JP2017526792A - 接着性を改良したオレフィン系熱可塑性エラストマー、特にtpe−v類およびtpe−o類 - Google Patents
接着性を改良したオレフィン系熱可塑性エラストマー、特にtpe−v類およびtpe−o類 Download PDFInfo
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- JP2017526792A JP2017526792A JP2017513496A JP2017513496A JP2017526792A JP 2017526792 A JP2017526792 A JP 2017526792A JP 2017513496 A JP2017513496 A JP 2017513496A JP 2017513496 A JP2017513496 A JP 2017513496A JP 2017526792 A JP2017526792 A JP 2017526792A
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- tpe
- adhesion
- elastomer composition
- thermoplastic elastomer
- adhesion promoters
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Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
- C08L23/0876—Neutralised polymers, i.e. ionomers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
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Abstract
Description
本発明による熱可塑性エラストマー組成物であり、20%のPP、40%のEPDM、10%の充填剤および20%の油から形成されている。この組成物はさらに4%のPP−g−MAHと2%のEPR−G−MAHとを含む。架橋システムはフェノール性架橋システムである。実施例1のショア硬度は40D、剥離強度はアルミニウム上で815N、ステンレス鋼上で830N、鋼鉄上で780Nである。破壊状態は、アルミニウム上では凝集破壊、他の2つの材料上では剥離破壊である。
本発明の熱可塑性エラストマー組成物であり、20%のPP、37%のEPDM、10%の充填剤および20%の油から形成されている。組成物はさらに6%のPP−g−MAHと3%のアイオノマーとを含む。架橋システムはフェノール性架橋システムである。実施例2のショア硬度は40D、剥離強度はアルミニウム上で812N、ステンレス鋼上で793N、鋼鉄上で822Nである。接着の破壊状態は凝集破壊である。
本発明の熱可塑性エラストマー組成物であり、90.5%のTPE−Vから形成されている。組成物はさらに7%のPP−g−MAHと2.5%のアイオノマーとを含む。架橋システムは二次押出である。実施例3のショア硬度は50A、剥離強度はアルミニウム上で226N、ステンレス鋼上で258N、鋼鉄上で253Nである。接着の破壊状態は凝集破壊である。
本発明の熱可塑性エラストマー組成物であり、90%のTPE−Vから形成されている。組成物はさらに6%のPP−g−MAHと4%のEPR−g−MAHとを含む。架橋システムは二次押出である。実施例4のショア硬度は50A、剥離強度はアルミニウム上で258N、ステンレス鋼上で231N、鋼鉄上で258Nである。接着の破壊状態は凝集破壊である。
本発明の熱可塑性エラストマー組成物であり、7%のポリプロピレン、54%のEPDM、10%の充填剤および17%の油から形成されている。組成物はさらに4.5%のPP−g−MAHと4.5%のEPR−g−MAHとを含む。架橋システムはフェノール樹脂である。実施例5のショア硬度は55A、極限伸びは260%、最大σは4.1MPa、密度は0.961g/cm3、剥離強度は67Nである。破壊状態は凝集破壊である。
本発明の熱可塑性エラストマー組成物であり、9%のポリプロピレン、56%のEPDM、10%の充填剤および12%の油から形成されている。組成物はさらに5%のPP−g−MAHと5%のEPR−g−MAHとを含む。架橋システムは過酸化物である。実施例6のショア硬度は55A、極限伸びは400%、最大σは5.1MPa、密度は0.940g/cm3、剥離強度は84.6Nである。破壊状態は凝集破壊である。
本発明の熱可塑性エラストマー組成物であり、8%のポリプロピレン、49%のEPDM、9%の充填剤および22%の油から形成されている。組成物はさらに5%のPP−g−MAHと5%のEPR−g−MAHとを含む。架橋システムは過酸化物である。実施例6のショア硬度は55A、極限伸びは480%、最大σは4.3MPa、密度は0.913g/cm3、剥離強度は81.5Nである。破壊状態は凝集破壊である。
最後の実施例は、40%のポリプロピレン、42%のEPDMおよび10%の充填剤から形成されている。この組成物はさらに5%のPP−g−MAHと2.5%のアイオノマーを含む。実施例12のショア硬度は40D、引張剥離強度はアルミニウム上で354N、ステンレス鋼上で608N、鋼鉄上で576N、メッキ鋼鉄上で391Nである。
Claims (11)
- ゴム成分とポリオレフィンとを含むオレフィン系熱可塑性エラストマー組成物であって、湿潤接着促進剤の群から選択される1種以上の第1の接着促進剤と、化学反応性接着促進剤の群から選択される1種以上の第2の接着促進剤とを含む接着促進剤系をさらに含むことを特徴とする、オレフィン系熱可塑性エラストマー組成物。
- 熱可塑性ポリオレフィン成分が、熱可塑性を有する結晶性もしくは半結晶性のポリオレフィンホモポリマーおよび/または熱可塑性を有する結晶性もしくは半結晶性のポリオレフィンコポリマーであり、熱可塑性ポリオレフィン成分のモノオレフィンモノマーが2〜7個の炭素原子を有し、特にエチレン、プロピレン、1−ブテン、イソブチレン、1−ペンテン、1−ヘキセン、1−オクテン、3−メチル−1−ペンテン、4−メチル−1−ペンテンおよび5−メチル−1−ヘキセンから選択され、好ましくは3〜6個の炭素原子を有し、特に好ましくはプロピレンであることを特徴とする、請求項1に記載のオレフィン系熱可塑性エラストマー組成物。
- 特に架橋性の高いゴム成分が、エチレン、プロピレンおよび非共役ジエンのターポリマーゴム(EPDM)および/またはコポリマー(例えばエチレン−プロピレンゴム(EPR)、エチレン/α−オレフィンコポリマーゴム(FAM)、またはエチレン/α−オレフィン/ジエンターポリマーゴム(EADM))から選択されることを特徴とする、請求項1または2に記載のオレフィン系熱可塑性エラストマー組成物。
- 湿潤接着促進剤の群が、アイオノマー、様々な酢酸ビニル含量を有するエチレン−酢酸ビニルゴム(EVM)、ならびに高分子の主鎖がポリプロピレン、ポリエチレン、ポリプロピレン−ポリエチレンコポリマー、ポリ−α−オレフィン、エチレン−プロピレン−ジエンゴム(EPDM)およびポリアミドによって形成されている無水マレイン酸グラフト化ポリマーからなることを特徴とする、請求項1、2または3のいずれか一項に記載のオレフィン系熱可塑性エラストマー組成物。
- 化学反応性接着促進剤の群が、無水物、エポキシド、シランおよびそのエステル、カルボキシル基、エステル基または酸塩化物のうち1種の官能基を含む接着促進剤からなることを特徴とする、先行する請求項のいずれかに記載のオレフィン系熱可塑性エラストマー組成物。
- 化学反応性接着促進剤の群が、無水マレイン酸グラフト化ポリマーからなり、該無水マレイン酸グラフト化ポリマーの高分子主鎖が、ポリプロピレン、ポリエチレン、ポリプロピレン−ポリエチレンコポリマー、ポリ−α−オレフィン、エチレン−プロピレン−ジエンゴム(EPDM)およびポリアミドにより形成され、かつグラフト性シロキサン、エポキシド、エポキシ化合物またはグリシジル化合物により形成されていることを特徴とする、請求項5に記載のオレフィン系熱可塑性エラストマー組成物。
- 接着促進剤系が、2〜8種、特に2〜6種、特に好ましくは2〜4種の接着促進剤を含むことを特徴とする、先行する請求項のいずれかに記載のオレフィン系熱可塑性エラストマー組成物。
- 組成物中の接着促進剤系の含量が、0.5〜25重量%、好ましくは1.0〜15重量%、特に好ましくは1.5〜10重量%であることを特徴とする、先行する請求項のいずれかに記載のオレフィン系熱可塑性エラストマー組成物。
- 補強充填剤、非補強充填剤、プロセスオイル、希釈油または伸展油、可塑剤、ワックス、安定剤、抗酸化剤、架橋剤、加工助剤、内部潤滑剤、外部潤滑剤、顔料および着色剤から選択される1種以上の添加剤を含有することを特徴とする、先行する請求項のいずれかに記載のオレフィン系熱可塑性エラストマー組成物。
- 先行する請求項のいずれかに記載の、接着性を改良したTPE−VまたはTPE−Oを製造する方法であって、該製造が1ステップで行われ、接着促進剤の組み合わせが架橋ステップの間に添加されること、または該製造が複数のステップで行われ、TPE−V化合物が得られた後に初めて単軸押出機、二軸押出機またはバンバリーミキサーなどの混合器を用いて接着性の改良が行われることを特徴とする方法。
- 金属ポリマー複合体の製造によって、自動車産業、造船、製造機器、電気/電子産業、建設および建築産業、医療技術、医薬産業、家具産業、包装産業、スポーツおよびレジャー産業、ならびに事務用品、家庭用品、化粧品の分野における部品を製造するための、先行する請求項のいずれか一項に記載の、接着性を改良したTPE−VまたはTPE−Oの使用。
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PCT/EP2015/070609 WO2016038089A1 (de) | 2014-09-11 | 2015-09-09 | Haftungsmodifizierte olefinische thermoplastische elastomere, insbesondere tpe-v, tpe-o |
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CN102633964A (zh) * | 2012-04-28 | 2012-08-15 | 南京信息工程大学 | 一种磺化sbs离子聚合物及其应用 |
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2014
- 2014-09-11 DE DE102014218260.3A patent/DE102014218260A1/de not_active Withdrawn
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2015
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- 2015-09-09 CN CN201580041030.XA patent/CN107075208A/zh active Pending
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- 2015-09-09 WO PCT/EP2015/070609 patent/WO2016038089A1/de active Application Filing
- 2015-09-09 BR BR112017003564A patent/BR112017003564A2/pt not_active Application Discontinuation
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- 2015-09-09 KR KR1020177006806A patent/KR101835311B1/ko active IP Right Grant
- 2015-09-09 EP EP15770463.6A patent/EP3191545B1/de active Active
- 2015-09-09 JP JP2017513496A patent/JP6240812B2/ja active Active
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JP2019127528A (ja) * | 2018-01-24 | 2019-08-01 | 三井化学株式会社 | 熱可塑性エラストマー組成物 |
JP7088679B2 (ja) | 2018-01-24 | 2022-06-21 | 三井化学株式会社 | 熱可塑性エラストマー組成物 |
Also Published As
Publication number | Publication date |
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KR101835311B1 (ko) | 2018-03-07 |
ES2675033T3 (es) | 2018-07-05 |
JP6240812B2 (ja) | 2017-11-29 |
KR20170040354A (ko) | 2017-04-12 |
PL3191545T3 (pl) | 2018-09-28 |
MY183817A (en) | 2021-03-17 |
MX2017002756A (es) | 2017-05-19 |
TWI561566B (en) | 2016-12-11 |
CN107075208A (zh) | 2017-08-18 |
TW201609916A (zh) | 2016-03-16 |
WO2016038089A1 (de) | 2016-03-17 |
RU2643036C1 (ru) | 2018-01-30 |
BR112017003564A2 (pt) | 2017-12-05 |
US20170260431A1 (en) | 2017-09-14 |
EP3191545B1 (de) | 2018-04-25 |
EP3191545A1 (de) | 2017-07-19 |
SG11201701949TA (en) | 2017-04-27 |
DE102014218260A1 (de) | 2016-03-17 |
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