JP4056859B2 - 水溶性フィルム - Google Patents
水溶性フィルム Download PDFInfo
- Publication number
- JP4056859B2 JP4056859B2 JP2002326747A JP2002326747A JP4056859B2 JP 4056859 B2 JP4056859 B2 JP 4056859B2 JP 2002326747 A JP2002326747 A JP 2002326747A JP 2002326747 A JP2002326747 A JP 2002326747A JP 4056859 B2 JP4056859 B2 JP 4056859B2
- Authority
- JP
- Japan
- Prior art keywords
- water
- film
- weight
- parts
- pva
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/002—Methods
- B29B7/007—Methods for continuous mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/58—Component parts, details or accessories; Auxiliary operations
- B29B7/72—Measuring, controlling or regulating
- B29B7/726—Measuring properties of mixture, e.g. temperature or density
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/88—Adding charges, i.e. additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/044—Solid compositions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2329/02—Homopolymers or copolymers of unsaturated alcohols
- C08J2329/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Wrappers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002326747A JP4056859B2 (ja) | 2002-11-11 | 2002-11-11 | 水溶性フィルム |
EP03025704A EP1418196B1 (fr) | 2002-11-11 | 2003-11-07 | Film soluble dans l'eau |
US10/703,519 US7067575B2 (en) | 2002-11-11 | 2003-11-10 | Water-soluble film of polyvinyl alcohol |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002326747A JP4056859B2 (ja) | 2002-11-11 | 2002-11-11 | 水溶性フィルム |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2004161823A JP2004161823A (ja) | 2004-06-10 |
JP4056859B2 true JP4056859B2 (ja) | 2008-03-05 |
Family
ID=32105520
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2002326747A Expired - Lifetime JP4056859B2 (ja) | 2002-11-11 | 2002-11-11 | 水溶性フィルム |
Country Status (3)
Country | Link |
---|---|
US (1) | US7067575B2 (fr) |
EP (1) | EP1418196B1 (fr) |
JP (1) | JP4056859B2 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20170131521A (ko) * | 2015-03-27 | 2017-11-29 | 모노졸, 엘엘씨 | 수용성 필름, 상기 필름을 이용한 패킷, 및 이들을 제조하고 사용하는 방법 |
Families Citing this family (92)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7022656B2 (en) * | 2003-03-19 | 2006-04-04 | Monosol, Llc. | Water-soluble copolymer film packet |
EP1624017A1 (fr) * | 2004-07-12 | 2006-02-08 | The Procter & Gamble Company | Composition emballée pour l'administration de ladite composition dans un milieu aqueux |
JP2006117861A (ja) * | 2004-10-25 | 2006-05-11 | Okamoto Ind Inc | 生崩壊性液状覆土代替材、並びに廃棄物,焼却灰,汚染土壌等の処理方法 |
JP2006257225A (ja) * | 2005-03-16 | 2006-09-28 | Nippon Synthetic Chem Ind Co Ltd:The | ポリビニルアルコール系フィルム及びその用途 |
JP2008539320A (ja) * | 2005-04-28 | 2008-11-13 | モノソル エルエルシー | 水溶性組成物及び構造体並びにこれらの製造方法及び使用方法 |
US20060275567A1 (en) * | 2005-06-07 | 2006-12-07 | Richard Vicari | Borate resistant films |
GB2442626A (en) * | 2005-06-16 | 2008-04-09 | Nippon Synthetic Chem Ind | Water-soluble film |
EP1808482A1 (fr) | 2006-01-14 | 2007-07-18 | Dalli-Werke GmbH & Co. KG | Compositions detergentes et procede de fabrication |
DE102006024568A1 (de) * | 2006-05-23 | 2007-12-06 | Huhtamaki Forchheim Zweigniederlassung Der Huhtamaki Deutschland Gmbh & Co. Kg | Verfahren zur Herstellung einer biologisch abbaubaren Kunststofffolie und Folie |
US20080176985A1 (en) * | 2006-11-13 | 2008-07-24 | Verrall Andrew P | Water-soluble film |
US20080110370A1 (en) * | 2006-11-13 | 2008-05-15 | Verrall Andrew P | Water-soluble film |
WO2008140988A1 (fr) * | 2007-05-10 | 2008-11-20 | Danisco Us Inc., Genencor Division | Systèmes de génération de peracide enzymatique stables |
WO2010045477A2 (fr) * | 2008-10-16 | 2010-04-22 | Obalon Therapeutics, Inc. | Dispositif occupant un volume intra-gastrique et son procédé de fabrication |
CN101746168B (zh) * | 2008-12-02 | 2012-10-10 | 日本合成化学工业株式会社 | 液压转印印刷用基膜 |
BR112013000101A2 (pt) | 2010-07-02 | 2016-05-17 | Procter & Gamble | filamentos compreendendo mantas de não tecido com agente ativo e métodos de fabricação dos mesmos |
JP5540107B2 (ja) | 2010-07-02 | 2014-07-02 | ザ プロクター アンド ギャンブル カンパニー | 不織布ウェブからフィルムを作製する方法 |
MX2012015187A (es) | 2010-07-02 | 2013-05-09 | Procter & Gamble | Metodo para suministrar un agente activo. |
CA2803636C (fr) | 2010-07-02 | 2017-05-16 | The Procter & Gamble Company | Produit detergent et son procede de fabrication |
ES2543044T3 (es) | 2010-12-22 | 2015-08-14 | Sekisui Specialty Chemicals America, Llc | Copolímeros de alcohol polivinílico/acrilato de alquilo solubles en agua fría y películas de los mismos |
US10087401B2 (en) | 2012-03-16 | 2018-10-02 | Monosol, Llc | Water soluble compositions incorporating enzymes, and method of making same |
US9394092B2 (en) | 2012-04-16 | 2016-07-19 | Monosol, Llc | Powdered pouch and method of making same |
US10829621B2 (en) | 2013-01-11 | 2020-11-10 | Monosol, Llc | Edible water-soluble film |
US10808210B2 (en) * | 2013-03-15 | 2020-10-20 | Monosol, Llc | Water-soluble film for delayed release |
GB2501607B (en) | 2013-03-25 | 2014-05-07 | Peter Morris Res And Dev Ltd | Polymer internal lubricant |
ES2775194T3 (es) | 2013-12-25 | 2020-07-24 | Kuraray Co | Alcohol polivinílico modificado y película soluble en agua que contiene el mismo |
EP2955219B1 (fr) * | 2014-06-12 | 2020-03-25 | The Procter and Gamble Company | Sachet soluble dans l'eau comprenant une zone en relief |
EP3199560B1 (fr) | 2014-09-26 | 2020-11-11 | Kuraray Co., Ltd. | Alcool polyvinylique modifié et film hydrosoluble |
US10358508B2 (en) | 2014-10-09 | 2019-07-23 | Kuraray Co., Ltd. | Modified polyvinyl alhohol, resin composition, and film |
EP3207085B1 (fr) | 2014-10-13 | 2021-07-21 | Monosol, LLC | Film à base de polyvinyle et d'alcool soluble dans l'eau, procédés associés et articles associés |
TWI677525B (zh) * | 2014-10-13 | 2019-11-21 | 美商摩諾索公司 | 水溶性聚乙烯醇摻合物膜、相關方法及相關物品 |
TWI689547B (zh) | 2014-10-13 | 2020-04-01 | 美商摩諾索公司 | 具有塑化劑摻合物的水溶性聚乙烯醇膜、相關方法及相關物品 |
CA2962792C (fr) * | 2014-10-13 | 2019-08-13 | The Procter & Gamble Company | Articles comprenant un film melange de poly(alcool de vinyle) soluble dans l'eau et procedes associes |
WO2016061054A1 (fr) * | 2014-10-13 | 2016-04-21 | The Procter & Gamble Company | Objets comprenant un film, soluble dans l'eau, de poly(alcool vinylique) présentant un mélange plastifiant et procédés associés |
JP2016108426A (ja) * | 2014-12-05 | 2016-06-20 | 日本合成化学工業株式会社 | 水溶性フィルム及び薬剤包装体 |
JP6397323B2 (ja) * | 2014-12-15 | 2018-09-26 | 積水化学工業株式会社 | 多層薬剤包装用フィルム |
JP6456132B2 (ja) * | 2014-12-19 | 2019-01-23 | 日本合成化学工業株式会社 | 水溶性フィルム及び薬剤包装体 |
CN104744716B (zh) * | 2015-04-03 | 2018-03-09 | 广州康华微创生物科技有限公司 | 一种壳聚糖与改性聚乙烯醇复合膜的制备方法 |
EP3284695B1 (fr) | 2015-04-15 | 2021-02-17 | Sekisui Chemical Co., Ltd. | Film d'emballage de produits chimiques |
WO2017029371A1 (fr) * | 2015-08-20 | 2017-02-23 | Unilever Plc | Récipient d'agent de nettoyage |
CN112048089B (zh) | 2015-09-11 | 2023-02-24 | 三菱化学株式会社 | 水溶性薄膜及药剂包装体 |
JP6805828B2 (ja) | 2015-09-11 | 2020-12-23 | 三菱ケミカル株式会社 | 水溶性フィルム、薬剤包装体及び水溶性フィルムの製造方法 |
JP6809227B2 (ja) * | 2015-09-11 | 2021-01-06 | 三菱ケミカル株式会社 | 液体洗剤包装用水溶性フィルム及び液体洗剤包装体 |
JP6992253B2 (ja) * | 2015-09-11 | 2022-01-13 | 三菱ケミカル株式会社 | 水溶性フィルム及び薬剤包装体 |
WO2017043506A1 (fr) * | 2015-09-11 | 2017-03-16 | 日本合成化学工業株式会社 | Film hydrosoluble et emballage chimique |
JP6729279B2 (ja) * | 2015-10-19 | 2020-07-22 | 三菱ケミカル株式会社 | 水溶性フィルム及び薬剤包装体 |
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JP6996081B2 (ja) * | 2015-12-16 | 2022-01-17 | 三菱ケミカル株式会社 | 水溶性フィルム及び薬剤包装体 |
JP6787064B2 (ja) * | 2015-12-17 | 2020-11-18 | 三菱ケミカル株式会社 | 水溶性フィルム及び薬剤包装体 |
JP6888288B2 (ja) * | 2015-12-18 | 2021-06-16 | 三菱ケミカル株式会社 | 液体洗剤包装用水溶性フィルム及び液体洗剤包装体 |
AU2017212659B2 (en) * | 2016-01-29 | 2021-08-19 | Monosol, Llc | Water soluble film for thermoforming deep-drawn profiles and thermoformed articles comprising same |
HUE059621T2 (hu) | 2016-04-13 | 2022-11-28 | Monosol Llc | Vízoldható film, a filmet hasznosító csomagolások, és eljárások ezek elõállítására és használatára |
US11268052B2 (en) | 2016-04-13 | 2022-03-08 | The Procter & Gamble Company | Container systems with water-soluble pouches comprising a PVOH resin blend |
RS63086B1 (sr) * | 2016-04-18 | 2022-04-29 | Monosol Llc | Film koji sadrži parfemske mikrokapsule i kontejner koji sadrži takav film i deterdžent |
JP7059205B2 (ja) | 2016-06-13 | 2022-04-25 | モノソル リミテッド ライアビリティ カンパニー | 水溶性の密封強度を改善するための第1のフィルムおよび第2のフィルムの使用 |
EP3469058A1 (fr) | 2016-06-13 | 2019-04-17 | Monosol, LLC | Articles en dose unitaire hydrosolubles, fabriqués à partir d'une combinaison de différents films |
US10745655B2 (en) | 2016-06-13 | 2020-08-18 | The Procter & Gamble Company | Water-soluble unit dose articles made from a combination of different films and containing household care compositions |
RU2704615C1 (ru) | 2016-06-13 | 2019-10-30 | Дзе Проктер Энд Гэмбл Компани | Водорастворимые изделия с разовой дозой, изготовленные из комбинации различных пленок и содержащие композиции для бытового применения |
EP3469060A1 (fr) | 2016-06-13 | 2019-04-17 | The Procter & Gamble Company | Articles de type dose unitaire hydrosolubles produits à partir d'une combinaison de films différents et contenant des compositions d'entretien ménager |
US10899518B2 (en) | 2016-06-13 | 2021-01-26 | Monosol, Llc | Water-soluble packets |
JP7146734B2 (ja) | 2016-08-01 | 2022-10-04 | モノソル リミテッド ライアビリティ カンパニー | 水溶性フィルムの塩素安定性のための可塑剤ブレンド |
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WO2018123892A1 (fr) | 2016-12-27 | 2018-07-05 | 日本合成化学工業株式会社 | Film soluble dans l'eau, et emballage pour médicament |
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EP3564151B1 (fr) | 2016-12-27 | 2022-08-03 | Mitsubishi Chemical Corporation | Emballage pour un produit chimique liquide, et procédé de fabrication de celui-ci |
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WO2019147532A1 (fr) | 2018-01-26 | 2019-08-01 | The Procter & Gamble Company | Articles en dose unitaire soluble dans l'eau comprenant un parfum |
EP3743501A1 (fr) | 2018-01-26 | 2020-12-02 | The Procter & Gamble Company | Articles en dose unitaire soluble dans l'eau comprenant une enzyme |
EP3743503A1 (fr) | 2018-01-26 | 2020-12-02 | The Procter & Gamble Company | Articles solubles dans l'eau et procédés connexes |
WO2019168829A1 (fr) | 2018-02-27 | 2019-09-06 | The Procter & Gamble Company | Produit de consommation comprenant un conditionnement plat contenant des articles de dose unitaire |
CN108587015A (zh) * | 2018-03-05 | 2018-09-28 | 扬州亿斯特新材料科技有限公司 | 一种pva聚乙烯醇系薄膜及其制备方法 |
CN111819229A (zh) * | 2018-03-29 | 2020-10-23 | 三菱化学株式会社 | 水溶性薄膜及其制造方法、以及药剂包装体 |
CN108424600A (zh) * | 2018-04-17 | 2018-08-21 | 河南工程学院 | 一种具有疏松结构的聚乙烯醇薄膜及其制备方法 |
JP2019189706A (ja) * | 2018-04-20 | 2019-10-31 | 三菱ケミカル株式会社 | 水溶性フィルム及び薬剤包装体 |
CN112334522B (zh) | 2018-05-02 | 2023-09-08 | 蒙诺苏尔有限公司 | 水溶性聚乙烯醇掺合物膜、相关方法和相关制品 |
US20210221979A1 (en) * | 2018-07-22 | 2021-07-22 | Bio Future World Llc | Pva bottles biodegradable and soluble in high temperature water |
US10982176B2 (en) | 2018-07-27 | 2021-04-20 | The Procter & Gamble Company | Process of laundering fabrics using a water-soluble unit dose article |
WO2020027020A1 (fr) | 2018-07-31 | 2020-02-06 | 三菱ケミカル株式会社 | Film d'alcool polyvinylique et emballage pour médicament |
EP3918045A1 (fr) | 2019-01-28 | 2021-12-08 | The Procter & Gamble Company | Emballage recyclable, renouvelable ou biodégradable |
EP3942008A1 (fr) | 2019-03-19 | 2022-01-26 | The Procter & Gamble Company | Procédé de réduction des mauvaises odeurs sur des tissus |
EP3712237A1 (fr) | 2019-03-19 | 2020-09-23 | The Procter & Gamble Company | Articles fibreux de dose unitaire soluble dans l'eau comprenant des structures fibreuses solubles dans l'eau |
CN109942866A (zh) * | 2019-04-10 | 2019-06-28 | 兰州职业技术学院 | 一种新能源材料的制备方法 |
EP3989913A1 (fr) | 2019-06-28 | 2022-05-04 | The Procter & Gamble Company | Articles fibreux solides solubles contenant des tensioactifs anioniques |
JP7512375B2 (ja) * | 2019-09-30 | 2024-07-08 | モノソル リミテッド ライアビリティ カンパニー | 不織布水溶性複合材料構造 |
US11718010B2 (en) | 2020-05-26 | 2023-08-08 | Peter Morris Research And Development Limited | Method of making a water-soluble polymer composition |
JPWO2022004341A1 (fr) * | 2020-06-29 | 2022-01-06 | ||
JP7506249B2 (ja) | 2020-07-31 | 2024-06-25 | ザ プロクター アンド ギャンブル カンパニー | ヘアケア用プリル含有水溶性繊維パウチ |
US20230242850A1 (en) * | 2022-01-28 | 2023-08-03 | The Procter & Gamble Company | Container systems with water-soluble pouches |
WO2024134545A1 (fr) * | 2022-12-21 | 2024-06-27 | Zobele Holding S.P.A. | Détergents en poudre pour lessive/nettoyage en sachets hydrosolubles |
CN116082643A (zh) * | 2023-02-17 | 2023-05-09 | 江苏乐离新材料科技有限公司 | 一种聚乙烯醇树脂有机硅改性水溶性设备保护膜溶液的制备方法 |
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JP3345104B2 (ja) | 1993-07-05 | 2002-11-18 | 株式会社クラレ | ポリビニルアルコール系フィルム |
JP3609894B2 (ja) | 1996-04-05 | 2005-01-12 | 株式会社クラレ | ホウ酸系物質包装用フィルム |
JPH1060207A (ja) | 1996-08-22 | 1998-03-03 | Dai Ichi Kogyo Seiyaku Co Ltd | 水溶性フィルム |
EP0884352B1 (fr) * | 1997-06-11 | 2001-09-05 | Kuraray Co., Ltd. | Feuille hydrosoluble |
JP5116911B2 (ja) * | 2000-05-19 | 2013-01-09 | 株式会社クラレ | 水溶性フィルムの製造法 |
EP1251147B1 (fr) * | 2001-04-20 | 2004-09-08 | Kuraray Co., Ltd. | Film soluble dans l'eau et emballage l'utilisant |
-
2002
- 2002-11-11 JP JP2002326747A patent/JP4056859B2/ja not_active Expired - Lifetime
-
2003
- 2003-11-07 EP EP03025704A patent/EP1418196B1/fr not_active Revoked
- 2003-11-10 US US10/703,519 patent/US7067575B2/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20170131521A (ko) * | 2015-03-27 | 2017-11-29 | 모노졸, 엘엘씨 | 수용성 필름, 상기 필름을 이용한 패킷, 및 이들을 제조하고 사용하는 방법 |
KR102579755B1 (ko) * | 2015-03-27 | 2023-09-15 | 모노졸, 엘엘씨 | 수용성 필름, 상기 필름을 이용한 패킷, 및 이들을 제조하고 사용하는 방법 |
Also Published As
Publication number | Publication date |
---|---|
JP2004161823A (ja) | 2004-06-10 |
EP1418196B1 (fr) | 2011-08-24 |
US7067575B2 (en) | 2006-06-27 |
EP1418196A1 (fr) | 2004-05-12 |
US20040092635A1 (en) | 2004-05-13 |
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