CN101547941B - α-烯烃低聚物的制造方法 - Google Patents
α-烯烃低聚物的制造方法 Download PDFInfo
- Publication number
- CN101547941B CN101547941B CN2007800450285A CN200780045028A CN101547941B CN 101547941 B CN101547941 B CN 101547941B CN 2007800450285 A CN2007800450285 A CN 2007800450285A CN 200780045028 A CN200780045028 A CN 200780045028A CN 101547941 B CN101547941 B CN 101547941B
- Authority
- CN
- China
- Prior art keywords
- olefin
- alpha
- reactor
- chromium
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/12—Olefin polymerisation or copolymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/62—Chromium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP354541/2006 | 2006-12-28 | ||
| JP2006354541 | 2006-12-28 | ||
| PCT/JP2007/070572 WO2008081638A1 (ja) | 2006-12-28 | 2007-10-22 | α-オレフィン低重合体の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101547941A CN101547941A (zh) | 2009-09-30 |
| CN101547941B true CN101547941B (zh) | 2011-12-28 |
Family
ID=39588323
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007800450285A Active CN101547941B (zh) | 2006-12-28 | 2007-10-22 | α-烯烃低聚物的制造方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9421534B2 (enExample) |
| EP (1) | EP2098542A4 (enExample) |
| JP (2) | JP5444615B2 (enExample) |
| CN (1) | CN101547941B (enExample) |
| BR (1) | BRPI0719595B1 (enExample) |
| CA (1) | CA2672385C (enExample) |
| EA (1) | EA024462B1 (enExample) |
| WO (1) | WO2008081638A1 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2672385C (en) | 2006-12-28 | 2014-10-14 | Mitsubishi Chemical Corporation | Process for production of .alpha.-olefin low polymers using chromium catalyst |
| ES2371218T3 (es) * | 2009-04-09 | 2011-12-28 | Saudi Basic Industries Corporation | Composición de catalizador y procedimiento para la oligomerización de etileno. |
| WO2011118533A1 (ja) * | 2010-03-26 | 2011-09-29 | 三菱化学株式会社 | α-オレフィン低重合体の製造方法 |
| JP5793899B2 (ja) * | 2011-03-09 | 2015-10-14 | 三菱化学株式会社 | 1−ヘキセンの製造方法 |
| JP2013231015A (ja) * | 2012-05-02 | 2013-11-14 | Idemitsu Kosan Co Ltd | オレフィンオリゴマーの製造方法 |
| FR2992962B1 (fr) * | 2012-07-04 | 2015-06-26 | Axens | Procede de separation de l'hexene-1 a partir d'un melange de produits issus d'une zone de trimerisation de l'ethylene |
| JP6459587B2 (ja) * | 2014-02-25 | 2019-01-30 | 三菱ケミカル株式会社 | α−オレフィン低重合体の製造方法 |
| RU2682668C1 (ru) * | 2015-03-27 | 2019-03-20 | Мицубиси Кемикал Корпорейшн | СПОСОБ ДЛЯ ПРОИЗВОДСТВА НИЗКОМОЛЕКУЛЯРНОГО ПОЛИМЕРА α-ОЛЕФИНА |
| WO2016206911A1 (en) * | 2015-06-23 | 2016-12-29 | Sabic Global Technologies B.V. | Polymerisation of ethylene in the presence of a silylchromate based catalyst |
| WO2020114745A1 (en) | 2018-12-04 | 2020-06-11 | Exxonmobil Chemical Patents Inc. | Methods for separating linear alpha olefins from combined product streams |
| KR102732601B1 (ko) * | 2021-01-18 | 2024-11-19 | 주식회사 엘지화학 | 올리고머 제조방법 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5750816A (en) * | 1995-03-02 | 1998-05-12 | Mitsubishi Chemical Corporation | Process for the preparation of α-olefin oligomers |
| CN1182729A (zh) * | 1996-02-02 | 1998-05-27 | 三菱化学株式会社 | 制造α-烯烃低聚物的方法 |
| CN1203925A (zh) * | 1997-06-26 | 1999-01-06 | 三井化学株式会社 | 丙烯聚合的方法 |
| CN1406217A (zh) * | 2000-12-26 | 2003-03-26 | 出光石油化学株式会社 | 生产乙烯类低聚物的方法 |
| CN1457330A (zh) * | 2001-02-23 | 2003-11-19 | 出光石油化学株式会社 | α-烯烃低聚物的生产方法 |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2860126A (en) | 1954-07-09 | 1958-11-11 | Phillips Petroleum Co | Polymerization process |
| US2964511A (en) * | 1956-03-12 | 1960-12-13 | Phillips Petroleum Co | Control of catalytic processes |
| GB855120A (en) | 1956-05-07 | 1960-11-30 | Phillips Petroleum Co | Method of supplying a catalyst to a reaction zone and apparatus therefor |
| US3250757A (en) * | 1961-05-18 | 1966-05-10 | Phillips Petroleum Co | Method and apparatus for controlling feed to a polymerization reaction |
| US4434313A (en) * | 1981-12-14 | 1984-02-28 | Exxon Research And Engineering Co. | Preparation of linear olefin products |
| US5198563A (en) * | 1989-08-10 | 1993-03-30 | Phillips Petroleum Company | Chromium compounds and uses thereof |
| CA2110654C (en) * | 1992-12-17 | 2006-03-21 | Albert Rossi | Dilute process for the polymerization of ethylene/alpha-olefin copolymer using metallocene catalyst systems |
| JP2618589B2 (ja) * | 1993-06-21 | 1997-06-11 | 日本合成アルコール株式会社 | エチレンの回収方法 |
| JPH0760048A (ja) | 1993-08-26 | 1995-03-07 | Mitsubishi Petrochem Eng Co Ltd | 酸化エチレン製造プラント排ガスからのエチレンの回収法 |
| CA2134503C (en) * | 1994-02-18 | 2001-04-10 | Mark E. Lashier | Olefin production |
| JP2756459B2 (ja) * | 1994-05-31 | 1998-05-25 | 日本合成アルコール株式会社 | エチレン水和反応における不純エチレン流の処理方法 |
| JP3847809B2 (ja) | 1995-03-02 | 2006-11-22 | 三菱化学株式会社 | α−オレフイン低重合体の製造方法 |
| JP3549136B2 (ja) * | 1996-07-30 | 2004-08-04 | 三菱化学株式会社 | α−オレフイン低重合体の製造方法 |
| JP3518968B2 (ja) * | 1996-08-08 | 2004-04-12 | 三菱化学株式会社 | α−オレフイン低重合体の製造方法 |
| JPH1171411A (ja) * | 1997-06-26 | 1999-03-16 | Mitsui Chem Inc | プロピレンの重合方法 |
| CA2241573A1 (en) | 1997-06-26 | 1998-12-26 | Hiroshi Nishikawa | Process for propylene polymerization |
| JPH1160511A (ja) * | 1997-08-25 | 1999-03-02 | Mitsubishi Chem Corp | α−オレフィン低重合体の製造方法 |
| US20020182124A1 (en) * | 1997-10-14 | 2002-12-05 | William M. Woodard | Olefin production process |
| US6380451B1 (en) * | 1999-12-29 | 2002-04-30 | Phillips Petroleum Company | Methods for restoring the heat transfer coefficient of an oligomerization reactor |
| GB0016895D0 (en) | 2000-07-11 | 2000-08-30 | Bp Chem Int Ltd | Olefin oligomerisation |
| US6593506B1 (en) * | 2000-10-12 | 2003-07-15 | Exxonmobil Chemical Patents Inc. | Olefin recovery in a polyolefin production process |
| JP2002256007A (ja) | 2000-12-26 | 2002-09-11 | Idemitsu Petrochem Co Ltd | α−オレフィン低重合体の製造方法 |
| JP4681773B2 (ja) * | 2001-08-28 | 2011-05-11 | 出光興産株式会社 | エチレン低重合体の製造方法 |
| DE10211386A1 (de) | 2002-03-14 | 2003-09-25 | Basf Ag | Verfahren zur Oligomerisierung von Olefinen unter Verwendung eines Cycloalkylalkyl-substituierten Triazacyclohexans |
| EP1491559B1 (en) * | 2002-03-29 | 2007-09-05 | Mitsui Chemicals, Inc. | Method of recycling waste gas in polymer production plant |
| EP2289952B2 (en) | 2004-08-27 | 2020-03-25 | Chevron Phillips Chemical Company LP | Energy efficient polyolefin process |
| FR2884247B1 (fr) * | 2005-04-11 | 2007-05-18 | Inst Francais Du Petrole | Procede et installation pour l'oligomerisation d'olefines mettant en oeuvre une separation membranaire |
| CA2672385C (en) | 2006-12-28 | 2014-10-14 | Mitsubishi Chemical Corporation | Process for production of .alpha.-olefin low polymers using chromium catalyst |
-
2007
- 2007-10-22 CA CA2672385A patent/CA2672385C/en active Active
- 2007-10-22 US US12/520,096 patent/US9421534B2/en active Active
- 2007-10-22 CN CN2007800450285A patent/CN101547941B/zh active Active
- 2007-10-22 EA EA200970640A patent/EA024462B1/ru not_active IP Right Cessation
- 2007-10-22 EP EP07830306A patent/EP2098542A4/en not_active Withdrawn
- 2007-10-22 WO PCT/JP2007/070572 patent/WO2008081638A1/ja not_active Ceased
- 2007-10-22 BR BRPI0719595-8A patent/BRPI0719595B1/pt active IP Right Grant
- 2007-12-28 JP JP2007341365A patent/JP5444615B2/ja active Active
-
2008
- 2008-12-22 JP JP2008326605A patent/JP2009102363A/ja active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5750816A (en) * | 1995-03-02 | 1998-05-12 | Mitsubishi Chemical Corporation | Process for the preparation of α-olefin oligomers |
| CN1182729A (zh) * | 1996-02-02 | 1998-05-27 | 三菱化学株式会社 | 制造α-烯烃低聚物的方法 |
| CN1203925A (zh) * | 1997-06-26 | 1999-01-06 | 三井化学株式会社 | 丙烯聚合的方法 |
| CN1406217A (zh) * | 2000-12-26 | 2003-03-26 | 出光石油化学株式会社 | 生产乙烯类低聚物的方法 |
| CN1457330A (zh) * | 2001-02-23 | 2003-11-19 | 出光石油化学株式会社 | α-烯烃低聚物的生产方法 |
Non-Patent Citations (3)
| Title |
|---|
| JP特开2003-64105A 2003.03.05 |
| JP特开平10-45833A 1998.02.17 |
| 化学工业出版社.化工辞典.《化工辞典》.化学工业出版社,1970,(第1版),524-525. * |
Also Published As
| Publication number | Publication date |
|---|---|
| EA024462B1 (ru) | 2016-09-30 |
| JP5444615B2 (ja) | 2014-03-19 |
| EA200970640A1 (ru) | 2010-02-26 |
| CA2672385C (en) | 2014-10-14 |
| EP2098542A4 (en) | 2011-03-09 |
| EP2098542A1 (en) | 2009-09-09 |
| BRPI0719595A2 (pt) | 2013-12-17 |
| US9421534B2 (en) | 2016-08-23 |
| WO2008081638A1 (ja) | 2008-07-10 |
| JP2008179631A (ja) | 2008-08-07 |
| CA2672385A1 (en) | 2008-07-10 |
| BRPI0719595B1 (pt) | 2017-12-26 |
| US20090326297A1 (en) | 2009-12-31 |
| CN101547941A (zh) | 2009-09-30 |
| JP2009102363A (ja) | 2009-05-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101547941B (zh) | α-烯烃低聚物的制造方法 | |
| US5856612A (en) | Process for producing α-olefin oligomer | |
| CN102596408B (zh) | 用于烯烃的(共-)三聚和烯烃低聚物的(共-)聚合的催化剂体系和方法 | |
| CN101553450A (zh) | 乙烯低聚物的制造方法 | |
| CN101200404A (zh) | 一种乙烯低聚合成短链烯烃的方法 | |
| CN107207383B (zh) | 制备烯烃的低聚物的方法 | |
| US8664345B2 (en) | Process for the preparation of a catalyst composition for dimerization, codimerization and oligomerization of olefins | |
| JP5593585B2 (ja) | α−オレフィン低重合体の製造方法 | |
| JPH08283330A (ja) | α−オレフイン低重合体の製造方法 | |
| CN106029611B (zh) | α-烯烃低聚物的制造方法 | |
| JP2019535504A (ja) | オレフィンオリゴマー化に使用される触媒系及びオレフィンオリゴマー化方法 | |
| TWI648300B (zh) | α-烯烴低聚合物之製造方法 | |
| JP5793899B2 (ja) | 1−ヘキセンの製造方法 | |
| JP3382077B2 (ja) | α−オレフイン低重合体の製造方法 | |
| CN118874543A (zh) | 用于乙烯二聚制备1-丁烯的催化剂体系 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder |
Address after: Tokyo, Japan Patentee after: MITSUBISHI CHEMICAL Corp. Address before: Tokyo, Japan Patentee before: MITSUBISHI RAYON Co.,Ltd. |
|
| CP01 | Change in the name or title of a patent holder | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170922 Address after: Tokyo, Japan Patentee after: MITSUBISHI RAYON Co.,Ltd. Address before: Tokyo, Japan Patentee before: MITSUBISHI CHEMICAL Corp. |
|
| TR01 | Transfer of patent right |