JP5337692B2 - ポリアミドおよびセピオライト型粘土のナノ複合材料組成物 - Google Patents
ポリアミドおよびセピオライト型粘土のナノ複合材料組成物 Download PDFInfo
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- JP5337692B2 JP5337692B2 JP2009515498A JP2009515498A JP5337692B2 JP 5337692 B2 JP5337692 B2 JP 5337692B2 JP 2009515498 A JP2009515498 A JP 2009515498A JP 2009515498 A JP2009515498 A JP 2009515498A JP 5337692 B2 JP5337692 B2 JP 5337692B2
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- JP
- Japan
- Prior art keywords
- polyamide
- sepiolite
- nanocomposite
- terephthalamide
- hexamethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims abstract description 92
- 239000002114 nanocomposite Substances 0.000 title claims abstract description 80
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- 229910052624 sepiolite Inorganic materials 0.000 claims description 70
- 235000019355 sepiolite Nutrition 0.000 claims description 70
- 229920000642 polymer Polymers 0.000 claims description 57
- 238000000034 method Methods 0.000 claims description 38
- 239000000463 material Substances 0.000 claims description 24
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- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 14
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- DJZKNOVUNYPPEE-UHFFFAOYSA-N tetradecane-1,4,11,14-tetracarboxamide Chemical compound NC(=O)CCCC(C(N)=O)CCCCCCC(C(N)=O)CCCC(N)=O DJZKNOVUNYPPEE-UHFFFAOYSA-N 0.000 claims description 9
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- LKWSTQPRPRGLDP-UHFFFAOYSA-N 4-(azacycloundecane-1-carbonyl)benzamide Chemical compound C1=CC(C(=O)N)=CC=C1C(=O)N1CCCCCCCCCC1 LKWSTQPRPRGLDP-UHFFFAOYSA-N 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
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- 239000005977 Ethylene Substances 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 229920003235 aromatic polyamide Polymers 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
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- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 claims 1
- 239000002105 nanoparticle Substances 0.000 abstract description 17
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- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 4
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- 239000003795 chemical substances by application Substances 0.000 description 1
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- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- BLEOOKKKXXCAMP-UHFFFAOYSA-N dimagnesium;dihydroxy(oxo)silane;hydrate Chemical compound O.[Mg+2].[Mg+2].O[Si](O)=O.O[Si](O)=O.O[Si](O)=O BLEOOKKKXXCAMP-UHFFFAOYSA-N 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- QFTYSVGGYOXFRQ-UHFFFAOYSA-N dodecane-1,12-diamine Chemical compound NCCCCCCCCCCCCN QFTYSVGGYOXFRQ-UHFFFAOYSA-N 0.000 description 1
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- RNYJXPUAFDFIQJ-UHFFFAOYSA-N hydron;octadecan-1-amine;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[NH3+] RNYJXPUAFDFIQJ-UHFFFAOYSA-N 0.000 description 1
- 239000010423 industrial mineral Substances 0.000 description 1
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- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
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- 229910001437 manganese ion Inorganic materials 0.000 description 1
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- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- OFVXDJYBTSEQDW-UHFFFAOYSA-N nonane-1,8-diamine Chemical compound CC(N)CCCCCCCN OFVXDJYBTSEQDW-UHFFFAOYSA-N 0.000 description 1
- SXJVFQLYZSNZBT-UHFFFAOYSA-N nonane-1,9-diamine Chemical compound NCCCCCCCCCN SXJVFQLYZSNZBT-UHFFFAOYSA-N 0.000 description 1
- FJXWKBZRTWEWBJ-UHFFFAOYSA-N nonanediamide Chemical compound NC(=O)CCCCCCCC(N)=O FJXWKBZRTWEWBJ-UHFFFAOYSA-N 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
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- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
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- 238000013374 right angle light scattering Methods 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000001542 size-exclusion chromatography Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- UYCAUPASBSROMS-AWQJXPNKSA-M sodium;2,2,2-trifluoroacetate Chemical compound [Na+].[O-][13C](=O)[13C](F)(F)F UYCAUPASBSROMS-AWQJXPNKSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
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- 238000010998 test method Methods 0.000 description 1
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- 238000004627 transmission electron microscopy Methods 0.000 description 1
- NSBGJRFJIJFMGW-UHFFFAOYSA-N trisodium;stiborate Chemical compound [Na+].[Na+].[Na+].[O-][Sb]([O-])([O-])=O NSBGJRFJIJFMGW-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Medicinal Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Composite Materials (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US81394306P | 2006-06-15 | 2006-06-15 | |
| US60/813,943 | 2006-06-15 | ||
| PCT/US2007/013975 WO2007146390A2 (en) | 2006-06-15 | 2007-06-12 | Nanocomposite compositions of polyamides and sepiolite-type clays |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010512422A JP2010512422A (ja) | 2010-04-22 |
| JP2010512422A5 JP2010512422A5 (enExample) | 2010-07-01 |
| JP5337692B2 true JP5337692B2 (ja) | 2013-11-06 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009515498A Expired - Fee Related JP5337692B2 (ja) | 2006-06-15 | 2007-06-12 | ポリアミドおよびセピオライト型粘土のナノ複合材料組成物 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US8198355B2 (enExample) |
| EP (1) | EP2027200B1 (enExample) |
| JP (1) | JP5337692B2 (enExample) |
| WO (1) | WO2007146390A2 (enExample) |
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| US8398306B2 (en) | 2005-11-07 | 2013-03-19 | Kraft Foods Global Brands Llc | Flexible package with internal, resealable closure feature |
| US8313246B2 (en) * | 2006-10-26 | 2012-11-20 | Ntn Corporation | Rocker bearing with outer ring and air disk brake system |
| US7871697B2 (en) | 2006-11-21 | 2011-01-18 | Kraft Foods Global Brands Llc | Peelable composite thermoplastic sealants in packaging films |
| US7871696B2 (en) | 2006-11-21 | 2011-01-18 | Kraft Foods Global Brands Llc | Peelable composite thermoplastic sealants in packaging films |
| US9232808B2 (en) | 2007-06-29 | 2016-01-12 | Kraft Foods Group Brands Llc | Processed cheese without emulsifying salts |
| DE102008021006A1 (de) * | 2008-04-25 | 2009-11-05 | Byk-Chemie Gmbh | Partikuläre Wachskomposite und Verfahren zu deren Herstellung sowie deren Verwendung |
| DE102008021007A1 (de) * | 2008-04-25 | 2009-11-12 | Byk-Chemie Gmbh | Dispersionen von Wachsen und anorganischen Nanopartikeln sowie deren Verwendung |
| JP5348692B2 (ja) * | 2009-08-25 | 2013-11-20 | 旭化成ケミカルズ株式会社 | ポリアミド樹脂組成物及びポリアミド樹脂組成物からなる成形品 |
| NZ591354A (en) | 2010-02-26 | 2012-09-28 | Kraft Foods Global Brands Llc | A low-tack, UV-cured pressure sensitive acrylic ester based adhesive for reclosable packaging |
| MX2012009795A (es) | 2010-02-26 | 2012-09-12 | Kraft Foods Global Brands Llc | Envase susceptible de volver a cerrarse usando adhesivo de baja pegajosidad. |
| EA023633B1 (ru) | 2010-07-26 | 2016-06-30 | ДСМ АйПи АССЕТС Б.В. | Деталь топливной системы и способ изготовления детали топливной системы |
| US9512292B2 (en) | 2010-07-26 | 2016-12-06 | Dsm Ip Assets B.V. | Fuel part and process for preparation of a fuel part |
| JP5911426B2 (ja) * | 2010-09-30 | 2016-04-27 | ユニチカ株式会社 | ポリアミド樹脂組成物、およびそれから得られる成形体 |
| KR101333587B1 (ko) | 2010-12-21 | 2013-11-28 | 제일모직주식회사 | 낮은 열팽창계수를 갖는 폴리아미드계 수지 조성물 |
| EP2468809A1 (de) * | 2010-12-23 | 2012-06-27 | LANXESS Deutschland GmbH | Zusammensetzungen |
| US9355765B2 (en) * | 2010-12-28 | 2016-05-31 | Shanghai Genius Advanced Material (Group) Co., Ltd. | Nano particle/polyamide composite material, preparation method therefor, and use thereof |
| US9533472B2 (en) | 2011-01-03 | 2017-01-03 | Intercontinental Great Brands Llc | Peelable sealant containing thermoplastic composite blends for packaging applications |
| ES2386711B1 (es) * | 2011-02-01 | 2013-07-09 | Tolsa, S.A. | Método de obtención de un compuesto basado en silicatos pseudolaminares y su uso como carga para materiales poliméricos. |
| US9765208B2 (en) | 2011-08-29 | 2017-09-19 | E I Du Pont De Nemours And Company | Composite wheel for a vehicle |
| US20130289148A1 (en) * | 2012-04-27 | 2013-10-31 | E I Du Pont De Nemours And Company | Toughened polyamide compositions |
| FR2990323B1 (fr) * | 2012-05-02 | 2014-06-06 | Schneider Electric Ind Sas | Element de boitier d'appareillage electrique comprenant une composition ignifuge specifique |
| CN102675867A (zh) * | 2012-05-22 | 2012-09-19 | 苏州新区华士达工程塑胶有限公司 | 一种增韧高光尼龙6的配方 |
| ITGE20120112A1 (it) | 2012-11-21 | 2014-05-22 | Dott Ing Mario Cozzani Srl | "materiale per la fabbricazione di otturatori di valvole per i cilindri dei compressori alternativi, e valvole così ottenute" |
| WO2014098772A1 (en) * | 2012-12-18 | 2014-06-26 | Agency For Science, Technology And Research | Method of preparing fiber-reinforced polymer composites and fiber-reinforced polymer composites prepared thereof |
| CN103122142A (zh) * | 2013-01-25 | 2013-05-29 | 上海瑞尔实业有限公司 | 一种纳米增强增韧pa6改性合金的制备方法 |
| CN103411806B (zh) * | 2013-07-31 | 2016-02-03 | 南京大学 | 一种粘性土单向直接拉伸试验的操作方法及其专用设备 |
| CN103834165B (zh) * | 2013-11-21 | 2016-04-27 | 安徽师范大学 | 一种汽车塑料件用陶瓷粉改性尼龙66材料 |
| CN103804896A (zh) * | 2013-12-20 | 2014-05-21 | 铜陵市金利电子有限公司 | 一种垫圈用高耐热易加工尼龙pa12材料组合物料 |
| CN103865254A (zh) * | 2014-04-08 | 2014-06-18 | 南京聚隆科技股份有限公司 | 一种电力金具用尼龙复合材料及制备方法 |
| CN104046008A (zh) * | 2014-06-05 | 2014-09-17 | 锐展(铜陵)科技有限公司 | 一种防眩光尼龙垫圈材料组合物料 |
| KR101823204B1 (ko) | 2015-08-24 | 2018-03-09 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
| JP2019529608A (ja) * | 2016-09-28 | 2019-10-17 | ディーエスエム アイピー アセッツ ビー.ブイ.Dsm Ip Assets B.V. | ポリマー組成物、成形部品およびそれを製造するための方法 |
| US20190225803A1 (en) * | 2016-09-28 | 2019-07-25 | Dsm Ip Assets B.V. | Polymer composition, molded part and processes for production thereof |
| KR101940418B1 (ko) | 2017-10-30 | 2019-01-18 | 롯데첨단소재(주) | 폴리아미드 수지 조성물 및 이를 포함하는 성형품 |
| CN111433026B (zh) * | 2017-12-05 | 2021-09-17 | 利安德巴塞尔先进聚合物公司 | 高性能聚酰胺化合物及其用途 |
| KR102171421B1 (ko) | 2017-12-31 | 2020-10-29 | 롯데첨단소재(주) | 폴리아미드 수지 조성물 및 이를 포함하는 성형품 |
| US11577496B2 (en) | 2017-12-31 | 2023-02-14 | Lotte Chemical Corporation | Polyamide resin composition and molded article comprising the same |
| KR102198388B1 (ko) | 2018-05-31 | 2021-01-05 | 롯데첨단소재(주) | 폴리아미드 수지 조성물 및 이를 포함하는 성형품 |
| CN109321218B (zh) * | 2018-11-15 | 2021-04-06 | 中国石油集团渤海钻探工程有限公司 | 低压漏失层封堵剂及其制备方法 |
| CN113896948B (zh) * | 2020-07-06 | 2023-12-12 | 合肥杰事杰新材料股份有限公司 | 一种活化海泡石纤维及其制备方法、以及包含该活化海泡石纤维的尼龙材料及其制备方法 |
| CN113956653A (zh) * | 2021-12-13 | 2022-01-21 | 广东捷辉科技有限公司 | 芳纶纤维增强聚酰胺复合材料及其制备方法 |
| CN120615111A (zh) * | 2023-01-30 | 2025-09-09 | 旭化成株式会社 | 聚酰胺树脂组合物 |
| CN121293742A (zh) * | 2024-10-28 | 2026-01-09 | 金发科技股份有限公司 | 一种耐烧蚀聚酰胺复合材料及其制备方法和应用 |
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| GB1114174A (en) | 1964-12-18 | 1968-05-15 | Berk Ltd | Synthetic thermoplastic polymer composition |
| JPS6057464B2 (ja) * | 1977-03-30 | 1985-12-14 | 三菱瓦斯化学株式会社 | ポリアミド樹脂組成物 |
| JPS58201845A (ja) * | 1982-04-12 | 1983-11-24 | Mitsubishi Gas Chem Co Inc | ポリアミド系樹脂組成物 |
| JPS62250053A (ja) * | 1986-04-22 | 1987-10-30 | Mitsubishi Petrochem Co Ltd | ポリアミド樹脂組成物 |
| DK35388A (da) | 1987-01-27 | 1988-07-28 | Du Pont | Termoplastisk formgiveligt materiale samt anvendelse heraf |
| JPS63251461A (ja) * | 1987-04-08 | 1988-10-18 | Toyota Central Res & Dev Lab Inc | ナイロン複合材料およびその製造方法 |
| US5164440A (en) * | 1988-07-20 | 1992-11-17 | Ube Industries, Ltd. | High rigidity and impact resistance resin composition |
| JPH02182758A (ja) * | 1989-01-10 | 1990-07-17 | Kanebo Ltd | ポリアミド樹脂組成物 |
| EP0789049A1 (de) * | 1996-02-09 | 1997-08-13 | Ciba SC Holding AG | Antistatisch ausgerüstete Polymere |
| US5866658A (en) | 1996-08-26 | 1999-02-02 | E. I. Du Pont De Nemours And Company | High performance ionomer blends |
| US7514490B2 (en) | 1997-08-08 | 2009-04-07 | Nederlandse Oganisatie Voor Toegepastnatuurwetenschappelijk Onderzoek Tno | Nanocomposite material |
| CA2320988A1 (en) * | 1998-02-13 | 1999-08-19 | Solutia Inc. | Polymer nanocomposite composition |
| JP4245716B2 (ja) * | 1999-01-28 | 2009-04-02 | 株式会社クラレ | ポリアミド組成物 |
| DE19905503A1 (de) * | 1999-02-10 | 2000-08-17 | Basf Ag | Thermoplastische Nanocomposites |
| BR9917441A (pt) * | 1999-08-13 | 2002-05-14 | Solutia Inc | Métodos para a preparação de composições de nanocompósito de poliamida por polimerização in situ |
| JP4562980B2 (ja) * | 2001-11-16 | 2010-10-13 | 三菱エンジニアリングプラスチックス株式会社 | ポリアミド樹脂厚肉成形品 |
| US7138454B2 (en) * | 2002-09-06 | 2006-11-21 | E. I. Du Pont De Nemours And Company | Toughened, glass filled polyamide compositions and blends having improved stiffness, and articles made therefrom |
| WO2007140469A2 (en) | 2006-05-31 | 2007-12-06 | The Dow Chemical Company | Additives for the use of microwave energy to selectively heat thermoplastic polymer systems |
| US20090142585A1 (en) * | 2007-11-08 | 2009-06-04 | Toshikazu Kobayashi | Nanocomposite compositions of polyamides, sepiolite-type clays and copper species and articles thereof |
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2007
- 2007-06-08 US US11/811,034 patent/US8198355B2/en not_active Expired - Fee Related
- 2007-06-12 WO PCT/US2007/013975 patent/WO2007146390A2/en not_active Ceased
- 2007-06-12 JP JP2009515498A patent/JP5337692B2/ja not_active Expired - Fee Related
- 2007-06-12 EP EP07809553A patent/EP2027200B1/en not_active Not-in-force
Also Published As
| Publication number | Publication date |
|---|---|
| US20100324195A1 (en) | 2010-12-23 |
| EP2027200A2 (en) | 2009-02-25 |
| WO2007146390A3 (en) | 2008-03-27 |
| EP2027200B1 (en) | 2011-07-27 |
| JP2010512422A (ja) | 2010-04-22 |
| WO2007146390A2 (en) | 2007-12-21 |
| US8198355B2 (en) | 2012-06-12 |
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