JP4570017B2 - 電圧安定性を向上したカスケード式有機電場発光デバイス - Google Patents
電圧安定性を向上したカスケード式有機電場発光デバイス Download PDFInfo
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- JP4570017B2 JP4570017B2 JP2003349868A JP2003349868A JP4570017B2 JP 4570017 B2 JP4570017 B2 JP 4570017B2 JP 2003349868 A JP2003349868 A JP 2003349868A JP 2003349868 A JP2003349868 A JP 2003349868A JP 4570017 B2 JP4570017 B2 JP 4570017B2
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- IYCCMKNEBXSMIX-UHFFFAOYSA-N N-[4-[4-(N-coronen-1-ylanilino)phenyl]phenyl]-N-phenylcoronen-1-amine 2-N,2-N,6-N,6-N-tetrakis(4-methylphenyl)naphthalene-2,6-diamine 2-N,2-N,6-N,6-N-tetranaphthalen-1-ylnaphthalene-2,6-diamine Chemical compound C1=CC(C)=CC=C1N(C=1C=C2C=CC(=CC2=CC=1)N(C=1C=CC(C)=CC=1)C=1C=CC(C)=CC=1)C1=CC=C(C)C=C1.C1=CC=C2C(N(C=3C=C4C=CC(=CC4=CC=3)N(C=3C4=CC=CC=C4C=CC=3)C=3C4=CC=CC=C4C=CC=3)C=3C4=CC=CC=C4C=CC=3)=CC=CC2=C1.C1=CC=CC=C1N(C=1C2=CC=C3C=CC4=CC=C5C=CC6=CC=C(C7=C6C5=C4C3=C72)C=1)C1=CC=C(C=2C=CC(=CC=2)N(C=2C=CC=CC=2)C=2C3=CC=C4C=CC5=CC=C6C=CC7=CC=C(C8=C7C6=C5C4=C83)C=2)C=C1 IYCCMKNEBXSMIX-UHFFFAOYSA-N 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 229910052771 Terbium Inorganic materials 0.000 description 1
- XBDYBAVJXHJMNQ-UHFFFAOYSA-N Tetrahydroanthracene Natural products C1=CC=C2C=C(CCCC3)C3=CC2=C1 XBDYBAVJXHJMNQ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910052769 Ytterbium Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- GENZLHCFIPDZNJ-UHFFFAOYSA-N [In+3].[O-2].[Mg+2] Chemical compound [In+3].[O-2].[Mg+2] GENZLHCFIPDZNJ-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 125000005605 benzo group Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000005606 carbostyryl group Chemical group 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000002220 fluorenes Chemical class 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- WIAWDMBHXUZQGV-UHFFFAOYSA-N heptacyclo[13.10.1.12,6.011,26.017,25.018,23.010,27]heptacosa-1(25),2,4,6(27),7,9,11,13,15(26),17,19,21,23-tridecaene Chemical group C=12C3=CC=CC2=CC=CC=1C1=CC=CC2=C1C3=C1C=C3C=CC=CC3=C1C2 WIAWDMBHXUZQGV-UHFFFAOYSA-N 0.000 description 1
- 229940058961 hydroxyquinoline derivative for amoebiasis and other protozoal diseases Drugs 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 238000000608 laser ablation Methods 0.000 description 1
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 1
- FQHFBFXXYOQXMN-UHFFFAOYSA-M lithium;quinolin-8-olate Chemical compound [Li+].C1=CN=C2C([O-])=CC=CC2=C1 FQHFBFXXYOQXMN-UHFFFAOYSA-M 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 230000001404 mediated effect Effects 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- CLTPAQDLCMKBIS-UHFFFAOYSA-N n-[4-[4-(dinaphthalen-1-ylamino)phenyl]phenyl]-n-naphthalen-1-ylnaphthalen-1-amine Chemical compound C1=CC=C2C(N(C=3C=CC(=CC=3)C=3C=CC(=CC=3)N(C=3C4=CC=CC=C4C=CC=3)C=3C4=CC=CC=C4C=CC=3)C=3C4=CC=CC=C4C=CC=3)=CC=CC2=C1 CLTPAQDLCMKBIS-UHFFFAOYSA-N 0.000 description 1
- TUPXWIUQIGEYST-UHFFFAOYSA-N n-[4-[4-(n-phenanthren-2-ylanilino)phenyl]phenyl]-n-phenylphenanthren-2-amine Chemical group C1=CC=CC=C1N(C=1C=C2C(C3=CC=CC=C3C=C2)=CC=1)C1=CC=C(C=2C=CC(=CC=2)N(C=2C=CC=CC=2)C=2C=C3C(C4=CC=CC=C4C=C3)=CC=2)C=C1 TUPXWIUQIGEYST-UHFFFAOYSA-N 0.000 description 1
- LOGWGDZTCDJKJZ-UHFFFAOYSA-N n-[4-[4-[n-(1,2-dihydroacenaphthylen-3-yl)anilino]phenyl]phenyl]-n-phenyl-1,2-dihydroacenaphthylen-3-amine;n-[4-[4-(n-naphthalen-2-ylanilino)phenyl]phenyl]-n-phenylnaphthalen-2-amine;n-[4-[4-[4-(n-naphthalen-1-ylanilino)phenyl]phenyl]phenyl]-n-phenylnapht Chemical group C1=CC=CC=C1N(C=1C=C2C=CC=CC2=CC=1)C1=CC=C(C=2C=CC(=CC=2)N(C=2C=CC=CC=2)C=2C=C3C=CC=CC3=CC=2)C=C1.C1=CC(C2=3)=CC=CC=3CCC2=C1N(C=1C=CC(=CC=1)C=1C=CC(=CC=1)N(C=1C=CC=CC=1)C=1C=2CCC3=CC=CC(C=23)=CC=1)C1=CC=CC=C1.C1=CC=CC=C1N(C=1C2=CC=CC=C2C=CC=1)C1=CC=C(C=2C=CC(=CC=2)C=2C=CC(=CC=2)N(C=2C=CC=CC=2)C=2C3=CC=CC=C3C=CC=2)C=C1 LOGWGDZTCDJKJZ-UHFFFAOYSA-N 0.000 description 1
- SBMXAWJSNIAHFR-UHFFFAOYSA-N n-naphthalen-2-ylnaphthalen-2-amine Chemical compound C1=CC=CC2=CC(NC=3C=C4C=CC=CC4=CC=3)=CC=C21 SBMXAWJSNIAHFR-UHFFFAOYSA-N 0.000 description 1
- UHVLDCDWBKWDDN-UHFFFAOYSA-N n-phenyl-n-[4-[4-(n-pyren-2-ylanilino)phenyl]phenyl]pyren-2-amine Chemical group C1=CC=CC=C1N(C=1C=C2C=CC3=CC=CC4=CC=C(C2=C43)C=1)C1=CC=C(C=2C=CC(=CC=2)N(C=2C=CC=CC=2)C=2C=C3C=CC4=CC=CC5=CC=C(C3=C54)C=2)C=C1 UHVLDCDWBKWDDN-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- USPVIMZDBBWXGM-UHFFFAOYSA-N nickel;oxotungsten Chemical compound [Ni].[W]=O USPVIMZDBBWXGM-UHFFFAOYSA-N 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 238000001579 optical reflectometry Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 1
- 229920002098 polyfluorene Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 150000004032 porphyrins Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- WVIICGIFSIBFOG-UHFFFAOYSA-N pyrylium Chemical compound C1=CC=[O+]C=C1 WVIICGIFSIBFOG-UHFFFAOYSA-N 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- YYMBJDOZVAITBP-UHFFFAOYSA-N rubrene Chemical compound C1=CC=CC=C1C(C1=C(C=2C=CC=CC=2)C2=CC=CC=C2C(C=2C=CC=CC=2)=C11)=C(C=CC=C2)C2=C1C1=CC=CC=C1 YYMBJDOZVAITBP-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 150000003967 siloles Chemical class 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 150000004772 tellurides Chemical class 0.000 description 1
- IFLREYGFSNHWGE-UHFFFAOYSA-N tetracene Chemical compound C1=CC=CC2=CC3=CC4=CC=CC=C4C=C3C=C21 IFLREYGFSNHWGE-UHFFFAOYSA-N 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- IBBLKSWSCDAPIF-UHFFFAOYSA-N thiopyran Chemical compound S1C=CC=C=C1 IBBLKSWSCDAPIF-UHFFFAOYSA-N 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- YVTHLONGBIQYBO-UHFFFAOYSA-N zinc indium(3+) oxygen(2-) Chemical compound [O--].[Zn++].[In+3] YVTHLONGBIQYBO-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
- H10K50/19—Tandem OLEDs
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B33/00—Electroluminescent light sources
- H05B33/12—Light sources with substantially two-dimensional radiating surfaces
- H05B33/14—Light sources with substantially two-dimensional radiating surfaces characterised by the chemical or physical composition or the arrangement of the electroluminescent material, or by the simultaneous addition of the electroluminescent material in or onto the light source
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
- H10K50/14—Carrier transporting layers
- H10K50/15—Hole transporting layers
- H10K50/155—Hole transporting layers comprising dopants
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
- H10K50/14—Carrier transporting layers
- H10K50/16—Electron transporting layers
- H10K50/165—Electron transporting layers comprising dopants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/917—Electroluminescent
Description
本発明の別の目的は、電圧安定性を向上させたカスケード式OLEDを製造することにある。
a)アノード;
b)カソード;
c)該アノードと該カソードとの間に配置された複数の有機電場発光ユニットであって、少なくとも正孔輸送層及び電子輸送層を含むもの;並びに
d)各隣接有機電場発光ユニット間に配置された連結ユニットであって、順に、n型ドープト有機層、界面層及びp型ドープト有機層を含み、該界面層が該n型ドープト有機層と該p型ドープト有機層との間における拡散又は反応を防止するもの
を含んで成るカスケード式有機電場発光デバイスによって達成される。
本発明の別の有利な効果として、当該カスケード式OLEDは、動作時の駆動電圧が非常に安定していることが挙げられる。
本発明の別の有利な効果として、当該カスケード式OLEDは、従来型のOLEDと同一電流下で動作させた場合に、明るさが増大することが挙げられる。
本発明の別の有利な効果として、当該カスケード式OLEDは、従来のスタック型OLEDと比較して、駆動電圧が低く、かつ、光学的出力が高いことが挙げられる。
本発明の別の有利な効果として、当該カスケード式OLEDをランプにおいて有効に使用できることが挙げられる。
1,1-ビス(4-ジ-p-トリルアミノフェニル)-4-フェニルシクロヘキサン
4,4’-ビス(ジフェニルアミノ)クアドリフェニル
ビス(4-ジメチルアミノ-2-メチルフェニル)-フェニルメタン
N,N,N-トリ(p-トリル)アミン
4-(ジ-p-トリルアミノ)-4’-[4(ジ-p-トリルアミノ)-スチリル]スチルベン
N,N,N’,N’-テトラ-p-トリル-4,4’-ジアミノビフェニル
N,N,N’,N’-テトラフェニル-4,4’-ジアミノビフェニル
N,N,N’,N’-テトラ-1-ナフチル-4,4’-ジアミノビフェニル
N,N,N’,N’-テトラ-2-ナフチル-4,4’-ジアミノビフェニル
N-フェニルカルバゾール
4,4’-ビス[N-(1-ナフチル)-N-フェニルアミノ]ビフェニル
4,4’-ビス[N-(1-ナフチル)-N-(2-ナフチル)アミノ]ビフェニル
4,4”-ビス[N-(1-ナフチル)-N-フェニルアミノ]-p-ターフェニル
4,4’-ビス[N-(2-ナフチル)-N-フェニルアミノ]ビフェニル
4,4’-ビス[N-(3-アセナフテニル)-N-フェニルアミノ]ビフェニル
1,5-ビス[N-(1-ナフチル)-N-フェニルアミノ]ナフタレン
4,4’-ビス[N-(9-アントリル)-N-フェニルアミノ]ビフェニル
4,4”-ビス[N-(1-アントリル)-N-フェニルアミノ]-p-ターフェニル
4,4’-ビス[N-(2-フェナントリル)-N-フェニルアミノ]ビフェニル
4,4’-ビス[N-(8-フルオルアンテニル)-N-フェニルアミノ]ビフェニル
4,4’-ビス[N-(2-ピレニル)-N-フェニルアミノ]ビフェニル
4,4’-ビス[N-(2-ナフタセニル)-N-フェニルアミノ]ビフェニル
4,4’-ビス[N-(2-ペリレニル)-N-フェニルアミノ]ビフェニル
4,4’-ビス[N-(1-コロネニル)-N-フェニルアミノ]ビフェニル
2,6-ビス(ジ-p-トリルアミノ)ナフタレン
2,6-ビス[ジ-(1-ナフチル)アミノ]ナフタレン
2,6-ビス[N-(1-ナフチル)-N-(2-ナフチル)アミノ]ナフタレン
N,N,N’,N’-テトラ(2-ナフチル)-4,4”-ジアミノ-p-ターフェニル
4,4’-ビス{N-フェニル-N-[4-(1-ナフチル)-フェニル]アミノ}ビフェニル
4,4’-ビス[N-フェニル-N-(2-ピレニル)アミノ]ビフェニル
2,6-ビス[N,N-ジ(2-ナフチル)アミン]フルオレン
1,5-ビス[N-(1-ナフチル)-N-フェニルアミノ]ナフタレン
4,4',4"-トリス[(3-メチルフェニル)フェニルアミノ]トリフェニルアミン
CO-1:アルミニウムトリスオキシン〔別名、トリス(8-キノリノラト)アルミニウム(III)〕
CO-2:マグネシウムビスオキシン〔別名、ビス(8-キノリノラト)マグネシウム(II)〕
CO-3:ビス[ベンゾ{f}-8-キノリノラト]亜鉛(II)
CO-4:ビス(2-メチル-8-キノリノラト)アルミニウム(III)-μ-オキソ-ビス(2-メチル-8-キノリノラト)アルミニウム(III)
CO-5:インジウムトリスオキシン〔別名、トリス(8-キノリノラト)インジウム〕
CO-6:アルミニウムトリス(5-メチルオキシン)〔別名、トリス(5-メチル-8-キノリノラト)アルミニウム(III)〕
CO-7:リチウムオキシン〔別名、(8-キノリノラト)リチウム(I)〕
CO-8:ガリウムオキシン〔別名、トリス(8-キノリノラト)ガリウム(III)〕
CO-9:ジルコニウムオキシン〔別名、テトラ(8-キノリノラト)ジルコニウム(IV)〕
本明細書において引用した特許明細書その他の刊行物の内容全体を本明細書の一部とする。
ITO:インジウム錫酸化物;ガラス基板上に透明アノードを形成する際に使用
CFx:フルオロカーボン重合体層;ITO上に正孔注入層を形成する際に使用
NPB: N,N'-ジ(ナフタレン-1-イル)-N,N'-ジフェニル-ベンジジン;有機ELユニットの正孔輸送層を形成する際に使用し、また連結ユニットのp型ドープト有機層を形成する際にホストとして使用
Alq:トリス(8-ヒドロキシキノリン)アルミニウム(III);有機ELユニットの電子輸送層及び発光層の双方を形成する際に使用し、また連結ユニットのn型ドープト有機層を形成する際にホストとして使用
F4-TCNQ:2,3,5,6-テトラフルオロ-7,7,8,8-テトラシアノキノジメタン;連結ユニットのp型ドープト有機層を形成する際にp型ドーパントとして使用
Li:リチウム;連結ユニットのn型ドープト有機層を形成する際にn型ドーパントとして使用
Mg:Ag:容積比10:0.5のマグネシウム:銀;カソードを形成する際に使用
従来型の非カスケード式OLEDを以下のように製作した。市販のガラススクラバーツールを使用して、透明ITO導電層を被覆した厚さ1.1mm以下のガラス基板を洗浄して乾燥した。ITOの厚さは約42nmであり、ITOのシート抵抗は約68Ω/□である。次いで、そのITO面を酸化的プラズマで処理して当該表面をアノードとして状態調節した。きれいなITO面上に、RFプラズマ処理チャンバ内でCHF3ガスを分解させることにより、HILとして厚さ1nmのCFx層を付着させた。次いで、基板を真空蒸着チャンバ内に移送して、該基板上にその他すべての層を付着させた。下記の層を、約10-6Torrの真空下で加熱ボートから昇華させ、下記の順序で付着させた。
(1)NPBからなる厚さ75nmのHTL
(2)Alqからなる厚さ60nmのETL(発光層としても作用)
(3)Mg:Agからなる厚さ約210nmのカソード
カスケード式OLEDを以下のように製作した。市販のガラススクラバーツールを使用して、透明ITO導電層を被覆した厚さ1.1mm以下のガラス基板を洗浄して乾燥した。ITOの厚さは約42nmであり、ITOのシート抵抗は約68Ω/□である。次いで、そのITO面を酸化的プラズマで処理して当該表面をアノードとして状態調節した。きれいなITO面上に、RFプラズマ処理チャンバ内でCHF3ガスを分解させることにより、HILとして厚さ1nmのCFx層を付着させた。次いで、基板を真空蒸着チャンバ内に移送して、該基板上にその他すべての層を付着させた。下記の層を、約10-6Torrの真空下で加熱ボートから昇華させ、下記の順序で付着させた。
(2)Alqからなる厚さ30nmのETL(発光層としても作用)
[NPB(90nm)/Alq(30nm)、EL1と表示、第1ELユニットを構成]
(3)Alqホストに1.2体積%のLiをドープしてなる厚さ30nmのn型ドープト有機層
(4)NPBホストに6体積%のF4-TCNQをドープしてなる厚さ60nmのp型ドープト有機層
[Liドープ型Alq(30nm)/F4-TCNQドープ型NPB(60nm)が第1連結ユニットを構成]
(5)NPBからなる厚さ30nmのHTL
(6)Alqからなる厚さ30nmのLEL
(7)Alqホストに1.2体積%のLiをドープしてなる厚さ30nmのETL
[NPB(30nm)/Alq(30nm)/Alq:Li(30nm)、EL2と表示、第2ELユニットを構成]
(8)Mg:Agからなる厚さ約210nmのカソード
カスケード式OLEDを、例2と同様に製作したが、但し、当該連結ユニットのLiドープ型Alq層とF4-TCNQドープ型NPB層との間に厚さ2nmのPbOを配置した。
本カスケード式デバイス構造をITO/CFx/EL1/Alq:Li(30nm)/PbO(2nm)/NPB:F4-TCNQ(60nm)/EL2/Mg:Agと表示する。
カスケード式OLEDを、例2と同様に製作したが、但し、当該連結ユニットのLiドープ型Alq層とF4-TCNQドープ型NPB層との間に厚さ4nmのSb2O5を配置した。
本カスケード式デバイス構造をITO/CFx/EL1/Alq:Li(30nm)/Sb2O5(4nm)/NPB:F4-TCNQ(60nm)/EL2/Mg:Agと表示する。
カスケード式OLEDを、例2と同様に製作したが、但し、当該連結ユニットのLiドープ型Alq層とF4-TCNQドープ型NPB層との間に厚さ0.5nmのAgを配置した。
本カスケード式デバイス構造をITO/CFx/EL1/Alq:Li(30nm)/Ag(0.5nm)/NPB:F4-TCNQ(60nm)/EL2/Mg:Agと表示する。
Claims (9)
- a)アノード;
b)カソード;
c)該アノードと該カソードとの間に配置された複数の有機電場発光ユニットであって、少なくとも正孔輸送層及び電子輸送層を含むもの;並びに
d)各隣接有機電場発光ユニット間に配置された連結ユニットであって、順に、n型ドープト有機層、界面層及びp型ドープト有機層を含み、該界面層が該n型ドープト有機層と該p型ドープト有機層との間における拡散又は反応を防止するもの
を含んで成るカスケード式有機電場発光デバイス。 - 該界面層がスペクトルの可視領域において90%以上の光透過率を有する、請求項1に記載のカスケード式有機電場発光デバイス。
- 該界面層が、電子エネルギーバンドギャップが4.0eV未満である少なくとも1種の材料を含む、請求項1に記載のカスケード式有機電場発光デバイス。
- 該界面層が、PbO、Sb 2 O 5 又はAgを含む、請求項1に記載のカスケード式有機電場発光デバイス。
- 該界面層の厚さが0.1nm〜10nmの範囲内にある、請求項1に記載のカスケード式有機電場発光デバイス。
- 該界面層の厚さが0.1nm〜5nmの範囲内にある、請求項1に記載のカスケード式有機電場発光デバイス。
- 該界面層が熱蒸発法で調製されたものである、請求項1に記載のカスケード式有機電場発光デバイス。
- 該界面層が電子ビーム蒸発法で調製されたものである、請求項1に記載のカスケード式有機電場発光デバイス。
- 該界面層がイオンスパッタ法で調製されたものである、請求項1に記載のカスケード式有機電場発光デバイス。
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Families Citing this family (174)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100721656B1 (ko) * | 2005-11-01 | 2007-05-23 | 주식회사 엘지화학 | 유기 전기 소자 |
SG176316A1 (en) * | 2001-12-05 | 2011-12-29 | Semiconductor Energy Lab | Organic semiconductor element |
US6872472B2 (en) * | 2002-02-15 | 2005-03-29 | Eastman Kodak Company | Providing an organic electroluminescent device having stacked electroluminescent units |
JP3933591B2 (ja) | 2002-03-26 | 2007-06-20 | 淳二 城戸 | 有機エレクトロルミネッセント素子 |
EP1367659B1 (en) * | 2002-05-21 | 2012-09-05 | Semiconductor Energy Laboratory Co., Ltd. | Organic field effect transistor |
JP4027164B2 (ja) * | 2002-06-21 | 2007-12-26 | 株式会社日立製作所 | 表示装置 |
US6876144B2 (en) * | 2002-09-09 | 2005-04-05 | Kuan-Chang Peng | Organic electroluminescent device having host material layer intermixed with luminescent material |
US7317047B2 (en) * | 2002-09-24 | 2008-01-08 | E.I. Du Pont De Nemours And Company | Electrically conducting organic polymer/nanoparticle composites and methods for use thereof |
TWI302563B (en) * | 2002-09-24 | 2008-11-01 | Du Pont | Electrically conducting organic polymer/nanoparticle composites and methods for use thereof |
CA2499377A1 (en) | 2002-09-24 | 2004-04-08 | E. I. Du Pont De Nemours And Company | Water dispersible polythiophenes made with polymeric acid colloids |
WO2004029133A1 (en) * | 2002-09-24 | 2004-04-08 | E.I. Du Pont De Nemours And Company | Water dispersible polyanilines made with polymeric acid colloids for electronics applications |
JP2004200141A (ja) * | 2002-10-24 | 2004-07-15 | Toyota Industries Corp | 有機el素子 |
US6991859B2 (en) * | 2003-03-18 | 2006-01-31 | Eastman Kodak Company | Cascaded organic electroluminescent devices |
US7390438B2 (en) * | 2003-04-22 | 2008-06-24 | E.I. Du Pont De Nemours And Company | Water dispersible substituted polydioxythiophenes made with fluorinated polymeric sulfonic acid colloids |
EP2182777A1 (en) * | 2003-04-24 | 2010-05-05 | Idemitsu Kosan Co., Ltd. | Organic electroluminescent device and display |
US6936961B2 (en) * | 2003-05-13 | 2005-08-30 | Eastman Kodak Company | Cascaded organic electroluminescent device having connecting units with N-type and P-type organic layers |
US8007924B2 (en) * | 2003-07-02 | 2011-08-30 | Idemitsu Kosan Co., Ltd. | Organic electroluminescent device and display using same |
US7504049B2 (en) * | 2003-08-25 | 2009-03-17 | Semiconductor Energy Laboratory Co., Ltd. | Electrode device for organic device, electronic device having electrode device for organic device, and method of forming electrode device for organic device |
US7511421B2 (en) * | 2003-08-25 | 2009-03-31 | Semiconductor Energy Laboratory Co., Ltd. | Mixed metal and organic electrode for organic device |
TW200513138A (en) * | 2003-09-23 | 2005-04-01 | Guan-Chang Peng | Organic light Emitting Device (OLED) |
JP4243237B2 (ja) * | 2003-11-10 | 2009-03-25 | 淳二 城戸 | 有機素子、有機el素子、有機太陽電池、及び、有機fet構造、並びに、有機素子の製造方法 |
CN101673808B (zh) * | 2003-12-26 | 2012-05-23 | 株式会社半导体能源研究所 | 发光元件 |
US7351358B2 (en) | 2004-03-17 | 2008-04-01 | E.I. Du Pont De Nemours And Company | Water dispersible polypyrroles made with polymeric acid colloids for electronics applications |
US8147962B2 (en) | 2004-04-13 | 2012-04-03 | E. I. Du Pont De Nemours And Company | Conductive polymer composites |
KR101197688B1 (ko) * | 2004-04-28 | 2012-11-05 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 발광소자 및 그 제조방법, 및 상기 발광소자를 사용한 발광장치 |
CN1965613B (zh) * | 2004-05-21 | 2010-06-16 | 株式会社半导体能源研究所 | 发光元件及使用该元件的发光装置 |
JP4461367B2 (ja) * | 2004-05-24 | 2010-05-12 | ソニー株式会社 | 表示素子 |
US7126267B2 (en) * | 2004-05-28 | 2006-10-24 | Eastman Kodak Company | Tandem OLED having stable intermediate connectors |
US7169232B2 (en) * | 2004-06-01 | 2007-01-30 | Eastman Kodak Company | Producing repetitive coatings on a flexible substrate |
JP2006295104A (ja) * | 2004-07-23 | 2006-10-26 | Semiconductor Energy Lab Co Ltd | 発光素子およびそれを用いた発光装置 |
CN100534247C (zh) * | 2004-08-03 | 2009-08-26 | 株式会社半导体能源研究所 | 发光元件和发光器件 |
US7273663B2 (en) * | 2004-08-20 | 2007-09-25 | Eastman Kodak Company | White OLED having multiple white electroluminescence units |
WO2006022193A1 (en) * | 2004-08-23 | 2006-03-02 | Semiconductor Energy Laboratory Co., Ltd. | Light emitting element, light emitting device, and lighting system |
DE102004042461A1 (de) * | 2004-08-31 | 2006-03-30 | Novaled Gmbh | Top-emittierendes, elektrolumineszierendes Bauelement mit Frequenzkonversionszentren |
EP2299781A3 (en) * | 2004-09-13 | 2011-05-04 | Semiconductor Energy Laboratory Co, Ltd. | Light emitting layer device |
CN101027799B (zh) * | 2004-09-24 | 2010-06-16 | 株式会社半导体能源研究所 | 发光器件 |
KR100719991B1 (ko) * | 2004-09-30 | 2007-05-21 | 산요덴키가부시키가이샤 | 일렉트로루미네센스 소자 |
US7964864B2 (en) * | 2004-09-30 | 2011-06-21 | Semiconductor Energy Laboratory Co., Ltd. | Light-emitting element and light-emitting device |
US7560862B2 (en) * | 2004-10-22 | 2009-07-14 | Eastman Kodak Company | White OLEDs with a color-compensated electroluminescent unit |
US20070262693A1 (en) * | 2004-10-29 | 2007-11-15 | Satoshi Seo | Composite Material, Light-Emitting Element, Light-Emitting Device and Manufacturing Method Thereof |
DE102004053631B4 (de) * | 2004-11-01 | 2008-04-30 | Samsung Sdi Germany Gmbh | Anzeigeelement auf Basis organischer lichtemittierender Materialien |
US7564052B2 (en) * | 2004-11-05 | 2009-07-21 | Semiconductor Energy Laboratory Co., Ltd. | Light-emitting element and light emitting device using the same |
US8202630B2 (en) * | 2004-11-05 | 2012-06-19 | Semiconductor Energy Laboratory Co., Ltd. | Light emitting element and light emitting device using the same |
JP5036164B2 (ja) * | 2004-11-05 | 2012-09-26 | 株式会社半導体エネルギー研究所 | 発光素子、発光装置および電子機器 |
US7776456B2 (en) * | 2004-12-03 | 2010-08-17 | Universal Display Corporation | Organic light emitting devices with an emissive region having emissive and non-emissive layers and method of making |
US7075231B1 (en) * | 2005-01-03 | 2006-07-11 | Eastman Kodak Company | Tandem OLEDs having low drive voltage |
US7166169B2 (en) * | 2005-01-11 | 2007-01-23 | Eastman Kodak Company | Vaporization source with baffle |
US7494722B2 (en) * | 2005-02-23 | 2009-02-24 | Eastman Kodak Company | Tandem OLED having an organic intermediate connector |
US8906517B2 (en) * | 2005-04-04 | 2014-12-09 | Sony Corporation | Organic electroluminescence device |
US20060250079A1 (en) * | 2005-04-05 | 2006-11-09 | The Hong Kong University Of Science And Technology | Intermediate layers treated by cf4-plasma for stacked organic light-emitting devices |
US8057916B2 (en) * | 2005-04-20 | 2011-11-15 | Global Oled Technology, Llc. | OLED device with improved performance |
US20060240277A1 (en) * | 2005-04-20 | 2006-10-26 | Eastman Kodak Company | Tandem OLED device |
US20060244370A1 (en) * | 2005-05-02 | 2006-11-02 | Eastman Kodak Company | Light-emitting layer spacing in tandem OLED devices |
US20060244371A1 (en) * | 2005-05-02 | 2006-11-02 | Eastman Kodak Company | OLED device having improved lifetime and output |
US8487527B2 (en) * | 2005-05-04 | 2013-07-16 | Lg Display Co., Ltd. | Organic light emitting devices |
US7777407B2 (en) * | 2005-05-04 | 2010-08-17 | Lg Display Co., Ltd. | Organic light emitting devices comprising a doped triazine electron transport layer |
US7811679B2 (en) * | 2005-05-20 | 2010-10-12 | Lg Display Co., Ltd. | Display devices with light absorbing metal nanoparticle layers |
US7728517B2 (en) * | 2005-05-20 | 2010-06-01 | Lg Display Co., Ltd. | Intermediate electrodes for stacked OLEDs |
US7795806B2 (en) * | 2005-05-20 | 2010-09-14 | Lg Display Co., Ltd. | Reduced reflectance display devices containing a thin-layer metal-organic mixed layer (MOML) |
US7943244B2 (en) * | 2005-05-20 | 2011-05-17 | Lg Display Co., Ltd. | Display device with metal-organic mixed layer anodes |
US7750561B2 (en) * | 2005-05-20 | 2010-07-06 | Lg Display Co., Ltd. | Stacked OLED structure |
TWI295900B (en) * | 2005-06-16 | 2008-04-11 | Au Optronics Corp | Method for improving color-shift of serially connected organic electroluminescence device |
US20070001583A1 (en) * | 2005-06-17 | 2007-01-04 | Fuji Photo Film Co., Ltd. | Light source, exposure apparatus, image display unit and medical device |
JP5489458B2 (ja) | 2005-06-28 | 2014-05-14 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 高仕事関数の透明コンダクタ |
WO2007002740A2 (en) | 2005-06-28 | 2007-01-04 | E. I. Du Pont De Nemours And Company | Buffer compositions |
US7531959B2 (en) * | 2005-06-29 | 2009-05-12 | Eastman Kodak Company | White light tandem OLED display with filters |
US7564182B2 (en) * | 2005-06-29 | 2009-07-21 | Eastman Kodak Company | Broadband light tandem OLED display |
KR100806812B1 (ko) * | 2005-07-25 | 2008-02-25 | 엘지.필립스 엘시디 주식회사 | 유기 el 소자 및 그 제조방법 |
KR100672535B1 (ko) * | 2005-07-25 | 2007-01-24 | 엘지전자 주식회사 | 유기 el 소자 및 그 제조방법 |
TW200714131A (en) * | 2005-07-29 | 2007-04-01 | Sanyo Electric Co | Organic electroluminescent element and organic electroluminescent display device |
US20070046179A1 (en) * | 2005-08-26 | 2007-03-01 | Chan-Ching Chang | Organic electro-luminescent device |
US20070046189A1 (en) * | 2005-08-31 | 2007-03-01 | Eastman Kodak Company | Intermediate connector for a tandem OLED device |
US7772761B2 (en) * | 2005-09-28 | 2010-08-10 | Osram Opto Semiconductors Gmbh | Organic electrophosphorescence device having interfacial layers |
KR100734842B1 (ko) * | 2005-10-28 | 2007-07-03 | 한국전자통신연구원 | 고출력/광대역 광소자용 유무기 나노 복합 박막 및 이를포함하는 광소자와 그 제조 방법 |
US20070098891A1 (en) * | 2005-10-31 | 2007-05-03 | Eastman Kodak Company | Vapor deposition apparatus and method |
US20070134512A1 (en) * | 2005-12-13 | 2007-06-14 | Eastman Kodak Company | Electroluminescent device containing an anthracene derivative |
EP1808909A1 (de) * | 2006-01-11 | 2007-07-18 | Novaled AG | Elekrolumineszente Lichtemissionseinrichtung |
US8680693B2 (en) * | 2006-01-18 | 2014-03-25 | Lg Chem. Ltd. | OLED having stacked organic light-emitting units |
US8216680B2 (en) * | 2006-02-03 | 2012-07-10 | E I Du Pont De Nemours And Company | Transparent composite conductors having high work function |
JP4896544B2 (ja) * | 2006-03-06 | 2012-03-14 | 富士フイルム株式会社 | 有機電界発光素子 |
JP5084305B2 (ja) * | 2006-03-08 | 2012-11-28 | 株式会社半導体エネルギー研究所 | 発光素子、発光装置並びに電子機器 |
TWI475737B (zh) | 2006-03-08 | 2015-03-01 | Semiconductor Energy Lab | 發光元件、發光裝置及電子裝置 |
US20070210705A1 (en) * | 2006-03-09 | 2007-09-13 | Hajime Yokoi | Organic electroluminescent element and manufacturing method of an organic electroluminescent element and a display |
JP2007287652A (ja) * | 2006-03-23 | 2007-11-01 | Fujifilm Corp | 発光素子 |
US7332860B2 (en) * | 2006-03-30 | 2008-02-19 | Eastman Kodak Company | Efficient white-light OLED display with filters |
KR101279315B1 (ko) * | 2006-04-18 | 2013-06-26 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 고에너지-포텐셜 이중층 조성물 |
US7951421B2 (en) * | 2006-04-20 | 2011-05-31 | Global Oled Technology Llc | Vapor deposition of a layer |
EP2355198B1 (en) | 2006-05-08 | 2015-09-09 | Global OLED Technology LLC | OLED electron-injecting layer |
CN101444141A (zh) * | 2006-05-11 | 2009-05-27 | 出光兴产株式会社 | 有机电致发光元件 |
US20070285001A1 (en) * | 2006-06-08 | 2007-12-13 | Toppoly Optoelectronics Corp. | System for displaying images |
TWI317182B (en) * | 2006-07-07 | 2009-11-11 | Au Optronics Corp | Tandem organic electroluminescent elements and uses of the same |
US20080032123A1 (en) * | 2006-08-02 | 2008-02-07 | Spindler Jeffrey P | Dual electron-transporting layer for oled device |
WO2008033388A2 (en) * | 2006-09-12 | 2008-03-20 | Qd Vision, Inc. | A composite including nanoparticles, methods, and products including a composite |
TW200816860A (en) * | 2006-09-22 | 2008-04-01 | Au Optronics Corp | Tandem organic electroluminescent elements and display using the same |
US20080180023A1 (en) * | 2006-09-28 | 2008-07-31 | Fujifilm Corporation | Organic electroluminescence element |
KR101426513B1 (ko) * | 2006-09-29 | 2014-08-05 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 퀴녹살린 유도체, 발광소자, 발광장치 및 전자기기 |
US20080191172A1 (en) * | 2006-12-29 | 2008-08-14 | Che-Hsiung Hsu | High work-function and high conductivity compositions of electrically conducting polymers |
US20080176099A1 (en) * | 2007-01-18 | 2008-07-24 | Hatwar Tukaram K | White oled device with improved functions |
JP4925903B2 (ja) * | 2007-04-13 | 2012-05-09 | 株式会社アルバック | 有機el素子、有機el素子製造方法 |
DE102007015468A1 (de) * | 2007-03-30 | 2008-10-02 | Osram Opto Semiconductors Gmbh | Organische strahlungsemittierende Vorrichtung, deren Verwendung sowie ein Herstellungsverfahren für die Vorrichtung |
US20080238300A1 (en) * | 2007-04-02 | 2008-10-02 | Sang Tae Park | Organic electroluminescence device and method for fabricating the same |
KR100859821B1 (ko) * | 2007-04-04 | 2008-09-23 | 박병주 | 이중 계면층을 갖는 유기반도체 소자 |
US20080251768A1 (en) | 2007-04-13 | 2008-10-16 | Che-Hsiung Hsu | Electrically conductive polymer compositions |
US7816859B2 (en) * | 2007-04-30 | 2010-10-19 | Global Oled Technology Llc | White light tandem OLED |
US7948165B2 (en) * | 2007-05-09 | 2011-05-24 | Global Oled Technology Llc | High-performance tandem white OLED |
US7911133B2 (en) * | 2007-05-10 | 2011-03-22 | Global Oled Technology Llc | Electroluminescent device having improved light output |
US8241526B2 (en) * | 2007-05-18 | 2012-08-14 | E I Du Pont De Nemours And Company | Aqueous dispersions of electrically conducting polymers containing high boiling solvent and additives |
US20090001885A1 (en) * | 2007-06-27 | 2009-01-01 | Spindler Jeffrey P | Tandem oled device |
DE102007058005B4 (de) * | 2007-09-25 | 2018-05-17 | Osram Oled Gmbh | Strahlungsemittierende Vorrichtung und Verfahren zu deren Herstellung |
US20090091242A1 (en) * | 2007-10-05 | 2009-04-09 | Liang-Sheng Liao | Hole-injecting layer in oleds |
JP4936069B2 (ja) * | 2007-10-31 | 2012-05-23 | 株式会社デンソー | モータ制御装置 |
WO2009067678A2 (en) * | 2007-11-24 | 2009-05-28 | Display Photonics, Inc. | Projection system based on self emitting display panel |
TWI364840B (en) * | 2007-12-03 | 2012-05-21 | Chimei Innolux Corp | Tandem organic light emitting device and method for assembling the same |
US8877350B2 (en) | 2007-12-11 | 2014-11-04 | Global Oled Technology Llc | White OLED with two blue light-emitting layers |
US7804245B2 (en) * | 2008-01-24 | 2010-09-28 | Global Oled Technology Llc | Electroluminescent device having improved brightness uniformity |
US7955719B2 (en) | 2008-01-30 | 2011-06-07 | Global Oled Technology Llc | Tandem OLED device with intermediate connector |
US7821201B2 (en) * | 2008-01-31 | 2010-10-26 | Global Oled Technology Llc | Tandem OLED device with intermediate connector |
US8115399B2 (en) * | 2008-02-19 | 2012-02-14 | General Electric Company | OLED light source |
JP5075027B2 (ja) * | 2008-06-23 | 2012-11-14 | パナソニック株式会社 | 有機エレクトロルミネッセンス素子の製造方法 |
US7977872B2 (en) * | 2008-09-16 | 2011-07-12 | Global Oled Technology Llc | High-color-temperature tandem white OLED |
US20100102706A1 (en) * | 2008-10-28 | 2010-04-29 | Miller Michael E | Electroluminescent device with increased fill factor |
WO2010056070A2 (ko) * | 2008-11-13 | 2010-05-20 | 주식회사 엘지화학 | 저전압 구동 유기발광소자 및 이의 제조 방법 |
TW201100480A (en) | 2009-03-12 | 2011-01-01 | Du Pont | Electrically conductive polymer compositions for coating applications |
WO2010113357A1 (ja) * | 2009-04-03 | 2010-10-07 | シャープ株式会社 | ドナー基板、転写膜の製造方法、及び、有機電界発光素子の製造方法 |
US8283054B2 (en) * | 2009-04-03 | 2012-10-09 | Global Oled Technology Llc | Tandem white OLED with efficient electron transfer |
JP5587980B2 (ja) | 2009-04-21 | 2014-09-10 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 導電性ポリマー組成物およびそれから作製されたフィルム |
CN102395627B (zh) | 2009-04-24 | 2015-04-01 | E.I.内穆尔杜邦公司 | 导电聚合物组合物和由其制得的膜 |
US8603642B2 (en) * | 2009-05-13 | 2013-12-10 | Global Oled Technology Llc | Internal connector for organic electronic devices |
US8664647B2 (en) | 2009-07-23 | 2014-03-04 | Kaneka Corporation | Organic electroluminescent element |
US8987726B2 (en) | 2009-07-23 | 2015-03-24 | Kaneka Corporation | Organic electroluminescent element |
JP5054737B2 (ja) * | 2009-08-05 | 2012-10-24 | 財団法人山形県産業技術振興機構 | 有機エレクトロルミネッセンス素子 |
TWI506121B (zh) | 2010-03-31 | 2015-11-01 | Semiconductor Energy Lab | 發光元件,發光裝置,電子裝置以及照明裝置 |
KR101874649B1 (ko) | 2010-04-22 | 2018-07-04 | 이데미쓰 고산 가부시키가이샤 | 유기 일렉트로 루미네선스 소자 및 조명 장치 |
US8633475B2 (en) | 2010-07-16 | 2014-01-21 | Idemitsu Kosan Co., Ltd. | Organic electroluminescence device and a method for producing the device |
US8963143B2 (en) * | 2010-11-09 | 2015-02-24 | Koninklijkle Philips N.V. | Organic electroluminescent device |
WO2012086662A1 (en) | 2010-12-24 | 2012-06-28 | Semiconductor Energy Laboratory Co., Ltd. | Lighting device |
US8552440B2 (en) | 2010-12-24 | 2013-10-08 | Semiconductor Energy Laboratory Co., Ltd. | Lighting device |
CN103262656B (zh) | 2010-12-28 | 2016-08-24 | 株式会社半导体能源研究所 | 发光单元、发光装置以及照明装置 |
US9516713B2 (en) | 2011-01-25 | 2016-12-06 | Semiconductor Energy Laboratory Co., Ltd. | Light-emitting device |
JP5925511B2 (ja) | 2011-02-11 | 2016-05-25 | 株式会社半導体エネルギー研究所 | 発光ユニット、発光装置、照明装置 |
US8772795B2 (en) | 2011-02-14 | 2014-07-08 | Semiconductor Energy Laboratory Co., Ltd. | Light-emitting device and lighting device |
US8735874B2 (en) | 2011-02-14 | 2014-05-27 | Semiconductor Energy Laboratory Co., Ltd. | Light-emitting device, display device, and method for manufacturing the same |
EP2503616A1 (en) | 2011-03-21 | 2012-09-26 | Polyphotonix Limited | Emissive element for light emitting device, light emitting device and method for manufacturing such element and device |
TWI466353B (zh) | 2011-03-24 | 2014-12-21 | Panasonic Corp | 白色發光有機電致發光元件及白色發光有機電致發光面板 |
US9012902B2 (en) | 2011-03-31 | 2015-04-21 | Panasonic Intellectual Property Management Co., Ltd. | Organic electroluminescent element |
KR101429924B1 (ko) | 2011-12-08 | 2014-08-14 | 엘지디스플레이 주식회사 | 탠덤형 백색 유기 발광 소자 |
KR101894332B1 (ko) * | 2011-12-29 | 2018-09-04 | 엘지디스플레이 주식회사 | 유기 발광 표시 장치 |
CN103377908B (zh) * | 2012-04-27 | 2016-12-07 | 陈枕流 | Led芯片斜切割方法、led发光基元及led照明装置 |
US9190623B2 (en) * | 2012-11-20 | 2015-11-17 | Universal Display Corporation | Organic electroluminescent materials and devices |
CN104051640A (zh) * | 2013-03-12 | 2014-09-17 | 海洋王照明科技股份有限公司 | 一种有机电致发光器件及其制备方法 |
SE537191C2 (sv) * | 2013-05-31 | 2015-03-03 | Scania Cv Ab | Intrinsiskt överladdningsskydd för battericell |
DE102013106800A1 (de) * | 2013-06-28 | 2014-12-31 | Osram Oled Gmbh | Optoelektronisches Bauelement und Verfahren zum Herstellen eines optoelektronischen Bauelements |
US9494792B2 (en) | 2013-07-30 | 2016-11-15 | Global Oled Technology Llc | Local seal for encapsulation of electro-optical element on a flexible substrate |
US9385342B2 (en) | 2013-07-30 | 2016-07-05 | Global Oled Technology Llc | Local seal for encapsulation of electro-optical element on a flexible substrate |
US9287522B2 (en) | 2013-07-30 | 2016-03-15 | Global Oled Technology Llc | Local seal for encapsulation of electro-optical element on a flexible substrate |
KR102173045B1 (ko) * | 2014-03-11 | 2020-11-03 | 삼성디스플레이 주식회사 | 유기 발광 소자 |
EP2918701A1 (en) * | 2014-03-14 | 2015-09-16 | Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO | Method of manufacturing a stacked organic light emitting diode, stacked OLED device, and apparatus for manufacturing thereof |
KR20160056444A (ko) * | 2014-11-11 | 2016-05-20 | 삼성디스플레이 주식회사 | 유기 발광 표시 장치의 제조 방법 |
KR102600474B1 (ko) | 2016-03-10 | 2023-11-13 | 삼성디스플레이 주식회사 | 유기 발광 소자 |
KR20170128664A (ko) * | 2016-05-12 | 2017-11-23 | 삼성디스플레이 주식회사 | 유기 발광 소자 |
KR102611206B1 (ko) | 2016-07-13 | 2023-12-08 | 삼성디스플레이 주식회사 | 유기 발광 소자 |
US11282981B2 (en) * | 2017-11-27 | 2022-03-22 | Seoul Viosys Co., Ltd. | Passivation covered light emitting unit stack |
US10892297B2 (en) | 2017-11-27 | 2021-01-12 | Seoul Viosys Co., Ltd. | Light emitting diode (LED) stack for a display |
US10892296B2 (en) | 2017-11-27 | 2021-01-12 | Seoul Viosys Co., Ltd. | Light emitting device having commonly connected LED sub-units |
US11527519B2 (en) | 2017-11-27 | 2022-12-13 | Seoul Viosys Co., Ltd. | LED unit for display and display apparatus having the same |
US10748881B2 (en) | 2017-12-05 | 2020-08-18 | Seoul Viosys Co., Ltd. | Light emitting device with LED stack for display and display apparatus having the same |
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US11552057B2 (en) | 2017-12-20 | 2023-01-10 | Seoul Viosys Co., Ltd. | LED unit for display and display apparatus having the same |
US11522006B2 (en) | 2017-12-21 | 2022-12-06 | Seoul Viosys Co., Ltd. | Light emitting stacked structure and display device having the same |
US11552061B2 (en) | 2017-12-22 | 2023-01-10 | Seoul Viosys Co., Ltd. | Light emitting device with LED stack for display and display apparatus having the same |
US11114499B2 (en) | 2018-01-02 | 2021-09-07 | Seoul Viosys Co., Ltd. | Display device having light emitting stacked structure |
US10784240B2 (en) | 2018-01-03 | 2020-09-22 | Seoul Viosys Co., Ltd. | Light emitting device with LED stack for display and display apparatus having the same |
CN112687811B (zh) | 2019-10-17 | 2023-09-12 | 北京夏禾科技有限公司 | 一种有机电致发光器件 |
CN114843410A (zh) | 2021-01-30 | 2022-08-02 | 北京夏禾科技有限公司 | 一种叠层有机电致发光器件 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04192376A (ja) * | 1990-11-22 | 1992-07-10 | Sekisui Chem Co Ltd | タンデム型有機太陽電池 |
JPH11307261A (ja) * | 1998-04-16 | 1999-11-05 | Tdk Corp | 有機el素子 |
JPH11329748A (ja) * | 1998-05-20 | 1999-11-30 | Idemitsu Kosan Co Ltd | 有機el発光素子およびそれを用いた発光装置 |
US6337492B1 (en) * | 1997-07-11 | 2002-01-08 | Emagin Corporation | Serially-connected organic light emitting diode stack having conductors sandwiching each light emitting layer |
JP2002083692A (ja) * | 2001-09-10 | 2002-03-22 | Pioneer Electronic Corp | 有機エレクトロルミネッセンス素子 |
JP2002168757A (ja) * | 2000-11-28 | 2002-06-14 | National Institute For Materials Science | 走査型トンネル顕微鏡用探針およびその作製方法 |
JP2002289360A (ja) * | 2001-03-27 | 2002-10-04 | Univ Toyama | 有機電界発光素子 |
JP2008249705A (ja) * | 2000-12-11 | 2008-10-16 | Univ Harvard | ナノセンサ |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3172862A (en) | 1960-09-29 | 1965-03-09 | Dow Chemical Co | Organic electroluminescent phosphors |
US3173050A (en) | 1962-09-19 | 1965-03-09 | Dow Chemical Co | Electroluminescent cell |
US3710167A (en) | 1970-07-02 | 1973-01-09 | Rca Corp | Organic electroluminescent cells having a tunnel injection cathode |
US4356429A (en) | 1980-07-17 | 1982-10-26 | Eastman Kodak Company | Organic electroluminescent cell |
US4769292A (en) | 1987-03-02 | 1988-09-06 | Eastman Kodak Company | Electroluminescent device with modified thin film luminescent zone |
US5006915A (en) * | 1989-02-14 | 1991-04-09 | Ricoh Company, Ltd. | Electric device and photoelectric conversion device comprising the same |
US5703436A (en) | 1994-12-13 | 1997-12-30 | The Trustees Of Princeton University | Transparent contacts for organic devices |
US6447879B1 (en) * | 1996-09-17 | 2002-09-10 | Kabushiki Kaisha Toshiba | Electronic Device and method of manufacturing the same |
US6274980B1 (en) | 1998-11-16 | 2001-08-14 | The Trustees Of Princeton University | Single-color stacked organic light emitting device |
JP2000268968A (ja) * | 1999-03-16 | 2000-09-29 | Sharp Corp | 有機エレクトロルミネッセンス素子 |
KR100329571B1 (ko) * | 2000-03-27 | 2002-03-23 | 김순택 | 유기 전자 발광소자 |
US6603150B2 (en) * | 2001-09-28 | 2003-08-05 | Eastman Kodak Company | Organic light-emitting diode having an interface layer between the hole-transporting layer and the light-emitting layer |
SG176316A1 (en) * | 2001-12-05 | 2011-12-29 | Semiconductor Energy Lab | Organic semiconductor element |
-
2002
- 2002-10-09 US US10/267,252 patent/US6717358B1/en not_active Expired - Lifetime
-
2003
- 2003-08-20 TW TW092122882A patent/TWI309142B/zh not_active IP Right Cessation
- 2003-09-29 DE DE60333530T patent/DE60333530D1/de not_active Expired - Lifetime
- 2003-09-29 EP EP03078085A patent/EP1408563B1/en not_active Expired - Lifetime
- 2003-10-08 JP JP2003349868A patent/JP4570017B2/ja not_active Expired - Lifetime
- 2003-10-08 KR KR1020030069854A patent/KR100973473B1/ko active IP Right Grant
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04192376A (ja) * | 1990-11-22 | 1992-07-10 | Sekisui Chem Co Ltd | タンデム型有機太陽電池 |
US6337492B1 (en) * | 1997-07-11 | 2002-01-08 | Emagin Corporation | Serially-connected organic light emitting diode stack having conductors sandwiching each light emitting layer |
JPH11307261A (ja) * | 1998-04-16 | 1999-11-05 | Tdk Corp | 有機el素子 |
JPH11329748A (ja) * | 1998-05-20 | 1999-11-30 | Idemitsu Kosan Co Ltd | 有機el発光素子およびそれを用いた発光装置 |
JP2002168757A (ja) * | 2000-11-28 | 2002-06-14 | National Institute For Materials Science | 走査型トンネル顕微鏡用探針およびその作製方法 |
JP2008249705A (ja) * | 2000-12-11 | 2008-10-16 | Univ Harvard | ナノセンサ |
JP2002289360A (ja) * | 2001-03-27 | 2002-10-04 | Univ Toyama | 有機電界発光素子 |
JP2002083692A (ja) * | 2001-09-10 | 2002-03-22 | Pioneer Electronic Corp | 有機エレクトロルミネッセンス素子 |
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EP1408563A3 (en) | 2006-10-04 |
DE60333530D1 (de) | 2010-09-09 |
TW200415936A (en) | 2004-08-16 |
KR100973473B1 (ko) | 2010-08-03 |
US6717358B1 (en) | 2004-04-06 |
EP1408563B1 (en) | 2010-07-28 |
JP2004281371A (ja) | 2004-10-07 |
TWI309142B (en) | 2009-04-21 |
EP1408563A2 (en) | 2004-04-14 |
KR20040032765A (ko) | 2004-04-17 |
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