JP4570780B2 - 低温フルオロカーボンエラストマ - Google Patents
低温フルオロカーボンエラストマ Download PDFInfo
- Publication number
- JP4570780B2 JP4570780B2 JP2000567586A JP2000567586A JP4570780B2 JP 4570780 B2 JP4570780 B2 JP 4570780B2 JP 2000567586 A JP2000567586 A JP 2000567586A JP 2000567586 A JP2000567586 A JP 2000567586A JP 4570780 B2 JP4570780 B2 JP 4570780B2
- Authority
- JP
- Japan
- Prior art keywords
- copolymer
- formula
- reactor
- temperature
- grams
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/22—Vinylidene fluoride
- C08F214/222—Vinylidene fluoride with fluorinated vinyl ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
- C08F216/14—Monomers containing only one unsaturated aliphatic radical
- C08F216/1408—Monomers containing halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Gasket Seals (AREA)
- Diaphragms And Bellows (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US9846198P | 1998-08-31 | 1998-08-31 | |
| US60/098,461 | 1998-08-31 | ||
| PCT/US1999/016561 WO2000012574A1 (en) | 1998-08-31 | 1999-07-21 | Low temperature fluorocarbon elastomers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2002523576A JP2002523576A (ja) | 2002-07-30 |
| JP2002523576A5 JP2002523576A5 (https=) | 2008-12-25 |
| JP4570780B2 true JP4570780B2 (ja) | 2010-10-27 |
Family
ID=22269374
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000567586A Expired - Fee Related JP4570780B2 (ja) | 1998-08-31 | 1999-07-21 | 低温フルオロカーボンエラストマ |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6294627B1 (https=) |
| EP (1) | EP1117710B1 (https=) |
| JP (1) | JP4570780B2 (https=) |
| CN (1) | CN1147514C (https=) |
| CA (1) | CA2341460A1 (https=) |
| DE (1) | DE69913550T2 (https=) |
| RU (1) | RU2261871C2 (https=) |
| WO (1) | WO2000012574A1 (https=) |
Families Citing this family (82)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6255536B1 (en) † | 1999-12-22 | 2001-07-03 | Dyneon Llc | Fluorine containing vinyl ethers |
| JP2003527468A (ja) * | 1999-12-29 | 2003-09-16 | ハイドロ−ケベック | 低いTgを有し、ビニリデンフルオライドを主成分とし、かつテトラフルオロエチレンもシロキサン基も含まないフルオロエラストマー |
| US7534845B2 (en) | 2000-04-21 | 2009-05-19 | Solvay Solexis S.P.A. | Fluorovinyl ethers and polymers obtainable therefrom |
| IT1318488B1 (it) | 2000-04-21 | 2003-08-25 | Ausimont Spa | Fluorovinileteri e polimeri da essi ottenibili. |
| IT1318487B1 (it) * | 2000-04-21 | 2003-08-25 | Ausimont Spa | Fluoroelastomeri. |
| US7351471B2 (en) | 2000-12-06 | 2008-04-01 | 3M Innovative Properties Company | Fluoropolymer coating compositions with multifunctional fluoroalkyl crosslinkers for anti-reflective polymer films |
| CA2328433A1 (fr) * | 2000-12-20 | 2002-06-20 | Hydro-Quebec | Elastomeres nitriles fluorosulfones reticulables a faible tg a base de fluorure de vinylidene et ne contenant ni du tetrafluoroethylene ni de groupement siloxane |
| US6730760B2 (en) * | 2001-01-31 | 2004-05-04 | 3M Innovative Properties Company | Perfluoroelastomers having a low glass transition temperature and method of making them |
| US6890995B2 (en) * | 2001-01-31 | 2005-05-10 | 3M Innovative Properties Company | Fluoropolymer compositions |
| US6794457B2 (en) * | 2001-04-30 | 2004-09-21 | 3M Innovative Properties Company | Fluoropolymer curing system containing a nitrogen cure site monomer |
| US7060772B2 (en) * | 2001-09-20 | 2006-06-13 | 3M Innovative Properties Company | Fluoropolymers from tetrafluoroethylene and perfluoro(alkoxyalkyl vinyl) ether |
| ITMI20012164A1 (it) * | 2001-10-18 | 2003-04-18 | Ausimont Spa | Fluoroelastomeri |
| ITMI20012165A1 (it) * | 2001-10-18 | 2003-04-18 | Ausimont Spa | Perfluoroelastomeri |
| US6995121B1 (en) | 2002-06-24 | 2006-02-07 | Seagate Technology Llc | Stability polymeric lubricants and thin film recording media comprising same |
| KR101022727B1 (ko) * | 2002-09-12 | 2011-03-22 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 내투과성이 향상된 플루오로엘라스토머 및 이의 제조 방법 |
| US6846542B1 (en) | 2002-09-30 | 2005-01-25 | Seagate Technology Llc | UV treatment for improving performance of lubricated thin film recording media and media obtained thereby |
| WO2004060944A1 (en) * | 2002-12-23 | 2004-07-22 | 3M Innovative Properties Company | Fluoroplastic polymers having nitrogen-containing cure sites |
| US7304115B2 (en) * | 2003-12-30 | 2007-12-04 | 3M Innovative Properties Company | Fluoropolymer coagulation method and composition |
| ITMI20041573A1 (it) | 2004-07-30 | 2006-01-31 | Solvay Solexis Spa | Fluoroelastomeri |
| JP2006117745A (ja) * | 2004-10-20 | 2006-05-11 | Three M Innovative Properties Co | フルオロエラストマー含有組成物からなるシール材料 |
| US20060105285A1 (en) * | 2004-11-17 | 2006-05-18 | Naiyong Jing | Nonelastomeric dental article with a protective fluoropolymer layer |
| US20060105179A1 (en) * | 2004-11-17 | 2006-05-18 | Hofman Gerald R A | Elastomeric dental article with a protective fluoropolymer layer |
| US20060104806A1 (en) * | 2004-11-18 | 2006-05-18 | Giesler William L | Low friction O-ring for use in a carbon face seal |
| US7402630B2 (en) * | 2004-12-16 | 2008-07-22 | 3M Innovative Properties Company | Curing compositions for fluoropolymers |
| US7300985B2 (en) * | 2004-12-21 | 2007-11-27 | 3M Innovative Properties Company | Fluoropolymers having pendant amidoxime or amidrazone structures |
| US7323514B2 (en) | 2004-12-30 | 2008-01-29 | 3M Innovative Properties Company | Low refractive index fluoropolymer coating compositions for use in antireflective polymer films |
| DE102005039145A1 (de) * | 2005-05-20 | 2006-11-23 | Grünenthal GmbH | Substituierte benzokondensierte Cyclohexanon-Derivate und deren Verwendung zur Herstellung von Arzneimitteln |
| US7294677B2 (en) * | 2005-08-25 | 2007-11-13 | 3M Innovative Properties Company | Catalyst for making fluoroelastomer compositions and methods of using the same |
| US20070088143A1 (en) * | 2005-10-19 | 2007-04-19 | Ming-Hong Hung | Alpha, alpha-dihydrofluorovinyl ethers, homopolymers and copolymers thereof |
| DE112006002940T5 (de) | 2005-11-05 | 2008-12-11 | 3M Innovative Properties Co., St. Paul | Optische Filme, umfassend einen hohen Brechungsindex aufweisende und antireflektierende Beschichtungen |
| ITMI20060083A1 (it) * | 2006-01-19 | 2007-07-20 | Solvay Solexis Spa | Fluoroelastomeri |
| WO2007111465A1 (en) * | 2006-03-27 | 2007-10-04 | Essilor International (Compagnie Generale D'optique) | Edging process of lens using transparent coating layer for protecting lens |
| JP5099123B2 (ja) | 2007-04-06 | 2012-12-12 | ユニマテック株式会社 | 含フッ素ポリエーテル化合物、その製造方法およびそれを含有する硬化性組成物 |
| RU2408608C2 (ru) * | 2009-03-25 | 2011-01-10 | Федеральное государственное унитарное предприятие "Ордена Ленина и ордена Трудового Красного Знамени научно-исследовательский институт синтетического каучука имени академика С.В. Лебедева" | Тройные бромсодержащие сополимеры на основе тетрафторэтилена для термоагрессивостойких материалов и способ их получения |
| JP5439915B2 (ja) | 2009-04-09 | 2014-03-12 | ユニマテック株式会社 | 硬化性含フッ素ポリエーテル組成物 |
| JP5547807B2 (ja) | 2009-06-25 | 2014-07-16 | スリーエム イノベイティブ プロパティズ カンパニー | フルオロポリマー用の硬化組成物 |
| EP2278325A1 (en) * | 2009-07-13 | 2011-01-26 | Spark Holland B.V. | Flow through cartridge for selecting an analyte online with high performance liquid chromatography |
| GB0917450D0 (en) * | 2009-10-06 | 2009-11-18 | 3M Innovative Properties Co | Triazine containing fluoropolyether elastomers having very low glass transition temperatures, compositions containing them and methods of making them |
| JP2013525955A (ja) | 2010-04-16 | 2013-06-20 | フレックス ライティング 2,エルエルシー | フィルムベースのライトガイドを備える照明デバイス |
| CN104093780B (zh) | 2011-11-09 | 2016-09-14 | 3M创新有限公司 | 用于含氟聚合物的固化组合物 |
| EP2986680B1 (en) | 2013-04-18 | 2017-05-17 | 3M Innovative Properties Company | Buried clay/nanosilica static dissipative coatings |
| US20150073111A1 (en) * | 2013-09-10 | 2015-03-12 | E I Du Pont De Nemours And Company | Fluoroelastomers having secondary cyano group cure sites |
| KR102279977B1 (ko) * | 2014-03-06 | 2021-07-22 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 고도 플루오르화 엘라스토머 |
| KR20170093891A (ko) | 2014-12-08 | 2017-08-16 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 아크릴 폴리비닐 아세탈 필름, 조성물, 및 열 접합성 물품 |
| CN107223140A (zh) | 2015-02-12 | 2017-09-29 | 3M创新有限公司 | 包含全氟烷氧基烷基侧基的四氟乙烯/六氟丙烯共聚物 |
| WO2016130911A1 (en) | 2015-02-12 | 2016-08-18 | 3M Innovative Properties Company | Tetrafluoroethylene/hexafluoropropylene copolymers including perfluoroalkoxyalkyl pendant groups and methods of making and using the same |
| US10844152B2 (en) | 2015-02-12 | 2020-11-24 | 3M Innovative Properties Company | Tetrafluoroethylene and perfluorinated allyl ether copolymers |
| WO2016160252A1 (en) | 2015-03-30 | 2016-10-06 | 3M Innovative Properties Company | Microstructured optical film comprising low refractive index layer disposed on base film substrate |
| WO2017031127A1 (en) | 2015-08-20 | 2017-02-23 | 3M Innovative Properties Company | Functionalized polyester polymers and film articles |
| JP6941604B2 (ja) | 2015-09-23 | 2021-09-29 | スリーエム イノベイティブ プロパティズ カンパニー | スルホニルペンダント基を有するテトラフルオロエチレンのコポリマーを作製する方法 |
| WO2017066266A1 (en) | 2015-10-13 | 2017-04-20 | 3M Innovative Properties Company | Fluoropolymer processing additive, compositions, and methods |
| EP3365389A4 (en) | 2015-10-23 | 2019-05-29 | 3M Innovative Properties Company | COMPOSITION WITH AMORPHIC FLUOROPOLYMER AND FLUOROON PLASTIC PARTICLES AND METHOD FOR THE PRODUCTION THEREOF |
| WO2017083688A1 (en) | 2015-11-13 | 2017-05-18 | 3M Innovative Properties Company | Compositions including a bimodal blend of amorphous fluoropolymers and their uses |
| WO2017112458A1 (en) | 2015-12-22 | 2017-06-29 | 3M Innovative Properties Company | Acrylic polyvinyl acetal graphic films |
| CN108430766B (zh) | 2015-12-22 | 2020-11-10 | 3M创新有限公司 | 包括结构化层的丙烯酸类膜 |
| JP7030054B2 (ja) | 2015-12-22 | 2022-03-04 | スリーエム イノベイティブ プロパティズ カンパニー | 接着剤層を備えたアクリルポリビニルアセタールフィルム |
| US11034830B2 (en) | 2015-12-22 | 2021-06-15 | 3M Innovative Properties Company | Acrylic polyvinyl acetal films comprising a second layer |
| KR20180104305A (ko) | 2016-01-21 | 2018-09-20 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 플루오로중합체의 적층 가공 |
| TW201815845A (zh) | 2016-05-17 | 2018-05-01 | 3M新設資產公司 | 包括二氟亞乙烯與四氟乙烯的共聚物之組成物及其使用方法 |
| US20190344496A1 (en) | 2016-12-20 | 2019-11-14 | 3M Innovative Properties Company | Composition including fluoropolymer and inorganic filler and method of making a three-dimensional article |
| EP3681948A4 (en) | 2017-09-14 | 2021-07-14 | 3M Innovative Properties Company | FLUORINATED COPOLYMER WITH SULFONYL SIDE GROUPS AS WELL AS COMPOSITIONS AND ARTICLES THEREFORE |
| CN111511711A (zh) | 2017-12-21 | 2020-08-07 | 3M创新有限公司 | 制备多官能多氟化合物的方法 |
| RU2018141773A (ru) | 2018-11-27 | 2020-05-27 | 3М Инновейтив Пропертиз Компани | Композиции полимерных процессинговых добавок и изделия, полученные с использованием указанных композиций |
| CN113195613A (zh) | 2018-12-17 | 2021-07-30 | 3M创新有限公司 | 包含可固化含氟聚合物和固化剂的组合物及其制备和使用方法 |
| WO2020183306A1 (en) | 2019-03-12 | 2020-09-17 | 3M Innovative Properties Company | Dispersible perfluorosulfonic acid ionomer compositions |
| JP2022535815A (ja) | 2019-06-04 | 2022-08-10 | スリーエム イノベイティブ プロパティズ カンパニー | 多官能性フッ素化化合物、その化合物から製造されるフッ素化ポリマー、及び関連方法 |
| WO2021046266A1 (en) | 2019-09-05 | 2021-03-11 | 3M Innovative Properties Company | Composition and article including fluoropolymer and branched silsesquioxane polymer |
| JP2023504273A (ja) | 2019-12-02 | 2023-02-02 | スリーエム イノベイティブ プロパティズ カンパニー | ペルフルオロスルホン酸アイオノマーの分散性粒子 |
| US20230027292A1 (en) * | 2019-12-13 | 2023-01-26 | Chromis Fiberoptics, Inc. | Amorphous fluorinated copolymers and methods of making and using the same |
| US20230015548A1 (en) * | 2019-12-17 | 2023-01-19 | The Chemours Company Fc, Llc | Ultra-low temperature elastomeric fluoropolymer compositions and processes for preparing the same |
| CN114901710B (zh) | 2019-12-20 | 2024-01-30 | 3M创新有限公司 | 氟化共聚物以及包括其的组合物和制品 |
| EP4081498A1 (en) | 2019-12-23 | 2022-11-02 | 3M Innovative Properties Company | Process of making fluoroolefins by thermal decomposition of fluorinated ionomers |
| WO2021137084A1 (en) | 2019-12-30 | 2021-07-08 | 3M Innovative Properties Company | Composition including fluoropolymer, benzoyl peroxide, and crosslinker and related articles and methods |
| EP4133542A1 (en) | 2020-04-09 | 2023-02-15 | 3M Innovative Properties Company | Composite including fluorinated polymer and salt nanoparticles and articles including the same |
| WO2021214664A1 (en) | 2020-04-21 | 2021-10-28 | 3M Innovative Properties Company | Particles including polytetrafluoroethylene and process for making a three-dimensional article |
| US20230279192A1 (en) | 2020-06-08 | 2023-09-07 | 3M Innovative Properties Company | Process for recycling a solid article including a fluorinated polymer |
| US20240132643A1 (en) | 2021-02-26 | 2024-04-25 | 3M Innovative Properties Company | Process for Making a Fluoropolymer and Fluoropolymer Made Therefrom |
| WO2022189938A1 (en) | 2021-03-10 | 2022-09-15 | 3M Innovative Properties Company | Branched silsesquioxane polymer and compositions and articles including the same |
| US20250239638A1 (en) | 2021-10-07 | 2025-07-24 | 3M Innovative Properties Company | Composite including fluorinated polymer and lithium fluoride nanoparticles and articles including the same |
| WO2023111750A1 (en) | 2021-12-13 | 2023-06-22 | 3M Innovative Properties Company | Process for recycling a solid article including a fluorinated polymer |
| WO2023224824A1 (en) | 2022-05-17 | 2023-11-23 | Dupont Specialty Products Usa, Llc | Method of making halo (alkyl vinyl) ether monomers and fluorinated polymers made with the halo (alkyl vinyl) ether monomer |
| CN120584153A (zh) | 2023-01-27 | 2025-09-02 | 杜邦特种产品美国有限责任公司 | 氟聚合物组合物以及由其制成的制品 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3450684A (en) * | 1963-07-24 | 1969-06-17 | Du Pont | Fluorocarbon polyethers |
| GB1145445A (en) | 1966-02-16 | 1969-03-12 | Du Pont | Fluorinated perfluorovinylethers, their preparation and copolymers thereof |
| US3470176A (en) | 1967-03-10 | 1969-09-30 | Minnesota Mining & Mfg | Catalyzed nitrile trimerization process |
| US3523118A (en) | 1967-05-01 | 1970-08-04 | Hooker Chemical Corp | Perfluoroalkyl-s-triazines |
| US3632788A (en) | 1968-11-25 | 1972-01-04 | Minnesota Mining & Mfg | Perfluoro olefin vinylidene fluoride elastomer product and process |
| CA950923A (en) | 1971-03-29 | 1974-07-09 | E. I. Du Pont De Nemours And Company | Polymers of perfluorovinyl ethers |
| US4005142A (en) | 1975-09-04 | 1977-01-25 | The United States Of America As Represented By The Secretary Of The Air Force | Fluorocarbon ether bis(o-aminophenol) compounds |
| JPS5718710A (en) * | 1980-07-08 | 1982-01-30 | Asahi Glass Co Ltd | Copolymer capable of giving elastomer containing fluorine having improved cold and oil resistance |
| JPS57109810A (en) | 1980-12-26 | 1982-07-08 | Asahi Glass Co Ltd | Copolymer giving fluorine-containing elastomer with cold and alcohol resistance |
| US4434106A (en) | 1982-04-06 | 1984-02-28 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Process for preparing perfluorotriazine elastomers and precursors thereof |
| US4525539A (en) | 1982-12-02 | 1985-06-25 | E. I. Du Pont De Nemours And Company | Vulcanizable nitrile-containing perfluoroelastomer |
| US4529784A (en) * | 1983-07-11 | 1985-07-16 | E. I. Du Pont De Nemours And Company | Fluorinated copolymers with improved cure site |
| JPS6150486A (ja) * | 1984-08-20 | 1986-03-12 | Victor Co Of Japan Ltd | 円盤状情報信号記録媒体再生装置 |
| JPH0822829B2 (ja) * | 1987-04-25 | 1996-03-06 | ダイキン工業株式会社 | 新規フルオロビニルエーテル及びその共重合体 |
| DE3863965D1 (de) | 1987-04-25 | 1991-09-05 | Daikin Ind Ltd | Fluorierte vinylaether. |
| US4912171A (en) | 1988-04-01 | 1990-03-27 | Minnesota Mining And Manufacturing Company | Fluoroelastomer curing process with phosphonium compound |
| IT1247934B (it) * | 1991-05-15 | 1995-01-05 | Ausimont Spa | Fluoroelastomeri a base di vinilidenfluoruro, dotati di superiore resistenza alle basi |
| US5214106A (en) | 1991-05-22 | 1993-05-25 | E. I. Du Pont De Nemours And Company | Cured fluoroelastomer compositions |
| JP3259317B2 (ja) | 1992-02-14 | 2002-02-25 | 日本メクトロン株式会社 | パ−オキサイド加硫可能な含フッ素エラストマ−の製造方法 |
| US5268405A (en) | 1993-03-31 | 1993-12-07 | E. I. Du Pont De Nemours And Company | Low temperature perfluoroelastomers |
| JP3599390B2 (ja) | 1994-11-04 | 2004-12-08 | 日本メクトロン株式会社 | パーフルオロ不飽和ニトリル化合物およびその製造法 |
| JP3327016B2 (ja) * | 1994-12-06 | 2002-09-24 | ダイキン工業株式会社 | 低温シール性に優れたフッ素ゴム共重合体及びその硬化用組成物 |
| DE19542501A1 (de) * | 1995-11-15 | 1997-05-22 | Bayer Ag | Peroxidisch vernetzbare Fluorkautschuke, ein Verfahren zu deren Herstellung und deren Verwendung |
| US5891965A (en) * | 1997-01-06 | 1999-04-06 | Dyneon Llc | Low temperature perfluoroether-containing fluoroelastomers |
-
1999
- 1999-05-18 US US09/313,438 patent/US6294627B1/en not_active Expired - Lifetime
- 1999-07-21 JP JP2000567586A patent/JP4570780B2/ja not_active Expired - Fee Related
- 1999-07-21 CN CNB998116653A patent/CN1147514C/zh not_active Expired - Fee Related
- 1999-07-21 CA CA002341460A patent/CA2341460A1/en not_active Abandoned
- 1999-07-21 EP EP99935827A patent/EP1117710B1/en not_active Expired - Lifetime
- 1999-07-21 WO PCT/US1999/016561 patent/WO2000012574A1/en not_active Ceased
- 1999-07-21 RU RU2001105952/04A patent/RU2261871C2/ru not_active IP Right Cessation
- 1999-07-21 DE DE69913550T patent/DE69913550T2/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| RU2261871C2 (ru) | 2005-10-10 |
| JP2002523576A (ja) | 2002-07-30 |
| WO2000012574A1 (en) | 2000-03-09 |
| US6294627B1 (en) | 2001-09-25 |
| CA2341460A1 (en) | 2000-03-09 |
| EP1117710A1 (en) | 2001-07-25 |
| DE69913550D1 (de) | 2004-01-22 |
| EP1117710B1 (en) | 2003-12-10 |
| CN1147514C (zh) | 2004-04-28 |
| CN1321170A (zh) | 2001-11-07 |
| DE69913550T2 (de) | 2004-09-23 |
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