JP5728954B2 - 炭化珪素半導体装置の製造方法 - Google Patents
炭化珪素半導体装置の製造方法 Download PDFInfo
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- 229910010271 silicon carbide Inorganic materials 0.000 title claims description 91
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 title claims description 65
- 238000004519 manufacturing process Methods 0.000 title claims description 52
- 238000000034 method Methods 0.000 title claims description 35
- 239000004065 semiconductor Substances 0.000 title claims description 23
- 239000010410 layer Substances 0.000 claims description 117
- 239000000758 substrate Substances 0.000 claims description 75
- 229910045601 alloy Inorganic materials 0.000 claims description 47
- 239000000956 alloy Substances 0.000 claims description 47
- 229910052782 aluminium Inorganic materials 0.000 claims description 12
- 238000000137 annealing Methods 0.000 claims description 12
- 229910052710 silicon Inorganic materials 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 6
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 6
- 238000004544 sputter deposition Methods 0.000 claims description 6
- 239000011229 interlayer Substances 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 4
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 4
- 125000004429 atom Chemical group 0.000 description 58
- 239000012535 impurity Substances 0.000 description 37
- 239000010936 titanium Substances 0.000 description 30
- 239000000463 material Substances 0.000 description 15
- 238000002161 passivation Methods 0.000 description 14
- 239000007789 gas Substances 0.000 description 11
- 229910004298 SiO 2 Inorganic materials 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 9
- 239000011261 inert gas Substances 0.000 description 9
- 238000005468 ion implantation Methods 0.000 description 8
- 238000005477 sputtering target Methods 0.000 description 7
- 230000010354 integration Effects 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 229910052796 boron Inorganic materials 0.000 description 5
- 238000005229 chemical vapour deposition Methods 0.000 description 5
- 239000004020 conductor Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 238000001020 plasma etching Methods 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 230000005669 field effect Effects 0.000 description 4
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 4
- 229920005591 polysilicon Polymers 0.000 description 4
- 229910021364 Al-Si alloy Inorganic materials 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000007740 vapor deposition Methods 0.000 description 3
- 229910018575 Al—Ti Inorganic materials 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 2
- 239000012808 vapor phase Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- ZOCHARZZJNPSEU-UHFFFAOYSA-N diboron Chemical compound B#B ZOCHARZZJNPSEU-UHFFFAOYSA-N 0.000 description 1
- 238000001312 dry etching Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
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Description
まず本実施の形態におけるMOSFET(酸化膜電界効果トランジスタ)の構成について説明する。
図4および図5を参照して、まず基板準備工程S10(図2)によって炭化珪素基板10が準備される。
図6および図7を参照して、ゲート絶縁膜形成工程S70(図2)によって、ゲート酸化膜15(絶縁膜)が形成される。具体的には、まず、上記工程が実施されて所望のイオン注入領域を含むn−SiC層12が形成されたn+基板11が熱酸化される。熱酸化は、たとえば酸素雰囲気中で1300℃程度に加熱し、40分間程度保持することにより実施することができる。これにより第2の主面12B上に、二酸化珪素(SiO2)からなる熱酸化膜15A(たとえば厚み50nm程度)が形成される。熱酸化膜15A上にレジストが塗布された後、露光および現像が行なわれ、ソースコンタクト電極16(図1参照)を形成すべき領域に応じた開口91Aを有するレジスト膜91が形成される。そして、当該レジスト膜91をマスクとして用いて、たとえばRIEにより熱酸化膜15Aが部分的に除去される。これにより、第2の主面12Bの一部を覆うゲート酸化膜15が形成される。
具体的には、合金膜形成工程S81(図3)によって、Si原子、Ti原子、およびAl原子とを含有する合金から作られた合金膜50が形成される。すなわち、第2の主面12B上およびn+基板11のn−SiC層12とは反対側の主面上に、合金膜50が形成される。合金膜の形成は、好ましくは、スパッタリングターゲット90を用いたスパッタ法によって行なわれる。スパッタリングターゲット90は、Al原子、Si原子、およびTi原子を含有する合金から作られている。次にレジスト膜91が除去されることにより、レジスト膜91上の合金膜50が除去(リフトオフ)されて、図8に示すように、ゲート酸化膜15から露出する第2の主面12B上およびn+基板11のn−SiC層12とは反対側の主面上に、合金膜50が残存する。これにより、一対のn+ソース領域14上のそれぞれから、ゲート酸化膜15から離れる向きにp+領域18上にまで延在するとともに、第2の主面12Bに接触して配置されるソースコンタクト電極16、およびn+基板11においてn−SiC層12が形成される側の主面である一方の主面11Aとは反対側の主面である他方の主面11Bに接触して配置されるドレイン電極20が形成される。ソースコンタクト電極16は、ゲート酸化膜15に接触するように第2の主面12B上に形成される。
本実施の形態の製造方法によれば、ソースコンタクト電極16が含むAl原子は、ソースコンタクト電極16がアニールされる前に、元素としてではなく、Si原子およびTi原子との合金として存在する。これにより、アニール中にAl原子がソースコンタクト電極16の外部へ拡散することが抑制される。よってAl原子がゲート酸化膜15中に拡散することが抑制されるので、ゲート酸化膜15の信頼性を高めることができる。
まず本実施の形態におけるJFET(接合型電界効果トランジスタ)の構成について説明する。
図12〜図14を参照して、まず基板準備工程S210(図11)によって炭化珪素基板30が準備される。
次にオーミック電極形成工程S270(図11)が行われる。この工程(S270)は、実施の形態1における工程(S80)と同様に実施することができる。具体的には、まず実施の形態1の工程S81(図3)と同様に、合金膜50が、レジスト膜91上および当該レジスト膜91から露出する領域に形成される。さらに、レジスト膜91が除去されることにより、レジスト膜91上の合金膜50が除去(リフトオフ)されて、第1のn型領域35、第1のp型領域36、第2のn型領域37および第2のp型領域43上に接触するように、合金膜50が残存する。
本実施の形態においても実施の形態1とほぼ同様のMOSFET1が製造される。まず実施の形態1と同様にゲート絶縁膜形成工程S70(図2)によってゲート酸化膜15(絶縁膜)が形成される。
さらに本実施の形態によれば、合金膜59をTi膜53が被覆することによって、合金膜59中のAl原子が酸化されることを防止することができる。これにより上記効果をより高めることができる。
本実施の形態においても実施の形態2(図10)とほぼ同様のJFET3が製造される。
本実施の形態によっても実施の形態2とほぼ同様の効果が得られる。
Claims (5)
- 基板面を有する炭化珪素基板を準備する工程と、
前記基板面の一部を覆うように絶縁膜を形成する工程と、
前記絶縁膜に接触するように前記基板面上にコンタクト電極を形成する工程とを備え、
前記炭化珪素基板は、p型領域およびn型領域を含み、
前記コンタクト電極はAl、TiおよびSi原子を含有し、前記コンタクト電極を形成する工程は、前記p型領域および前記n型領域の双方に接して配置されかつSi原子とAl原子とを含有する合金から作られた合金膜を形成する工程と、前記合金膜上にTi原子膜を形成する工程とを含み、さらに
前記炭化珪素基板が含む前記p型領域と前記コンタクト電極とがオーミックに接続されかつ前記炭化珪素基板が含む前記n型領域と前記コンタクト電極とがオーミックに接続されるように前記コンタクト電極をアニールする工程とを備える、炭化珪素半導体装置の製造方法。 - 前記合金膜は、前記合金から作られたターゲットを用いたスパッタ法によって形成される、請求項1に記載の炭化珪素半導体装置の製造方法。
- 前記絶縁膜は酸化珪素膜および窒化珪素膜の少なくともいずれかを含む、請求項1または請求項2に記載の炭化珪素半導体装置の製造方法。
- 前記絶縁膜上にゲート電極を形成する工程をさらに備える、請求項1から請求項3のいずれか1項に記載の炭化珪素半導体装置の製造方法。
- 前記絶縁膜は層間絶縁膜である、請求項1から請求項4のいずれか1項に記載の炭化珪素半導体装置の製造方法。
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2011004576A JP5728954B2 (ja) | 2011-01-13 | 2011-01-13 | 炭化珪素半導体装置の製造方法 |
PCT/JP2011/077799 WO2012096070A1 (ja) | 2011-01-13 | 2011-12-01 | 炭化珪素半導体装置の製造方法 |
KR1020137013834A KR20130109168A (ko) | 2011-01-13 | 2011-12-01 | 탄화규소 반도체 장치의 제조 방법 |
EP20110855485 EP2667403A4 (en) | 2011-01-13 | 2011-12-01 | PROCESS FOR MANUFACTURING A SEMICONDUCTOR DEVICE WITH SILICON CARBIDE |
CN2011800598382A CN103262218A (zh) | 2011-01-13 | 2011-12-01 | 制造碳化硅半导体器件的方法 |
TW100148105A TW201246283A (en) | 2011-01-13 | 2011-12-22 | Method of manufacturing silicon carbide semiconductor device |
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JP2014038899A (ja) | 2012-08-13 | 2014-02-27 | Sumitomo Electric Ind Ltd | 炭化珪素半導体装置およびその製造方法 |
JP5949305B2 (ja) * | 2012-08-13 | 2016-07-06 | 住友電気工業株式会社 | 炭化珪素半導体装置の製造方法 |
CN104718604B (zh) * | 2012-10-23 | 2017-06-30 | 富士电机株式会社 | 半导体装置的制造方法 |
JP5961563B2 (ja) | 2013-01-25 | 2016-08-02 | 株式会社豊田中央研究所 | 半導体装置の製造方法 |
JP6075185B2 (ja) * | 2013-04-26 | 2017-02-08 | 住友電気工業株式会社 | 炭化珪素半導体装置の製造方法 |
JP2015015352A (ja) * | 2013-07-04 | 2015-01-22 | 住友電気工業株式会社 | 炭化珪素半導体装置の製造方法 |
JP2015032614A (ja) | 2013-07-31 | 2015-02-16 | 住友電気工業株式会社 | 炭化珪素半導体装置およびその製造方法 |
JP2015032615A (ja) | 2013-07-31 | 2015-02-16 | 住友電気工業株式会社 | 炭化珪素半導体装置の製造方法 |
US9214572B2 (en) * | 2013-09-20 | 2015-12-15 | Monolith Semiconductor Inc. | High voltage MOSFET devices and methods of making the devices |
JP6183200B2 (ja) * | 2013-12-16 | 2017-08-23 | 住友電気工業株式会社 | 炭化珪素半導体装置およびその製造方法 |
CN106024597A (zh) * | 2016-05-30 | 2016-10-12 | 北京世纪金光半导体有限公司 | 一种碳化硅欧姆接触形成方法 |
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EP2667403A1 (en) | 2013-11-27 |
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KR20130109168A (ko) | 2013-10-07 |
US20120184094A1 (en) | 2012-07-19 |
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