JP5444615B2 - α−オレフィン低重合体の製造方法 - Google Patents

α−オレフィン低重合体の製造方法 Download PDF

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Publication number
JP5444615B2
JP5444615B2 JP2007341365A JP2007341365A JP5444615B2 JP 5444615 B2 JP5444615 B2 JP 5444615B2 JP 2007341365 A JP2007341365 A JP 2007341365A JP 2007341365 A JP2007341365 A JP 2007341365A JP 5444615 B2 JP5444615 B2 JP 5444615B2
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Prior art keywords
olefin
reactor
ethylene
chromium
solvent
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Japanese (ja)
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JP2008179631A (ja
JP2008179631A5 (enExample
Inventor
浩樹 江本
圭 吉鶴
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Mitsubishi Chemical Corp
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Mitsubishi Chemical Corp
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Publication of JP2008179631A5 publication Critical patent/JP2008179631A5/ja
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Catalysts (AREA)
JP2007341365A 2006-12-28 2007-12-28 α−オレフィン低重合体の製造方法 Active JP5444615B2 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2007341365A JP5444615B2 (ja) 2006-12-28 2007-12-28 α−オレフィン低重合体の製造方法

Applications Claiming Priority (3)

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JP2006354541 2006-12-28
JP2006354541 2006-12-28
JP2007341365A JP5444615B2 (ja) 2006-12-28 2007-12-28 α−オレフィン低重合体の製造方法

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JP2008326605A Division JP2009102363A (ja) 2006-12-28 2008-12-22 α−オレフィン低重合体の製造方法

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JP2008179631A JP2008179631A (ja) 2008-08-07
JP2008179631A5 JP2008179631A5 (enExample) 2009-02-12
JP5444615B2 true JP5444615B2 (ja) 2014-03-19

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JP2008326605A Pending JP2009102363A (ja) 2006-12-28 2008-12-22 α−オレフィン低重合体の製造方法

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US (1) US9421534B2 (enExample)
EP (1) EP2098542A4 (enExample)
JP (2) JP5444615B2 (enExample)
CN (1) CN101547941B (enExample)
BR (1) BRPI0719595B1 (enExample)
CA (1) CA2672385C (enExample)
EA (1) EA024462B1 (enExample)
WO (1) WO2008081638A1 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2672385C (en) 2006-12-28 2014-10-14 Mitsubishi Chemical Corporation Process for production of .alpha.-olefin low polymers using chromium catalyst
ES2371218T3 (es) * 2009-04-09 2011-12-28 Saudi Basic Industries Corporation Composición de catalizador y procedimiento para la oligomerización de etileno.
WO2011118533A1 (ja) * 2010-03-26 2011-09-29 三菱化学株式会社 α－オレフィン低重合体の製造方法
JP5793899B2 (ja) * 2011-03-09 2015-10-14 三菱化学株式会社 １−ヘキセンの製造方法
JP2013231015A (ja) * 2012-05-02 2013-11-14 Idemitsu Kosan Co Ltd オレフィンオリゴマーの製造方法
FR2992962B1 (fr) * 2012-07-04 2015-06-26 Axens Procede de separation de l'hexene-1 a partir d'un melange de produits issus d'une zone de trimerisation de l'ethylene
JP6459587B2 (ja) * 2014-02-25 2019-01-30 三菱ケミカル株式会社 α−オレフィン低重合体の製造方法
RU2682668C1 (ru) * 2015-03-27 2019-03-20 Мицубиси Кемикал Корпорейшн СПОСОБ ДЛЯ ПРОИЗВОДСТВА НИЗКОМОЛЕКУЛЯРНОГО ПОЛИМЕРА α-ОЛЕФИНА
WO2016206911A1 (en) * 2015-06-23 2016-12-29 Sabic Global Technologies B.V. Polymerisation of ethylene in the presence of a silylchromate based catalyst
WO2020114745A1 (en) 2018-12-04 2020-06-11 Exxonmobil Chemical Patents Inc. Methods for separating linear alpha olefins from combined product streams
KR102732601B1 (ko) * 2021-01-18 2024-11-19 주식회사 엘지화학 올리고머 제조방법

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US2860126A (en) 1954-07-09 1958-11-11 Phillips Petroleum Co Polymerization process
US2964511A (en) * 1956-03-12 1960-12-13 Phillips Petroleum Co Control of catalytic processes
GB855120A (en) 1956-05-07 1960-11-30 Phillips Petroleum Co Method of supplying a catalyst to a reaction zone and apparatus therefor
US3250757A (en) * 1961-05-18 1966-05-10 Phillips Petroleum Co Method and apparatus for controlling feed to a polymerization reaction
US4434313A (en) * 1981-12-14 1984-02-28 Exxon Research And Engineering Co. Preparation of linear olefin products
US5198563A (en) * 1989-08-10 1993-03-30 Phillips Petroleum Company Chromium compounds and uses thereof
CA2110654C (en) * 1992-12-17 2006-03-21 Albert Rossi Dilute process for the polymerization of ethylene/alpha-olefin copolymer using metallocene catalyst systems
JP2618589B2 (ja) * 1993-06-21 1997-06-11 日本合成アルコール株式会社 エチレンの回収方法
JPH0760048A (ja) 1993-08-26 1995-03-07 Mitsubishi Petrochem Eng Co Ltd 酸化エチレン製造プラント排ガスからのエチレンの回収法
CA2134503C (en) * 1994-02-18 2001-04-10 Mark E. Lashier Olefin production
JP2756459B2 (ja) * 1994-05-31 1998-05-25 日本合成アルコール株式会社 エチレン水和反応における不純エチレン流の処理方法
KR100414008B1 (ko) * 1995-03-02 2004-04-29 미쓰비시 가가꾸 가부시키가이샤 α-올레핀올리고머의제조방법
JP3847809B2 (ja) 1995-03-02 2006-11-22 三菱化学株式会社 α−オレフイン低重合体の製造方法
US5856612A (en) 1996-02-02 1999-01-05 Mitsubishi Chemical Corporation Process for producing α-olefin oligomer
JP3549136B2 (ja) * 1996-07-30 2004-08-04 三菱化学株式会社 α−オレフイン低重合体の製造方法
JP3518968B2 (ja) * 1996-08-08 2004-04-12 三菱化学株式会社 α−オレフイン低重合体の製造方法
JPH1171411A (ja) * 1997-06-26 1999-03-16 Mitsui Chem Inc プロピレンの重合方法
CA2241573A1 (en) 1997-06-26 1998-12-26 Hiroshi Nishikawa Process for propylene polymerization
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JPH1160511A (ja) * 1997-08-25 1999-03-02 Mitsubishi Chem Corp α−オレフィン低重合体の製造方法
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JP4681773B2 (ja) * 2001-08-28 2011-05-11 出光興産株式会社 エチレン低重合体の製造方法
DE10211386A1 (de) 2002-03-14 2003-09-25 Basf Ag Verfahren zur Oligomerisierung von Olefinen unter Verwendung eines Cycloalkylalkyl-substituierten Triazacyclohexans
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CA2672385C (en) 2006-12-28 2014-10-14 Mitsubishi Chemical Corporation Process for production of .alpha.-olefin low polymers using chromium catalyst

Also Published As

Publication number Publication date
EA024462B1 (ru) 2016-09-30
EA200970640A1 (ru) 2010-02-26
CA2672385C (en) 2014-10-14
EP2098542A4 (en) 2011-03-09
EP2098542A1 (en) 2009-09-09
BRPI0719595A2 (pt) 2013-12-17
US9421534B2 (en) 2016-08-23
WO2008081638A1 (ja) 2008-07-10
JP2008179631A (ja) 2008-08-07
CA2672385A1 (en) 2008-07-10
BRPI0719595B1 (pt) 2017-12-26
US20090326297A1 (en) 2009-12-31
CN101547941A (zh) 2009-09-30
CN101547941B (zh) 2011-12-28
JP2009102363A (ja) 2009-05-14

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