JP5750375B2 - フッ素化イオノマーの分散微粒子を使用する水性重合により製造されるフルオロポリマー - Google Patents

フッ素化イオノマーの分散微粒子を使用する水性重合により製造されるフルオロポリマー Download PDF

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JP5750375B2
JP5750375B2 JP2011543633A JP2011543633A JP5750375B2 JP 5750375 B2 JP5750375 B2 JP 5750375B2 JP 2011543633 A JP2011543633 A JP 2011543633A JP 2011543633 A JP2011543633 A JP 2011543633A JP 5750375 B2 JP5750375 B2 JP 5750375B2
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reactor
fluorinated
polymerization
tfe
fluorinated ionomer
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JP2012513530A5 (enExample
JP2012513530A (ja
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ケネス・ウェイン・レフュー
ラルフ・バーチャード・ロイド
チャールズ・ジョウゼフ・ノエルケ
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EIDP Inc
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EI Du Pont de Nemours and Co
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine
    • C08F214/26Tetrafluoroethene
    • C08F214/262Tetrafluoroethene with fluorinated vinyl ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18Monomers containing fluorine
    • C08F14/26Tetrafluoroethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine
    • C08F214/26Tetrafluoroethene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
JP2011543633A 2008-12-23 2009-12-22 フッ素化イオノマーの分散微粒子を使用する水性重合により製造されるフルオロポリマー Active JP5750375B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US14011408P 2008-12-23 2008-12-23
US61/140,114 2008-12-23
PCT/US2009/069155 WO2010075359A1 (en) 2008-12-23 2009-12-22 Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer

Publications (3)

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JP2012513530A JP2012513530A (ja) 2012-06-14
JP2012513530A5 JP2012513530A5 (enExample) 2013-02-07
JP5750375B2 true JP5750375B2 (ja) 2015-07-22

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US (1) US8153738B2 (enExample)
EP (2) EP2367858B1 (enExample)
JP (1) JP5750375B2 (enExample)
CN (1) CN102264777B (enExample)
WO (1) WO2010075359A1 (enExample)

Families Citing this family (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101998968B (zh) * 2008-04-14 2012-08-29 旭硝子株式会社 聚四氟乙烯细粉的制造方法
US20090281241A1 (en) * 2008-05-09 2009-11-12 E. I. Du Pont De Nemours And Company Aqueous Polymerization of Fluorinated Monomer Using a Mixture of Fluoropolyether Acids or Salts
US8436054B2 (en) 2008-12-23 2013-05-07 E I Du Pont De Nemours And Company Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer produced in situ
US8835547B2 (en) * 2008-12-23 2014-09-16 E I Du Pont De Nemours And Company Fluoropolymer particles having a nucleus of fluorinated ionomer
CN106188353B (zh) 2010-11-09 2018-08-31 科慕埃弗西有限公司 使用烃表面活性剂的含氟单体的含水聚合
JP6201236B2 (ja) 2010-11-09 2017-09-27 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー フルオロモノマーの水性重合における核形成
US9074025B2 (en) 2010-11-09 2015-07-07 The Chemours Company Fc, Llc Reducing the telogenic behavior of hydrocarbon-containing surfactants in aqueous dispersion fluoromonomer polymerization
GB201021790D0 (en) 2010-12-23 2011-02-02 3M Innovative Properties Co Fluoropolymer compostions and purification methods thereof
WO2014084399A1 (ja) 2012-11-30 2014-06-05 ダイキン工業株式会社 ポリテトラフルオロエチレン水性分散液及びポリテトラフルオロエチレンファインパウダー
US9574020B2 (en) * 2012-11-30 2017-02-21 Daikin Industries, Ltd. Production method for fluoropolymer aqueous dispersion
EP2927248B1 (en) 2012-11-30 2018-06-13 Daikin Industries, Ltd. Production method for polytetrafluoroethylene aqueous dispersion
EP2935370A1 (en) * 2012-12-18 2015-10-28 E. I. du Pont de Nemours and Company Process for producing fluoroelastomers
CN109111663A (zh) * 2013-07-30 2019-01-01 索尔维特殊聚合物意大利有限公司 含氟热塑性弹性体组合物
JP6622209B2 (ja) 2013-11-26 2019-12-18 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー フルオロモノマーの水性重合において核を形成するためのポリアルキレンオキシドの使用
US9902787B2 (en) 2014-06-04 2018-02-27 Daikin Industries, Ltd. Polytetrafluoroethylene powder
CN106459546A (zh) * 2014-06-04 2017-02-22 大金工业株式会社 聚四氟乙烯水性分散液
WO2016182886A1 (en) * 2015-05-11 2016-11-17 Compact Membrane Systems, Inc. Improved membranes for separation of alkenes from alkanes
SG11202000862YA (en) * 2017-08-10 2020-02-27 Daikin Ind Ltd Method for producing purified polytetrafluoroethylene aqueous dispersion liquid, method for producing modified polytetrafluoroethylene powder, method for producing polytetrafluoroethylene molded body, and composition
US11767379B2 (en) 2018-03-01 2023-09-26 Daikin Industries, Ltd. Method for manufacturing fluoropolymer
TWI821458B (zh) 2018-11-19 2023-11-11 日商大金工業股份有限公司 組成物及拉伸體
EP3885372A4 (en) * 2018-11-19 2022-08-17 Daikin Industries, Ltd. PROCESS FOR PRODUCTION OF MODIFIED POLYTETRAFLUORETHYLENE AND COMPOSITION
WO2020218620A1 (ja) 2019-04-26 2020-10-29 ダイキン工業株式会社 フルオロポリマー水性分散液の製造方法、排水の処理方法、及び、フルオロポリマー水性分散液
JP7417129B2 (ja) 2019-04-26 2024-01-18 ダイキン工業株式会社 水の処理方法および組成物
CN118146427A (zh) * 2019-07-23 2024-06-07 大金工业株式会社 含氟聚合物的制造方法、聚四氟乙烯组合物和聚四氟乙烯粉末
CN120271939A (zh) 2019-09-05 2025-07-08 大金工业株式会社 组合物及其制造方法
JP7368759B2 (ja) 2019-09-05 2023-10-25 ダイキン工業株式会社 パーフルオロエラストマーの製造方法および組成物
WO2021100834A1 (ja) * 2019-11-19 2021-05-27 ダイキン工業株式会社 ポリテトラフルオロエチレンの製造方法
WO2021100836A1 (ja) 2019-11-19 2021-05-27 ダイキン工業株式会社 フルオロポリマーの製造方法、ポリテトラフルオロエチレンの製造方法、パーフルオロエラストマーの製造方法および組成物
CN116234794A (zh) 2020-10-01 2023-06-06 科慕埃弗西有限公司 含氟聚合物的水性聚合反应中的低反应性烃分散剂
EP4249525A4 (en) 2020-11-19 2024-10-16 Daikin Industries, Ltd. METHOD FOR PREPARING AN AQUEOUS PERFLUOROLASTOMER DISPERSION, COMPOSITION, CROSS-LINKABLE COMPOSITION AND CROSS-LINKED PRODUCT
JP7606110B2 (ja) 2020-11-19 2024-12-25 ダイキン工業株式会社 ポリテトラフルオロエチレンの製造方法およびポリテトラフルオロエチレンを含有する組成物
CN116406386A (zh) 2020-11-19 2023-07-07 大金工业株式会社 含氟弹性体水性分散液的制造方法和组合物
EP4286426A4 (en) * 2021-01-28 2025-02-12 Daikin Industries, Ltd. Method for producing fluoropolymer composition
CN116981741A (zh) 2021-03-10 2023-10-31 大金工业株式会社 涂料组合物、涂布膜、层积体和涂装物品
EP4342921A4 (en) 2021-05-19 2025-04-23 Daikin Industries, Ltd. Process for producing a fluoropolymer, process for producing polytetrafluoroethylene and composition
JP7741413B2 (ja) 2021-06-11 2025-09-18 ダイキン工業株式会社 含フッ素エラストマー水性分散液の製造方法、組成物および水性分散液
CN115466343B (zh) * 2021-06-11 2023-10-27 中昊晨光化工研究院有限公司 一种聚醚二酸或其盐类表面活性剂及其应用
WO2023277140A1 (ja) 2021-06-30 2023-01-05 ダイキン工業株式会社 高純度フルオロポリマー含有組成物の製造方法および高純度フルオロポリマー含有組成物
CN117500848A (zh) 2021-06-30 2024-02-02 大金工业株式会社 含氟聚合物组合物的制造方法和含氟聚合物组合物
JP7657762B2 (ja) * 2021-09-30 2025-04-07 ダイキン工業株式会社 ポリテトラフルオロエチレンファインパウダー
WO2023182229A1 (ja) 2022-03-23 2023-09-28 ダイキン工業株式会社 フルオロポリマーの製造方法および組成物
WO2023210819A1 (ja) 2022-04-28 2023-11-02 ダイキン工業株式会社 フルオロポリマーの製造方法
WO2023210818A1 (ja) 2022-04-28 2023-11-02 ダイキン工業株式会社 フッ素ゴムを含有する組成物
CN119072500A (zh) 2022-04-28 2024-12-03 大金工业株式会社 含有氟树脂的组合物的制造方法和含有氟树脂的组合物
CN120530501A (zh) 2023-01-18 2025-08-22 大金工业株式会社 四氟乙烯系聚合物组合物、电化学器件用粘结剂、电极合剂、电极和二次电池
CN120548621A (zh) 2023-01-18 2025-08-26 大金工业株式会社 电化学器件用合剂、电化学器件用合剂片、电极和电化学器件
WO2024214644A1 (ja) * 2023-04-10 2024-10-17 Agc株式会社 含フッ素重合体の製造方法、水性分散液及び固体組成物
CN121712810A (zh) 2023-08-14 2026-03-20 大金工业株式会社 含氟聚合物水性分散液的制造方法和含氟聚合物水性分散液
CN121752344A (zh) 2023-08-28 2026-03-27 大金工业株式会社 水溶性含氟聚合物的回收方法

Family Cites Families (62)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2559752A (en) 1951-03-06 1951-07-10 Du Pont Aqueous colloidal dispersions of polymers
US2713593A (en) 1953-12-21 1955-07-19 Minnesota Mining & Mfg Fluorocarbon acids and derivatives
US3037953A (en) 1961-04-26 1962-06-05 Du Pont Concentration of aqueous colloidal dispersions of polytetrafluoroethylene
US3271341A (en) 1961-08-07 1966-09-06 Du Pont Aqueous colloidal dispersions of polymer
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US3291843A (en) 1963-10-08 1966-12-13 Du Pont Fluorinated vinyl ethers and their preparation
US3391099A (en) 1966-04-25 1968-07-02 Du Pont Polymerization process
GB1292268A (en) 1970-02-16 1972-10-11 Bitterfeld Chemie Process for the dimerisation of hexafluoropropene epoxide
US3704272A (en) 1970-09-15 1972-11-28 Du Pont Concentration of polytetrafluoroethylene aqueous dispersion
US4358545A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
JPS5816622U (ja) 1981-07-23 1983-02-01 株式会社リコー カメラシステムにおける信号伝達装置
US4380618A (en) 1981-08-21 1983-04-19 E. I. Du Pont De Nemours And Company Batch polymerization process
US4552631A (en) 1983-03-10 1985-11-12 E. I. Du Pont De Nemours And Company Reinforced membrane, electrochemical cell and electrolysis process
DE3486428T2 (de) 1983-12-26 1996-10-10 Daikin Ind Ltd Halogen enthaltendes Polyether
US4621116A (en) 1984-12-07 1986-11-04 E. I. Du Pont De Nemours And Company Process for copolymerization of tetrafluoroethylene in the presence of a dispersing agent comprising a perfluoroalkoxybenzene sulfonic acid or salt
US4743658A (en) 1985-10-21 1988-05-10 E. I. Du Pont De Nemours And Company Stable tetrafluoroethylene copolymers
US4940525A (en) 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
US4952630A (en) 1987-12-31 1990-08-28 E. I. Du Pont De Nemours And Company Modified polytetrafluoroethylene resins and blends thereof
JP3172983B2 (ja) 1993-09-20 2001-06-04 ダイキン工業株式会社 ビニリデンフルオライド系重合体の水性分散液およびその製法
US5422411A (en) 1993-09-21 1995-06-06 Ballard Power Systems Inc. Trifluorostyrene and substituted trifluorostyrene copolymeric compositions and ion-exchange membranes formed therefrom
US5637748A (en) 1995-03-01 1997-06-10 E. I. Du Pont De Nemours And Company Process for synthesizing fluorinated nitrile compounds
JP3346090B2 (ja) 1995-03-31 2002-11-18 ダイキン工業株式会社 ポリテトラフルオロエチレン水性分散液組成物及びその用途
US5688884A (en) 1995-08-31 1997-11-18 E. I. Du Pont De Nemours And Company Polymerization process
US5789508A (en) 1995-08-31 1998-08-04 E. I. Du Pont De Nemours And Company Polymerization process
US5763552A (en) 1996-07-26 1998-06-09 E. I. Du Pont De Nemours And Company Hydrogen-containing flourosurfacant and its use in polymerization
US5969067A (en) 1996-09-13 1999-10-19 E.I. Dupont De Nemours And Company Phosphorus-containing fluoromonomers and polymers thereof
US5866711A (en) 1996-09-13 1999-02-02 E. I. Du Pont De Nemours And Company Fluorocyanate and fluorocarbamate monomers and polymers thereof
EP0932646B1 (en) 1996-10-15 2001-07-25 E.I. Du Pont De Nemours And Company Compositions containing particles of highly fluorinated ion exchange polymer
CN1154633C (zh) * 1997-03-31 2004-06-23 大金工业株式会社 卤代乙烯醚类磺酸衍生物的制法
US6395848B1 (en) 1999-05-20 2002-05-28 E. I. Du Pont De Nemours And Company Polymerization of fluoromonomers
US6482979B1 (en) 1999-12-22 2002-11-19 Dyneon Llc Perfluorinated acid fluorides and preparation thereof
DE60119307T2 (de) 2000-02-16 2007-04-12 Daikin Industries, Ltd. Verfahren zur herstellung eines fluorionomers, verfahren zur reinigung und konzentrierung von ionomeren und verfahren zur filmbildung
US6737489B2 (en) * 2001-05-21 2004-05-18 3M Innovative Properties Company Polymers containing perfluorovinyl ethers and applications for such polymers
US7045571B2 (en) 2001-05-21 2006-05-16 3M Innovative Properties Company Emulsion polymerization of fluorinated monomers
EP1472307B1 (en) 2002-01-04 2018-09-05 The Chemours Company FC, LLC Concentrated fluoropolymer dispersions
US6902839B2 (en) 2002-05-31 2005-06-07 Korea Advanced Institute Of Science And Technology Polymer electrolyte membrane for fuel cell and method for producing the same
JP4096764B2 (ja) 2002-06-17 2008-06-04 ダイキン工業株式会社 含フッ素結晶性ポリマー分散体製造方法
US6841616B2 (en) 2003-03-28 2005-01-11 Arkema Inc. Polymerization of halogen-containing monomers using siloxane surfactant
JP2004358397A (ja) 2003-06-05 2004-12-24 Daikin Ind Ltd 界面活性剤、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
JP2004359870A (ja) 2003-06-05 2004-12-24 Daikin Ind Ltd 界面活性剤、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
WO2005003075A1 (ja) 2003-07-02 2005-01-13 Daikin Industries, Ltd. フルオロアルキルカルボン酸誘導体、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
WO2005020363A2 (en) 2003-08-19 2005-03-03 E.I. Dupont De Nemours And Company Membranes of fluorinated ionomer blended with nonionomeric fluoropolymers for electrochemical cells
US20050090613A1 (en) 2003-10-22 2005-04-28 Daikin Industries, Ltd. Process for preparing fluorine-containing polymer latex
EP1529785B1 (en) * 2003-10-24 2011-03-16 3M Innovative Properties Company Aqueous dispersions of polytetrafluoroethylene particles
US7071271B2 (en) * 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
EP1533325B1 (en) 2003-11-17 2011-10-19 3M Innovative Properties Company Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant
JP2005320501A (ja) * 2004-04-07 2005-11-17 Daikin Ind Ltd 含フッ素エラストマー重合体の製造方法
US7563828B2 (en) * 2004-07-16 2009-07-21 Alcatel-Lucent Usa Inc. Solid state proton conductor system derived from hybrid composite inorganic-organic multicomponent material
US20060014887A1 (en) 2004-07-19 2006-01-19 3M Innovative Properties Company Method of hydrolyzing a dispersion of ionic fluoropolymer
GB0511779D0 (en) 2005-06-10 2005-07-20 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers in the presence of a partially fluorinated oligomer as an emulsifier
GB0514398D0 (en) 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant
GB0514387D0 (en) 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant
US7795332B2 (en) 2005-07-15 2010-09-14 3M Innovative Properties Company Method of removing fluorinated carboxylic acid from aqueous liquid
EP1939222B2 (en) 2005-10-17 2019-09-04 AGC Inc. Process for producing an AQUEOUS POLYTETRAFLUOROETHYLENE EMULSION, AND POLYTETRAFLUOROETHYLENE FINE POWDER AND POROUS MATERIAL PRODUCED FROM THE SAME
WO2007046377A1 (ja) 2005-10-20 2007-04-26 Asahi Glass Company, Limited 溶融成形可能なフッ素樹脂の製造方法
CN101291987B (zh) 2005-10-20 2012-05-09 旭硝子株式会社 聚四氟乙烯水性分散液及其制品
RU2409592C2 (ru) 2005-10-26 2011-01-20 Асахи Гласс Компани, Лимитед Фторсодержащий полимер с низким остаточным содержанием фторированного эмульгатора и способ его получения
US8580896B2 (en) * 2006-05-10 2013-11-12 Daikin Industries, Ltd. Process for preparing fluorine-containing polymer
EP2084195B1 (en) 2006-11-09 2011-06-08 E.I. Du Pont De Nemours And Company Aqueous polymerization of fluorinated monomers using polymerization agent comprising fluoropolyether acid or salt and hydrocarbon surfactant
EP2079766B1 (en) * 2006-11-09 2011-05-18 E.I. Du Pont De Nemours And Company Aqueous polymerization of fluorinated monomer using polymerization agent comprising high molecular weight fluoropolyether acid or salt and fluoropolyether acid or salt surfactant
US7989566B2 (en) 2008-01-22 2011-08-02 Dupont Performance Elastomers Llc Process for producing fluoropolymers
US8058376B2 (en) * 2008-12-23 2011-11-15 E. I. Du Pont De Nemours And Company Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated lonomer produced in situ

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Publication number Publication date
US8153738B2 (en) 2012-04-10
CN102264777A (zh) 2011-11-30
CN102264777B (zh) 2014-05-07
EP3091039B1 (en) 2023-03-01
US20100160490A1 (en) 2010-06-24
EP3091039A1 (en) 2016-11-09
EP2367858A1 (en) 2011-09-28
WO2010075359A1 (en) 2010-07-01
JP2012513530A (ja) 2012-06-14
EP2367858B1 (en) 2016-05-04

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