DE69633135T2 - Fluorierte oniumsatze, härtbare zusammensetzungen, welche selbige enthalten, und härtungsverfahren unter deren verwendung - Google Patents
Fluorierte oniumsatze, härtbare zusammensetzungen, welche selbige enthalten, und härtungsverfahren unter deren verwendung Download PDFInfo
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- DE69633135T2 DE69633135T2 DE69633135T DE69633135T DE69633135T2 DE 69633135 T2 DE69633135 T2 DE 69633135T2 DE 69633135 T DE69633135 T DE 69633135T DE 69633135 T DE69633135 T DE 69633135T DE 69633135 T2 DE69633135 T2 DE 69633135T2
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- onium
- curing
- composition
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- 238000000034 method Methods 0.000 title claims description 13
- 230000008569 process Effects 0.000 title description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 21
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- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical group FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 11
- 125000003118 aryl group Chemical group 0.000 claims description 10
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 8
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims description 8
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- 125000000753 cycloalkyl group Chemical group 0.000 claims description 6
- 239000006082 mold release agent Substances 0.000 claims description 6
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 125000001153 fluoro group Chemical group F* 0.000 claims description 4
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- 125000001033 ether group Chemical group 0.000 claims description 2
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- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 61
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 4
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- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 3
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- 150000004714 phosphonium salts Chemical group 0.000 description 3
- 238000001394 phosphorus-31 nuclear magnetic resonance spectrum Methods 0.000 description 3
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
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- COWKRCCNQSQUGJ-UHFFFAOYSA-N 1,1,2,2,3-pentafluoropropan-1-ol Chemical compound OC(F)(F)C(F)(F)CF COWKRCCNQSQUGJ-UHFFFAOYSA-N 0.000 description 2
- OWLGMGLVCDLDNG-UHFFFAOYSA-N 2-[3-[bis(2-methylpropyl)phosphanyl]propyl]phenol Chemical compound CC(C)CP(CC(C)C)CCCC1=CC=CC=C1O OWLGMGLVCDLDNG-UHFFFAOYSA-N 0.000 description 2
- TXBIZRLVIDXDGB-UHFFFAOYSA-N 2-methylpropylphosphane Chemical compound CC(C)CP TXBIZRLVIDXDGB-UHFFFAOYSA-N 0.000 description 2
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- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
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- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
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- UGMUDSKJLAUMTC-UHFFFAOYSA-N 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanamide Chemical compound NC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F UGMUDSKJLAUMTC-UHFFFAOYSA-N 0.000 description 1
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- UMKARVFXJJITLN-UHFFFAOYSA-N lead;phosphorous acid Chemical compound [Pb].OP(O)O UMKARVFXJJITLN-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- UHNWOJJPXCYKCG-UHFFFAOYSA-L magnesium oxalate Chemical compound [Mg+2].[O-]C(=O)C([O-])=O UHNWOJJPXCYKCG-UHFFFAOYSA-L 0.000 description 1
- 238000007734 materials engineering Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 150000002891 organic anions Chemical class 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 125000005460 perfluorocycloalkyl group Chemical group 0.000 description 1
- RVZRBWKZFJCCIB-UHFFFAOYSA-N perfluorotributylamine Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)N(C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F RVZRBWKZFJCCIB-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 description 1
- REJGOFYVRVIODZ-UHFFFAOYSA-N phosphanium;chloride Chemical class P.Cl REJGOFYVRVIODZ-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- 239000006235 reinforcing carbon black Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000002390 rotary evaporation Methods 0.000 description 1
- 238000010074 rubber mixing Methods 0.000 description 1
- 238000001577 simple distillation Methods 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- UUCCCPNEFXQJEL-UHFFFAOYSA-L strontium dihydroxide Chemical compound [OH-].[OH-].[Sr+2] UUCCCPNEFXQJEL-UHFFFAOYSA-L 0.000 description 1
- 229910001866 strontium hydroxide Inorganic materials 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- OBTWBSRJZRCYQV-UHFFFAOYSA-N sulfuryl difluoride Chemical compound FS(F)(=O)=O OBTWBSRJZRCYQV-UHFFFAOYSA-N 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-M toluene-4-sulfonate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-M 0.000 description 1
- 238000007056 transamidation reaction Methods 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US576097 | 1995-12-21 | ||
| US08/576,097 US5591804A (en) | 1995-12-21 | 1995-12-21 | Fluorinated onium salts, curable compositions containing same, and method of curing using same |
| PCT/US1996/018936 WO1997023556A1 (en) | 1995-12-21 | 1996-11-26 | Fluorinated onium salts, curable compositions containing same, and method of curing using same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69633135D1 DE69633135D1 (de) | 2004-09-16 |
| DE69633135T2 true DE69633135T2 (de) | 2005-09-08 |
Family
ID=24302974
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69633135T Expired - Fee Related DE69633135T2 (de) | 1995-12-21 | 1996-11-26 | Fluorierte oniumsatze, härtbare zusammensetzungen, welche selbige enthalten, und härtungsverfahren unter deren verwendung |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5591804A (enExample) |
| EP (1) | EP0868477B1 (enExample) |
| JP (1) | JP3723221B2 (enExample) |
| AU (1) | AU1061797A (enExample) |
| CA (1) | CA2238941C (enExample) |
| DE (1) | DE69633135T2 (enExample) |
| WO (1) | WO1997023556A1 (enExample) |
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|---|---|---|---|---|
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| US5728773A (en) * | 1997-02-21 | 1998-03-17 | Minnesota Mining And Manufacturing Company | Fluoroelastomer composition with organo-onium and blocked-carbonate compounds |
| US6096428A (en) * | 1998-04-09 | 2000-08-01 | 3M Innovative Properties Company | Multi-layer compositions comprising a fluoropolymer |
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| US6326436B2 (en) | 1998-08-21 | 2001-12-04 | Dupont Dow Elastomers, L.L.C. | Fluoroelastomer composition having excellent processability and low temperature properties |
| US6329469B1 (en) | 1998-08-21 | 2001-12-11 | Dupont Dow Elastomers, L.L.C. | Fluoroelastomer composition having excellent processability and low temperature properties |
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| EP1194462A1 (en) | 1999-07-02 | 2002-04-10 | Dyneon LLC | Fluoroelastomer compositions and articles made therefrom |
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| IT1318487B1 (it) | 2000-04-21 | 2003-08-25 | Ausimont Spa | Fluoroelastomeri. |
| EP1167441B1 (en) * | 2000-06-29 | 2015-07-29 | 3M Innovative Properties Company | Fluoroelastomer composition comprising a mineral oil |
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| US6916871B2 (en) * | 2001-10-31 | 2005-07-12 | 3M Innovative Properties Company | Composition and method for making a fluoroelastomer |
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| US20040114772A1 (en) * | 2002-03-21 | 2004-06-17 | David Zlotnick | Method and system for transmitting and/or receiving audio signals with a desired direction |
| ITMI20020598A1 (it) | 2002-03-22 | 2003-09-22 | Ausimont Spa | Fluoroelastomeri vulcanizzabili |
| CN1662566B (zh) * | 2002-06-21 | 2010-06-16 | 3M创新有限公司 | 极性端基量减少的含氟聚合物的制备方法 |
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| US6956085B2 (en) * | 2003-02-14 | 2005-10-18 | 3M Innovative Properties Company | Fluoroelastomer compositions |
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| ATE517932T1 (de) * | 2003-06-09 | 2011-08-15 | 3M Innovative Properties Co | Aus der schmelze verarbeitbare polymerzusammensetzung, die fluorpolymer mit langkettenverzweigungen enthält |
| WO2005066218A1 (en) * | 2003-12-30 | 2005-07-21 | 3M Innovative Properties Company | Fluoropolymer coagulation method and composition |
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| US20100069554A1 (en) * | 2008-09-18 | 2010-03-18 | Dupont Performance Elastomers L.L.C. | Curable fluoropolymer compositions |
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| TWI523900B (zh) | 2010-07-20 | 2016-03-01 | 首威索勒希斯股份有限公司 | 氟彈性體組合物 |
| US8309641B2 (en) | 2010-08-13 | 2012-11-13 | E I Du Pont De Nemours And Company | Curable fluoroelastomer compositions |
| US8227535B2 (en) | 2010-12-07 | 2012-07-24 | E I Du Pont De Nemours And Company | Polyhydroxy curable fluoroelastomer compositions |
| GB201108963D0 (en) | 2011-05-27 | 2011-07-13 | 3M Innovative Properties Co | Composite materials comprising polyamides and fluoroelastomers |
| EP2557109B1 (en) | 2011-08-11 | 2019-01-23 | 3M Innovative Properties Company | Method of bonding a fluoroelastomer compound to a metal substrate using low molecular weight functional hydrocarbons as bonding promoter |
| US9074074B2 (en) | 2011-12-15 | 2015-07-07 | The Chemours Company Fc, Llc | Polyhydroxy curable fluoroelastomer compositions |
| EP2934878B1 (en) | 2012-12-18 | 2016-09-21 | E. I. du Pont de Nemours and Company | Laminates of fluoroelastomer and heat-resistant acrylate elastomer |
| WO2014123851A2 (en) | 2013-02-07 | 2014-08-14 | E. I. Du Pont De Nemours And Company | Polyhydroxy curable fluoroelastomer composition |
| CN110168002A (zh) | 2016-12-28 | 2019-08-23 | 3M创新有限公司 | 含硅卤化弹性体 |
| JP7466447B2 (ja) | 2017-12-22 | 2024-04-12 | スリーエム イノベイティブ プロパティズ カンパニー | ケイ素含有表面層を有する過酸化物硬化ハロゲン化エラストマー |
| CN111757906A (zh) | 2018-02-19 | 2020-10-09 | 3M创新有限公司 | 可固化含氟弹性体组合物 |
| WO2019159067A1 (en) | 2018-02-19 | 2019-08-22 | 3M Innovative Properties Company | Curable fluoroelastomer composition |
| WO2019159066A1 (en) | 2018-02-19 | 2019-08-22 | 3M Innovative Properties Company | Blends of crosslinking agents for fluoroelastomers |
| EP3775019A1 (en) | 2018-04-10 | 2021-02-17 | 3M Innovative Properties Company | Blends of crosslinking agents for fluoroelastomers |
| US20210108101A1 (en) | 2018-06-12 | 2021-04-15 | 3M Innovative Properties Company | Fluorinated polymer coating compositions and articles therefrom |
| EP3807355B1 (en) | 2018-06-13 | 2022-04-27 | 3M Innovative Properties Company | Curable fluoroelastomer composition |
| EP3837309A1 (en) | 2018-08-13 | 2021-06-23 | 3M Innovative Properties Company | Curable fluoroelastomer composition |
| EP3980488A1 (en) | 2019-06-06 | 2022-04-13 | 3M Innovative Properties Company | Curable fluoropolymer compositions comprising a compound containing a phthalonitrile and a nucleophilic functional group and cured articles therefrom |
| US12428384B2 (en) | 2019-06-28 | 2025-09-30 | 3M Innovative Properties Company | Hydroxy-functionalized triazine compounds, curable fluoropolymer compositions comprising such compounds and cured articles therefrom |
| JP7698633B2 (ja) | 2019-08-27 | 2025-06-25 | スリーエム イノベイティブ プロパティズ カンパニー | 金属フッ化物粒子を含む硬化性フルオロポリマー組成物及びそれからの物品 |
| JP2025532134A (ja) | 2022-09-20 | 2025-09-29 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | フルオロエラストマー用硬化剤としての非フッ素化レゾルシノール及びヒドロキノン類似体 |
| WO2024064107A1 (en) | 2022-09-20 | 2024-03-28 | The Chemours Company Fc, Llc | Fluorinated resorcinol and hydroquinone analogs as curing agents for fluoroelastomers |
| JP2025533279A (ja) | 2022-10-12 | 2025-10-03 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | 硬化性フルオロエラストマー組成物及びそれから形成される低摩擦の硬化フルオロエラストマー（ｆｋＭ） |
| WO2025193781A1 (en) | 2024-03-13 | 2025-09-18 | The Chemours Company Fc, Llc | Fluorinated resorcinol and hydroquinone analogs as curing agents for fluoroelastomers |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3442664A (en) * | 1966-04-26 | 1969-05-06 | Minnesota Mining & Mfg | Treating composition,method of treating and treated surfaces |
| US3518292A (en) * | 1967-03-27 | 1970-06-30 | Dow Corning | Quaternary phosphonium silicon complexes |
| US4094911A (en) * | 1969-03-10 | 1978-06-13 | Minnesota Mining And Manufacturing Company | Poly(perfluoroalkylene oxide) derivatives |
| US3876654A (en) * | 1970-12-23 | 1975-04-08 | Du Pont | Fluoroelastomer composition |
| USB493537I5 (enExample) * | 1973-10-16 | 1976-03-23 | ||
| SE426839B (sv) * | 1977-12-14 | 1983-02-14 | Montedison Spa | Vulkbara kompositioner av vinylidenfluoridelaster samt forfarande for vulkning herav |
| US4233421A (en) * | 1979-02-26 | 1980-11-11 | Minnesota Mining And Manufacturing Company | Fluoroelastomer composition containing sulfonium curing agents |
| US5086123A (en) * | 1984-02-27 | 1992-02-04 | Minnesota Mining And Manufacturing Company | Fluoroelastomer compositions containing fluoroaliphatic sulfonamides as curing agents |
| US4535184A (en) * | 1984-06-08 | 1985-08-13 | E. I. Du Pont De Nemours And Company | Tris(disubstituted amino)sulfonium perfluorocarbanion salts |
| JPS6121149A (ja) * | 1984-07-09 | 1986-01-29 | Daikin Ind Ltd | 加硫成形用組成物 |
| US4927887A (en) * | 1984-09-21 | 1990-05-22 | Bridgestone/Firestone, Inc. | Modified rubber compositions containing aromatic six-membered heterocyclic nitrogen-containing groups |
| US4828923A (en) * | 1987-04-10 | 1989-05-09 | Nippon Zeon Co., Ltd. | Rubber laminates of fluororubber and nitrile rubber |
| US4882390A (en) * | 1988-04-01 | 1989-11-21 | Minnesota Mining And Manufacturing Company | Fluoroelastomer composition with organo-onium compounds |
| US4912171A (en) * | 1988-04-01 | 1990-03-27 | Minnesota Mining And Manufacturing Company | Fluoroelastomer curing process with phosphonium compound |
| CA1328533C (en) * | 1988-04-01 | 1994-04-12 | Werner Marie Aschille Grootaert | Fluoroelastomer composition |
| JP2583444B2 (ja) * | 1988-06-23 | 1997-02-19 | 日本ゼオン株式会社 | ゴム積層体の製造方法 |
| US5322904A (en) * | 1988-09-28 | 1994-06-21 | Exfluor Research Corporation | Liquid-phase fluorination |
| US5384374A (en) * | 1991-01-11 | 1995-01-24 | Minnesota Mining And Manufacturing Company | Curing fluorocarbon elastomers |
| JPH05339536A (ja) * | 1992-06-11 | 1993-12-21 | Minnesota Mining & Mfg Co <3M> | フッ素ゴム塗布用組成物 |
| US5262490A (en) * | 1992-08-24 | 1993-11-16 | Minnesota Mining And Manufacturing Company | Fluoroelastomer composition with organo-onium compounds |
| US5274159A (en) * | 1993-02-18 | 1993-12-28 | Minnesota Mining And Manufacturing Company | Destructable fluorinated alkoxysilane surfactants and repellent coatings derived therefrom |
-
1995
- 1995-12-21 US US08/576,097 patent/US5591804A/en not_active Expired - Fee Related
-
1996
- 1996-11-26 WO PCT/US1996/018936 patent/WO1997023556A1/en not_active Ceased
- 1996-11-26 DE DE69633135T patent/DE69633135T2/de not_active Expired - Fee Related
- 1996-11-26 JP JP52364697A patent/JP3723221B2/ja not_active Expired - Fee Related
- 1996-11-26 CA CA002238941A patent/CA2238941C/en not_active Expired - Fee Related
- 1996-11-26 AU AU10617/97A patent/AU1061797A/en not_active Abandoned
- 1996-11-26 EP EP96941490A patent/EP0868477B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CA2238941A1 (en) | 1997-07-03 |
| CA2238941C (en) | 2006-10-03 |
| JP3723221B2 (ja) | 2005-12-07 |
| AU1061797A (en) | 1997-07-17 |
| DE69633135D1 (de) | 2004-09-16 |
| EP0868477B1 (en) | 2004-08-11 |
| US5591804A (en) | 1997-01-07 |
| JP2000502389A (ja) | 2000-02-29 |
| WO1997023556A1 (en) | 1997-07-03 |
| EP0868477A1 (en) | 1998-10-07 |
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