JP2017516907A - 金属表面に対して接着力を有する熱可塑性エラストマー組成物 - Google Patents
金属表面に対して接着力を有する熱可塑性エラストマー組成物 Download PDFInfo
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- JP2017516907A JP2017516907A JP2017513325A JP2017513325A JP2017516907A JP 2017516907 A JP2017516907 A JP 2017516907A JP 2017513325 A JP2017513325 A JP 2017513325A JP 2017513325 A JP2017513325 A JP 2017513325A JP 2017516907 A JP2017516907 A JP 2017516907A
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- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
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Abstract
Description
・85%リン酸に80℃で3分間
・30%硝酸に23℃で3分間
・70%硫酸に23℃で60分間
・pH10の水酸化アンモニウムに23℃で3分間
本発明に従って開発および試験されたTPE化合物の全ては、共回転スクリュー、および溶融ポンプを備える二軸押出機において製造された。スクリューの直径は27mmであり、L/D比は46である。前記押出機は、8つの温度調節可能な押出し領域を有する。前記スクリューの回転速度は、100〜800rpmの間にある。次に、水の存在下で、造粒が行われる。
極性官能基化されたTPS(A):KRATON FG 1901GT、KRATON MD 66845 GS
接着補助樹脂(B):ENDEX(登録商標)155、NORSOLENE(登録商標)W140、EASTOTAC(登録商標)H−130R
プロセスオイル(C):Shell Ondina(登録商標)941
任意的に、MAHでグラフトされた熱可塑性物質(PE):SCONA TSPE 2102GAHDS
さらなる原料を、比較例のために使用した。
官能基化されていないTPS:Kraton G 1651 ES、SEPTON 4033
熱可塑性物質(PP):Moplen(登録商標)HP 501 L
TPU:DESMOPAN(登録商標) 487
フィラー:OMYACARB(登録商標) 5 GU
MNT法によって前処理されたアルミニウムの金属板を、追加の処理をせずに、直接用いた。
a)汚れおよび酸化層を除去するために、Scotch−Brite(商標)WR−RL研磨用原反、赤色、Art.No.61152を用いて、前記表面を研磨する。
b)アセトンで脱脂する。
VDI 2019に基づいて、以下の条件で製造した試験片において、全ての接着力測定を行った(図1参照)。
さらなるパラメータの試験のために、125mm×125mm×2mmの寸法を有する表1の純粋なTPE化合物の試験板を製造した。表2に従って、硬度、密度、引っ張り強さおよび破断伸びを測定した。硬度および密度の測定を、これらの試験板および該試験板の一部において行った。引っ張り強さおよび破断伸びの測定のために、2±0.05mmの密度を有し、「純粋なTPE」試験板から打抜かれたS2試験片を、各場合において使用した。
DIN ISO 1817に基づいて、各試験片(接着力の試験のための図1の試験片、引っ張り強さおよび破断点伸びのためのS2試験片、硬度および密度のための項目5で挙げた試験板または該試験板の一部)を、以下の化学物質に連続して曝した。
・85%リン酸に80℃で3分間
・30%硝酸に23℃で3分間
・70%硫酸に23℃で60分間
・pH10の水酸化アンモニウムに23℃で3分間
例I、II、およびIIIは、参照例を示している。例Iの化合物は上記化学物質に対する耐性を有するが、金属に接着しない。また、低分子量用に使用される官能基化されていないTPSを交換しても、挙動は変わらない。参照化合物III、すなわち、TPUは、NMT法に従って前処理されたアルミニウムに良好に接着し、前処理の程度が低い金属への接着に乏しいが、化学物質への耐性がない。さらに、純粋なTPSは、所望のショアA硬度の上限である。本発明に係る他の例IV〜VIIの全てによって、本発明の目的が得られる。
Claims (12)
- (D)重量平均分子量(Mw)が50,000〜500,000g/molであるスチレン含有ブロックコポリマー(TPS)を含む極性官能基化されたTPEであって、カルボン酸基、無水カルボン酸基、エポキシ基、ヒドロキシ基、アミン基、またはアミド基からなる群から選ばれる極性基を有する極性官能基化されたTPEと、
(E)脂肪族合成樹脂および芳香族合成樹脂またはこれらの混合物から選ばれる、接着補助樹脂と、
(F)プロセスオイルと、を含む、
TPE化合物。 - 前記TPE化合物は、30〜90ShAのショアA硬度を有する、
請求項1に記載のTPE化合物。 - 前記TPSは、A−B−Aトリブロックコポリマーである、
請求項1または2に記載のTPE化合物。 - 前記トリブロックコポリマーのAブロックはポリスチレンであり、前記トリブロックコポリマーのBブロックは、ポリブタジエン、ポリイソプレン、および/またはポリイソブテンから選ばれる、
請求項3に記載のTPE化合物。 - 前記Aブロックにおいて、前記スチレンモノマーは、スチレン誘導体、好ましくは、α−メチルスチレン、2−メチルスチレン、3−メチルスチレン、4−メチルスチレン、4−tert−ブチルスチレン、および4−シクロヘキシルスチレン、またはビニルナフタレン誘導体、好ましくは、1−ビニルナフタレンおよび2−ビニルナフタレンで、部分的または完全に置換され得る、
請求項4に記載のTPE化合物。 - 前記Bブロックは、ジエンの混合物を含み得る、
請求項4に記載のTPE化合物。 - 前記Bブロックは、部分的または完全に、水素化されている、
請求項4に記載のTPE化合物。 - 前記TPEは、前記極性官能基化されたTPEに対して、前記極性基のグラフト化レベルが0.5〜5.0%である、
請求項1乃至7のいずれか1項に記載のTPE化合物。 - 金属、ガラス、セラミック、熱可塑性物質、およびそれらの混合物を有する複合材料の製造のための、請求項1乃至8のいずれか1項に記載のTPE化合物の使用。
- 前記金属は、アルミニウム、銅、チタン、鋼鉄、ステンレス鋼、および/またはこれらの合金から選ばれる、
請求項9に記載のTPE化合物の使用。 - 押出機、密閉式混合機、または混練機、好ましくは、押出機または二軸押出機を用いた請求項1乃至8のいずれか1項に係るTPE化合物の製造方法。
- 請求項1乃至8のいずれか1項に記載のTPE化合物と、金属、ガラス、セラミック、熱可塑性物質およびそれらの混合物から選ばれる、さらなる物質とを用いた複合材料の製造方法であって、
前記複合材料は、射出成形、射出成形−インサート法、押出し成形、圧縮成形法を用いて、好ましくは、射出成形、射出成形−インサート法、および押出し成形を用いて、より好ましくは、射出成形−インサート法を用いて製造される、
複合材料の製造方法。
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PCT/EP2015/060906 WO2015177099A1 (de) | 2014-05-19 | 2015-05-18 | Thermoplastische elastomerenzusammensetzungen mit haftung zu metallischen oberflächen |
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JP2007106850A (ja) * | 2005-10-12 | 2007-04-26 | Toagosei Co Ltd | 低圧成型用熱可塑性樹脂組成物 |
JP2008143975A (ja) * | 2006-12-07 | 2008-06-26 | Yasuhara Chemical Co Ltd | 熱伝導性ホットメルト接着剤組成物 |
JP2014070099A (ja) * | 2012-09-27 | 2014-04-21 | Henkel Japan Ltd | ラベル用ホットメルト粘着剤 |
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WO2015177099A1 (de) | 2015-11-26 |
JP6626887B2 (ja) | 2019-12-25 |
CN106795356A (zh) | 2017-05-31 |
DE102014007211A1 (de) | 2015-11-19 |
EP3146007A1 (de) | 2017-03-29 |
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