JP6643475B2 - ルーフィング組成物用のプロピレンに基いたエラストマーおよび同を調製する方法 - Google Patents
ルーフィング組成物用のプロピレンに基いたエラストマーおよび同を調製する方法 Download PDFInfo
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- JP6643475B2 JP6643475B2 JP2018523459A JP2018523459A JP6643475B2 JP 6643475 B2 JP6643475 B2 JP 6643475B2 JP 2018523459 A JP2018523459 A JP 2018523459A JP 2018523459 A JP2018523459 A JP 2018523459A JP 6643475 B2 JP6643475 B2 JP 6643475B2
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
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Description
リ、リアン;ザカリアス、フェリックス・エム;ダーマラジャン、ナラヤナスワミ;カルファス、ジャン;ブラント、パトリック
関連出願の相互参照
本出願は、2015年11月9日に出願された米国特許仮出願第62/252,864号および2015年12月28日に出願された欧州特許出願第15202779.3号の優先権を主張し、これらの内容は参照によって本明細書に組み込まれる。
技術分野
ポリマーブレンド
多段重合
プロピレンに基いたエラストマー
(i)PBEの重量に基いて約10〜約25重量%、または約12〜約20重量%、または約16重量%〜約17重量%のエチレン由来単位;
(ii)80〜約110℃、または約85〜約110℃、または約90〜約105℃のTm;
(iii)約75J/g未満、または50J/g未満、または30J/g未満、または約1.0〜約15J/g、または約3.0〜約10J/gのHf;
(iv)約0.5〜約3.0g/10分、または約0.75〜約2.0g/10分のMI;
(v)約0.5〜約10g/10分、または0.75〜約8g/10分、または約0.75〜約5g/10分のMFR;
(vi)約175,000〜約260,000g/モル、または約190,000〜約250,000g/モル、または約200,000〜約250,000g/モル、または約210,000〜約240,000g/モルのMw;
(vii)約90,000〜約130,000g/モル、または約95,000〜約125,000g/モル、または約100,000〜約120,000g/モルのMn;
(viii)約1.0〜約5、または約1.5〜約4、または約1.8〜約3のMWD;および/または
(ix)30未満、または25未満、または20未満のショアD硬度。
いくつかの実施形態では、このようなPBEは本明細書に記載されたリアクターブレンドされたPBEである。
エチレンコポリマー
1)0.85g/cm3、0.86g/cm3、0.87g/cm3、0.88g/cm3または0.885g/cm3の最低値から0.91g/cm3、0.905g/cm3または0.902g/cm3の最高値までの密度。いくつかの実施形態では、エチレンに基いたプラストマーは、0.85〜0.91g/cm3、または0.86〜0.91g/cm3、または0.87〜0.91g/cm3、または0.88〜0.905g/cm3、または0.88〜0.902g/cm3、または0.885〜0.902g/cm3の範囲の密度を有してもよく、望ましい範囲が任意の下限から任意の上限までの範囲を含んでもよいもの;
2)90J/g以下、70J/g以下、50J/g以下または30J/g以下の融解熱(Hf)。いくつかの実施形態では、エチレンに基いたプラストマーは10〜70J/g、または10〜50J/g、または10〜30J/gのHfを有してもよく、望ましい範囲が任意の下限から任意の上限までの範囲を含んでもよいもの;
3)5重量%の最低値から40%、30%または20%の最高値までの結晶化度であって、望ましい範囲が任意の下限から任意の上限までの範囲を含んでもよいもの;
4)100℃以下、95℃以下、90℃以下、80℃以下、70℃以下、60℃以下または50℃以下の融点(Tm、最初の融解時のピーク);
5)90℃以下、80℃以下、70℃以下、60℃以下、50℃以下または40℃以下の結晶化温度(Tc、ピーク);
6)−20℃以下、−30℃以下または−40℃以下のガラス転移温度(Tg);
7)30〜2,000kg/モル、50〜1,000kg/モルまたは90〜500kg/モルのMwであって、望ましい範囲が任意の下限から任意の上限までの範囲を含んでもよいもの;
8)1〜5、1.4〜4.5、1.6〜4、1.8〜3.5または1.8〜2.5のMw/Mnであって、望ましい範囲が任意の下限から任意の上限までの範囲を含んでもよいもの;
9)0.1〜100g/10分、0.3〜60g/10分、0.5〜40g/10分または0.7〜20g/10分のメルトインデックス(MI、2.16kg@190℃)であって、望ましい範囲が任意の下限から任意の上限までの範囲を含んでもよいもの;および/または
10)25〜40muまたは30〜35muのムーニー粘度(ML、(1+4)@125℃)であって、望ましい範囲が任意の下限から任意の上限までの範囲を含んでもよいもの。
ムーニー粘度は、米国特許第6,686,415号に記載された定義および測定手順によって定義され、測定されることになり、その内容はその全体が参照によって組み込まれる。
熱可塑性樹脂
フィラーおよび添加物
ルーフィング組成物
以下の特性のうちの少なくとも3種、または少なくとも4種、または少なくとも5種、または少なくとも6種、または少なくとも7種、または少なくとも8種、または9種の全てを有してもよい:
(i)2.5x1010未満、または2.4x1010未満、または2.3x1010未満、または2.2x1010未満、または2.1x1010ダイン/cm2未満の−40℃での貯蔵弾性率(E’);
(ii)1.5x1010未満、または1.4x1010未満、または1.3x1010ダイン/cm2未満の−30℃での貯蔵弾性率(E’);
(iii)5x109未満、または4.5x109未満、または4x109ダイン/cm2未満の−20℃での貯蔵弾性率(E’);
(iv)2x109ダイン/cm2未満の0℃での貯蔵弾性率(E’);
(v)1.5x109未満、または1.4x109未満、または1.3x109ダイン/cm2未満の20℃での貯蔵弾性率(E’);
(vi)6.5x108超、または7x108超、または7.5x108ダイン/cm2ダイン/cm2超の40℃での貯蔵弾性率(E’);
(vii)4x108超、または4.1x108超、または4.2x108超、または4.3x108超、または4.4x108ダイン/cm2超の60℃での貯蔵弾性率(E’);
(viii)2x108超、または2.2x108超、または2.3x108超、または2.5x108超、または2.6x108ダイン/cm2超の80℃での貯蔵弾性率(E’);または
(ix)1x108超、または1.2x108超、または1.3x108超、または1.4x108超、または1.5x108ダイン/cm2超の100℃での貯蔵弾性率(E’)。
[実施例]
Claims (9)
- ポリマーブレンドであって、
(a)70重量%〜95重量%のプロピレンに基いたエラストマーであって、前記プロピレンに基いたエラストマーが前記プロピレンに基いたエラストマーの重量に基いて15重量%〜30重量%のエチレン含有量を有する、プロピレンに基いたエラストマー、および
(b)エチレンおよびプロピレンから成る5重量%〜30重量%のエチレンコポリマーであって、前記エチレンコポリマーが前記エチレンコポリマーの重量に基いて70重量%以上のエチレン含有量を有する、エチレンコポリマー
を含んでいる、ポリマーブレンド。 - 前記プロピレンに基いたエラストマーが、16重量%〜18重量%のエチレン含有量、120℃未満の融解温度および75J/g未満の融解熱を有する、請求項1に記載のポリマーブレンド。
- 膜組成物であって、
(a)前記膜組成物の重量に基いて20重量%〜50重量%の請求項1に記載のポリマーブレンド;
(b)前記膜組成物の重量に基いて5重量%〜30重量%の熱可塑性樹脂;
(c)少なくとも1種の難燃剤;および
(d)少なくとも1種の紫外線安定剤
を含んでいる膜組成物。 - 前記熱可塑性樹脂がプロピレンホモポリマーおよびプロピレンインパクトコポリマーから成る群から選ばれる、請求項3に記載の膜。
- 前記熱可塑性樹脂が25g/10分超および5g/10分未満から成る群から選ばれるメルトフローレート(230℃、2.16kg)を有する、請求項4に記載の膜。
- 前記プロピレンに基いたエラストマーが、16〜18重量%のエチレン含有量、120℃未満の融解温度および75J/g未満の融解熱を有する、請求項3〜5のいずれか1項に記載の膜。
- 前記プロピレンに基いたエラストマーが第1のポリマー成分と第2のポリマー成分とのブレンドであり、前記第1のポリマー成分が前記第1のポリマー成分の全重量に基いて5超から30重量%未満のエチレン含有量R1を有し、かつ前記第2のポリマー成分が前記第2のポリマー成分の全重量に基いて1超から10重量%未満のエチレン含有量R2を有する、請求項3〜6のいずれか1項に記載の膜。
- 前記ポリマーブレンドが、以下の特性のうちの少なくとも3種を有する、請求項3〜7のいずれか1項に記載の膜:
(i)2.5x1010ダイン/cm2未満の−40℃での貯蔵弾性率(E’);
(ii)1.5x1010ダイン/cm2未満の−30℃での貯蔵弾性率(E’);
(iii)5x109ダイン/cm2未満の−20℃での貯蔵弾性率(E’);
(iv)2x109ダイン/cm2未満の0℃での貯蔵弾性率(E’);
(v)1.5x109ダイン/cm2未満の20℃での貯蔵弾性率(E’);
(vi)6.5x108ダイン/cm2超の40℃での貯蔵弾性率(E’);
(vii)4x108ダイン/cm2超の60℃での貯蔵弾性率(E’);
(viii)2x108ダイン/cm2超の80℃での貯蔵弾性率(E’);または
(ix)1x108ダイン/cm2超の100℃での貯蔵弾性率(E’)。 - 請求項3〜8のいずれか1項に記載の膜を含んでいるルーフィング組成物。
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EP15202779 | 2015-12-28 | ||
PCT/US2016/050725 WO2017082999A1 (en) | 2015-11-09 | 2016-09-08 | Propylene-based elastomers for roofing compositions and methods for preparing the same |
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