JP3723221B2 - フッ素化オニウム塩類、フッ素化オニウム含有硬化性組成物、およびフッ素化オニウムを使用する硬化方法 - Google Patents
フッ素化オニウム塩類、フッ素化オニウム含有硬化性組成物、およびフッ素化オニウムを使用する硬化方法 Download PDFInfo
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- JP3723221B2 JP3723221B2 JP52364697A JP52364697A JP3723221B2 JP 3723221 B2 JP3723221 B2 JP 3723221B2 JP 52364697 A JP52364697 A JP 52364697A JP 52364697 A JP52364697 A JP 52364697A JP 3723221 B2 JP3723221 B2 JP 3723221B2
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- onium
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- curing
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- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 238000010943 off-gassing Methods 0.000 description 1
- 150000002891 organic anions Chemical class 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 125000005460 perfluorocycloalkyl group Chemical group 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 description 1
- REJGOFYVRVIODZ-UHFFFAOYSA-N phosphanium;chloride Chemical class P.Cl REJGOFYVRVIODZ-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000002390 rotary evaporation Methods 0.000 description 1
- 238000010074 rubber mixing Methods 0.000 description 1
- 238000001577 simple distillation Methods 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- UUCCCPNEFXQJEL-UHFFFAOYSA-L strontium dihydroxide Chemical compound [OH-].[OH-].[Sr+2] UUCCCPNEFXQJEL-UHFFFAOYSA-L 0.000 description 1
- 229910001866 strontium hydroxide Inorganic materials 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- OBTWBSRJZRCYQV-UHFFFAOYSA-N sulfuryl difluoride Chemical group FS(F)(=O)=O OBTWBSRJZRCYQV-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- OKUCEQDKBKYEJY-UHFFFAOYSA-N tert-butyl 3-(methylamino)pyrrolidine-1-carboxylate Chemical compound CNC1CCN(C(=O)OC(C)(C)C)C1 OKUCEQDKBKYEJY-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-M toluene-4-sulfonate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-M 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 description 1
- 229920003249 vinylidene fluoride hexafluoropropylene elastomer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/576,097 | 1995-12-21 | ||
| US08/576,097 US5591804A (en) | 1995-12-21 | 1995-12-21 | Fluorinated onium salts, curable compositions containing same, and method of curing using same |
| PCT/US1996/018936 WO1997023556A1 (en) | 1995-12-21 | 1996-11-26 | Fluorinated onium salts, curable compositions containing same, and method of curing using same |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2000502389A JP2000502389A (ja) | 2000-02-29 |
| JP2000502389A5 JP2000502389A5 (enExample) | 2004-11-04 |
| JP3723221B2 true JP3723221B2 (ja) | 2005-12-07 |
Family
ID=24302974
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP52364697A Expired - Fee Related JP3723221B2 (ja) | 1995-12-21 | 1996-11-26 | フッ素化オニウム塩類、フッ素化オニウム含有硬化性組成物、およびフッ素化オニウムを使用する硬化方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5591804A (enExample) |
| EP (1) | EP0868477B1 (enExample) |
| JP (1) | JP3723221B2 (enExample) |
| AU (1) | AU1061797A (enExample) |
| CA (1) | CA2238941C (enExample) |
| DE (1) | DE69633135T2 (enExample) |
| WO (1) | WO1997023556A1 (enExample) |
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| US20040114772A1 (en) * | 2002-03-21 | 2004-06-17 | David Zlotnick | Method and system for transmitting and/or receiving audio signals with a desired direction |
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| CN1662566B (zh) * | 2002-06-21 | 2010-06-16 | 3M创新有限公司 | 极性端基量减少的含氟聚合物的制备方法 |
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| US8309641B2 (en) | 2010-08-13 | 2012-11-13 | E I Du Pont De Nemours And Company | Curable fluoroelastomer compositions |
| US8227535B2 (en) | 2010-12-07 | 2012-07-24 | E I Du Pont De Nemours And Company | Polyhydroxy curable fluoroelastomer compositions |
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| US9074074B2 (en) | 2011-12-15 | 2015-07-07 | The Chemours Company Fc, Llc | Polyhydroxy curable fluoroelastomer compositions |
| EP2934878B1 (en) | 2012-12-18 | 2016-09-21 | E. I. du Pont de Nemours and Company | Laminates of fluoroelastomer and heat-resistant acrylate elastomer |
| WO2014123851A2 (en) | 2013-02-07 | 2014-08-14 | E. I. Du Pont De Nemours And Company | Polyhydroxy curable fluoroelastomer composition |
| CN110168002A (zh) | 2016-12-28 | 2019-08-23 | 3M创新有限公司 | 含硅卤化弹性体 |
| JP7466447B2 (ja) | 2017-12-22 | 2024-04-12 | スリーエム イノベイティブ プロパティズ カンパニー | ケイ素含有表面層を有する過酸化物硬化ハロゲン化エラストマー |
| CN111757906A (zh) | 2018-02-19 | 2020-10-09 | 3M创新有限公司 | 可固化含氟弹性体组合物 |
| WO2019159067A1 (en) | 2018-02-19 | 2019-08-22 | 3M Innovative Properties Company | Curable fluoroelastomer composition |
| WO2019159066A1 (en) | 2018-02-19 | 2019-08-22 | 3M Innovative Properties Company | Blends of crosslinking agents for fluoroelastomers |
| EP3775019A1 (en) | 2018-04-10 | 2021-02-17 | 3M Innovative Properties Company | Blends of crosslinking agents for fluoroelastomers |
| US20210108101A1 (en) | 2018-06-12 | 2021-04-15 | 3M Innovative Properties Company | Fluorinated polymer coating compositions and articles therefrom |
| EP3807355B1 (en) | 2018-06-13 | 2022-04-27 | 3M Innovative Properties Company | Curable fluoroelastomer composition |
| EP3837309A1 (en) | 2018-08-13 | 2021-06-23 | 3M Innovative Properties Company | Curable fluoroelastomer composition |
| EP3980488A1 (en) | 2019-06-06 | 2022-04-13 | 3M Innovative Properties Company | Curable fluoropolymer compositions comprising a compound containing a phthalonitrile and a nucleophilic functional group and cured articles therefrom |
| US12428384B2 (en) | 2019-06-28 | 2025-09-30 | 3M Innovative Properties Company | Hydroxy-functionalized triazine compounds, curable fluoropolymer compositions comprising such compounds and cured articles therefrom |
| JP7698633B2 (ja) | 2019-08-27 | 2025-06-25 | スリーエム イノベイティブ プロパティズ カンパニー | 金属フッ化物粒子を含む硬化性フルオロポリマー組成物及びそれからの物品 |
| JP2025532134A (ja) | 2022-09-20 | 2025-09-29 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | フルオロエラストマー用硬化剤としての非フッ素化レゾルシノール及びヒドロキノン類似体 |
| WO2024064107A1 (en) | 2022-09-20 | 2024-03-28 | The Chemours Company Fc, Llc | Fluorinated resorcinol and hydroquinone analogs as curing agents for fluoroelastomers |
| JP2025533279A (ja) | 2022-10-12 | 2025-10-03 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | 硬化性フルオロエラストマー組成物及びそれから形成される低摩擦の硬化フルオロエラストマー（ｆｋＭ） |
| WO2025193781A1 (en) | 2024-03-13 | 2025-09-18 | The Chemours Company Fc, Llc | Fluorinated resorcinol and hydroquinone analogs as curing agents for fluoroelastomers |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3442664A (en) * | 1966-04-26 | 1969-05-06 | Minnesota Mining & Mfg | Treating composition,method of treating and treated surfaces |
| US3518292A (en) * | 1967-03-27 | 1970-06-30 | Dow Corning | Quaternary phosphonium silicon complexes |
| US4094911A (en) * | 1969-03-10 | 1978-06-13 | Minnesota Mining And Manufacturing Company | Poly(perfluoroalkylene oxide) derivatives |
| US3876654A (en) * | 1970-12-23 | 1975-04-08 | Du Pont | Fluoroelastomer composition |
| USB493537I5 (enExample) * | 1973-10-16 | 1976-03-23 | ||
| SE426839B (sv) * | 1977-12-14 | 1983-02-14 | Montedison Spa | Vulkbara kompositioner av vinylidenfluoridelaster samt forfarande for vulkning herav |
| US4233421A (en) * | 1979-02-26 | 1980-11-11 | Minnesota Mining And Manufacturing Company | Fluoroelastomer composition containing sulfonium curing agents |
| US5086123A (en) * | 1984-02-27 | 1992-02-04 | Minnesota Mining And Manufacturing Company | Fluoroelastomer compositions containing fluoroaliphatic sulfonamides as curing agents |
| US4535184A (en) * | 1984-06-08 | 1985-08-13 | E. I. Du Pont De Nemours And Company | Tris(disubstituted amino)sulfonium perfluorocarbanion salts |
| JPS6121149A (ja) * | 1984-07-09 | 1986-01-29 | Daikin Ind Ltd | 加硫成形用組成物 |
| US4927887A (en) * | 1984-09-21 | 1990-05-22 | Bridgestone/Firestone, Inc. | Modified rubber compositions containing aromatic six-membered heterocyclic nitrogen-containing groups |
| US4828923A (en) * | 1987-04-10 | 1989-05-09 | Nippon Zeon Co., Ltd. | Rubber laminates of fluororubber and nitrile rubber |
| US4882390A (en) * | 1988-04-01 | 1989-11-21 | Minnesota Mining And Manufacturing Company | Fluoroelastomer composition with organo-onium compounds |
| US4912171A (en) * | 1988-04-01 | 1990-03-27 | Minnesota Mining And Manufacturing Company | Fluoroelastomer curing process with phosphonium compound |
| CA1328533C (en) * | 1988-04-01 | 1994-04-12 | Werner Marie Aschille Grootaert | Fluoroelastomer composition |
| JP2583444B2 (ja) * | 1988-06-23 | 1997-02-19 | 日本ゼオン株式会社 | ゴム積層体の製造方法 |
| US5322904A (en) * | 1988-09-28 | 1994-06-21 | Exfluor Research Corporation | Liquid-phase fluorination |
| US5384374A (en) * | 1991-01-11 | 1995-01-24 | Minnesota Mining And Manufacturing Company | Curing fluorocarbon elastomers |
| JPH05339536A (ja) * | 1992-06-11 | 1993-12-21 | Minnesota Mining & Mfg Co <3M> | フッ素ゴム塗布用組成物 |
| US5262490A (en) * | 1992-08-24 | 1993-11-16 | Minnesota Mining And Manufacturing Company | Fluoroelastomer composition with organo-onium compounds |
| US5274159A (en) * | 1993-02-18 | 1993-12-28 | Minnesota Mining And Manufacturing Company | Destructable fluorinated alkoxysilane surfactants and repellent coatings derived therefrom |
-
1995
- 1995-12-21 US US08/576,097 patent/US5591804A/en not_active Expired - Fee Related
-
1996
- 1996-11-26 WO PCT/US1996/018936 patent/WO1997023556A1/en not_active Ceased
- 1996-11-26 DE DE69633135T patent/DE69633135T2/de not_active Expired - Fee Related
- 1996-11-26 JP JP52364697A patent/JP3723221B2/ja not_active Expired - Fee Related
- 1996-11-26 CA CA002238941A patent/CA2238941C/en not_active Expired - Fee Related
- 1996-11-26 AU AU10617/97A patent/AU1061797A/en not_active Abandoned
- 1996-11-26 EP EP96941490A patent/EP0868477B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69633135T2 (de) | 2005-09-08 |
| CA2238941A1 (en) | 1997-07-03 |
| CA2238941C (en) | 2006-10-03 |
| AU1061797A (en) | 1997-07-17 |
| DE69633135D1 (de) | 2004-09-16 |
| EP0868477B1 (en) | 2004-08-11 |
| US5591804A (en) | 1997-01-07 |
| JP2000502389A (ja) | 2000-02-29 |
| WO1997023556A1 (en) | 1997-07-03 |
| EP0868477A1 (en) | 1998-10-07 |
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