JP2012513530A5 - - Google Patents
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- Publication number
- JP2012513530A5 JP2012513530A5 JP2011543633A JP2011543633A JP2012513530A5 JP 2012513530 A5 JP2012513530 A5 JP 2012513530A5 JP 2011543633 A JP2011543633 A JP 2011543633A JP 2011543633 A JP2011543633 A JP 2011543633A JP 2012513530 A5 JP2012513530 A5 JP 2012513530A5
- Authority
- JP
- Japan
- Prior art keywords
- fluorinated
- fluorinated ionomer
- polymerization medium
- ionomer
- aqueous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000000034 method Methods 0.000 claims description 29
- 229920000554 ionomer Polymers 0.000 claims description 21
- 238000006116 polymerization reaction Methods 0.000 claims description 13
- 239000000178 monomer Substances 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 10
- 239000010419 fine particle Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- 229920002313 fluoropolymer Polymers 0.000 claims description 7
- 239000004811 fluoropolymer Substances 0.000 claims description 7
- 230000000379 polymerizing effect Effects 0.000 claims description 5
- 239000003999 initiator Substances 0.000 claims description 4
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 15
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 description 10
- 239000002609 medium Substances 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- -1 sulfonamido anion Chemical class 0.000 description 7
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 125000003010 ionic group Chemical group 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 150000007942 carboxylates Chemical class 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- YSYRISKCBOPJRG-UHFFFAOYSA-N 4,5-difluoro-2,2-bis(trifluoromethyl)-1,3-dioxole Chemical compound FC1=C(F)OC(C(F)(F)F)(C(F)(F)F)O1 YSYRISKCBOPJRG-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 239000011859 microparticle Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 2
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 description 1
- JMGNVALALWCTLC-UHFFFAOYSA-N 1-fluoro-2-(2-fluoroethenoxy)ethene Chemical compound FC=COC=CF JMGNVALALWCTLC-UHFFFAOYSA-N 0.000 description 1
- RFJVDJWCXSPUBY-UHFFFAOYSA-N 2-(difluoromethylidene)-4,4,5-trifluoro-5-(trifluoromethyl)-1,3-dioxolane Chemical compound FC(F)=C1OC(F)(F)C(F)(C(F)(F)F)O1 RFJVDJWCXSPUBY-UHFFFAOYSA-N 0.000 description 1
- QMIWYOZFFSLIAK-UHFFFAOYSA-N 3,3,3-trifluoro-2-(trifluoromethyl)prop-1-ene Chemical group FC(F)(F)C(=C)C(F)(F)F QMIWYOZFFSLIAK-UHFFFAOYSA-N 0.000 description 1
- SLWGRAIAXWXVQY-UHFFFAOYSA-N 3-(2-ethoxypropoxy)prop-2-enenitrile Chemical compound CCOC(C)COC=CC#N SLWGRAIAXWXVQY-UHFFFAOYSA-N 0.000 description 1
- ZXABMDQSAABDMG-UHFFFAOYSA-N 3-ethenoxyprop-1-ene Chemical compound C=CCOC=C ZXABMDQSAABDMG-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920006169 Perfluoroelastomer Polymers 0.000 description 1
- 229920001774 Perfluoroether Polymers 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- PYLIXCKOHOHGKQ-UHFFFAOYSA-L disodium;hydrogen phosphate;heptahydrate Chemical compound O.O.O.O.O.O.O.[Na+].[Na+].OP([O-])([O-])=O PYLIXCKOHOHGKQ-UHFFFAOYSA-L 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- WRUGWIBCXHJTDG-UHFFFAOYSA-L magnesium sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Mg+2].[O-]S([O-])(=O)=O WRUGWIBCXHJTDG-UHFFFAOYSA-L 0.000 description 1
- 229940061634 magnesium sulfate heptahydrate Drugs 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14011408P | 2008-12-23 | 2008-12-23 | |
| US61/140,114 | 2008-12-23 | ||
| PCT/US2009/069155 WO2010075359A1 (en) | 2008-12-23 | 2009-12-22 | Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012513530A JP2012513530A (ja) | 2012-06-14 |
| JP2012513530A5 true JP2012513530A5 (enExample) | 2013-02-07 |
| JP5750375B2 JP5750375B2 (ja) | 2015-07-22 |
Family
ID=41559919
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011543633A Active JP5750375B2 (ja) | 2008-12-23 | 2009-12-22 | フッ素化イオノマーの分散微粒子を使用する水性重合により製造されるフルオロポリマー |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US8153738B2 (enExample) |
| EP (2) | EP3091039B1 (enExample) |
| JP (1) | JP5750375B2 (enExample) |
| CN (1) | CN102264777B (enExample) |
| WO (1) | WO2010075359A1 (enExample) |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE541870T1 (de) * | 2008-04-14 | 2012-02-15 | Asahi Glass Co Ltd | Verfahren zur herstellung von polytetrafluorethylen-feinpulver |
| US20090281241A1 (en) * | 2008-05-09 | 2009-11-12 | E. I. Du Pont De Nemours And Company | Aqueous Polymerization of Fluorinated Monomer Using a Mixture of Fluoropolyether Acids or Salts |
| US8835547B2 (en) * | 2008-12-23 | 2014-09-16 | E I Du Pont De Nemours And Company | Fluoropolymer particles having a nucleus of fluorinated ionomer |
| US8436054B2 (en) | 2008-12-23 | 2013-05-07 | E I Du Pont De Nemours And Company | Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer produced in situ |
| EP2638083B1 (en) | 2010-11-09 | 2019-04-10 | The Chemours Company FC, LLC | Reducing the telogenic behavior of hydrocarbon-containing surfactants in aqueous dispersion fluoromonomer polymerization |
| WO2012064841A1 (en) | 2010-11-09 | 2012-05-18 | E. I. Du Pont De Nemours And Company | Aqueous polymerization of fluoromonomer using hydrocarbon surfactant |
| CN103201301B (zh) | 2010-11-09 | 2017-02-08 | 纳幕尔杜邦公司 | 含氟单体的含水聚合反应中的成核作用 |
| GB201021790D0 (en) | 2010-12-23 | 2011-02-02 | 3M Innovative Properties Co | Fluoropolymer compostions and purification methods thereof |
| CN113717401A (zh) * | 2012-11-30 | 2021-11-30 | 大金工业株式会社 | 聚四氟乙烯水性分散液和聚四氟乙烯细粉 |
| US9243080B2 (en) | 2012-11-30 | 2016-01-26 | Daikin Industries, Ltd. | Production method for polytetrafluoroethylene aqueous dispersion |
| WO2014084397A1 (ja) * | 2012-11-30 | 2014-06-05 | ダイキン工業株式会社 | ポリテトラフルオロエチレン水性分散液の製造方法 |
| US20150210787A1 (en) * | 2012-12-18 | 2015-07-30 | E. I. Du Pont De Nemours And Company | Process for Producing Fluoroelastomers |
| EP3027684B1 (en) * | 2013-07-30 | 2017-05-17 | Solvay Specialty Polymers Italy S.p.A. | Fluorine-containing thermoplastic elastomer composition |
| CN106414510B (zh) | 2013-11-26 | 2018-11-30 | 得凯莫斯公司弗罗里达有限公司 | 采用聚环氧烷在含氟单体的水相聚合中成核 |
| WO2015186793A1 (ja) * | 2014-06-04 | 2015-12-10 | ダイキン工業株式会社 | ポリテトラフルオロエチレン水性分散液 |
| US9902787B2 (en) | 2014-06-04 | 2018-02-27 | Daikin Industries, Ltd. | Polytetrafluoroethylene powder |
| WO2016182880A1 (en) * | 2015-05-11 | 2016-11-17 | Compact Membrane Systems, Inc. | Improved membranes for separation of alkenes from alkanes |
| SG11202000862YA (en) * | 2017-08-10 | 2020-02-27 | Daikin Ind Ltd | Method for producing purified polytetrafluoroethylene aqueous dispersion liquid, method for producing modified polytetrafluoroethylene powder, method for producing polytetrafluoroethylene molded body, and composition |
| CN116622018A (zh) | 2018-03-01 | 2023-08-22 | 大金工业株式会社 | 含氟聚合物的制造方法 |
| CN113039213B (zh) * | 2018-11-19 | 2023-07-28 | 大金工业株式会社 | 改性聚四氟乙烯的制造方法和组合物 |
| US12195617B2 (en) | 2018-11-19 | 2025-01-14 | Daikin Industries, Ltd. | Composition and stretched body |
| EP3960713A4 (en) | 2019-04-26 | 2023-01-18 | Daikin Industries, Ltd. | Water treatment method and composition |
| CN113728014B (zh) | 2019-04-26 | 2024-07-26 | 大金工业株式会社 | 含氟聚合物水性分散液的制造方法、排水的处理方法和含氟聚合物水性分散液 |
| JP7201948B2 (ja) * | 2019-07-23 | 2023-01-11 | ダイキン工業株式会社 | フルオロポリマーの製造方法、ポリテトラフルオロエチレン組成物及びポリテトラフルオロエチレン粉末 |
| JP7368759B2 (ja) | 2019-09-05 | 2023-10-25 | ダイキン工業株式会社 | パーフルオロエラストマーの製造方法および組成物 |
| WO2021045227A1 (ja) | 2019-09-05 | 2021-03-11 | ダイキン工業株式会社 | 組成物およびその製造方法 |
| EP4063405A4 (en) * | 2019-11-19 | 2024-01-10 | Daikin Industries, Ltd. | PROCESS FOR PRODUCING POLYTETRAFLUOROETHYLENE |
| JP7352110B2 (ja) * | 2019-11-19 | 2023-09-28 | ダイキン工業株式会社 | フルオロポリマーの製造方法、ポリテトラフルオロエチレンの製造方法、パーフルオロエラストマーの製造方法および組成物 |
| JP2023543807A (ja) | 2020-10-01 | 2023-10-18 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | フルオロポリマーの水性重合における低反応性炭化水素分散剤 |
| WO2022107894A1 (ja) | 2020-11-19 | 2022-05-27 | ダイキン工業株式会社 | ポリテトラフルオロエチレンの製造方法およびポリテトラフルオロエチレンを含有する組成物 |
| EP4249525A4 (en) | 2020-11-19 | 2024-10-16 | Daikin Industries, Ltd. | METHOD FOR PREPARING AN AQUEOUS PERFLUOROLASTOMER DISPERSION, COMPOSITION, CROSS-LINKABLE COMPOSITION AND CROSS-LINKED PRODUCT |
| JP7709062B2 (ja) | 2020-11-19 | 2025-07-16 | ダイキン工業株式会社 | 含フッ素エラストマー水性分散液の製造方法および組成物 |
| CN116670181A (zh) * | 2021-01-28 | 2023-08-29 | 大金工业株式会社 | 含氟聚合物组合物的制造方法 |
| JP7727213B2 (ja) | 2021-03-10 | 2025-08-21 | ダイキン工業株式会社 | 塗料組成物、塗布膜、積層体および塗装物品 |
| JPWO2022244784A1 (enExample) | 2021-05-19 | 2022-11-24 | ||
| CN115466343B (zh) * | 2021-06-11 | 2023-10-27 | 中昊晨光化工研究院有限公司 | 一种聚醚二酸或其盐类表面活性剂及其应用 |
| CN117529511A (zh) | 2021-06-11 | 2024-02-06 | 大金工业株式会社 | 含氟弹性体水性分散液的制造方法、组合物和水性分散液 |
| EP4365211A4 (en) | 2021-06-30 | 2025-07-16 | Daikin Ind Ltd | METHOD FOR PRODUCING A COMPOSITION CONTAINING A HIGH-PURITY FLUOROPOLYMER, AND COMPOSITION CONTAINING A HIGH-PURITY FLUOROPOLYMER |
| JP7747987B2 (ja) | 2021-06-30 | 2025-10-02 | ダイキン工業株式会社 | フルオロポリマー組成物の製造方法およびフルオロポリマー組成物 |
| JP7657762B2 (ja) * | 2021-09-30 | 2025-04-07 | ダイキン工業株式会社 | ポリテトラフルオロエチレンファインパウダー |
| EP4497762A1 (en) | 2022-03-23 | 2025-01-29 | Daikin Industries, Ltd. | Method for producing fluoropolymer, and composition |
| WO2023210818A1 (ja) | 2022-04-28 | 2023-11-02 | ダイキン工業株式会社 | フッ素ゴムを含有する組成物 |
| EP4516819A1 (en) | 2022-04-28 | 2025-03-05 | Daikin Industries, Ltd. | Method for producing fluoropolymer |
| WO2023210820A1 (ja) | 2022-04-28 | 2023-11-02 | ダイキン工業株式会社 | フッ素樹脂を含有する組成物の製造方法およびフッ素樹脂を含有する組成物 |
| WO2024154773A1 (ja) | 2023-01-18 | 2024-07-25 | ダイキン工業株式会社 | テトラフルオロエチレン系ポリマー組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池 |
| CN120548621A (zh) | 2023-01-18 | 2025-08-26 | 大金工业株式会社 | 电化学器件用合剂、电化学器件用合剂片、电极和电化学器件 |
| JP7658519B2 (ja) * | 2023-04-10 | 2025-04-08 | Ａｇｃ株式会社 | 含フッ素重合体の製造方法、水性分散液及び固体組成物 |
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-
2009
- 2009-12-18 US US12/641,360 patent/US8153738B2/en active Active
- 2009-12-22 EP EP16167765.3A patent/EP3091039B1/en active Active
- 2009-12-22 EP EP09775078.0A patent/EP2367858B1/en active Active
- 2009-12-22 WO PCT/US2009/069155 patent/WO2010075359A1/en not_active Ceased
- 2009-12-22 CN CN200980152447.8A patent/CN102264777B/zh active Active
- 2009-12-22 JP JP2011543633A patent/JP5750375B2/ja active Active
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