JP3778045B2 - 低誘電率材料の製造方法および低誘電率材料、並びにこの低誘電率材料を用いた絶縁膜および半導体装置 - Google Patents
低誘電率材料の製造方法および低誘電率材料、並びにこの低誘電率材料を用いた絶縁膜および半導体装置 Download PDFInfo
- Publication number
- JP3778045B2 JP3778045B2 JP2001311405A JP2001311405A JP3778045B2 JP 3778045 B2 JP3778045 B2 JP 3778045B2 JP 2001311405 A JP2001311405 A JP 2001311405A JP 2001311405 A JP2001311405 A JP 2001311405A JP 3778045 B2 JP3778045 B2 JP 3778045B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- dielectric constant
- low dielectric
- hydrogen atom
- constant material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000463 material Substances 0.000 title claims description 124
- 239000004065 semiconductor Substances 0.000 title claims description 50
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- BGECDVWSWDRFSP-UHFFFAOYSA-N borazine Chemical group B1NBNBN1 BGECDVWSWDRFSP-UHFFFAOYSA-N 0.000 claims description 77
- 239000000126 substance Substances 0.000 claims description 76
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 39
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 30
- 239000011810 insulating material Substances 0.000 claims description 20
- 125000003545 alkoxy group Chemical group 0.000 claims description 18
- 125000003342 alkenyl group Chemical group 0.000 claims description 16
- 125000003282 alkyl amino group Chemical group 0.000 claims description 16
- 125000005103 alkyl silyl group Chemical group 0.000 claims description 16
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 16
- -1 phosphino group Chemical group 0.000 claims description 16
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 claims description 16
- 229920000642 polymer Polymers 0.000 claims description 14
- 125000005309 thioalkoxy group Chemical group 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 125000003277 amino group Chemical group 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 6
- 239000011147 inorganic material Substances 0.000 claims description 6
- 239000011368 organic material Substances 0.000 claims description 6
- 229910052796 boron Inorganic materials 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 239000013081 microcrystal Substances 0.000 claims description 3
- 125000003107 substituted aryl group Chemical group 0.000 claims description 2
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 226
- 239000010949 copper Substances 0.000 description 108
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 107
- 229910052802 copper Inorganic materials 0.000 description 107
- 239000010408 film Substances 0.000 description 103
- 230000004888 barrier function Effects 0.000 description 28
- 229910052751 metal Inorganic materials 0.000 description 28
- 239000002184 metal Substances 0.000 description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 21
- 229910052814 silicon oxide Inorganic materials 0.000 description 18
- 238000009792 diffusion process Methods 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 238000000034 method Methods 0.000 description 12
- 239000000758 substrate Substances 0.000 description 11
- 239000011229 interlayer Substances 0.000 description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 9
- 239000002861 polymer material Substances 0.000 description 9
- 229920006037 cross link polymer Polymers 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 229910052581 Si3N4 Inorganic materials 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 7
- 125000001424 substituent group Chemical group 0.000 description 7
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 6
- 229910052731 fluorine Inorganic materials 0.000 description 6
- 239000011737 fluorine Substances 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000003989 dielectric material Substances 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 238000004528 spin coating Methods 0.000 description 5
- 150000008378 aryl ethers Chemical class 0.000 description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 4
- 239000010931 gold Substances 0.000 description 4
- 229910052737 gold Inorganic materials 0.000 description 4
- 229920000592 inorganic polymer Polymers 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000006482 condensation reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000010354 integration Effects 0.000 description 3
- 229920000620 organic polymer Polymers 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 2
- JGYJAQQYSVBSRY-UHFFFAOYSA-N CNN1BNBNB1 Chemical compound CNN1BNBNB1 JGYJAQQYSVBSRY-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229910020177 SiOF Inorganic materials 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910021426 porous silicon Inorganic materials 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- IVHJCRXBQPGLOV-UHFFFAOYSA-N azanylidynetungsten Chemical compound [W]#N IVHJCRXBQPGLOV-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000013590 bulk material Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- ZOCHARZZJNPSEU-UHFFFAOYSA-N diboron Chemical compound B#B ZOCHARZZJNPSEU-UHFFFAOYSA-N 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
- 229920000052 poly(p-xylylene) Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02118—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer carbon based polymeric organic or inorganic material, e.g. polyimides, poly cyclobutene or PVC
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02123—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon
- H01L21/02164—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material being a silicon oxide, e.g. SiO2
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/312—Organic layers, e.g. photoresist
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/314—Inorganic layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76822—Modification of the material of dielectric layers, e.g. grading, after-treatment to improve the stability of the layers, to increase their density etc.
- H01L21/76828—Modification of the material of dielectric layers, e.g. grading, after-treatment to improve the stability of the layers, to increase their density etc. thermal treatment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76829—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76829—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers
- H01L21/76834—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers formation of thin insulating films on the sidewalls or on top of conductors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76835—Combinations of two or more different dielectric layers having a low dielectric constant
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/532—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body characterised by the materials
- H01L23/5329—Insulating materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/43—Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/49—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
- H01L29/51—Insulating materials associated therewith
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/532—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body characterised by the materials
- H01L23/53204—Conductive materials
- H01L23/53209—Conductive materials based on metals, e.g. alloys, metal silicides
- H01L23/53228—Conductive materials based on metals, e.g. alloys, metal silicides the principal metal being copper
- H01L23/53238—Additional layers associated with copper layers, e.g. adhesion, barrier, cladding layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/0002—Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/10—Details of semiconductor or other solid state devices to be connected
- H01L2924/11—Device type
- H01L2924/12—Passive devices, e.g. 2 terminal devices
- H01L2924/1204—Optical Diode
- H01L2924/12044—OLED
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/30—Technical effects
- H01L2924/301—Electrical effects
- H01L2924/3011—Impedance
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001311405A JP3778045B2 (ja) | 2001-10-09 | 2001-10-09 | 低誘電率材料の製造方法および低誘電率材料、並びにこの低誘電率材料を用いた絶縁膜および半導体装置 |
US10/266,794 US6924240B2 (en) | 2001-10-09 | 2002-10-09 | Low dielectric constant material, insulating film comprising the low dielectric constant material, and semiconductor device |
US11/107,800 US20050181628A1 (en) | 2001-10-09 | 2005-04-18 | Process for preparing low dielectric constant material |
US12/558,810 US8674046B2 (en) | 2001-10-09 | 2009-09-14 | Source material for preparing low dielectric constant material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001311405A JP3778045B2 (ja) | 2001-10-09 | 2001-10-09 | 低誘電率材料の製造方法および低誘電率材料、並びにこの低誘電率材料を用いた絶縁膜および半導体装置 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2005267805A Division JP4415921B2 (ja) | 2005-09-15 | 2005-09-15 | 半導体装置 |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2003119289A JP2003119289A (ja) | 2003-04-23 |
JP2003119289A5 JP2003119289A5 (US06924240-20050802-C00022.png) | 2005-11-04 |
JP3778045B2 true JP3778045B2 (ja) | 2006-05-24 |
Family
ID=19130242
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2001311405A Expired - Fee Related JP3778045B2 (ja) | 2001-10-09 | 2001-10-09 | 低誘電率材料の製造方法および低誘電率材料、並びにこの低誘電率材料を用いた絶縁膜および半導体装置 |
Country Status (2)
Country | Link |
---|---|
US (3) | US6924240B2 (US06924240-20050802-C00022.png) |
JP (1) | JP3778045B2 (US06924240-20050802-C00022.png) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8288294B2 (en) | 2008-06-30 | 2012-10-16 | Mitsubishi Heavy Industries, Ltd. | Insulating film for semiconductor device, process and apparatus for producing insulating film for semiconductor device, semiconductor device, and process for producing the semiconductor device |
Families Citing this family (44)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7064088B2 (en) * | 1998-02-05 | 2006-06-20 | Asm Japan K.K. | Method for forming low-k hard film |
US20060258176A1 (en) * | 1998-02-05 | 2006-11-16 | Asm Japan K.K. | Method for forming insulation film |
US7354873B2 (en) * | 1998-02-05 | 2008-04-08 | Asm Japan K.K. | Method for forming insulation film |
US7582575B2 (en) * | 1998-02-05 | 2009-09-01 | Asm Japan K.K. | Method for forming insulation film |
US6924545B2 (en) | 2001-03-27 | 2005-08-02 | National Institute Of Advanced Industrial Science | Low-dielectric-constant interlayer insulating film composed of borazine-silicon-based polymer and semiconductor device |
JP3778045B2 (ja) * | 2001-10-09 | 2006-05-24 | 三菱電機株式会社 | 低誘電率材料の製造方法および低誘電率材料、並びにこの低誘電率材料を用いた絶縁膜および半導体装置 |
JP2005038971A (ja) * | 2003-07-17 | 2005-02-10 | Ebara Corp | 半導体装置及びその製造方法 |
US7148154B2 (en) * | 2003-08-20 | 2006-12-12 | Asm Japan K.K. | Method of forming silicon-containing insulation film having low dielectric constant and low film stress |
JP4461215B2 (ja) | 2003-09-08 | 2010-05-12 | 独立行政法人産業技術総合研究所 | 低誘電率絶縁材料とそれを用いた半導体装置 |
US7268432B2 (en) * | 2003-10-10 | 2007-09-11 | International Business Machines Corporation | Interconnect structures with engineered dielectrics with nanocolumnar porosity |
US8358011B1 (en) * | 2007-09-07 | 2013-01-22 | International Business Machines Corporation | Interconnect structures with engineered dielectrics with nanocolumnar porosity |
US20050282015A1 (en) | 2003-12-01 | 2005-12-22 | Teruhiko Kumada | Composition for low dielectric material, low dielectric material and method for production thereof |
US7088010B2 (en) * | 2003-12-18 | 2006-08-08 | Intel Corporation | Chip packaging compositions, packages and systems made therewith, and methods of making same |
JP4504671B2 (ja) * | 2003-12-18 | 2010-07-14 | 株式会社日本触媒 | アルキルボラジン化合物およびその製造方法 |
US7208627B2 (en) | 2003-12-18 | 2007-04-24 | Nippon Shokubai Co., Ltd | Alkylborazine compound and production method for the same |
JP4666301B2 (ja) * | 2004-01-14 | 2011-04-06 | Jx日鉱日石エネルギー株式会社 | 燃料電池用水素の発生方法および燃料電池システム |
CN101044603A (zh) * | 2004-10-19 | 2007-09-26 | 三菱电机株式会社 | 等离子体cvd装置 |
JP4785028B2 (ja) * | 2004-11-08 | 2011-10-05 | 国立大学法人北海道大学 | ヘキサアルキルボラジンの製造方法 |
JP4904030B2 (ja) * | 2005-08-24 | 2012-03-28 | 株式会社日本触媒 | ボラジン化合物の製造方法 |
KR20080027759A (ko) * | 2005-07-07 | 2008-03-28 | 마쯔시다덴기산교 가부시키가이샤 | 다층배선구조 및 그 형성방법 |
TW200708537A (en) | 2005-08-23 | 2007-03-01 | Nippon Catalytic Chem Ind | Method for producing a purified borazine compound, method for filling a container with a borazine compound and container for preserving a borazine compound |
JP4904032B2 (ja) * | 2005-08-30 | 2012-03-28 | 株式会社日本触媒 | 精製ボラジン化合物の製造方法 |
JP4904029B2 (ja) * | 2005-08-23 | 2012-03-28 | 株式会社日本触媒 | ボラジン化合物の保存方法 |
CN101310038B (zh) | 2005-11-17 | 2011-05-04 | 株式会社日本触媒 | 化学气相沉积成膜用组合物及生产低介电常数膜的方法 |
JP4497323B2 (ja) | 2006-03-29 | 2010-07-07 | 三菱電機株式会社 | プラズマcvd装置 |
US20070296064A1 (en) * | 2006-06-22 | 2007-12-27 | Gates Stephen M | Electronic structures utilizing etch resistant boron and phosphorus materials and methods to form same |
US7718553B2 (en) * | 2006-09-21 | 2010-05-18 | Asm Japan K.K. | Method for forming insulation film having high density |
JP5143397B2 (ja) * | 2006-10-30 | 2013-02-13 | 株式会社日本触媒 | ボラジン化合物の保存方法およびボラジン化合物保存用容器 |
JP2008189627A (ja) * | 2007-02-07 | 2008-08-21 | Nippon Shokubai Co Ltd | ボラジン化合物の製造方法 |
JP2008208049A (ja) * | 2007-02-23 | 2008-09-11 | Nippon Shokubai Co Ltd | ボラジン化合物の製造方法、及びボラジン化合物 |
US7781352B2 (en) * | 2007-06-06 | 2010-08-24 | Asm Japan K.K. | Method for forming inorganic silazane-based dielectric film |
JP2009102234A (ja) * | 2007-10-20 | 2009-05-14 | Nippon Shokubai Co Ltd | 放熱材料形成用化合物 |
US7651959B2 (en) | 2007-12-03 | 2010-01-26 | Asm Japan K.K. | Method for forming silazane-based dielectric film |
US7622369B1 (en) | 2008-05-30 | 2009-11-24 | Asm Japan K.K. | Device isolation technology on semiconductor substrate |
JP2010021401A (ja) * | 2008-07-11 | 2010-01-28 | Fujitsu Microelectronics Ltd | 半導体装置及びその製造方法 |
US8765233B2 (en) * | 2008-12-09 | 2014-07-01 | Asm Japan K.K. | Method for forming low-carbon CVD film for filling trenches |
JP5213897B2 (ja) * | 2010-03-18 | 2013-06-19 | ルネサスエレクトロニクス株式会社 | 半導体装置の製造方法 |
US20120235304A1 (en) * | 2011-03-18 | 2012-09-20 | Globalfoundries Inc. | Ultraviolet (uv)-reflecting film for beol processing |
JP6007031B2 (ja) * | 2012-08-23 | 2016-10-12 | 株式会社日立国際電気 | 半導体装置の製造方法、基板処理装置およびプログラム |
US10968522B2 (en) * | 2018-04-02 | 2021-04-06 | Elwha Llc | Fabrication of metallic optical metasurfaces |
US10665545B2 (en) * | 2018-09-19 | 2020-05-26 | Taiwan Semiconductor Manufacturing Co., Ltd. | Semiconductor devices, semiconductor packages and methods of forming the same |
JP7197328B2 (ja) | 2018-11-05 | 2022-12-27 | 株式会社Adeka | 薄膜形成用原料及び薄膜の製造方法 |
CN110129769B (zh) * | 2019-05-17 | 2021-05-14 | 江苏菲沃泰纳米科技股份有限公司 | 疏水性的低介电常数膜及其制备方法 |
CN110158052B (zh) | 2019-05-17 | 2021-05-14 | 江苏菲沃泰纳米科技股份有限公司 | 低介电常数膜及其制备方法 |
Family Cites Families (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3052641A (en) * | 1959-08-03 | 1962-09-04 | United States Borax Chem | Boron-nitrogen polymers |
US3288726A (en) * | 1961-11-30 | 1966-11-29 | American Potash & Chem Corp | B-n linked borazene derivatives and their preparation |
DE1206899B (de) * | 1963-11-29 | 1965-12-16 | Bayer Ag | Verfahren zur Herstellung von siliciumhaltigen N, N', N"-Triorgano-B, B', B"-trihydrido-borazolen |
JPS6147735A (ja) * | 1984-08-11 | 1986-03-08 | Isoji Taniguchi | 有機窒化ホウ素重合体の製造法 |
US4581468A (en) * | 1985-05-13 | 1986-04-08 | Ultrasystems, Inc. | Boron nitride preceramic polymers |
US4801439A (en) * | 1986-09-15 | 1989-01-31 | Sri International | Catalytic process for making compounds having a non-Lewis acid/base bond between a group IIIA metal and group VA nonmetal |
US4906763A (en) * | 1987-02-13 | 1990-03-06 | Paciorek Kazimiera J L | Boron nitride preceramic polymers |
JP2572813B2 (ja) * | 1988-05-19 | 1997-01-16 | 三菱化学株式会社 | ボラジン縮合体焼成物およびその製造方法 |
US5202399A (en) * | 1988-05-24 | 1993-04-13 | Truste Of The University Of Pennsylvania | Poly(b-alkenyl-borazine) ceramic precursors |
US5204295A (en) * | 1989-02-17 | 1993-04-20 | University Of New Mexico | Precursors for boron nitride coatings |
US5030744A (en) * | 1989-03-23 | 1991-07-09 | Tonen Corporation | Polyborosilazane and process for producing same |
US5502142A (en) * | 1990-03-09 | 1996-03-26 | The Trustees Of The University Of Pennsylvania | Direct thermal synthesis and ceramic applications of poly(borazylenes) |
JPH0413730A (ja) * | 1990-05-08 | 1992-01-17 | Tonen Corp | 繊維強化有機高分子化合物複合材料 |
DE4113791A1 (de) | 1991-04-26 | 1992-10-29 | Solvay Deutschland | Verfahren zur abscheidung einer bor und stickstoff enthaltenden schicht |
FR2691150B1 (fr) * | 1992-05-15 | 1994-08-12 | Rhone Poulenc Chimie | Triéthylnylborazines, leur préparation et leur utilisation notamment pour la préparation de céramique essentiellement à base de nitrure de bore. |
US5252684A (en) | 1992-11-02 | 1993-10-12 | Zank Gregg A | Borazine derivatized hydridopolysilazane polymers |
JPH11307633A (ja) * | 1997-11-17 | 1999-11-05 | Sony Corp | 低誘電率膜を有する半導体装置、およびその製造方法 |
JP3789501B2 (ja) | 1994-12-14 | 2006-06-28 | ソニー株式会社 | 半導体装置に用いられる絶縁膜構造の製造方法 |
FR2757848B1 (fr) * | 1996-12-27 | 1999-03-26 | Europ Propulsion | Preformes fibreuses gainees d'un revetement bn original, composites les incorporant et leurs preparations |
US5855962A (en) * | 1997-01-09 | 1999-01-05 | International Business Machines Corporation | Flowable spin-on insulator |
US6235851B1 (en) * | 1997-05-23 | 2001-05-22 | Daicel Chemical Industries, Ltd. | Polymerizable adamantane derivatives and process for producing the same |
JP4314650B2 (ja) | 1998-08-08 | 2009-08-19 | 東京エレクトロン株式会社 | 半導体装置の層間絶縁膜の形成方法 |
JP3767248B2 (ja) | 1999-06-01 | 2006-04-19 | 三菱電機株式会社 | 半導体装置 |
JP3508629B2 (ja) | 1999-06-28 | 2004-03-22 | 三菱電機株式会社 | 耐熱低誘電率薄膜の形成方法、その耐熱低誘電率薄膜からなる半導体層間絶縁膜及びこの半導体層間絶縁膜を用いた半導体装置 |
JP2001015595A (ja) | 1999-06-29 | 2001-01-19 | Mitsubishi Electric Corp | 半導体装置 |
TW521386B (en) * | 2000-06-28 | 2003-02-21 | Mitsubishi Heavy Ind Ltd | Hexagonal boron nitride film with low dielectric constant, layer dielectric film and method of production thereof, and plasma CVD apparatus |
US6924545B2 (en) * | 2001-03-27 | 2005-08-02 | National Institute Of Advanced Industrial Science | Low-dielectric-constant interlayer insulating film composed of borazine-silicon-based polymer and semiconductor device |
JP2002317049A (ja) | 2001-04-18 | 2002-10-31 | Nippon Shokubai Co Ltd | ホウ素含有ポリマー組成物 |
JP3778045B2 (ja) * | 2001-10-09 | 2006-05-24 | 三菱電機株式会社 | 低誘電率材料の製造方法および低誘電率材料、並びにこの低誘電率材料を用いた絶縁膜および半導体装置 |
JP4263453B2 (ja) * | 2002-09-25 | 2009-05-13 | パナソニック株式会社 | 無機酸化物及びこれを用いた発光装置 |
US7625642B2 (en) * | 2002-09-26 | 2009-12-01 | Hitachi Chemical Co., Ltd | Borazine-based resin, and method for production thereof, borazine based resin composition, insulating coating and method for formation thereof, and electronic parts having the insulating coating |
-
2001
- 2001-10-09 JP JP2001311405A patent/JP3778045B2/ja not_active Expired - Fee Related
-
2002
- 2002-10-09 US US10/266,794 patent/US6924240B2/en not_active Expired - Lifetime
-
2005
- 2005-04-18 US US11/107,800 patent/US20050181628A1/en not_active Abandoned
-
2009
- 2009-09-14 US US12/558,810 patent/US8674046B2/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8288294B2 (en) | 2008-06-30 | 2012-10-16 | Mitsubishi Heavy Industries, Ltd. | Insulating film for semiconductor device, process and apparatus for producing insulating film for semiconductor device, semiconductor device, and process for producing the semiconductor device |
Also Published As
Publication number | Publication date |
---|---|
JP2003119289A (ja) | 2003-04-23 |
US20100004425A1 (en) | 2010-01-07 |
US20050181628A1 (en) | 2005-08-18 |
US6924240B2 (en) | 2005-08-02 |
US8674046B2 (en) | 2014-03-18 |
US20030100175A1 (en) | 2003-05-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP3778045B2 (ja) | 低誘電率材料の製造方法および低誘電率材料、並びにこの低誘電率材料を用いた絶縁膜および半導体装置 | |
JP3084367B1 (ja) | 層間絶縁膜の形成方法及び半導体装置 | |
US7998856B2 (en) | Interconnects with a dielectric sealant layer | |
US6184121B1 (en) | Chip interconnect wiring structure with low dielectric constant insulator and methods for fabricating the same | |
TWI300971B (en) | Semiconductor device | |
US7088003B2 (en) | Structures and methods for integration of ultralow-k dielectrics with improved reliability | |
US8017522B2 (en) | Mechanically robust metal/low-κ interconnects | |
JP4461215B2 (ja) | 低誘電率絶縁材料とそれを用いた半導体装置 | |
US7442756B2 (en) | Polymer for sealing porous materials during chip production | |
US7144803B2 (en) | Methods of forming boron carbo-nitride layers for integrated circuit devices | |
JP5224738B2 (ja) | 低誘電率材料形成用原料 | |
TW200807625A (en) | Electronic structures utilizing etch resistant boron and phosphorus materials and methods to form same | |
US8338290B2 (en) | Method for fabricating semiconductor device | |
JP2005533880A (ja) | チップ製造時における多孔性材料の封止方法およびそのための化合物 | |
US20020063338A1 (en) | Semiconductor device | |
TWI254716B (en) | Semiconductor device and semiconductor package | |
US7514709B2 (en) | Organo-silsesquioxane polymers for forming low-k dielectrics | |
JP4415921B2 (ja) | 半導体装置 | |
US20050095828A1 (en) | Process for sealing plasma-damaged, porous low-k materials | |
KR20040084737A (ko) | 반도체 장치의 제조 방법 | |
JP2000150510A (ja) | 複合多孔質絶縁膜およびその形成方法、ならびに電子装置およびその製造方法 | |
JP2012012607A (ja) | 低誘電率材料形成用原料 | |
JP4493278B2 (ja) | 多孔性樹脂絶縁膜、電子装置及びそれらの製造方法 | |
US20060115980A1 (en) | Method for decreasing a dielectric constant of a low-k film | |
JP2000243831A (ja) | 半導体装置とその製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20031023 |
|
RD01 | Notification of change of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7421 Effective date: 20040709 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20050728 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20050915 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20051115 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20060113 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20060207 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20060220 |
|
R151 | Written notification of patent or utility model registration |
Ref document number: 3778045 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R151 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20060113 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100310 Year of fee payment: 4 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100310 Year of fee payment: 4 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110310 Year of fee payment: 5 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110310 Year of fee payment: 5 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120310 Year of fee payment: 6 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130310 Year of fee payment: 7 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130310 Year of fee payment: 7 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140310 Year of fee payment: 8 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |