JP5156167B2 - プロピレン−エチレンポリマー及び製造法 - Google Patents
プロピレン−エチレンポリマー及び製造法 Download PDFInfo
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- JP5156167B2 JP5156167B2 JP2002582103A JP2002582103A JP5156167B2 JP 5156167 B2 JP5156167 B2 JP 5156167B2 JP 2002582103 A JP2002582103 A JP 2002582103A JP 2002582103 A JP2002582103 A JP 2002582103A JP 5156167 B2 JP5156167 B2 JP 5156167B2
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- Prior art keywords
- propylene
- copolymer
- polymerization
- ethylene
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- -1 Propylene-ethylene Chemical group 0.000 title claims description 73
- 238000004519 manufacturing process Methods 0.000 title description 8
- 229920000573 polyethylene Polymers 0.000 title description 3
- 229920001577 copolymer Polymers 0.000 claims abstract description 119
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 98
- 238000006116 polymerization reaction Methods 0.000 claims description 86
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 68
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 65
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 59
- 239000005977 Ethylene Substances 0.000 claims description 59
- 238000000034 method Methods 0.000 claims description 38
- 150000001450 anions Chemical class 0.000 claims description 35
- 239000003054 catalyst Substances 0.000 claims description 33
- 238000002844 melting Methods 0.000 claims description 20
- 230000008018 melting Effects 0.000 claims description 20
- 229920001155 polypropylene Polymers 0.000 claims description 17
- 239000004743 Polypropylene Substances 0.000 claims description 15
- 125000003118 aryl group Chemical group 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 13
- 230000004927 fusion Effects 0.000 claims description 11
- 229910052757 nitrogen Inorganic materials 0.000 claims description 11
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims description 10
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 230000004913 activation Effects 0.000 claims description 5
- 150000003623 transition metal compounds Chemical class 0.000 claims description 5
- NMLGKEDSNASIHM-UHFFFAOYSA-N (2,3,4,5,6,7,8-heptafluoronaphthalen-1-yl)oxyboronic acid Chemical compound FC1=C(F)C(F)=C2C(OB(O)O)=C(F)C(F)=C(F)C2=C1F NMLGKEDSNASIHM-UHFFFAOYSA-N 0.000 claims description 4
- 239000002685 polymerization catalyst Substances 0.000 claims description 4
- 125000004122 cyclic group Chemical group 0.000 claims description 3
- 125000002524 organometallic group Chemical group 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 238000001994 activation Methods 0.000 claims 2
- 238000010924 continuous production Methods 0.000 claims 1
- 230000000707 stereoselective effect Effects 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 abstract description 20
- 239000012968 metallocene catalyst Substances 0.000 abstract description 13
- 238000009827 uniform distribution Methods 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 description 88
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 63
- 239000000203 mixture Substances 0.000 description 51
- 239000000523 sample Substances 0.000 description 35
- 239000003446 ligand Substances 0.000 description 33
- 239000000178 monomer Substances 0.000 description 33
- 238000003780 insertion Methods 0.000 description 32
- 238000009826 distribution Methods 0.000 description 26
- 238000005481 NMR spectroscopy Methods 0.000 description 22
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 21
- 230000037431 insertion Effects 0.000 description 21
- 229910052799 carbon Inorganic materials 0.000 description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 19
- 239000012190 activator Substances 0.000 description 18
- 150000001768 cations Chemical class 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 16
- 229910052796 boron Inorganic materials 0.000 description 15
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 14
- 239000002904 solvent Substances 0.000 description 14
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 12
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 11
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 11
- 238000005194 fractionation Methods 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 238000004458 analytical method Methods 0.000 description 10
- 238000005259 measurement Methods 0.000 description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 239000012954 diazonium Substances 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-O diazynium Chemical compound [NH+]#N IJGRMHOSHXDMSA-UHFFFAOYSA-O 0.000 description 8
- 238000000113 differential scanning calorimetry Methods 0.000 description 8
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002243 precursor Substances 0.000 description 8
- 230000009257 reactivity Effects 0.000 description 8
- 239000004711 α-olefin Substances 0.000 description 8
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- OJOSABWCUVCSTQ-UHFFFAOYSA-N cyclohepta-2,4,6-trienylium Chemical compound C1=CC=C[CH+]=C[CH]1 OJOSABWCUVCSTQ-UHFFFAOYSA-N 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 229920002521 macromolecule Polymers 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 229910052752 metalloid Inorganic materials 0.000 description 7
- 150000002738 metalloids Chemical class 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 6
- 125000004429 atom Chemical group 0.000 description 6
- JLTDJTHDQAWBAV-UHFFFAOYSA-O dimethyl(phenyl)azanium Chemical compound C[NH+](C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-O 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 239000002516 radical scavenger Substances 0.000 description 6
- 230000002441 reversible effect Effects 0.000 description 6
- OLFPYUPGPBITMH-UHFFFAOYSA-N tritylium Chemical compound C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1 OLFPYUPGPBITMH-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
- 239000012683 anionic precursor Substances 0.000 description 5
- 238000009835 boiling Methods 0.000 description 5
- 229920001971 elastomer Polymers 0.000 description 5
- 239000000806 elastomer Substances 0.000 description 5
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 5
- 150000004678 hydrides Chemical group 0.000 description 5
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 5
- 229920005629 polypropylene homopolymer Polymers 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- 229910052723 transition metal Inorganic materials 0.000 description 5
- IMFACGCPASFAPR-UHFFFAOYSA-O tributylazanium Chemical compound CCCC[NH+](CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-O 0.000 description 5
- 229910052795 boron group element Inorganic materials 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005227 gel permeation chromatography Methods 0.000 description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- OJJVPGJEBAZOIF-UHFFFAOYSA-N (2,3,4,5-tetrafluorophenoxy)boronic acid Chemical compound OB(O)OC1=CC(F)=C(F)C(F)=C1F OJJVPGJEBAZOIF-UHFFFAOYSA-N 0.000 description 3
- FWUHUNUOUDQTFG-UHFFFAOYSA-N (3,4,5-trifluorophenoxy)boronic acid Chemical compound OB(O)OC1=CC(F)=C(F)C(F)=C1 FWUHUNUOUDQTFG-UHFFFAOYSA-N 0.000 description 3
- BNUHTPCULLFDEA-UHFFFAOYSA-N 1,2,2-trifluoroethenoxyboronic acid Chemical compound OB(O)OC(F)=C(F)F BNUHTPCULLFDEA-UHFFFAOYSA-N 0.000 description 3
- 125000004361 3,4,5-trifluorophenyl group Chemical group [H]C1=C(F)C(F)=C(F)C([H])=C1* 0.000 description 3
- 0 CC(C)(C1(C)NC1)N* Chemical compound CC(C)(C1(C)NC1)N* 0.000 description 3
- 150000004645 aluminates Chemical class 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 150000001491 aromatic compounds Chemical class 0.000 description 3
- 238000000429 assembly Methods 0.000 description 3
- 230000000712 assembly Effects 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229910052735 hafnium Inorganic materials 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 150000008040 ionic compounds Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 3
- OUHOZBRDLAZZLQ-UHFFFAOYSA-N (2,3,5,6-tetrafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=CC(F)=C1F OUHOZBRDLAZZLQ-UHFFFAOYSA-N 0.000 description 2
- HTGQCLJTWPSFNL-UHFFFAOYSA-N (2-methylphenoxy)boronic acid Chemical compound CC1=CC=CC=C1OB(O)O HTGQCLJTWPSFNL-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- 239000007848 Bronsted acid Substances 0.000 description 2
- OKTJSMMVPCPJKN-OUBTZVSYSA-N Carbon-13 Chemical compound [13C] OKTJSMMVPCPJKN-OUBTZVSYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- 239000002841 Lewis acid Substances 0.000 description 2
- 239000002879 Lewis base Substances 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 description 2
- 239000013256 coordination polymer Substances 0.000 description 2
- 125000005131 dialkylammonium group Chemical group 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
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- 229960004132 diethyl ether Drugs 0.000 description 2
- GGSUCNLOZRCGPQ-UHFFFAOYSA-O diethyl(phenyl)azanium Chemical compound CC[NH+](CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-O 0.000 description 2
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
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- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 2
- 238000012685 gas phase polymerization Methods 0.000 description 2
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- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 2
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- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 2
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 2
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- ILFOXVJEPKJXFI-UHFFFAOYSA-N (2,3,4,5,6,7,8,9,10-nonafluoroanthracen-1-yl)oxy-(2,3,4,5,6-pentafluorophenoxy)borinic acid Chemical compound B(O)(OC1=C(C(=C(C2=C1C(=C3C(=C2F)C(=C(C(=C3F)F)F)F)F)F)F)F)OC4=C(C(=C(C(=C4F)F)F)F)F ILFOXVJEPKJXFI-UHFFFAOYSA-N 0.000 description 1
- DQVXWCCLFKMJTQ-UHFFFAOYSA-N (4-methylphenoxy)boronic acid Chemical compound CC1=CC=C(OB(O)O)C=C1 DQVXWCCLFKMJTQ-UHFFFAOYSA-N 0.000 description 1
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- YQNVPNRHJFZONU-UHFFFAOYSA-N CC(C)C(C)(C)N Chemical compound CC(C)C(C)(C)N YQNVPNRHJFZONU-UHFFFAOYSA-N 0.000 description 1
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- 241001441571 Hiodontidae Species 0.000 description 1
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- HCIMXTXCDVBLOA-UHFFFAOYSA-N [4-(trifluoromethyl)phenoxy]boronic acid Chemical compound OB(O)OC1=CC=C(C(F)(F)F)C=C1 HCIMXTXCDVBLOA-UHFFFAOYSA-N 0.000 description 1
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- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
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- BOXSCYUXSBYGRD-UHFFFAOYSA-N cyclopenta-1,3-diene;iron(3+) Chemical compound [Fe+3].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 BOXSCYUXSBYGRD-UHFFFAOYSA-N 0.000 description 1
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- XBPCUCUWBYBCDP-UHFFFAOYSA-O dicyclohexylazanium Chemical compound C1CCCCC1[NH2+]C1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-O 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- IDAPTOGYAAQMGT-UHFFFAOYSA-N diphenylmethylbenzene borate Chemical compound [O-]B([O-])[O-].C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1 IDAPTOGYAAQMGT-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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| US09/834,256 US6525157B2 (en) | 1997-08-12 | 2001-04-12 | Propylene ethylene polymers |
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| US33665501P | 2001-12-05 | 2001-12-05 | |
| US60/336,655 | 2001-12-05 | ||
| US34218601P | 2001-12-19 | 2001-12-19 | |
| US60/342,186 | 2001-12-19 | ||
| PCT/US2002/010515 WO2002083754A1 (en) | 2001-04-12 | 2002-04-02 | Propylene ethylene polymers and production process |
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| CA2506650A1 (en) * | 2002-11-28 | 2004-06-10 | Basell Poliolefine Italia S.P.A. | Butene-1 copolymers and process for their preparation |
| US7928165B2 (en) | 2003-11-14 | 2011-04-19 | Exxonmobil Chemical Patents Inc. | Transparent and translucent crosslinked propylene-based elastomers, and their production and use |
| EP1778781A1 (en) | 2004-08-13 | 2007-05-02 | ExxonMobil Chemical Patents, Inc., A Corporation of the State of Delaware | Polymeric compositions including their uses and methods of production |
| ATE404628T1 (de) | 2004-12-16 | 2008-08-15 | Exxonmobil Chem Patents Inc | Polymerzusammensetzungen einschliesslich ihrer verwendungen und herstellungsverfahren |
| ATE467658T1 (de) | 2004-12-17 | 2010-05-15 | Exxonmobil Chem Patents Inc | Homogenes polymerblend und artikel daraus |
| US8013069B2 (en) | 2005-01-31 | 2011-09-06 | Exxonmobil Chemical Patents Inc. | Polymer blends and pellets and methods of producing same |
| WO2006083505A1 (en) | 2005-01-31 | 2006-08-10 | Exxonmobil Chemical Patents Inc. | Polymeric compositions including their uses and methods of production |
| US8927108B2 (en) | 2006-01-10 | 2015-01-06 | Exxonmobil Chemical Patents Inc. | Films incorporating polymeric material combinations, articles made therefrom, and methods of making such films and articles |
| US8476326B2 (en) * | 2006-09-22 | 2013-07-02 | Dow Global Technologies Llc | Fibrillated polyolefin foam |
| KR101406772B1 (ko) * | 2007-10-22 | 2014-06-19 | 다우 글로벌 테크놀로지스 엘엘씨 | 중합체 조성물 및 제품의 성형방법 |
| WO2009073685A1 (en) * | 2007-12-05 | 2009-06-11 | Dow Global Technologies Inc. | Polypropylene melt-blown sealant films for retort packaging |
| US9938400B2 (en) | 2008-04-23 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Propylene copolymers in soft thermoplastic blends |
| JP5722456B2 (ja) * | 2010-11-09 | 2015-05-20 | エクソンモービル ケミカル パテンツ インコーポレイテッド | ２成分繊維およびそれらを作製する方法 |
| US11492477B2 (en) | 2013-06-04 | 2022-11-08 | Exxonmobil Chemicals Patent Inc. | Polymer compositions and nonwoven compositions prepared therefrom |
| EP3011088B1 (en) | 2013-06-18 | 2020-12-02 | ExxonMobil Chemical Patents Inc. | Fibers and nonwoven materials prepared therefrom |
| CN105308225B (zh) | 2013-06-18 | 2019-01-01 | 埃克森美孚化学专利公司 | 纤维及由其制备的无纺材料 |
| US9469753B2 (en) | 2013-07-22 | 2016-10-18 | Exxonmobil Chemical Patents Inc. | Propylene copolymers in elastomeric compositions |
| CN105492206B (zh) | 2013-09-30 | 2017-10-17 | 埃克森美孚化学专利公司 | 聚合物组合物和由其制得的制品 |
| KR101580591B1 (ko) * | 2014-06-10 | 2015-12-28 | 주식회사 엘지화학 | 프로필렌계 엘라스토머 |
| WO2015190831A1 (ko) * | 2014-06-10 | 2015-12-17 | 주식회사 엘지화학 | 프로필렌계 엘라스토머 |
| WO2015191195A1 (en) | 2014-06-10 | 2015-12-17 | Exxonmobil Chemical Patents Inc. | Propylene-based polymers having improved stability and methods for producing the same |
| KR101579616B1 (ko) * | 2014-06-10 | 2015-12-22 | 주식회사 엘지화학 | 프로필렌계 엘라스토머 |
| US20170181498A1 (en) | 2014-07-25 | 2017-06-29 | Exxonmobil Chemical Patents Inc. | Footwear Compositions Comprising Propylene-Based Elastomers |
| SG11201701351TA (en) * | 2014-08-21 | 2017-03-30 | Dow Global Technologies Llc | Hot melt adhesive composition including a crystalline block composite |
| EP3296355B1 (en) | 2014-09-05 | 2019-06-19 | ExxonMobil Chemical Patents Inc. | Fibers comprising polymer compositions and nonwoven materials prepared therefrom |
| US10011709B2 (en) | 2015-02-26 | 2018-07-03 | Exxonmobil Chemical Patents Inc. | Compositions comprising propylene-based elastomers and polyalphaolefins |
| WO2016137556A1 (en) | 2015-02-26 | 2016-09-01 | Exxonmobil Chemical Patents Inc. | Process for forming thermoplastic vulcanizates and thermoplastic vulcanizates made therefrom |
| EP3277752B1 (en) | 2015-03-27 | 2024-09-18 | ExxonMobil Chemical Patents Inc. | Propylene-based polymer compositions for grip applications |
| WO2016190981A1 (en) | 2015-05-22 | 2016-12-01 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates comprising propylene-based elastomers and methods for making the same |
| JP6700313B2 (ja) | 2015-05-29 | 2020-05-27 | エクソンモービル・ケミカル・パテンツ・インク | 広い分子量分布のポリプロピレンを含んでいる熱可塑性加硫物 |
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| WO2018034759A1 (en) | 2016-08-15 | 2018-02-22 | Exxonmobil Chemical Patents Inc. | Propylene-olefin copolymers and methods for making the same |
| US11186753B2 (en) | 2016-09-23 | 2021-11-30 | Exxonmobil Chemical Patents Inc. | Shrinkable thermoplastic vulcanizate and method and article |
| US11370850B2 (en) * | 2018-05-12 | 2022-06-28 | Pretium Innovation, Llc | Polymerization compositions and methods for making and using same |
| CN113039312B (zh) | 2018-11-16 | 2023-10-10 | 埃克森美孚化学专利公司 | 用于纤维和非织造材料的聚α-烯烃改性的聚合物共混物 |
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| CN116529431A (zh) | 2020-11-19 | 2023-08-01 | 埃克森美孚化学专利公司 | 具有改进的触感和机械性能的无纺布 |
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| CN120813639A (zh) | 2023-03-03 | 2025-10-17 | 埃克森美孚技术与工程公司 | 发泡的基于丙烯的弹性体组合物，其制备方法和由其制成的产品 |
| CN120813645A (zh) | 2023-03-06 | 2025-10-17 | 埃克森美孚技术与工程公司 | 用于地下防水应用的基于丙烯的弹性体组合物 |
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- 2002-04-02 JP JP2002582103A patent/JP5156167B2/ja not_active Expired - Lifetime
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- 2002-04-02 WO PCT/US2002/010515 patent/WO2002083754A1/en not_active Ceased
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Also Published As
| Publication number | Publication date |
|---|---|
| US20110313117A1 (en) | 2011-12-22 |
| EP1390417B1 (en) | 2010-10-20 |
| EP1390417A1 (en) | 2004-02-25 |
| JP2004528447A (ja) | 2004-09-16 |
| US20070244276A1 (en) | 2007-10-18 |
| DE60238049D1 (de) | 2010-12-02 |
| WO2002083754A1 (en) | 2002-10-24 |
| US8026323B2 (en) | 2011-09-27 |
| US8501892B2 (en) | 2013-08-06 |
| ATE485319T1 (de) | 2010-11-15 |
| JP2013049863A (ja) | 2013-03-14 |
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