JP2017510693A5 - - Google Patents
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- JP2017510693A5 JP2017510693A5 JP2016575634A JP2016575634A JP2017510693A5 JP 2017510693 A5 JP2017510693 A5 JP 2017510693A5 JP 2016575634 A JP2016575634 A JP 2016575634A JP 2016575634 A JP2016575634 A JP 2016575634A JP 2017510693 A5 JP2017510693 A5 JP 2017510693A5
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- Prior art keywords
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- acid
- Prior art date
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- 239000000178 monomer Substances 0.000 claims description 66
- 229920000642 polymer Polymers 0.000 claims description 61
- 238000000034 method Methods 0.000 claims description 34
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 25
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 13
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 12
- 239000000654 additive Substances 0.000 claims description 12
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 claims description 8
- 230000000996 additive effect Effects 0.000 claims description 8
- MNCGMVDMOKPCSQ-UHFFFAOYSA-M sodium;2-phenylethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 MNCGMVDMOKPCSQ-UHFFFAOYSA-M 0.000 claims description 8
- -1 bets Chemical compound 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 229910021645 metal ion Inorganic materials 0.000 claims description 7
- 239000007800 oxidant agent Substances 0.000 claims description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 239000003638 chemical reducing agent Substances 0.000 claims description 5
- 239000003999 initiator Substances 0.000 claims description 5
- 230000003472 neutralizing effect Effects 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 3
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 claims description 3
- 239000012736 aqueous medium Substances 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- 150000005846 sugar alcohols Polymers 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims description 2
- 239000003505 polymerization initiator Substances 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- IRLPACMLTUPBCL-KQYNXXCUSA-N 5'-adenylyl sulfate Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(=O)OS(O)(=O)=O)[C@@H](O)[C@H]1O IRLPACMLTUPBCL-KQYNXXCUSA-N 0.000 claims 3
- 239000000243 solution Substances 0.000 description 18
- 239000003599 detergent Substances 0.000 description 9
- 238000005553 drilling Methods 0.000 description 8
- 239000007844 bleaching agent Substances 0.000 description 6
- 229920002959 polymer blend Polymers 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 description 4
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 4
- 239000000872 buffer Substances 0.000 description 4
- 239000008235 industrial water Substances 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- 239000002671 adjuvant Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000004851 dishwashing Methods 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- HVCNQTCZNBPWBV-UHFFFAOYSA-N 2-hydroxy-2-sulfinoacetic acid Chemical compound OC(=O)C(O)S(O)=O HVCNQTCZNBPWBV-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 229920000388 Polyphosphate Polymers 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000003623 enhancer Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 239000003752 hydrotrope Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920001444 polymaleic acid Polymers 0.000 description 2
- 239000001205 polyphosphate Substances 0.000 description 2
- 235000011176 polyphosphates Nutrition 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000006254 rheological additive Substances 0.000 description 2
- 239000002455 scale inhibitor Substances 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001735 carboxylic acids Chemical group 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003248 enzyme activator Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201461953239P | 2014-03-14 | 2014-03-14 | |
| US61/953,239 | 2014-03-14 | ||
| PCT/US2015/020408 WO2015138872A1 (en) | 2014-03-14 | 2015-03-13 | Itaconic acid polymers and copolymers |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020005968A Division JP2020063458A (ja) | 2014-03-14 | 2020-01-17 | イタコン酸ポリマーおよびコポリマー |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2017510693A JP2017510693A (ja) | 2017-04-13 |
| JP2017510693A5 true JP2017510693A5 (enExample) | 2018-03-22 |
| JP7071039B2 JP7071039B2 (ja) | 2022-05-18 |
Family
ID=52780051
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016575634A Active JP7071039B2 (ja) | 2014-03-14 | 2015-03-13 | イタコン酸ポリマーおよびコポリマー |
| JP2020005968A Pending JP2020063458A (ja) | 2014-03-14 | 2020-01-17 | イタコン酸ポリマーおよびコポリマー |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020005968A Pending JP2020063458A (ja) | 2014-03-14 | 2020-01-17 | イタコン酸ポリマーおよびコポリマー |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US11214758B2 (enExample) |
| EP (1) | EP3116924B1 (enExample) |
| JP (2) | JP7071039B2 (enExample) |
| KR (1) | KR102350475B1 (enExample) |
| CN (1) | CN106574018A (enExample) |
| BR (1) | BR112016021154A2 (enExample) |
| ES (1) | ES2823562T3 (enExample) |
| TW (1) | TWI637053B (enExample) |
| WO (1) | WO2015138872A1 (enExample) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102350475B1 (ko) * | 2014-03-14 | 2022-01-11 | 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 | 이타콘산 폴리머 및 코폴리머 |
| CN107771191B (zh) | 2015-06-17 | 2020-08-28 | 科莱恩国际有限公司 | 作为水泥浆中的降失水剂的水溶性或水溶胀性聚合物 |
| JP7032402B2 (ja) | 2016-12-12 | 2022-03-08 | クラリアント・インターナシヨナル・リミテツド | ある特定のレベルのバイオベース炭素を含むポリマー |
| JP7050784B2 (ja) | 2016-12-12 | 2022-04-08 | クラリアント・インターナシヨナル・リミテツド | 化粧料組成物、皮膚科学的組成物または医薬組成物におけるバイオベースのポリマーの使用 |
| ES3017507T3 (en) | 2016-12-15 | 2025-05-13 | Clariant Int Ltd | Water-soluble and/or water-swellable hybrid polymer |
| WO2018108665A1 (en) | 2016-12-15 | 2018-06-21 | Clariant International Ltd | Water-soluble and/or water-swellable hybrid polymer |
| ES3033231T3 (en) | 2016-12-15 | 2025-07-31 | Clariant Int Ltd | Water-soluble and/or water-swellable hybrid polymer |
| EP3554646B1 (en) | 2016-12-15 | 2025-03-19 | Clariant International Ltd | Water-soluble and/or water-swellable hybrid polymer |
| US10472594B2 (en) | 2017-04-11 | 2019-11-12 | Itaconix Corporation | Sulfonated copolymers for detergent composition |
| EP3418366A1 (en) * | 2017-06-19 | 2018-12-26 | The Procter & Gamble Company | Automatic dishwashing cleaning composition |
| EP3418364A1 (en) | 2017-06-19 | 2018-12-26 | The Procter & Gamble Company | Automatic dishwashing cleaning composition |
| EP3441450A1 (en) * | 2017-08-11 | 2019-02-13 | The Procter & Gamble Company | Automatic dishwashing composition |
| EP3676360B1 (en) * | 2017-08-30 | 2021-09-15 | Dow Global Technologies LLC | Automatic dishwashing composition with dispersant polymer |
| PL3710567T3 (pl) * | 2017-11-15 | 2022-03-21 | Dow Global Technologies Llc | Polimer dyspergujący do preparatów do automatycznego mycia naczyń |
| GB201809123D0 (en) | 2018-06-04 | 2018-07-18 | Reckitt Benckiser Finish Bv | Composition |
| US11549082B2 (en) * | 2018-09-20 | 2023-01-10 | Baker Hughes Holdings Llc | Cleaning agent comprising a polyacrylate terpolymer for removal of fouling deposits from metal surfaces |
| DE102018133650A1 (de) * | 2018-12-28 | 2020-07-02 | Henkel Ag & Co. Kgaa | Geschirrspülmittel mit verbesserter Klarspülleistung |
| JP6829754B1 (ja) * | 2019-11-19 | 2021-02-10 | 住友精化株式会社 | 二次電池用結着剤 |
| US12460160B2 (en) | 2019-11-19 | 2025-11-04 | Lubrizol Advanced Materials, Inc. | Redeposition inhibiting styrene maleic anhydride copolymers and detergent compositions containing same |
| AU2020393542A1 (en) * | 2019-11-25 | 2022-06-02 | Kao Corporation | Liquid detergent composition for textile products |
| CN114867831A (zh) | 2019-12-19 | 2022-08-05 | 路博润先进材料公司 | 再沉积抑制性聚合物和含有所述再沉积抑制性聚合物的洗涤剂组合物 |
| EP4100449A4 (en) * | 2020-02-05 | 2024-04-10 | Itaconix Corporation | COPOLYMER FORMULATIONS OF POLY(ITACONIC ACID-CO-2-ACRYLAMIDO-2-METHYLPROPANESULPHONIC ACID) FOR DISHWASHER COMPOSITIONS |
| US11879111B2 (en) | 2020-03-27 | 2024-01-23 | Ecolab Usa Inc. | Detergent compositions, cleaning systems and methods of cleaning cosmetic and other soils |
| WO2022093611A1 (en) | 2020-10-26 | 2022-05-05 | Ecolab Usa Inc. | Calcite scale control agent for geothermal wells |
| US12054582B2 (en) | 2021-03-17 | 2024-08-06 | Akzo Nobel Coatings International B.V. | Alkyd resin, coating composition, and substrate coated with such coating composition |
| CN113336888B (zh) * | 2021-05-28 | 2022-09-13 | 华南农业大学 | 生物基酸碱响应性超亲水油水分离膜及其制备方法和应用 |
| EP4269548A1 (en) | 2022-04-27 | 2023-11-01 | Dalli-Werke GmbH & Co. KG | Detergent composition with antiscalants |
| CN117624961A (zh) * | 2023-12-11 | 2024-03-01 | 广东卫斯理化工科技有限公司 | 一种脱胶纸剂 |
| WO2025212774A1 (en) | 2024-04-03 | 2025-10-09 | Lubrizol Advanced Materials, Inc. | Highly acidic cleaning compositions for hard surfaces |
Family Cites Families (90)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB401413A (en) | 1932-06-29 | 1933-11-16 | Robert Henry Marriott | Compositions particularly suitable for use as shampoos or for washing purposes |
| GB461221A (en) | 1936-04-17 | 1937-02-12 | Robert Henry Marriott | Compositions suitable for use in the washing of textile materials or for other washing purposes |
| US2503280A (en) | 1947-10-24 | 1950-04-11 | Du Pont | Azo catalysts in preparation of sulfonic acids |
| US2507088A (en) | 1948-01-08 | 1950-05-09 | Du Pont | Sulfoxidation process |
| US3260741A (en) | 1962-11-09 | 1966-07-12 | Exxon Research Engineering Co | Sulfoxidation process |
| US3372188A (en) | 1965-03-12 | 1968-03-05 | Union Oil Co | Sulfoxidation process in the presence of sulfur trioxide |
| DK129804A (enExample) | 1969-01-17 | |||
| US3812044A (en) | 1970-12-28 | 1974-05-21 | Procter & Gamble | Detergent composition containing a polyfunctionally-substituted aromatic acid sequestering agent |
| CA992423A (en) | 1972-04-28 | 1976-07-06 | The Procter And Gamble Company | Crystallization seed-containing detergent composition |
| ZA734721B (en) | 1972-07-14 | 1974-03-27 | Procter & Gamble | Detergent compositions |
| US4105827A (en) | 1973-04-20 | 1978-08-08 | Interox | Particulate peroxygen compounds coated with sodium sesquicarbonate or Na2 SO4 mNa2 CO3 |
| US3843598A (en) | 1973-12-03 | 1974-10-22 | Velsicol Chemical Corp | Fire retardant polymers containing halogenated n-phenyl benzamides |
| GB1600981A (en) | 1977-06-09 | 1981-10-21 | Ici Ltd | Detergent composition |
| US4485223A (en) * | 1981-10-29 | 1984-11-27 | Pfizer Inc. | (Meth)acrylic acid/itaconic acid copolymers, their preparation and use as antiscalants |
| JPS5891709A (ja) * | 1981-10-29 | 1983-05-31 | フアイザ−・インコ−ポレ−テツド | （メト）アクリル酸／イタコン酸共重合体、その製法およびスケ−ル防止剤 |
| FR2544722B1 (fr) | 1983-04-20 | 1985-07-05 | Coatex Sa | Agent hydrosoluble de complexation des cations metalliques compose de terpolymeres acryliques disposant d'un haut pouvoir complexant et d'un effet de seuil eleve |
| US4497718A (en) | 1983-04-20 | 1985-02-05 | Lever Brothers Company | Homogeneous aqueous fabric softening composition with stilbene sulfonic acid fluorescent whitener |
| US4760025A (en) | 1984-05-29 | 1988-07-26 | Genencor, Inc. | Modified enzymes and methods for making same |
| DE3426368A1 (de) | 1984-07-18 | 1986-01-23 | Basf Ag, 6700 Ludwigshafen | Copolymerisate fuer wasch- und reinigungsmittel |
| JPS6286098A (ja) * | 1985-10-11 | 1987-04-20 | 株式会社日本触媒 | 洗剤用ビルダー |
| US4902499A (en) | 1986-04-04 | 1990-02-20 | The Procter & Gamble Company | Hair care compositions containing a rigid silicone polymer |
| JP2508001B2 (ja) | 1986-06-25 | 1996-06-19 | 三菱瓦斯化学株式会社 | 耐塩性カタラ−ゼおよび過酸化水素の分解法 |
| US4824590A (en) | 1986-09-08 | 1989-04-25 | The Procter & Gamble Company | Thickened aqueous compositions with suspended solids |
| US4762621A (en) | 1986-11-13 | 1988-08-09 | The B. F. Goodrich Company | Itaconate ester copolymers as scale inhibitors |
| GB8629837D0 (en) | 1986-12-13 | 1987-01-21 | Interox Chemicals Ltd | Bleach activation |
| US5245075A (en) | 1987-11-13 | 1993-09-14 | Ausimont S.R.L. | Peroxy carboxylic amino derivatives |
| US5288627A (en) | 1988-01-07 | 1994-02-22 | Novo Nordisk A/S | Endoprotease from Fusarium oxysporumDSM 2672 for use in detergents |
| US5292447A (en) | 1988-06-14 | 1994-03-08 | Ausimont S.R.L. | Heterocyclic peroxides having n-amidic heteroatoms |
| US5039447A (en) | 1988-12-12 | 1991-08-13 | Monsanto Company | Pourable sulfone peracid compositions |
| GB8908416D0 (en) | 1989-04-13 | 1989-06-01 | Unilever Plc | Bleach activation |
| IL91362A0 (en) | 1989-08-20 | 1990-03-19 | Yissum Res Dev Co | Bisphosphonates,process for preparing them and pharmaceutical compositions containing them |
| ES2144990T3 (es) | 1989-08-25 | 2000-07-01 | Henkel Of America Inc | Enzima proteolitica alcalina y metodo de produccion. |
| US5223592A (en) | 1991-03-27 | 1993-06-29 | Rohm And Haas Company | Process for polymerization of itaconic acid |
| ES2119812T3 (es) | 1991-03-27 | 1998-10-16 | Novo Nordisk As | Catalasa, su produccion y uso. |
| GB9108136D0 (en) | 1991-04-17 | 1991-06-05 | Unilever Plc | Concentrated detergent powder compositions |
| AU1527292A (en) | 1991-04-30 | 1992-11-05 | Calgon Corporation | Terpolymer of itaconic acid for high ph scale control |
| CA2097431A1 (en) | 1991-10-31 | 1993-05-01 | Brian E. Jones | Haloalkaliphilic microorganisms |
| US5389279A (en) | 1991-12-31 | 1995-02-14 | Lever Brothers Company, Division Of Conopco, Inc. | Compositions comprising nonionic glycolipid surfactants |
| ATE192934T1 (de) | 1992-03-04 | 2000-06-15 | Genencor Int | Verwendung von aspergillus niger catalase-r zur wasserstoffperoxid-neutralisierung |
| US5336744A (en) | 1993-03-17 | 1994-08-09 | Rohm And Haas Company | Process for polymerization of itaconic acid |
| GB9305863D0 (en) | 1993-03-22 | 1993-05-12 | Unilever Plc | Peroxyacids |
| US5576281A (en) | 1993-04-05 | 1996-11-19 | Olin Corporation | Biogradable low foaming surfactants as a rinse aid for autodish applications |
| US5888954A (en) | 1993-05-08 | 1999-03-30 | Henkel Kommanditgesellschaft Auf Aktien | Corrosion inhibitors for silver |
| DE69434962T2 (de) | 1993-10-14 | 2008-01-17 | The Procter & Gamble Company, Cincinnati | Proteasehaltige reinigungsmittel |
| JPH0852496A (ja) | 1994-08-11 | 1996-02-27 | Sanyo Chem Ind Ltd | スケール防止剤 |
| JP3103310B2 (ja) | 1996-09-18 | 2000-10-30 | 株式会社モディー | 自転車用ハンドル |
| US6022721A (en) | 1997-01-03 | 2000-02-08 | Development Center For Biotechnology | Catalase, the gene thereof and composition comprising the same, and process for preparing catalase using genetic engineering technology |
| AU6914098A (en) | 1997-04-03 | 1998-10-30 | Universite Laval | Transgenic expression in genital tract and sexual accessory glands |
| DE19714122A1 (de) | 1997-04-05 | 1998-10-08 | Clariant Gmbh | Bleichaktive Metall-Komplexe |
| US6599871B2 (en) | 1997-08-02 | 2003-07-29 | The Procter & Gamble Company | Detergent tablet |
| JP4025392B2 (ja) | 1997-08-07 | 2007-12-19 | 天野エンザイム株式会社 | 耐酸性カタラーゼの製造法 |
| AR015977A1 (es) | 1997-10-23 | 2001-05-30 | Genencor Int | Variantes de proteasa multiplemente substituida con carga neta alterada para su empleo en detergentes |
| US6313201B1 (en) | 1997-12-25 | 2001-11-06 | Mitsubishi Gas Chemical Company, Inc. | Modified catalase, a composition thereof and process for preparing the catalase |
| US6462013B1 (en) | 1998-06-26 | 2002-10-08 | National Starch And Chemical Investment Holding Corporation | Isotropic liquid detergent comprising ethylenically unsaturated acid monomer-C1 to C24 chain transfer agent polymerization product |
| AU3420100A (en) | 1999-03-31 | 2000-10-23 | Novozymes A/S | Lipase variant |
| US6559363B1 (en) | 1999-07-05 | 2003-05-06 | Toyo Boseki Kabushiki Kaisha | Cotton plants with improved cotton fiber characteristics and method for producing cotton fibers from these cotton plants |
| AU1492201A (en) | 1999-09-24 | 2001-04-24 | University Of Georgia Research Foundation, Inc., The | Free radical initiation system and method of polymerizing ethylenical dicarboxylic acids |
| JP2001252692A (ja) | 2000-03-13 | 2001-09-18 | Jsr Corp | 炭酸カルシウム系スケール防止剤および炭酸カルシウム系スケール防止剤用共重合体の製造方法 |
| US6358733B1 (en) | 2000-05-19 | 2002-03-19 | Apolife, Inc. | Expression of heterologous multi-domain proteins in yeast |
| US7041488B2 (en) | 2001-06-06 | 2006-05-09 | Novozymes A/S | Endo-beta-1,4-glucanase from bacillus |
| DE10206504A1 (de) | 2002-02-16 | 2003-08-28 | Cognis Deutschland Gmbh | Verfahren zur Gewinnung von Hydroperoxiden |
| CN1230456C (zh) | 2003-03-25 | 2005-12-07 | 青岛琅琊台集团股份有限公司 | 衣康酸共聚物及其制备方法和应用 |
| US7985569B2 (en) | 2003-11-19 | 2011-07-26 | Danisco Us Inc. | Cellulomonas 69B4 serine protease variants |
| DE102004003710A1 (de) | 2004-01-24 | 2005-08-11 | Clariant Gmbh | Verwendung von Übergangsmetallkomplexen als Bleichkatalysatoren in Wasch- und Reinigungsmitteln |
| CN1321180C (zh) | 2004-04-09 | 2007-06-13 | 江南大学 | 一种提高微生物法制备的过氧化氢酶保存稳定性的方法 |
| DE102004041142A1 (de) * | 2004-08-24 | 2006-03-02 | Basf Ag | Verfahren zum Passivieren von metallischen Oberflächen unter Verwendung von Itaconsäure Homo- oder Copolymeren |
| CN101010366B (zh) * | 2004-08-26 | 2011-01-12 | 路博润高级材料公司 | 具有改善的稳定性的涂料组合物 |
| RU2433182C2 (ru) | 2005-10-12 | 2011-11-10 | Джененкор Интернэшнл, Инк. | Применение и получение стабильной при хранении нейтральной металлопротеиназы |
| ES2398923T3 (es) * | 2006-02-24 | 2013-03-22 | Lubrizol Advanced Materials, Inc. | Polímeros que contienen macrómeros de copoliol de silicona y composiciones para higiene personal que los contienen |
| JP2007262403A (ja) | 2006-03-03 | 2007-10-11 | Nippon Shokubai Co Ltd | イタコン酸系共重合体、その製造方法およびこれを用いてなる洗剤組成物 |
| DE102006022224A1 (de) | 2006-05-11 | 2007-11-15 | Henkel Kgaa | Subtilisin aus Bacillus pumilus und Wasch- und Reinigungsmittel enthaltend dieses neue Subtilisin |
| MX2008015592A (es) | 2006-06-05 | 2008-12-18 | Procter & Gamble | Estabilizante de enzima. |
| US7490418B2 (en) | 2006-06-30 | 2009-02-17 | Michel Obeydani | Footwear with manually extendable spikes |
| GB0704933D0 (en) | 2007-03-15 | 2007-04-25 | Reckitt Benckiser Nv | Detergent composition |
| DE102007016389A1 (de) | 2007-04-03 | 2008-10-09 | Henkel Ag & Co. Kgaa | Mittel zur Behandlung harter Oberflächen |
| WO2008119833A1 (de) | 2007-04-03 | 2008-10-09 | Henkel Ag & Co. Kgaa | Mittel zur behandlung harter oberflächen |
| DE102007042860A1 (de) | 2007-09-10 | 2009-03-12 | Henkel Ag & Co. Kgaa | Reinigungsmittel |
| MX2010003792A (es) | 2007-10-12 | 2010-07-06 | Basf Se | Formulacion para lavado de platos que comprende una mezcla de policarboxilatos hidrofobicamente modificados y policarboxilatos hidrofilicamente modificados. |
| EP2100947A1 (en) | 2008-03-14 | 2009-09-16 | The Procter and Gamble Company | Automatic dishwashing detergent composition |
| EP2283066B1 (en) | 2008-05-16 | 2019-01-02 | University Of New Hampshire | Polycarboxylic acid polymers |
| CN105483099B (zh) | 2008-06-06 | 2020-06-23 | 丹尼斯科美国公司 | 具有改良特性的嗜热脂肪土芽孢杆菌α-淀粉酶(AMYS)变体 |
| JP2011132637A (ja) | 2009-12-25 | 2011-07-07 | Taihokohzai:Kk | 緑液系スケール形成抑制剤及びスケール形成抑制方法 |
| US8420758B2 (en) | 2010-03-11 | 2013-04-16 | Itaconix Corporation | Regulated and continuous polymerization of polycarboxylic acid polymers |
| CN101898837A (zh) | 2010-04-08 | 2010-12-01 | 山东省特种设备检验研究院淄博分院 | 醚基衣康酸磺酸盐类多元共聚物阻垢剂及其制法 |
| JP6087814B2 (ja) * | 2010-07-09 | 2017-03-01 | ルブリゾル アドバンスド マテリアルズ， インコーポレイテッド | 構造化アクリレートコポリマー増粘剤 |
| KR101847482B1 (ko) * | 2010-12-02 | 2018-04-10 | 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 | 이타콘산으로부터 유래된 폴리머 |
| CN102838215A (zh) | 2012-09-18 | 2012-12-26 | 济南大学 | 一种多效复合型缓蚀阻垢剂的制备方法 |
| WO2014151439A1 (en) | 2013-03-15 | 2014-09-25 | Lubrizol Advanced Materials, Inc. | Itaconic acid polymers for oral care applications |
| CN110105480A (zh) | 2013-03-15 | 2019-08-09 | 路博润先进材料公司 | 衣康酸聚合物 |
| KR102350475B1 (ko) * | 2014-03-14 | 2022-01-11 | 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 | 이타콘산 폴리머 및 코폴리머 |
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2015
- 2015-03-13 KR KR1020167028558A patent/KR102350475B1/ko active Active
- 2015-03-13 CN CN201580024475.7A patent/CN106574018A/zh active Pending
- 2015-03-13 BR BR112016021154-5A patent/BR112016021154A2/pt not_active Application Discontinuation
- 2015-03-13 JP JP2016575634A patent/JP7071039B2/ja active Active
- 2015-03-13 TW TW104108103A patent/TWI637053B/zh active
- 2015-03-13 WO PCT/US2015/020408 patent/WO2015138872A1/en not_active Ceased
- 2015-03-13 US US15/125,820 patent/US11214758B2/en active Active
- 2015-03-13 EP EP15712768.9A patent/EP3116924B1/en not_active Revoked
- 2015-03-13 ES ES15712768T patent/ES2823562T3/es active Active
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2020
- 2020-01-17 JP JP2020005968A patent/JP2020063458A/ja active Pending
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