
fluorinated
polymerization
tfe
fluorinated ionomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2011543633A
Other languages
English (en)
Japanese (ja)
Other versions
JP2012513530A5 (enExample
JP2012513530A (ja
Inventor
ケネス・ウェイン・レフュー
ラルフ・バーチャード・ロイド
チャールズ・ジョウゼフ・ノエルケ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of JP2012513530A publication Critical patent/JP2012513530A/ja
Publication of JP2012513530A5 publication Critical patent/JP2012513530A5/ja
Application granted granted Critical
Publication of JP5750375B2 publication Critical patent/JP5750375B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/26—Tetrafluoroethene
    • C08F214/262—Tetrafluoroethene with fluorinated vinyl ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C08F14/26—Tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/26—Tetrafluoroethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
JP2011543633A 2008-12-23 2009-12-22 フッ素化イオノマーの分散微粒子を使用する水性重合により製造されるフルオロポリマー Active JP5750375B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US14011408P 2008-12-23 2008-12-23
US61/140,114 2008-12-23
PCT/US2009/069155 WO2010075359A1 (en) 2008-12-23 2009-12-22 Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer

Publications (3)

Publication Number Publication Date
JP2012513530A JP2012513530A (ja) 2012-06-14
JP2012513530A5 JP2012513530A5 (enExample) 2013-02-07
JP5750375B2 true JP5750375B2 (ja) 2015-07-22

Family

ID=41559919

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2011543633A Active JP5750375B2 (ja) 2008-12-23 2009-12-22 フッ素化イオノマーの分散微粒子を使用する水性重合により製造されるフルオロポリマー

Country Status (5)

Country Link
US (1) US8153738B2 (enExample)
EP (2) EP3091039B1 (enExample)
JP (1) JP5750375B2 (enExample)
CN (1) CN102264777B (enExample)
WO (1) WO2010075359A1 (enExample)

Families Citing this family (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5392251B2 (ja) * 2008-04-14 2014-01-22 旭硝子株式会社 ポリテトラフルオロエチレンファインパウダーの製造方法
US20090281241A1 (en) * 2008-05-09 2009-11-12 E. I. Du Pont De Nemours And Company Aqueous Polymerization of Fluorinated Monomer Using a Mixture of Fluoropolyether Acids or Salts
US8835547B2 (en) * 2008-12-23 2014-09-16 E I Du Pont De Nemours And Company Fluoropolymer particles having a nucleus of fluorinated ionomer
US8436054B2 (en) 2008-12-23 2013-05-07 E I Du Pont De Nemours And Company Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer produced in situ
EP3533811B1 (en) 2010-11-09 2021-08-11 The Chemours Company FC, LLC Nucleation in aqueous polymerization of fluoromonomer
JP6109073B2 (ja) 2010-11-09 2017-04-05 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company 炭化水素界面活性剤を用いたフルオロモノマーの水性重合
CN103210003B (zh) 2010-11-09 2016-09-07 纳幕尔杜邦公司 减弱含烃表面活性剂在含氟单体含水分散体聚合反应中的调聚性能
GB201021790D0 (en) 2010-12-23 2011-02-02 3M Innovative Properties Co Fluoropolymer compostions and purification methods thereof
US9527980B2 (en) 2012-11-30 2016-12-27 Daikin Industries, Ltd. Polytetrafluoroethylene aqueous dispersion, and polytetrafluoroethylene fine powder
CN111040058B (zh) * 2012-11-30 2022-10-25 大金工业株式会社 聚四氟乙烯水性分散液的制造方法
CN104812781B (zh) 2012-11-30 2018-10-16 大金工业株式会社 聚四氟乙烯水性分散液的制造方法
EP2935370A1 (en) * 2012-12-18 2015-10-28 E. I. du Pont de Nemours and Company Process for producing fluoroelastomers
CN109111663A (zh) * 2013-07-30 2019-01-01 索尔维特殊聚合物意大利有限公司 含氟热塑性弹性体组合物
US9676929B2 (en) 2013-11-26 2017-06-13 The Chemours Company Fc, Llc Employing polyalkylene oxides for nucleation in aqueous polymerization of fluoromonomer
JP6365664B2 (ja) * 2014-06-04 2018-08-01 ダイキン工業株式会社 ポリテトラフルオロエチレン水性分散液
EP3153532B1 (en) * 2014-06-04 2019-11-20 Daikin Industries, Ltd. Polytetrafluoroethylene powder
EP3294695B1 (en) * 2015-05-11 2020-09-30 Compact Membrane Systems, Inc. Thin film composite membranes for separation of alkenes from alkanes
US11851519B2 (en) * 2017-08-10 2023-12-26 Daikin Industries, Ltd. Method for producing purified polytetrafluoroethylene aqueous dispersion liquid, method for producing modified polytetrafluoroethylene powder, method for producing polytetrafluoroethylene molded body, and composition
WO2019168183A1 (ja) 2018-03-01 2019-09-06 ダイキン工業株式会社 フルオロポリマーの製造方法
US12195617B2 (en) 2018-11-19 2025-01-14 Daikin Industries, Ltd. Composition and stretched body
JP7174272B2 (ja) * 2018-11-19 2022-11-17 ダイキン工業株式会社 変性ポリテトラフルオロエチレンの製造方法及び組成物
EP3960773B1 (en) 2019-04-26 2025-07-16 Daikin Industries, Ltd. Method for producing aqueous fluoropolymer dispersion, drainage treatment method, and aqueous fluoropolymer dispersion
JP7417129B2 (ja) 2019-04-26 2024-01-18 ダイキン工業株式会社 水の処理方法および組成物
JP7201948B2 (ja) * 2019-07-23 2023-01-11 ダイキン工業株式会社 フルオロポリマーの製造方法、ポリテトラフルオロエチレン組成物及びポリテトラフルオロエチレン粉末
CN114269840A (zh) 2019-09-05 2022-04-01 大金工业株式会社 组合物及其制造方法
CN114364710B (zh) 2019-09-05 2024-02-09 大金工业株式会社 全氟弹性体的制造方法和组合物
WO2021100834A1 (ja) * 2019-11-19 2021-05-27 ダイキン工業株式会社 ポリテトラフルオロエチレンの製造方法
JP7352110B2 (ja) * 2019-11-19 2023-09-28 ダイキン工業株式会社 フルオロポリマーの製造方法、ポリテトラフルオロエチレンの製造方法、パーフルオロエラストマーの製造方法および組成物
EP4222141B1 (en) 2020-10-01 2025-08-06 The Chemours Company FC, LLC Low reactivity hydrocarbon dispersing agents in the aqueous polymerization of fluoropolymers
WO2022107890A1 (ja) 2020-11-19 2022-05-27 ダイキン工業株式会社 パーフルオロエラストマー水性分散液の製造方法、組成物、架橋性組成物および架橋物
EP4249517A4 (en) 2020-11-19 2024-10-16 Daikin Industries, Ltd. PROCESS FOR PRODUCING AN AQUEOUS DISPERSION OF FLUORINE-CONTAINING ELASTOMER, AND COMPOSITION
JP7606110B2 (ja) 2020-11-19 2024-12-25 ダイキン工業株式会社 ポリテトラフルオロエチレンの製造方法およびポリテトラフルオロエチレンを含有する組成物
JP7674667B2 (ja) * 2021-01-28 2025-05-12 ダイキン工業株式会社 フルオロポリマー組成物の製造方法
KR20230150868A (ko) 2021-03-10 2023-10-31 다이킨 고교 가부시키가이샤 도료 조성물, 도포막, 적층체 및 도장 물품
WO2022244784A1 (ja) 2021-05-19 2022-11-24 ダイキン工業株式会社 フルオロポリマーの製造方法、ポリテトラフルオロエチレンの製造方法および組成物
JP7741413B2 (ja) 2021-06-11 2025-09-18 ダイキン工業株式会社 含フッ素エラストマー水性分散液の製造方法、組成物および水性分散液
CN115466343B (zh) * 2021-06-11 2023-10-27 中昊晨光化工研究院有限公司 一种聚醚二酸或其盐类表面活性剂及其应用
JP7747987B2 (ja) 2021-06-30 2025-10-02 ダイキン工業株式会社 フルオロポリマー組成物の製造方法およびフルオロポリマー組成物
CN117500847A (zh) 2021-06-30 2024-02-02 大金工业株式会社 含有高纯度含氟聚合物的组合物的制造方法和含有高纯度含氟聚合物的组合物
EP4393966A4 (en) * 2021-09-30 2025-09-03 Daikin Ind Ltd FINE POLYTETRAFLUOROETHYLENE POWDER
WO2023182229A1 (ja) 2022-03-23 2023-09-28 ダイキン工業株式会社 フルオロポリマーの製造方法および組成物
EP4516820A4 (en) 2022-04-28 2026-04-22 Daikin Ind Ltd PROCESS FOR PRODUCING A COMPOSITION CONTAINING A FLUORIDE RESIN, AND COMPOSITION CONTAINING A FLUORIDE RESIN
EP4516855A4 (en) 2022-04-28 2026-06-03 Daikin Ind Ltd COMPOSITION INCLUDES FLUORIDE RUBBER
EP4516819A4 (en) 2022-04-28 2026-05-06 Daikin Ind Ltd FLUORIDE POLYMER MANUFACTURING PROCESS
JP7653042B2 (ja) 2023-01-18 2025-03-28 ダイキン工業株式会社 テトラフルオロエチレン系ポリマー組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池
JP7492186B1 (ja) 2023-01-18 2024-05-29 ダイキン工業株式会社 電気化学デバイス用合剤、電気化学デバイス用合剤シート、電極、及び、電気化学デバイス
WO2024214644A1 (ja) * 2023-04-10 2024-10-17 Agc株式会社 含フッ素重合体の製造方法、水性分散液及び固体組成物
CN121712810A (zh) 2023-08-14 2026-03-20 大金工业株式会社 含氟聚合物水性分散液的制造方法和含氟聚合物水性分散液
JP7689278B2 (ja) 2023-08-28 2025-06-06 ダイキン工業株式会社 水溶性含フッ素ポリマーの回収方法
JP2025093905A (ja) 2023-12-12 2025-06-24 ダイキン工業株式会社 テトラフルオロエチレン系ポリマー組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池
WO2025127124A1 (ja) 2023-12-12 2025-06-19 ダイキン工業株式会社 テトラフルオロエチレン系ポリマー組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池
CN122349673A (zh) 2023-12-12 2026-07-07 大金工业株式会社 四氟乙烯系聚合物组合物、电化学器件用粘结剂、电极合剂、电极和二次电池
WO2025127120A1 (ja) 2023-12-12 2025-06-19 ダイキン工業株式会社 テトラフルオロエチレン系ポリマー組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池
WO2025126950A1 (ja) 2023-12-12 2025-06-19 ダイキン工業株式会社 フルオロポリマー水性分散液

Family Cites Families (62)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2559752A (en) 1951-03-06 1951-07-10 Du Pont Aqueous colloidal dispersions of polymers
US2713593A (en) 1953-12-21 1955-07-19 Minnesota Mining & Mfg Fluorocarbon acids and derivatives
US3037953A (en) 1961-04-26 1962-06-05 Du Pont Concentration of aqueous colloidal dispersions of polytetrafluoroethylene
US3271341A (en) 1961-08-07 1966-09-06 Du Pont Aqueous colloidal dispersions of polymer
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US3291843A (en) 1963-10-08 1966-12-13 Du Pont Fluorinated vinyl ethers and their preparation
US3391099A (en) 1966-04-25 1968-07-02 Du Pont Polymerization process
GB1292268A (en) 1970-02-16 1972-10-11 Bitterfeld Chemie Process for the dimerisation of hexafluoropropene epoxide
US3704272A (en) 1970-09-15 1972-11-28 Du Pont Concentration of polytetrafluoroethylene aqueous dispersion
US4358545A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
JPS5816622U (ja) 1981-07-23 1983-02-01 株式会社リコー カメラシステムにおける信号伝達装置
US4380618A (en) 1981-08-21 1983-04-19 E. I. Du Pont De Nemours And Company Batch polymerization process
US4552631A (en) 1983-03-10 1985-11-12 E. I. Du Pont De Nemours And Company Reinforced membrane, electrochemical cell and electrolysis process
EP0148482B1 (en) 1983-12-26 1992-03-25 Daikin Industries, Limited Process for preparing halogen-containing polyether
US4621116A (en) 1984-12-07 1986-11-04 E. I. Du Pont De Nemours And Company Process for copolymerization of tetrafluoroethylene in the presence of a dispersing agent comprising a perfluoroalkoxybenzene sulfonic acid or salt
US4743658A (en) 1985-10-21 1988-05-10 E. I. Du Pont De Nemours And Company Stable tetrafluoroethylene copolymers
US4940525A (en) 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
US4952630A (en) 1987-12-31 1990-08-28 E. I. Du Pont De Nemours And Company Modified polytetrafluoroethylene resins and blends thereof
JP3172983B2 (ja) 1993-09-20 2001-06-04 ダイキン工業株式会社 ビニリデンフルオライド系重合体の水性分散液およびその製法
US5422411A (en) 1993-09-21 1995-06-06 Ballard Power Systems Inc. Trifluorostyrene and substituted trifluorostyrene copolymeric compositions and ion-exchange membranes formed therefrom
US5637748A (en) 1995-03-01 1997-06-10 E. I. Du Pont De Nemours And Company Process for synthesizing fluorinated nitrile compounds
JP3346090B2 (ja) 1995-03-31 2002-11-18 ダイキン工業株式会社 ポリテトラフルオロエチレン水性分散液組成物及びその用途
US5789508A (en) 1995-08-31 1998-08-04 E. I. Du Pont De Nemours And Company Polymerization process
US5688884A (en) 1995-08-31 1997-11-18 E. I. Du Pont De Nemours And Company Polymerization process
US5763552A (en) 1996-07-26 1998-06-09 E. I. Du Pont De Nemours And Company Hydrogen-containing flourosurfacant and its use in polymerization
US5866711A (en) 1996-09-13 1999-02-02 E. I. Du Pont De Nemours And Company Fluorocyanate and fluorocarbamate monomers and polymers thereof
US5969067A (en) 1996-09-13 1999-10-19 E.I. Dupont De Nemours And Company Phosphorus-containing fluoromonomers and polymers thereof
WO1998016581A1 (en) 1996-10-15 1998-04-23 E.I. Du Pont De Nemours And Company Compositions containing particles of highly fluorinated ion exchange polymer
WO1998043952A1 (en) * 1997-03-31 1998-10-08 Daikin Industries, Ltd. Process for producing perfluorovinyl ethersulfonic acid derivatives and copolymer of the same
US6395848B1 (en) 1999-05-20 2002-05-28 E. I. Du Pont De Nemours And Company Polymerization of fluoromonomers
US6482979B1 (en) 1999-12-22 2002-11-19 Dyneon Llc Perfluorinated acid fluorides and preparation thereof
DE60119307T2 (de) * 2000-02-16 2007-04-12 Daikin Industries, Ltd. Verfahren zur herstellung eines fluorionomers, verfahren zur reinigung und konzentrierung von ionomeren und verfahren zur filmbildung
US7045571B2 (en) 2001-05-21 2006-05-16 3M Innovative Properties Company Emulsion polymerization of fluorinated monomers
US6737489B2 (en) * 2001-05-21 2004-05-18 3M Innovative Properties Company Polymers containing perfluorovinyl ethers and applications for such polymers
MXPA04006460A (es) 2002-01-04 2004-10-04 Du Pont Dispersiones de fluoropolimeros concentradas.
US6902839B2 (en) 2002-05-31 2005-06-07 Korea Advanced Institute Of Science And Technology Polymer electrolyte membrane for fuel cell and method for producing the same
JP4096764B2 (ja) 2002-06-17 2008-06-04 ダイキン工業株式会社 含フッ素結晶性ポリマー分散体製造方法
US6841616B2 (en) 2003-03-28 2005-01-11 Arkema Inc. Polymerization of halogen-containing monomers using siloxane surfactant
JP2004358397A (ja) 2003-06-05 2004-12-24 Daikin Ind Ltd 界面活性剤、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
JP2004359870A (ja) 2003-06-05 2004-12-24 Daikin Ind Ltd 界面活性剤、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
WO2005003075A1 (ja) 2003-07-02 2005-01-13 Daikin Industries, Ltd. フルオロアルキルカルボン酸誘導体、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
EP1661198A2 (en) 2003-08-19 2006-05-31 E.I. Dupont De Nemours And Company Membranes of fluorinated ionomer blended with nonionomeric fluoropolymers for electrochemical cells
US20050090613A1 (en) 2003-10-22 2005-04-28 Daikin Industries, Ltd. Process for preparing fluorine-containing polymer latex
EP1529785B1 (en) * 2003-10-24 2011-03-16 3M Innovative Properties Company Aqueous dispersions of polytetrafluoroethylene particles
US7071271B2 (en) * 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
EP1533325B1 (en) 2003-11-17 2011-10-19 3M Innovative Properties Company Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant
JP2005320501A (ja) * 2004-04-07 2005-11-17 Daikin Ind Ltd 含フッ素エラストマー重合体の製造方法
US7563828B2 (en) * 2004-07-16 2009-07-21 Alcatel-Lucent Usa Inc. Solid state proton conductor system derived from hybrid composite inorganic-organic multicomponent material
US20060014887A1 (en) 2004-07-19 2006-01-19 3M Innovative Properties Company Method of hydrolyzing a dispersion of ionic fluoropolymer
GB0511779D0 (en) * 2005-06-10 2005-07-20 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers in the presence of a partially fluorinated oligomer as an emulsifier
US20070015937A1 (en) 2005-07-15 2007-01-18 3M Innovative Properties Company Process for recovery of fluorinated carboxylic acid surfactants from exhaust gas
GB0514398D0 (en) 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant
GB0514387D0 (en) 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant
WO2007046345A1 (ja) 2005-10-17 2007-04-26 Asahi Glass Company, Limited ポリテトラフルオロエチレン水性乳化液、それから得られるポリテトラフルオロエチレンファインパウダーおよび多孔体
JP5141256B2 (ja) 2005-10-20 2013-02-13 旭硝子株式会社 ポリテトラフルオロエチレン水性分散液およびその製品
EP1939223B1 (en) 2005-10-20 2011-07-13 Asahi Glass Company, Limited Method for producing melt-moldable fluororesin
JP5343355B2 (ja) 2005-10-26 2013-11-13 旭硝子株式会社 含フッ素乳化剤の残留量が少ないフッ素樹脂およびその製造方法
US8580896B2 (en) * 2006-05-10 2013-11-12 Daikin Industries, Ltd. Process for preparing fluorine-containing polymer
ATE512165T1 (de) 2006-11-09 2011-06-15 Du Pont Wässrige polymerisation von fluorierten monomeren unter verwendung eines polymerisationsmittels, das fluorpolyethersäure oder -salz und kohlenwasserstofftensid umfasst
JP5588679B2 (ja) * 2006-11-09 2014-09-10 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー フルオロポリエーテル酸または塩および短鎖フッ素系界面活性剤を含む重合剤を用いるフッ素化モノマーの水性重合
US7989566B2 (en) 2008-01-22 2011-08-02 Dupont Performance Elastomers Llc Process for producing fluoropolymers
US8058376B2 (en) * 2008-12-23 2011-11-15 E. I. Du Pont De Nemours And Company Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated lonomer produced in situ

Also Published As

Publication number Publication date
US8153738B2 (en) 2012-04-10
EP2367858B1 (en) 2016-05-04
EP3091039A1 (en) 2016-11-09
CN102264777B (zh) 2014-05-07
JP2012513530A (ja) 2012-06-14
EP2367858A1 (en) 2011-09-28
EP3091039B1 (en) 2023-03-01
US20100160490A1 (en) 2010-06-24
CN102264777A (zh) 2011-11-30
WO2010075359A1 (en) 2010-07-01

Similar Documents

Publication Publication Date Title
JP5481495B2 (ja) フッ素化イオノマーの核を有するフルオロポリマー粒子
US8153738B2 (en) Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer
JP5703233B2 (ja) その場生成されるフッ素化イオノマーの分散した微粒子を使用する水性重合によって製造されるフルオロポリマー
JP5588679B2 (ja) フルオロポリエーテル酸または塩および短鎖フッ素系界面活性剤を含む重合剤を用いるフッ素化モノマーの水性重合
JP5758810B2 (ja) その場生成されるフッ素化イオノマーの分散した微粒子を使用する水性重合によって製造されるフッ素化イオノマー
EP2367862B1 (en) Aqueous polymerization of fluorinated monomer using hydrogen containing branched fluoroether surfactant
JP2012513533A (ja) フッ素化イオノマーの分散した微粒子を使用する水性重合によって製造されるフッ素化イオノマー

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20121214

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20121214

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20130612

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20130625

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20130925

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20131002

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20131224

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20140617

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20140912

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20140922

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20141217

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20150428

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20150518

R150 Certificate of patent or registration of utility model

Ref document number: 5750375

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313113

S531 Written request for registration of change of domicile

Free format text: JAPANESE INTERMEDIATE CODE: R313531

R360 Written notification for declining of transfer of rights

Free format text: JAPANESE INTERMEDIATE CODE: R360

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R360 Written notification for declining of transfer of rights

Free format text: JAPANESE INTERMEDIATE CODE: R360

R371 Transfer withdrawn

Free format text: JAPANESE INTERMEDIATE CODE: R371

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313113

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250