JP4698835B2 - 触媒特性改良のため触媒表面からイオン化可能種を除去する方法 - Google Patents

触媒特性改良のため触媒表面からイオン化可能種を除去する方法 Download PDF

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JP4698835B2
JP4698835B2 JP2000569912A JP2000569912A JP4698835B2 JP 4698835 B2 JP4698835 B2 JP 4698835B2 JP 2000569912 A JP2000569912 A JP 2000569912A JP 2000569912 A JP2000569912 A JP 2000569912A JP 4698835 B2 JP4698835 B2 JP 4698835B2
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catalyst
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JP2002524245A (ja
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ロツクマイヤー，ジヨン・ロバート
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シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2000569912A 1998-09-14 1999-09-09 触媒特性改良のため触媒表面からイオン化可能種を除去する方法 Expired - Lifetime JP4698835B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10019498P 1998-09-14 1998-09-14
US60/100,194 1998-09-14
PCT/EP1999/006721 WO2000015333A1 (en) 1998-09-14 1999-09-09 Process for removing ionizable species from catalyst surface to improve catalytic properties

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JP2002524245A JP2002524245A (ja) 2002-08-06
JP4698835B2 true JP4698835B2 (ja) 2011-06-08

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US (1) US6368998B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
EP (1) EP1115485A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
JP (1) JP4698835B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
KR (1) KR100572966B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CN (1) CN1167500C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
AU (1) AU750895B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
BR (1) BR9913600A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CA (1) CA2343783C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
GC (1) GC0000069A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
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MY (1) MY121089A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
RU (1) RU2232049C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
TR (1) TR200100748T2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
TW (1) TWI232133B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
WO (1) WO2000015333A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
ZA (1) ZA200101901B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

Families Citing this family (94)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7232918B2 (en) * 2001-11-06 2007-06-19 Shell Oil Company Catalyst composition
US7232786B2 (en) * 1998-09-14 2007-06-19 Shell Oil Company Catalyst composition
AU757495B2 (en) * 1998-09-14 2003-02-20 Shell Internationale Research Maatschappij B.V. Process for preparing catalysts with improved catalytic properties
US7504525B2 (en) * 1998-09-14 2009-03-17 Shell Oil Company Catalyst composition
KR100641542B1 (ko) * 1998-09-14 2006-10-31 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 에폭시화 촉매 캐리어, 이의 제조 및 용도
KR100887001B1 (ko) 2001-03-30 2009-03-04 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 8족 금속을 함유한 촉매의 제조방법과 알케닐카르복실레이트 제조 시의 용도
US6624109B2 (en) * 2001-10-23 2003-09-23 Council Of Scientific And Industrial Research Process for the synthesis of highly active modified carbon supported palladium catalyst
US7193094B2 (en) 2001-11-20 2007-03-20 Shell Oil Company Process and systems for the epoxidation of an olefin
US6831037B2 (en) 2002-02-25 2004-12-14 Saint-Gobain Norpro Corporation Catalyst carriers
US6987080B2 (en) * 2002-03-01 2006-01-17 Scientific Design Company, Inc. Ethylene oxide catalyst carrier preparation
JP4421201B2 (ja) 2002-03-27 2010-02-24 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒を調製する方法、触媒、および触媒の使用
US6750173B2 (en) * 2002-04-08 2004-06-15 Scientific Design Company, Inc. Ethylene oxide catalyst
EP1517751B2 (en) 2002-06-28 2016-06-01 Shell Internationale Research Maatschappij B.V. A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
AU2003247652A1 (en) 2002-06-28 2004-01-19 Shell Internationale Research Maatschappij B.V. A method for the start-up of an epoxidation process and a process for the epoxidation of an olefin
CN100457258C (zh) 2002-09-30 2009-02-04 国际壳牌研究有限公司 制备银基环氧化催化剂的碳酸钙载体
AU2003284183A1 (en) 2002-10-28 2004-05-25 Shell Oil Company A process for preparing an olefin oxide, a method of using the olefin oxide and a catalyst composition
TWI346574B (en) 2003-03-31 2011-08-11 Shell Int Research A catalyst composition, a process for preparing the catalyst composition and a use of the catalyst composition
MXPA05010375A (es) 2003-04-01 2005-11-17 Shell Int Research Proceso de epoxidacion de olefina y catalizador para utilizar en el proceso.
US7348444B2 (en) * 2003-04-07 2008-03-25 Shell Oil Company Process for the production of an olefin oxide
US6846774B2 (en) 2003-04-23 2005-01-25 Scientific Design Co., Inc. Ethylene oxide catalyst
US6858560B2 (en) 2003-04-23 2005-02-22 Scientific Design Co., Inc. Ethylene oxide catalyst
MX260863B (es) 2003-05-07 2008-09-26 Shell Int Research Catalizadores que contienen plata, su elaboracion y uso de los mismos.
US20040224841A1 (en) * 2003-05-07 2004-11-11 Marek Matusz Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof
US20040225138A1 (en) * 2003-05-07 2004-11-11 Mcallister Paul Michael Reactor system and process for the manufacture of ethylene oxide
US8148555B2 (en) 2003-06-26 2012-04-03 Shell Oil Company Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
US20060293180A1 (en) * 2003-08-22 2006-12-28 Thorsteinson Erlind M Modified alumina carriers and silver-based catalysts for the production of alkylene oxides
CN1838991A (zh) * 2003-08-22 2006-09-27 联合碳化化学及塑料技术公司 改进的氧化铝载体和用于制造烯化氧的银基催化剂
RU2360735C2 (ru) * 2003-10-16 2009-07-10 Дау Текнолоджи Инвестментс Ллс Катализаторы для получения алкиленоксидов, имеющие улучшенную стабильность, эффективность и/или активность
TW200600190A (en) * 2004-04-01 2006-01-01 Shell Int Research Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation
TW200602123A (en) * 2004-04-01 2006-01-16 Shell Int Research Process for preparing a catalyst, the catalyst, and a use of the catalyst
TW200613056A (en) * 2004-04-01 2006-05-01 Shell Int Research A process for preparing a silver catalyst, the catalyst, and a use of the catalyst for olefin oxidation
ATE554080T1 (de) 2004-06-18 2012-05-15 Shell Int Research Verfahren zur herstellung eines olefinoxids, 1,2- diols, a 1,2-diolethers oder alkanolamins
BRPI0512172A (pt) * 2004-06-18 2008-02-12 Shell Int Research processo para a produção de óxido de olefina, 1,2-diol, éter de 1,2-diol ou alcanolamina
KR20070045316A (ko) * 2004-08-12 2007-05-02 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 성형된 촉매의 제조방법, 성형된 촉매 및 이 촉매의 용도
US8536083B2 (en) 2004-09-01 2013-09-17 Shell Oil Company Olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier
WO2006028940A2 (en) 2004-09-01 2006-03-16 Shell Internationale Research Maatschappij B.V. An olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier
BRPI0515905A (pt) * 2004-09-24 2008-08-12 Shell Int Research processo para selecionar partìculas moldadas, um processo para instalar um sistema, um processo para reagir uma carga de alimentação gasosa em um tal sistema, um produto de programa de computação e um sistema de computação
EP1850955A1 (en) * 2005-02-21 2007-11-07 Shell Internationale Researchmaatschappij B.V. An olefin epoxidation process, a catalyst for use in the process, a carrier for use in making the catalyst, and a process for making the carrier
KR20070112870A (ko) * 2005-03-22 2007-11-27 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 반응기 시스템 및 에틸렌옥사이드의 제조방법
EP1724824A3 (en) * 2005-05-17 2010-08-25 Apprecia Technology Inc. Equipment and method for measuring silicon concentration in phosphoric acid solution
RU2007149318A (ru) * 2005-06-07 2009-07-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Кктализатор, способ приготовления катализатора и способ получения оксида олефина, 1, 2-диола, эфира 1, 2-диола или алканоламина
MX2007015465A (es) 2005-06-07 2008-02-25 Saint Gobain Ceramics Un portador catalizador y un procedimiento para preparar el portador catalizador.
CN101272853A (zh) * 2005-08-11 2008-09-24 国际壳牌研究有限公司 成型催化剂的制备方法、催化剂和催化剂的用途
GB2433503A (en) * 2005-12-22 2007-06-27 Shell Int Research Epoxidation of an olefin by reacting olefin, oxygen & catalyst in a microchannel reactor, and chemicals derivable from an olefin oxide
US20070203349A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070197801A1 (en) * 2005-12-22 2007-08-23 Bolk Jeroen W Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitables for such a process
US7704908B2 (en) * 2005-12-22 2010-04-27 Shell Oil Company Method for reusing rhenium from a donor spent epoxidation catalyst
US20070151451A1 (en) * 2005-12-22 2007-07-05 Rekers Dominicus M Process for the cooling, concentration or purification of ethylene oxide
US20070203348A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070203350A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070203352A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070213545A1 (en) * 2005-12-22 2007-09-13 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070154377A1 (en) * 2005-12-22 2007-07-05 Rekers Dominicus M Process for the removal of combustible volatile contaminant materials from a process stream
US20070197808A1 (en) * 2005-12-22 2007-08-23 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US7459589B2 (en) * 2005-12-22 2008-12-02 Shell Oil Company Process for the preparation of an alkylene glycol
CA2641225A1 (en) * 2006-02-03 2007-08-16 Shell Internationale Research Maatschappij B.V. A process for treating a catalyst, the catalyst, and use of the catalyst
WO2007116585A1 (ja) 2006-04-10 2007-10-18 Mitsubishi Chemical Corporation 酸化エチレン製造用触媒およびその製造方法ならびに酸化エチレンの製造方法
CN101360562B (zh) * 2006-04-10 2013-02-06 三菱化学株式会社 环氧乙烷制造用催化剂及其制造方法、以及环氧乙烷的制造方法
JP4978277B2 (ja) * 2006-04-10 2012-07-18 三菱化学株式会社 酸化エチレン製造用触媒およびその製造方法ならびに酸化エチレンの製造方法
CA2669585A1 (en) * 2006-11-20 2008-05-29 Shell Internationale Research Maatschappij B.V. A process for treating a carrier, a process for preparing a catalyst, the catalyst, and use of the catalyst
US20080154051A1 (en) * 2006-12-20 2008-06-26 Jeroen Willem Bolk Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process
US20080154052A1 (en) * 2006-12-20 2008-06-26 Jeroen Willem Bolk Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process
AR066468A1 (es) 2007-05-09 2009-08-19 Shell Int Research Un catalizador de epoxidacion, un proceso para preparar el mismo, y un proceso para producir un oxido de olefina , un 1,2- diol, un 1,2 - diol eter, un 1,2- carbonato, o una alcanolamina
WO2008141030A1 (en) * 2007-05-09 2008-11-20 Shell Oil Company A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
CN101715444B (zh) 2007-05-09 2012-11-21 国际壳牌研究有限公司 环氧化催化剂及其制备方法和生产环氧烷、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或烷醇胺的方法
RU2474470C2 (ru) 2007-05-18 2013-02-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Реакторная система, абсорбент и способ осуществления реакции в подаваемом материале
US9144765B2 (en) 2007-05-18 2015-09-29 Shell Oil Company Reactor system, an absorbent and a process for reacting a feed
JP5507446B2 (ja) * 2007-05-18 2014-05-28 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 反応器システム並びにオレフィンオキシド、１，２−ジオール、１，２−ジオールエーテル、１，２−カーボネートおよびアルカノールアミンの調製方法
WO2009029578A2 (en) 2007-08-27 2009-03-05 Shell Oil Company A carrier, a process for preparing the carrier, an olefin epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
US7763096B2 (en) 2008-05-06 2010-07-27 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Recovery of rhenium
BRPI0912391B1 (pt) 2008-05-07 2018-04-17 Shell Internationale Research Maatschappij B.V. Processo para epoxidação de uma olefina
BRPI0912381A2 (pt) 2008-05-07 2017-07-04 Shell Int Research processo para a partida de um processo de epoxidação, processo para a produção de óxido de etileno, 1,2-diol, 1, 2-diol éter, 1, 2-carbonato, ou uma alcanolamina
JP2011524857A (ja) * 2008-05-15 2011-09-08 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー アルキレンカーボネートおよびアルキレングリコールの調製のための方法
WO2009140319A1 (en) 2008-05-15 2009-11-19 Shell Oil Company Process for the preparation of alkylene carbonate and/or alkylene glycol
JP2013521119A (ja) 2010-03-01 2013-06-10 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー エポキシ化触媒、前記触媒の調製方法及びオレフィンオキシドの製造方法
CN102883810B (zh) * 2010-04-30 2015-03-25 旭化成化学株式会社 催化剂表面体去除装置
US9018126B2 (en) 2010-07-13 2015-04-28 Shell Oil Company Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide
CN102463141B (zh) 2010-11-02 2015-05-06 中国石油化工股份有限公司 一种氧化铝载体、其制备方法、由其制成的银催化剂及其应用
US8742146B2 (en) 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
US8742147B2 (en) 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
JP6104888B2 (ja) 2011-04-29 2017-03-29 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー Ｅｏ触媒の選択率を改善する方法
JP5984593B2 (ja) * 2011-09-30 2016-09-06 株式会社日本触媒 エチレンオキシド製造用触媒およびそれを用いたエチレンオキシドの製造方法
TWI632138B (zh) * 2013-05-16 2018-08-11 科學設計股份有限公司 具有降低鈉含量之建基於銀之環氧乙烷觸媒
TWI632954B (zh) 2013-05-16 2018-08-21 科學設計股份有限公司 改善環氧乙烷觸媒的催化效能之載體處理
US10300462B2 (en) 2013-12-19 2019-05-28 Scientific Design Company, Inc. High concentration silver solutions for ethylene oxide catalyst preparation
CN104492247B (zh) * 2014-12-15 2016-06-08 沈阳三聚凯特催化剂有限公司 一种瓷球脱硫剂的制备方法
CN108368039B (zh) 2015-12-15 2020-07-14 国际壳牌研究有限公司 从环氧乙烷制造中的循环气体流去除碘化物杂质的方法和系统
CN108368074B (zh) 2015-12-15 2022-03-29 国际壳牌研究有限公司 从环氧乙烷制造中的循环气体流去除烷基碘杂质的方法和系统
BR112018011943B1 (pt) 2015-12-15 2021-11-30 Shell Internationale Research Maatschappij B.V. Processo e sistema de reação para produção de óxido de etileno, carbonato de etileno e/ou etilenoglicol a partir de etileno
TWI740863B (zh) 2015-12-15 2021-10-01 荷蘭商蜆殼國際研究所 防護床系統及方法
TWI772330B (zh) 2016-10-14 2022-08-01 荷蘭商蜆殼國際研究所 用於定量分析氣態製程流之方法及設備
EP3548471B1 (en) 2016-12-02 2021-05-19 Shell Internationale Research Maatschappij B.V. Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide
WO2018128638A1 (en) 2017-01-05 2018-07-12 Scientific Design Company, Inc. Carrier, catalyst, methods for producing them and method for producing ethylene oxide
TW202239752A (zh) 2020-12-29 2022-10-16 荷蘭商蜆殼國際研究所 用於生產環氧乙烷之製程

Family Cites Families (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB568978A (en) * 1941-07-05 1945-04-30 Houdry Process Corp Alumina
US2424083A (en) * 1943-08-11 1947-07-15 Shell Dev Supported silver catalyst
US2901441A (en) 1953-01-28 1959-08-25 Publicker Ind Inc Preparation of an oxidation catalyst
FR2005978A1 (en) 1968-04-10 1969-12-19 Institu Cercetari Petroc Catalyst for oxidation of ethylene to ethylene oxide
US4356312A (en) * 1972-01-07 1982-10-26 Shell Oil Company Ethylene oxide process
US3972829A (en) 1974-11-07 1976-08-03 Universal Oil Products Company Method of depositing a catalytically active metallic component on a carrier material
US4005049A (en) 1975-05-23 1977-01-25 Standard Oil Company (Indiana) Silver catalysts
US4212772A (en) 1976-05-19 1980-07-15 Basf Aktiengesellschaft Catalyst for the manufacture of ethylene oxide
IT1078404B (it) * 1976-05-19 1985-05-08 Basf Ag Catalizzatore per la preparazione di ossido di etilene
GB1575810A (en) 1976-10-21 1980-10-01 Shell Int Research Process for the performance of silver catalysts
DE2819595A1 (de) * 1977-05-12 1978-12-07 Basf Ag Katalysator zur herstellung von aethylenoxid
DE2740480B2 (de) 1977-09-08 1979-07-05 Hoechst Ag, 6000 Frankfurt Verfahren zur Verbesserung der Wirksamkeit von Silber-Trägerkatalysatoren
US5387751A (en) 1978-02-10 1995-02-07 Imperial Chemical Industries Plc Production of olefine oxides
US4916243A (en) 1979-03-20 1990-04-10 Union Carbide Chemicals And Plastics Company Inc. New catalyst composition and process for oxidation of ethylene to ethylene oxide
HU177860B (en) 1979-05-22 1982-01-28 Mta Koezponti Hivatala Method for producing carrier metal catalyzers
DE2933950A1 (de) * 1979-08-22 1981-03-12 Basf Ag Traegerkatalysatoren fuer die herstellung von aethylenoxid.
JPS5689843A (en) * 1979-12-25 1981-07-21 Nippon Shokubai Kagaku Kogyo Co Ltd Silver catalyst for production of ethylene oxide
JPS56105750A (en) * 1980-01-24 1981-08-22 Nippon Shokubai Kagaku Kogyo Co Ltd Silver catalyst for production of ethylene oxide
JPS56164013A (en) 1980-05-23 1981-12-16 Showa Alum Ind Kk Preparation of alumina with low content of radioactive element
US4382149A (en) * 1980-11-05 1983-05-03 Borden, Inc. Supported silver catalyst
US4379134A (en) * 1981-02-13 1983-04-05 Union Carbide Corporation Process of preparing high purity alumina bodies
US4367167A (en) 1981-07-17 1983-01-04 The Dow Chemical Company Process for preparing supported metal catalysts
US4366092A (en) 1981-07-31 1982-12-28 The Dow Chemical Company Process for making a silver-gold alloy catalyst for oxidizing ethylene to ethylene oxide
US4361504A (en) * 1981-09-04 1982-11-30 The Dow Chemical Company Process for making a silver catalyst useful in ethylene oxide production
GB8304749D0 (en) * 1983-02-21 1983-03-23 Ici Plc Catalysts
AU570489B2 (en) 1983-07-05 1988-03-17 Union Carbide Corporation Alkoxylation using calcium catalysts
US4628129A (en) * 1985-02-04 1986-12-09 Union Carbide Corporation Process for the preparation of ethylene glycol
GB8613818D0 (en) 1986-06-06 1986-07-09 Ici Plc Catalysts
EP0211521B1 (en) 1985-07-31 1990-03-21 Imperial Chemical Industries Plc Process of promoting catalysts for the production of alkylene oxides
US4994587A (en) * 1985-08-12 1991-02-19 Union Carbide Chemicals And Plastics Company, Inc. Catalytic system for epoxidation of alkenes employing low sodium catalyst supports
US4994588A (en) 1985-08-13 1991-02-19 Union Carbide Chemicals And Plastics Company Inc. Fluorine-containing catalytic system for expoxidation of alkenes
US4994589A (en) 1985-08-13 1991-02-19 Union Carbide Chemicals And Plastics Company Inc. Catalytic system for epoxidation of alkenes
GB8526774D0 (en) * 1985-10-30 1985-12-04 Sandoz Ltd Bacillus thuringiensis hybrids
US4820675A (en) * 1986-10-31 1989-04-11 Shell Oil Company Ethylene oxide catalyst & process for preparing the catalyst
US4761394A (en) * 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4766105A (en) * 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US5057481A (en) * 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US4908343A (en) 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
GB8716653D0 (en) 1987-07-15 1987-08-19 Shell Int Research Silver-containing catalyst
ES2004759A6 (es) * 1987-07-17 1989-02-01 Espanola Alumina Sa Metodo de obtencion de alumina especial a partir del polvo producido en la calcinacion de alumina metalurgica
US4797220A (en) * 1988-02-03 1989-01-10 Miller Dale A Descaling and anti-oxidizing composition and process therefor
US5055442A (en) 1989-02-17 1991-10-08 Nippon Shokubai Kagaku Kogyo Co., Ltd. Carrier for catalyst and method for production thereof
US5037794A (en) 1989-09-12 1991-08-06 The B. F. Goodrich Company Attrition resistant catalyst support
US5187140A (en) * 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
US5112795A (en) 1990-10-12 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Supported silver catalyst, and processes for making and using same
US5100859A (en) 1991-01-22 1992-03-31 Norton Company Catalyst carrier
DK0563414T3 (da) * 1992-03-30 1997-03-17 Union Carbide Chem Plastic Fremgangsmåde til fremstilling af en katalysator til produktion af alkenylalkanoater
RU2046015C1 (ru) * 1992-04-08 1995-10-20 Владимир Сергеевич Соколов Способ приготовления катализатора для получения окиси этилена
US6184175B1 (en) * 1993-03-01 2001-02-06 Scientic Design Company, Inc. Process for preparing silver catalyst
DE4311608A1 (de) 1993-04-08 1994-12-15 Huels Chemische Werke Ag Silberkatalysator zur Oxidation von Ethylen zu Ethylenoxid und Verfahren zur Herstellung von Ethylenoxid
US5447897A (en) 1993-05-17 1995-09-05 Shell Oil Company Ethylene oxide catalyst and process
US5380697A (en) 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
US5364826A (en) 1993-09-13 1994-11-15 Shell Oil Company Process for preparing ethylene oxide catalysts
US5418202A (en) 1993-12-30 1995-05-23 Shell Oil Company Ethylene oxide catalyst and process
US5545603A (en) 1994-11-01 1996-08-13 Shell Oil Company Ethylene oxide catalyst and process
DE69600628T2 (de) * 1995-02-01 1999-02-25 Shell Internationale Research Maatschappij B.V., Den Haag/S'gravenhage Alkylenoxidkatalysator und verfahren
JP3802106B2 (ja) 1995-06-08 2006-07-26 日本ケッチェン株式会社 炭化水素油の水素化処理触媒とその製造方法およびその活性化方法
US5739075A (en) * 1995-10-06 1998-04-14 Shell Oil Company Process for preparing ethylene oxide catalysts
TW426545B (en) * 1997-12-25 2001-03-21 Nippon Catalytic Chem Ind Silver catalyst for production of ethylene oxide, method for production thereof, and method for production of ethylene oxide
DE69919425T2 (de) 1998-02-20 2005-09-08 Nippon Shokubai Co. Ltd. Silberkatalysator zur Herstellung von Ethylenoxid , Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Ethylenoxid
JP4050041B2 (ja) * 2001-11-06 2008-02-20 株式会社日本触媒 酸化エチレン製造用触媒、その製造方法および当該触媒による酸化エチレンの製造方法

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