JP4409621B2 - ナノサイズダイヤモンド及びプラチナナノコロイドを含有する繊維及びそれを用いた寝具 - Google Patents
ナノサイズダイヤモンド及びプラチナナノコロイドを含有する繊維及びそれを用いた寝具 Download PDFInfo
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- JP4409621B2 JP4409621B2 JP2008558584A JP2008558584A JP4409621B2 JP 4409621 B2 JP4409621 B2 JP 4409621B2 JP 2008558584 A JP2008558584 A JP 2008558584A JP 2008558584 A JP2008558584 A JP 2008558584A JP 4409621 B2 JP4409621 B2 JP 4409621B2
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Description
本発明の繊維は、ナノサイズダイヤモンド及びプラチナナノコロイドが分散した液をスプレー、パディング、プリント、コーティング、浸漬等の方法で繊維に付着させて、常温又は加熱して乾燥させることによって得られる。分散液中のナノサイズダイヤモンド及びプラチナナノコロイドの濃度は、特に限定されないが、それぞれ1%以下であるのが好ましく、0.1%以下であるのがさらに好ましい。ナノサイズダイヤモンド及びプラチナナノコロイドの分散液には、必要に応じて分散剤、バインダー、増粘剤等を加えても良いが、これらの物質は遠赤外線放射効果を妨げるので、できるだけ少なく添加するのが好ましい。バインダーとしては、アクリル樹脂、ウレタン樹脂、シリコーン樹脂、アミノプラスト樹脂、エポキシ樹脂等が挙げられる。なかでも、洗濯耐久性の観点から、アクリル樹脂及びウレタン樹脂が好ましい。分散剤としては、ポリアクリル酸系のポリマーや、無機系の分散剤が使用できる。増粘剤としては、ポリビニルアルコール、メチルセルロース、カルボキシメチルセルロース、ヒドロキシエチルセルロース等が使用できる。
(1) 粗ダイヤモンド
ナノサイズダイヤモンドとしては、爆射法によって合成された粗ダイヤモンド(以下、ブレンドダイヤモンド又はBDとも云う)、及びBDを精製することによって得られるUDD(Ultra Dispersed Diamond)を使用することができる。前記爆射法は、Science, Vol. 133, No.3467(1961), pp1821-1822、特開平1-234311号、特開平2-141414号、Bull. Soc. Chem. Fr. Vol. 134(1997), pp. 875-890、Diamond and Related materials Vol. 9(2000), pp861-865、Chemical Physics Letters, 222(1994), pp. 343-346、Carbon, Vol. 33, No. 12(1995), pp. 1663-1671、Physics of the Solid State, Vol. 42, No. 8(2000), pp. 1575-1578、K. Xu. Z. Jin, F. Wei and T. Jiang, Energetic Materials, 1, 19(1993)、特開昭63-303806号、特開昭56-26711号、英国特許第1154633号、特開平3-271109号、特表平6-505694号(WO93/13016号)、炭素, 第22巻, No. 2, 189〜191頁(1984)、Van Thiei. M. & Rec., F. H., J. Appl. Phys. 62, pp. 1761〜1767(1987)、特表平7-505831号(WO94/18123号)及び米国特許第5861349号等に記載されている。
ナノサイズダイヤモンドの分散物は、爆薬の爆射によって得られたダイヤモンド-非ダイヤモンド混合物(初期BD)を酸化処理した後、揮発性又はその分解反応生成物が揮発性となる塩基性材料を加えて中和し、ダイヤモンドを含有する相を分離することによって製造する。
プラチナナノコロイドは、WO2005/023468に記載の方法により得ることができる。また、市販品を使用しても良く、株式会社ワインレッドケミカル社製のプラチナナノコロイド(WRPT)等が使用できる。プラチナの粒径は特に限定されないが、好ましくは10〜20 nmである。
遠赤外線放射特性は、FT-IR、放射照度計等の赤外線測定装置によって試料から放射される遠赤外線量を測定し、理想黒体(全波長を100%放射及び吸収する物質)に対してどの程度の遠赤外線が放出されているかで評価する。測定は室温で行っても良いが、遠赤外線を吸収するCO2やH2OによりS/N比が悪化するのを防ぐため、試料を40〜50℃に加熱して行うのが好ましい。高温で測定することによって遠赤外線の放射量が増加しS/N比が改良される。赤外線測定装置としては、例えばミネラッド社製SA-200赤外線放射計が挙げられる。
TNT(トリニトロトルエン)とRDX(シクロトリメチレントリニトロアミン)を60/40の比で含む0.65 kgの爆発物を3 m3の爆発チャンバー内で爆発させて生成するBDを保存するための雰囲気を形成した後、同様の条件で2回目の爆発を起こしBDを合成した。爆発生成物が膨張し熱平衡に達した後、直径15 mmの断面を有する超音速ラバルノズルを通して35秒間ガス混合物をチャンバーより流出させた。チャンバー壁との熱交換及びガスにより行なわれた仕事(断熱膨張及び気化)のため、生成物の冷却速度は280℃/分であった。サイクロンで捕獲した生成物(黒色の粉末、BD)の比重は2.58 g/cm3であった。このBDは比重から計算して、74容積%のグラファイト系炭素と容積26%のダイヤモンドからなっていると推定された。
混合分散液20 mL中のナノサイズダイヤモンド及び/又はプラチナナノコロイドの量を表1に示すように変更した以外は、実施例1と同様にして試料を作製し、遠赤外線放射量を測定し、波長3〜15μmにおける放射率を求めた。比較例1は、ナノサイズダイヤモンド及び/又はプラチナナノコロイドを付着させる前のポリエステル綿を使用した。結果を表1に示す。また図2〜10にそれぞれ実施例2〜5及び比較例1〜5の遠赤外線放射輝度(遠赤外線放射量)の測定結果示す。データの説明は図1と同様である。
8.5質量%のセルロース、5.8質量%の水酸化ナトリウム及びセルロースに対して32質量%の二硫化炭素を含有するビスコース溶液に、実施例1で作製した混合分散液(20 mLあたり0.1 mgのナノサイズダイヤモンド及び0.001 mgのプラチナナノコロイドを含む)を、20℃でセルロース100 gあたり66.7 mLの割合で添加した。このナノサイズダイヤモンド及びプラチナナノコロイドを含むビスコース溶液を、硫酸110 g/L、硫酸亜鉛15 g/L及び硫酸ナトリウム350 g/Lを含む紡糸浴(60℃)中に紡糸速度50 m/分、延伸率50%で紡糸し、繊度1.7デシテックスのビスコースレーヨンのトウを得た。これを繊維長52 mm切断して脱硫、漂白した。
ナノサイズダイヤモンド及びプラチナナノコロイドの添加量を変更した以外は実施例6と同様にして、実施例7〜10のビスコースレーヨンのトウを作製した。なお、実施例7〜10の繊維あたりのナノサイズダイヤモンド及びプラチナナノコロイドの添加量は、それぞれ実施例2〜5で作製したナノサイズダイヤモンド及びプラチナナノコロイドを含有する綿の繊維あたりの添加量と同じ値であった。
BDの精製において、酸化性エッチング処理の条件のみを表2の様に変更した以外実施例1と同様にして、比重の異なるナノサイズダイヤモンドを作製し、ナノサイズダイヤモンド及びプラチナナノコロイドが付着したポリエステル綿を得た。これらのポリエステル綿について、実施例1と同様にして遠赤外線放射率を測定した結果、実施例1〜5と同様、非常に優れた遠赤外線放射効果を発揮した。
実施例3と同様の方法でナノサイズダイヤモンド及びプラチナナノコロイドを付着させたポリエステル綿を作製し、寝具を作製した。この寝具を用いて、20人(男10人、女10人)の被験者に15℃及び60%RHの恒温恒湿室で一晩睡眠を取ってもらい、保温効果を評価した。比較として、ナノサイズダイヤモンド及びプラチナナノコロイドを付着させていないポリエステル綿を用いて作製した寝具で、同様の試験を行った。
Claims (5)
- 繊維1 kgあたり、ナノサイズダイヤモンドを3.3〜330 mg、及びプラチナナノコロイドを0.033〜17 mg含有し、前記プラチナナノコロイドの含有量が、前記ナノサイズダイヤモンドの含有量の1/1000〜1倍であることを特徴とする保温性に優れた繊維。
- 請求項1に記載の繊維において、前記ダイヤモンド及び前記プラチナナノコロイドを付着させてなることを特徴とする保温性に優れた繊維。
- 請求項1又は2に記載の繊維において、前記ダイヤモンド及び前記プラチナナノコロイドを練り込んでなることを特徴とする保温性に優れた繊維。
- 請求項1〜3のいずれかに記載の繊維において、前記ナノサイズダイヤモンドの比重が2.63〜3.38 g/cm3であることを特徴とする保温性に優れた繊維。
- 請求項1〜4のいずれかに記載の繊維を含有してなる保温性に優れた寝具。
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JP2015232197A (ja) * | 2010-12-24 | 2015-12-24 | 株式会社バイオフェイス東京研究所 | 吸水性・蒸散性に加え抗菌活性を有するプラチナ繊維 |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009245578A (ja) * | 2008-03-13 | 2009-10-22 | Canon Inc | 番組記録アシスト装置及び映像記録再生装置、番組記録アシスト方法 |
JP4953323B2 (ja) * | 2008-10-28 | 2012-06-13 | ビジョン開発株式会社 | グラファイト系炭素とダイヤモンドとからなる粒子を含有する繊維及びそれを用いた寝具 |
KR101313768B1 (ko) * | 2010-02-12 | 2013-10-01 | 주식회사 네오엔비즈 | 나노 다이아몬드 분산액 및 그 제조 방법 |
JP5275324B2 (ja) * | 2010-11-19 | 2013-08-28 | ビジョン開発株式会社 | 撥水性繊維、及びそれを用いた繊維製品 |
EP2892859A2 (en) | 2012-09-04 | 2015-07-15 | OCV Intellectual Capital, LLC | Dispersion of carbon enhanced reinforcement fibers in aqueous or non-aqueous media |
CN104047173B (zh) * | 2014-07-05 | 2016-04-06 | 山东来利来生态纺织科技有限公司 | 一种永久性防电磁辐射织物 |
FR3045316B1 (fr) | 2015-12-22 | 2018-01-26 | Iyashi Dome | Dispositif de sudation par infrarouge |
JP6741555B2 (ja) * | 2016-10-27 | 2020-08-19 | 株式会社ベネクス | ケラチノサイト活性化剤 |
US20180148860A1 (en) * | 2016-11-29 | 2018-05-31 | The H.D. Lee Company, Inc. | Method for preparing nanodiamond-containing thermoplastic fibers and the use of such fibers in yarns and fabrics |
KR101955169B1 (ko) * | 2018-12-21 | 2019-03-08 | 주식회사 바이오포톤 | 휴대용 전신 찜질장치 |
KR101972296B1 (ko) * | 2019-01-18 | 2019-04-24 | 주식회사 바이오포톤 | 전신 찜질장치 |
CN115811947A (zh) * | 2020-06-01 | 2023-03-17 | 株式会社威耐可适 | 使用提高睡眠质量的含有铂纳米胶体及其它纳米粒子的纤维制衣服、及睡衣来使副交感神经兴奋、提高睡眠质量并从疲劳中恢复的方法 |
JP7104454B1 (ja) * | 2022-03-11 | 2022-07-21 | 株式会社ファーベスト | 赤外線放射樹脂組成物 |
Family Cites Families (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3422032A (en) | 1965-09-07 | 1969-01-14 | Allied Chem | Synthetic diamantiferous composition |
JPS5825042B2 (ja) | 1979-08-10 | 1983-05-25 | 科学技術庁無機材質研究所長 | 衝撃圧縮によるダイヤモンド粉末の合成法 |
GB8401838D0 (en) * | 1984-01-24 | 1984-02-29 | Tribohesion Ltd | Coating process |
JPS63303806A (ja) | 1987-05-30 | 1988-12-12 | Onoda Cement Co Ltd | ダイヤモンドの精製法 |
JP2624285B2 (ja) | 1988-03-15 | 1997-06-25 | 和子 山本 | 合成ダイヤモンド分離装置 |
JPH0775662B2 (ja) | 1988-11-22 | 1995-08-16 | 工業技術院長 | 水中爆発によるダイヤモンド合成方法 |
JPH0680203B2 (ja) | 1989-10-20 | 1994-10-12 | 信秀 前田 | 遠赤外線放射性肌着 |
JPH03190990A (ja) | 1989-12-20 | 1991-08-20 | Toshio Komuro | 赤外線微弱エネルギー放射用の粉末及びそれを混入した合成繊維 |
CN1052712A (zh) * | 1989-12-20 | 1991-07-03 | 小室俊夫 | 红外线微能放射用粉末及混入该粉末的合成纤维及其纤维产品 |
JPH0751220B2 (ja) | 1990-03-22 | 1995-06-05 | 工業技術院長 | ダイヤモンドの合成方法 |
RU2051092C1 (ru) | 1991-12-25 | 1995-12-27 | Научно-производственное объединение "Алтай" | Алмазсодержащее вещество и способ его получения |
JP2585166B2 (ja) | 1992-07-16 | 1997-02-26 | スワニー株式会社 | 金属を含有した繊維からなる靴下 |
RU2041165C1 (ru) | 1993-02-12 | 1995-08-09 | Научно-производственное объединение "Алтай" | Алмазоуглеродное вещество и способ его получения |
JP2830475B2 (ja) | 1993-12-28 | 1998-12-02 | 三菱自動車工業株式会社 | 居眠り運転警報装置 |
US6432537B1 (en) * | 1995-12-01 | 2002-08-13 | E.I. Du Pont De Nemours And Company | Diamond-like-carbon coated aramid fibers having improved mechanical properties |
JP3026650U (ja) * | 1996-01-08 | 1996-07-16 | アイビック工業株式会社 | 男性用サポ−タ− |
JP3042096U (ja) * | 1997-04-02 | 1997-10-07 | 株式会社真圧心クリニック | 導電性繊維生地 |
JP3133706B2 (ja) | 1997-06-19 | 2001-02-13 | 三洋電機株式会社 | 不揮発性半導体メモリ装置 |
US6041801A (en) * | 1998-07-01 | 2000-03-28 | Deka Products Limited Partnership | System and method for measuring when fluid has stopped flowing within a line |
DK1291405T3 (da) * | 2000-05-19 | 2006-07-10 | Toshio Komuro | Sammensætning til fjerninfraröd stråling med fortrinlige antistatiske egenskaber og fiber- og tekstilprodukt begge indeholdende denne |
JP3349140B2 (ja) | 2000-11-24 | 2002-11-20 | スワニー株式会社 | 遠赤外線放射性粒子含有レーヨン系繊維及びその繊維を含有した下着 |
JP2003081768A (ja) | 2001-09-17 | 2003-03-19 | Aaben:Kk | 化粧料 |
JP4712378B2 (ja) * | 2002-06-05 | 2011-06-29 | 俊夫 小室 | 抗血栓性を有する白金含有セラミックス組成物及びそれを含む物品 |
US8028050B2 (en) * | 2003-06-13 | 2011-09-27 | Alcatel-Lucent Usa Inc. | Restoration for virtual private networks |
WO2005023468A1 (ja) | 2003-08-28 | 2005-03-17 | Tama-Tlo, Ltd. | 貴金属コロイド、貴金属微粒子、組成物および貴金属微粒子の製造方法 |
AU2005335123B2 (en) * | 2004-11-09 | 2011-02-03 | Board Of Regents, The University Of Texas System | The fabrication and application of nanofiber ribbons and sheets and twisted and non-twisted nanofiber yarns |
JP2006274486A (ja) * | 2005-03-29 | 2006-10-12 | Teijin Ltd | 芳香族ポリアミドコンポジットファイバー及びその製造方法 |
KR101395425B1 (ko) * | 2006-02-23 | 2014-05-15 | 피코데온 리미티드 오와이 | 유리 기재 상의 코팅 및 코팅된 유리 제품 |
JP2008106392A (ja) * | 2006-10-25 | 2008-05-08 | Nippon Aruta:Kk | 機能性繊維及び同機能性繊維を含む加工品並びに成型品 |
KR20070083399A (ko) * | 2007-01-03 | 2007-08-24 | 홍기복 | 금속 나노(금,백금)를 함침시킨 의복 |
JP3133706U (ja) * | 2007-05-10 | 2007-07-19 | 株式会社イヴ | プラチナ素材入り健康リング |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2015232197A (ja) * | 2010-12-24 | 2015-12-24 | 株式会社バイオフェイス東京研究所 | 吸水性・蒸散性に加え抗菌活性を有するプラチナ繊維 |
JP2016014214A (ja) * | 2010-12-24 | 2016-01-28 | 株式会社バイオフェイス東京研究所 | 発熱性に加え抗菌活性を有するプラチナ繊維 |
Also Published As
Publication number | Publication date |
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ATE533885T1 (de) | 2011-12-15 |
US9005751B2 (en) | 2015-04-14 |
SI2072666T1 (sl) | 2012-01-31 |
PT2072666E (pt) | 2011-12-16 |
JPWO2009041302A1 (ja) | 2011-01-27 |
HRP20110864T1 (hr) | 2011-12-31 |
CN101878337A (zh) | 2010-11-03 |
KR101164106B1 (ko) | 2012-07-12 |
EP2072666B1 (en) | 2011-11-16 |
US20100200800A1 (en) | 2010-08-12 |
EP2072666A4 (en) | 2010-08-04 |
CY1112378T1 (el) | 2015-12-09 |
CN101878337B (zh) | 2012-12-05 |
PL2072666T3 (pl) | 2012-04-30 |
DK2072666T3 (da) | 2012-03-05 |
WO2009041302A1 (ja) | 2009-04-02 |
ES2376179T3 (es) | 2012-03-09 |
EP2072666A1 (en) | 2009-06-24 |
KR20090077029A (ko) | 2009-07-14 |
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