JP5105387B2 - イソシアネート基への付加及び活性化c−c二重結合への放射線付加により硬化可能な被覆組成物 - Google Patents
イソシアネート基への付加及び活性化c−c二重結合への放射線付加により硬化可能な被覆組成物 Download PDFInfo
- Publication number
- JP5105387B2 JP5105387B2 JP2000591094A JP2000591094A JP5105387B2 JP 5105387 B2 JP5105387 B2 JP 5105387B2 JP 2000591094 A JP2000591094 A JP 2000591094A JP 2000591094 A JP2000591094 A JP 2000591094A JP 5105387 B2 JP5105387 B2 JP 5105387B2
- Authority
- JP
- Japan
- Prior art keywords
- compound
- coating
- group
- film
- isocyanate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
- C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/891—Compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- A61K6/893—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C265/00—Derivatives of isocyanic acid
- C07C265/14—Derivatives of isocyanic acid containing at least two isocyanate groups bound to the same carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
- C07C275/46—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups containing any of the groups, X being a hetero atom, Y being any atom, e.g. acylureas
- C07C275/58—Y being a hetero atom
- C07C275/60—Y being an oxygen atom, e.g. allophanic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
- C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
- C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
- C08G18/673—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen containing two or more acrylate or alkylacrylate ester groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/7806—Nitrogen containing -N-C=0 groups
- C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
- C08G18/7837—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing allophanate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/81—Unsaturated isocyanates or isothiocyanates
- C08G18/8141—Unsaturated isocyanates or isothiocyanates masked
- C08G18/815—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen
- C08G18/8158—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen
- C08G18/8175—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen with esters of acrylic or alkylacrylic acid having only one group containing active hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Materials Engineering (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Engineering & Computer Science (AREA)
- Veterinary Medicine (AREA)
- Wood Science & Technology (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Dental Preparations (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19860041A DE19860041A1 (de) | 1998-12-23 | 1998-12-23 | Durch Addition an Isocyanatgruppen als auch durch strahlungsinduzierte Addition an aktivierte C-C-Doppelbindungen härtbare Beschichtungsmittel |
| DE19860041.0 | 1998-12-23 | ||
| PCT/EP1999/009905 WO2000039183A1 (de) | 1998-12-23 | 1999-12-14 | Durch addition an isocyanatgruppen als auch durch strahlungsinduzierte addition an aktivierte c-c-doppelbindungen härtbare beschichtungsmittel |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011034145A Division JP5466658B2 (ja) | 1998-12-23 | 2011-02-21 | ポリイソシアネートと活性化二重結合を含むアルコールaとから誘導される化合物 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2002533542A JP2002533542A (ja) | 2002-10-08 |
| JP2002533542A5 JP2002533542A5 (https=) | 2011-04-14 |
| JP5105387B2 true JP5105387B2 (ja) | 2012-12-26 |
Family
ID=7892663
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000591094A Expired - Fee Related JP5105387B2 (ja) | 1998-12-23 | 1999-12-14 | イソシアネート基への付加及び活性化c−c二重結合への放射線付加により硬化可能な被覆組成物 |
| JP2011034145A Expired - Fee Related JP5466658B2 (ja) | 1998-12-23 | 2011-02-21 | ポリイソシアネートと活性化二重結合を含むアルコールaとから誘導される化合物 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011034145A Expired - Fee Related JP5466658B2 (ja) | 1998-12-23 | 2011-02-21 | ポリイソシアネートと活性化二重結合を含むアルコールaとから誘導される化合物 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6617413B1 (https=) |
| EP (1) | EP1144476B1 (https=) |
| JP (2) | JP5105387B2 (https=) |
| KR (1) | KR100687109B1 (https=) |
| CN (1) | CN1230457C (https=) |
| AT (1) | ATE255609T1 (https=) |
| CA (1) | CA2356685C (https=) |
| DE (2) | DE19860041A1 (https=) |
| ES (1) | ES2212662T3 (https=) |
| WO (1) | WO2000039183A1 (https=) |
Families Citing this family (132)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PT1204709E (pt) | 1999-07-30 | 2007-05-31 | Ppg Ind Ohio Inc | Composições de revestimento que têm resistência ao arranhão melhorada, substratos revestidos e métodos relacionados com eles |
| US6610777B1 (en) | 1999-07-30 | 2003-08-26 | Ppg Industries Ohio, Inc. | Flexible coating compositions having improved scratch resistance, coated substrates and methods related thereto |
| WO2001009259A1 (en) | 1999-07-30 | 2001-02-08 | Ppg Industries Ohio, Inc. | Coating compositions having improved scratch resistance, coated substrates and methods related thereto |
| CN1238398C (zh) * | 1999-09-30 | 2006-01-25 | 巴斯福股份公司 | 能够用紫外线和热硬化的聚氨酯水分散体,以及它们的用途 |
| DE10031258A1 (de) | 2000-06-27 | 2002-01-10 | Basf Ag | Härtbare wässrige Polyurethandispersionen |
| JP4535574B2 (ja) * | 2000-07-27 | 2010-09-01 | 株式会社興人 | 新規なウレタンアクリルアミド類および該ウレタンアクリルアミド類を含有した紫外線及び電子線硬化性樹脂組成物 |
| US6635341B1 (en) | 2000-07-31 | 2003-10-21 | Ppg Industries Ohio, Inc. | Coating compositions comprising silyl blocked components, coating, coated substrates and methods related thereto |
| CN1454243A (zh) * | 2000-07-31 | 2003-11-05 | Ppg工业俄亥俄公司 | 具有改进的耐划伤性的双固化涂料组合物、经涂覆的底材及与之相关的方法 |
| DE10041635A1 (de) * | 2000-08-24 | 2002-03-28 | Basf Coatings Ag | Thermisch und mit aktinischer Strahlung härtbare Einkomponentensysteme und ihre Verwendung |
| DE10041634C2 (de) | 2000-08-24 | 2002-10-17 | Basf Coatings Ag | Wäßrige Dispersion und ihre Verwendung zur Herstellung von thermisch und mit aktinischer Strahlung härtbaren Beschichtungsstoffen, Klebstoffen und Dichtungsmassen |
| DE10048275C1 (de) | 2000-09-29 | 2002-05-29 | Basf Coatings Ag | Thermisch und mit aktinischer Strahlung härtbares Mehrkomponentensystem und seine Verwendung |
| DE10048670A1 (de) * | 2000-09-30 | 2002-04-25 | Basf Coatings Ag | Beschichtungsstoffsystem für die Herstellung farb- und/oder effektgebender Mehrschichtlackierungen auf der Basis von Mehrkomponentenbeschichtungsstoffen |
| DE10048849A1 (de) * | 2000-10-02 | 2002-04-18 | Basf Coatings Ag | Verfahren zur Herstellung eines thermisch und mit aktinischer Strahlung härtbaren Mehrkomponentensystems und seine Verwendung |
| DE10048847A1 (de) | 2000-10-02 | 2002-04-18 | Basf Coatings Ag | Lösemittelhaltiges, thermisch und mit aktinischer Strahlung härtbares Mehrkomponentensystem und seine Verwendung |
| WO2002040602A1 (en) * | 2000-11-20 | 2002-05-23 | Ciba Specialty Chemicals Holding Inc. | Fluorinated-photoinitiators in dual cure resins |
| US20030026908A1 (en) * | 2001-04-30 | 2003-02-06 | Matthew Lane | Sandable, self-healable coating compositions and a process of using the same |
| DE10129970A1 (de) * | 2001-06-21 | 2003-01-09 | Basf Coatings Ag | Thermisch und mit aktinischer Strahlung härtbare Beschichtungsstoffe, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE10140156A1 (de) * | 2001-08-16 | 2003-03-20 | Basf Coatings Ag | Thermisch und mit aktinischer Strahlung härtbare Beschichtungsstoffe und ihre Verwendung |
| DE10140155A1 (de) | 2001-08-16 | 2003-03-06 | Basf Coatings Ag | Thermisch sowie thermisch und mit aktinischer Strahlung härtbare Beschichtungsstoffe und ihre Verwendung |
| US6844029B2 (en) * | 2001-10-26 | 2005-01-18 | Kansai Paint Co., Ltd. | Photocurable primer composition and coating method by use of the same |
| KR100354193B1 (ko) * | 2001-12-21 | 2002-09-27 | (주) 베리콤 | 광중합형 치과용 조성물 |
| FR2837820B1 (fr) * | 2002-03-27 | 2005-03-11 | Rhodia Chimie Sa | Composition polyisocyanate de faible viscosite possedant une fonctionnalite elevee et procede de preparation |
| DE10241299A1 (de) | 2002-09-04 | 2004-03-25 | Basf Ag | Strahlungshärtbare Polyurethane mit verkappten Aminogrupppen |
| DE10246512A1 (de) | 2002-10-04 | 2004-04-15 | Bayer Ag | Niedrigviskose strahlenhärtende und thermisch härtende Polyisocyanate |
| DE10255664B4 (de) * | 2002-11-28 | 2006-05-04 | Kodak Polychrome Graphics Gmbh | Für lithographische Druckplatten geeignete Photopolymerzusammensetzung |
| DE10260269A1 (de) | 2002-12-20 | 2004-07-01 | Bayer Ag | Neue Dual Cure-Systeme |
| DE10346327A1 (de) * | 2003-10-06 | 2005-04-21 | Basf Ag | Strahlungshärtbare Beschichtungsmittel, enthaltend ein aliphatisches Urethan (meth)acrylat |
| US7144955B2 (en) * | 2003-10-27 | 2006-12-05 | Bayer Materialscience Llc | Acrylate-functional blocked polyisocyanate resin for UV/thermally curable coatings |
| DE10357712A1 (de) * | 2003-12-09 | 2005-07-14 | Bayer Materialscience Ag | Härter |
| DE102004009437A1 (de) | 2004-02-24 | 2005-09-15 | Basf Ag | Strahlungshärtbare Verbundschichtplatte oder -folie |
| DE102004012902A1 (de) * | 2004-03-17 | 2005-10-06 | Bayer Materialscience Ag | Herstellung von neuen strahlenhärtenden Bindemitteln |
| DE102004012903A1 (de) * | 2004-03-17 | 2005-10-06 | Bayer Materialscience Ag | Niedrigviskose Allophanate mit aktinisch härtbaren Gruppen |
| DE102004043363A1 (de) * | 2004-09-08 | 2006-03-09 | Bayer Materialscience Ag | Abspalterfrei-härtende blockierte Polyisocyanate für Dual Cure Systeme |
| DE102004043538A1 (de) * | 2004-09-09 | 2006-03-16 | Bayer Materialscience Ag | Herstellung von neuen strahlenhärtenden Bindemitteln |
| DE102004043540A1 (de) | 2004-09-09 | 2006-03-30 | Bayer Materialscience Ag | Niedrigviskose Allophanate mit aktinisch härtbaren Gruppen |
| DE102004043539A1 (de) * | 2004-09-09 | 2006-03-30 | Bayer Materialscience Ag | Niedrigviskose Allophanate mit aktinisch härtbaren Gruppen |
| DE102004043537A1 (de) * | 2004-09-09 | 2006-03-16 | Bayer Materialscience Ag | Herstellung von neuen strahlenhärtenden Bindemitteln |
| DE102004048873A1 (de) * | 2004-10-07 | 2006-04-13 | Bayer Materialscience Ag | Verfahren zur Herstellung von niedrigviskosen Allophanaten mit aktinisch härtbaren Gruppen |
| JP5065036B2 (ja) | 2004-11-04 | 2012-10-31 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング | 特に自動車の構築に使用される成形部材を製造する方法、およびこの目的で適切なコーティングを有するシート |
| EP1809462B1 (de) | 2004-11-04 | 2010-08-25 | BASF Coatings GmbH | Verfahren zur herstellung von formteilen, insbesondere zur anwendung im automobilbau, und hierfür geeignete, eine beschichtung aufweisende folien |
| US20060106157A1 (en) * | 2004-11-17 | 2006-05-18 | Sawant Suresh G | Urethane acrylate tie coats |
| US20060128923A1 (en) * | 2004-12-15 | 2006-06-15 | Bayer Materialscience Llc | Radiation curable compositions |
| DE102004060966A1 (de) * | 2004-12-17 | 2006-06-29 | Basf Coatings Ag | Strukturviskose härtbare Gemische, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE102004063102A1 (de) | 2004-12-22 | 2006-07-13 | Basf Ag | Strahlungshärtbare Verbindungen |
| DE102005008032A1 (de) * | 2005-02-22 | 2006-08-31 | Bayer Materialscience Ag | Verfahren zur Herstellung von Hydroxyalkyl(meth)acrylaten und deren Verwendung |
| JP2008531778A (ja) * | 2005-02-24 | 2008-08-14 | ビーエーエスエフ ソシエタス・ヨーロピア | 放射線硬化性ポリウレタンで少なくとも部分的に被覆された顔料、その生産と利用 |
| JP5769359B2 (ja) * | 2005-02-24 | 2015-08-26 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 放射線硬化な水性ポリウレタン分散液 |
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| DE102005020605A1 (de) | 2005-05-03 | 2006-11-09 | Basf Coatings Ag | Verfahren zur Herstellung von eine Beschichtung(B) aufweisenden Folien(F), die so erhaltenen Folien(F) sowie ihre Verwendung zur Herstellung von Formteilen, insbesondere ihre Anwendung im Automobilbau |
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| ES2450172T3 (es) | 2005-08-11 | 2014-03-24 | Basf Se | Copolímeros para aplicaciones cosméticas |
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-
1998
- 1998-12-23 DE DE19860041A patent/DE19860041A1/de not_active Withdrawn
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- 1999-12-14 JP JP2000591094A patent/JP5105387B2/ja not_active Expired - Fee Related
- 1999-12-14 CN CNB998161586A patent/CN1230457C/zh not_active Expired - Fee Related
- 1999-12-14 KR KR1020017007950A patent/KR100687109B1/ko not_active Expired - Fee Related
- 1999-12-14 EP EP19990964568 patent/EP1144476B1/de not_active Revoked
- 1999-12-14 DE DE59907967T patent/DE59907967D1/de not_active Expired - Lifetime
- 1999-12-14 AT AT99964568T patent/ATE255609T1/de not_active IP Right Cessation
- 1999-12-14 CA CA 2356685 patent/CA2356685C/en not_active Expired - Fee Related
- 1999-12-14 WO PCT/EP1999/009905 patent/WO2000039183A1/de not_active Ceased
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- 1999-12-14 US US09/868,712 patent/US6617413B1/en not_active Expired - Lifetime
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Also Published As
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|---|---|
| JP5466658B2 (ja) | 2014-04-09 |
| KR100687109B1 (ko) | 2007-02-27 |
| ATE255609T1 (de) | 2003-12-15 |
| CN1230457C (zh) | 2005-12-07 |
| CA2356685C (en) | 2009-10-20 |
| CN1334833A (zh) | 2002-02-06 |
| DE59907967D1 (de) | 2004-01-15 |
| CA2356685A1 (en) | 2000-07-06 |
| US6617413B1 (en) | 2003-09-09 |
| DE19860041A1 (de) | 2000-06-29 |
| WO2000039183A1 (de) | 2000-07-06 |
| JP2002533542A (ja) | 2002-10-08 |
| ES2212662T3 (es) | 2004-07-16 |
| JP2011099119A (ja) | 2011-05-19 |
| KR20010099893A (ko) | 2001-11-09 |
| EP1144476A1 (de) | 2001-10-17 |
| EP1144476B1 (de) | 2003-12-03 |
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