JP5021331B2 - 廃棄物からの白金族金属の回収方法 - Google Patents
廃棄物からの白金族金属の回収方法 Download PDFInfo
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- JP5021331B2 JP5021331B2 JP2007036166A JP2007036166A JP5021331B2 JP 5021331 B2 JP5021331 B2 JP 5021331B2 JP 2007036166 A JP2007036166 A JP 2007036166A JP 2007036166 A JP2007036166 A JP 2007036166A JP 5021331 B2 JP5021331 B2 JP 5021331B2
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- Prior art keywords
- platinum group
- group metal
- molten salt
- salt
- waste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910052751 metal Inorganic materials 0.000 title claims description 90
- 239000002184 metal Substances 0.000 title claims description 89
- 239000002699 waste material Substances 0.000 title claims description 36
- 238000000034 method Methods 0.000 title claims description 24
- -1 platinum group metals Chemical class 0.000 title description 15
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 115
- 150000003839 salts Chemical class 0.000 claims description 100
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 48
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 42
- 239000007864 aqueous solution Substances 0.000 claims description 32
- 229910052741 iridium Inorganic materials 0.000 claims description 28
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 28
- 238000006243 chemical reaction Methods 0.000 claims description 25
- 239000011780 sodium chloride Substances 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 235000011164 potassium chloride Nutrition 0.000 claims description 21
- 239000001103 potassium chloride Substances 0.000 claims description 21
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 17
- 229910052707 ruthenium Inorganic materials 0.000 claims description 17
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 11
- 239000000460 chlorine Substances 0.000 claims description 11
- 229910052801 chlorine Inorganic materials 0.000 claims description 11
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 238000000926 separation method Methods 0.000 claims description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- 229910052762 osmium Inorganic materials 0.000 claims description 2
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 229910052703 rhodium Inorganic materials 0.000 claims description 2
- 239000010948 rhodium Substances 0.000 claims description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 2
- 239000000706 filtrate Substances 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 description 21
- 238000011282 treatment Methods 0.000 description 15
- 239000000203 mixture Substances 0.000 description 12
- 238000004090 dissolution Methods 0.000 description 11
- 238000011084 recovery Methods 0.000 description 11
- 229910052799 carbon Inorganic materials 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical class [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 7
- 239000012535 impurity Substances 0.000 description 7
- 238000004064 recycling Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 150000002503 iridium Chemical class 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 229910052792 caesium Inorganic materials 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910001510 metal chloride Inorganic materials 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229910000510 noble metal Inorganic materials 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 150000003303 ruthenium Chemical class 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- UAKDOGDHPSNTNT-UHFFFAOYSA-J [Ir+3].[Cl-].[Cs+].[Cl-].[Cl-].[Cl-] Chemical group [Ir+3].[Cl-].[Cs+].[Cl-].[Cl-].[Cl-] UAKDOGDHPSNTNT-UHFFFAOYSA-J 0.000 description 2
- 229910001514 alkali metal chloride Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 229910000566 Platinum-iridium alloy Inorganic materials 0.000 description 1
- 229910001260 Pt alloy Inorganic materials 0.000 description 1
- 229910000629 Rh alloy Inorganic materials 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- AIYUHDOJVYHVIT-UHFFFAOYSA-M caesium chloride Chemical compound [Cl-].[Cs+] AIYUHDOJVYHVIT-UHFFFAOYSA-M 0.000 description 1
- QVSNPWNESIUVRT-UHFFFAOYSA-K cesium;trichlororuthenium Chemical compound [Cs].Cl[Ru](Cl)Cl QVSNPWNESIUVRT-UHFFFAOYSA-K 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- KFIKNZBXPKXFTA-UHFFFAOYSA-N dipotassium;dioxido(dioxo)ruthenium Chemical compound [K+].[K+].[O-][Ru]([O-])(=O)=O KFIKNZBXPKXFTA-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 238000011221 initial treatment Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 description 1
- HWLDNSXPUQTBOD-UHFFFAOYSA-N platinum-iridium alloy Chemical class [Ir].[Pt] HWLDNSXPUQTBOD-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000005297 pyrex Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000003923 scrap metal Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000010887 waste solvent Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/02—Obtaining noble metals by dry processes
- C22B11/021—Recovery of noble metals from waste materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
- C01G55/005—Halides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/04—Obtaining noble metals by wet processes
- C22B11/042—Recovery of noble metals from waste materials
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/06—Chloridising
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/001—Dry processes
- C22B7/002—Dry processes by treating with halogens, sulfur or compounds thereof; by carburising, by treating with hydrogen (hydriding)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Processing Of Solid Wastes (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007036166A JP5021331B2 (ja) | 2007-02-16 | 2007-02-16 | 廃棄物からの白金族金属の回収方法 |
PCT/JP2008/052012 WO2008099747A1 (ja) | 2007-02-16 | 2008-02-07 | 廃棄物からの白金族金属の回収方法 |
TW97105133A TWI445824B (zh) | 2007-02-16 | 2008-02-14 | 從廢棄物回收白金族金屬的方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007036166A JP5021331B2 (ja) | 2007-02-16 | 2007-02-16 | 廃棄物からの白金族金属の回収方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2008202063A JP2008202063A (ja) | 2008-09-04 |
JP5021331B2 true JP5021331B2 (ja) | 2012-09-05 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2007036166A Active JP5021331B2 (ja) | 2007-02-16 | 2007-02-16 | 廃棄物からの白金族金属の回収方法 |
Country Status (3)
Country | Link |
---|---|
JP (1) | JP5021331B2 (zh) |
TW (1) | TWI445824B (zh) |
WO (1) | WO2008099747A1 (zh) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4514807B2 (ja) * | 2008-04-10 | 2010-07-28 | 山本貴金属地金株式会社 | 貴金属微粒子の製造方法 |
JP5408993B2 (ja) * | 2008-12-24 | 2014-02-05 | 山本貴金属地金株式会社 | 白金族元素の回収方法 |
KR101091699B1 (ko) * | 2009-05-18 | 2011-12-08 | 한국지질자원연구원 | 자동차 폐 촉매로부터 백금족 금속의 침출방법 |
JP5361759B2 (ja) * | 2010-02-15 | 2013-12-04 | 山本貴金属地金株式会社 | 貴金属微粒子の製造方法 |
CN104056841A (zh) * | 2013-07-10 | 2014-09-24 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种提钛尾渣的处理方法 |
EP3085796B1 (de) * | 2015-04-21 | 2017-07-19 | Heraeus Deutschland GmbH & Co. KG | Verfahren zum aufschluss eines metallisches iridium und/oder iridiumoxid umfassenden gemischs von feststoffpartikeln |
KR101817079B1 (ko) | 2017-09-25 | 2018-02-21 | 케이에스메탈주식회사 | 귀금속 광석의 선광과정에서 발생하는 폐슬러지로부터 백금족 금속 회수방법 |
CN111900425B (zh) * | 2020-07-03 | 2021-12-17 | 广东邦普循环科技有限公司 | 一种新能源汽车氢燃料电池的回收方法 |
CN113462900B (zh) * | 2021-07-04 | 2022-06-21 | 贵研资源(易门)有限公司 | 一种从废铑派克催化剂中回收铑的方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5168493A (en) * | 1974-12-10 | 1976-06-14 | Japan Carlit Co Ltd | Ruteniumu mataha sonokagobutsuofukumu nanyoseibutsushitsuno kayokaho |
JPS58194745A (ja) * | 1982-05-06 | 1983-11-12 | Tanaka Kikinzoku Kogyo Kk | ルテニウムの回収方法 |
JPS6092433A (ja) * | 1983-10-26 | 1985-05-24 | Daido Steel Co Ltd | 貴金属の回収方法 |
JP2692882B2 (ja) * | 1988-08-23 | 1997-12-17 | 田中貴金属工業株式会社 | 廃触媒からの貴金属の回収方法 |
JP3564852B2 (ja) * | 1996-02-19 | 2004-09-15 | 三菱マテリアル株式会社 | 高純度金属ルテニウム粉末の製造方法 |
JP4607303B2 (ja) * | 2000-09-13 | 2011-01-05 | 株式会社フルヤ金属 | 金属電極から白金族金属を回収する方法 |
JP3943564B2 (ja) * | 2004-01-30 | 2007-07-11 | 日鉱金属株式会社 | Se含有物の塩化処理方法 |
-
2007
- 2007-02-16 JP JP2007036166A patent/JP5021331B2/ja active Active
-
2008
- 2008-02-07 WO PCT/JP2008/052012 patent/WO2008099747A1/ja active Application Filing
- 2008-02-14 TW TW97105133A patent/TWI445824B/zh active
Also Published As
Publication number | Publication date |
---|---|
JP2008202063A (ja) | 2008-09-04 |
TWI445824B (zh) | 2014-07-21 |
WO2008099747A1 (ja) | 2008-08-21 |
TW200848519A (en) | 2008-12-16 |
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