JP2015519451A - 界面活性剤溶液中における低温安定剤としてのn−メチル−n−アシルグルカミンの使用 - Google Patents
界面活性剤溶液中における低温安定剤としてのn−メチル−n−アシルグルカミンの使用 Download PDFInfo
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- JP2015519451A JP2015519451A JP2015514481A JP2015514481A JP2015519451A JP 2015519451 A JP2015519451 A JP 2015519451A JP 2015514481 A JP2015514481 A JP 2015514481A JP 2015514481 A JP2015514481 A JP 2015514481A JP 2015519451 A JP2015519451 A JP 2015519451A
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- component
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- alkyl
- methyl
- acyl
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- 239000000654 additive Substances 0.000 claims abstract description 4
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- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 description 2
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- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 2
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- WSDISUOETYTPRL-UHFFFAOYSA-N dmdm hydantoin Chemical compound CC1(C)N(CO)C(=O)N(CO)C1=O WSDISUOETYTPRL-UHFFFAOYSA-N 0.000 description 2
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- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000007942 carboxylates Chemical group 0.000 description 1
- 235000012730 carminic acid Nutrition 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 239000010628 chamomile oil Substances 0.000 description 1
- 235000019480 chamomile oil Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000017803 cinnamon Nutrition 0.000 description 1
- 239000001507 cistus ladaniferus l. oil Substances 0.000 description 1
- 229940043350 citral Drugs 0.000 description 1
- 229930003633 citronellal Natural products 0.000 description 1
- 235000000983 citronellal Nutrition 0.000 description 1
- 235000000484 citronellol Nutrition 0.000 description 1
- 239000010500 citrus oil Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000010634 clove oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000973 cosmetic coloring agent Substances 0.000 description 1
- 229940019836 cyclamen aldehyde Drugs 0.000 description 1
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
- 125000006182 dimethyl benzyl group Chemical group 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- ZITKDVFRMRXIJQ-UHFFFAOYSA-N dodecane-1,2-diol Chemical compound CCCCCCCCCCC(O)CO ZITKDVFRMRXIJQ-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229960002217 eugenol Drugs 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- WPFVBOQKRVRMJB-UHFFFAOYSA-N hydroxycitronellal Chemical compound O=CCC(C)CCCC(C)(C)O WPFVBOQKRVRMJB-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229930002839 ionone Natural products 0.000 description 1
- 150000002499 ionone derivatives Chemical class 0.000 description 1
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000010656 jasmine oil Substances 0.000 description 1
- 239000001851 juniperus communis l. berry oil Substances 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 235000020638 mussel Nutrition 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 229940067107 phenylethyl alcohol Drugs 0.000 description 1
- QJFMCHRSDOLMHA-UHFFFAOYSA-N phenylmethanamine;hydrobromide Chemical compound Br.NCC1=CC=CC=C1 QJFMCHRSDOLMHA-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000006268 reductive amination reaction Methods 0.000 description 1
- 239000010666 rose oil Substances 0.000 description 1
- 235000019719 rose oil Nutrition 0.000 description 1
- 239000010670 sage oil Substances 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 150000004666 short chain fatty acids Chemical class 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- 239000010679 vetiver oil Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
- A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
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- Chemical & Material Sciences (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
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- Detergent Compositions (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
Description
(式中、R2COは、1〜8個のC−原子を有する脂肪族アシル残基であり、R3は、水素又は1〜8個のC−原子を有するアルキル残基又はヒドロキシアルキル残基であり、[Z]は、3〜12個のC−原子及び3〜10個のOH−基を有するポリヒドロキシアルキル残基である。)好ましいものとして、カルボン酸−N−アルキルグルカミンが知られており、その場合、R2COは、ギ酸、酢酸、プロピオン酸、酪酸又はカプロン酸のアシル残基であり、かつ、アルキル残基R3は、メチル又はオクチルである。実施例では、油酸スルホナート−ナトリウム塩、ヤシ脂肪アルコールエーテルサルフェート−ナトリウム塩及びヤシ脂肪酸−トリエタノールアンモニウム塩を含有する混合物の可溶化剤として、酢酸−N−オクチルグルカミン、酪酸−N−オクチルグルカミン及びカプロン酸−N−メチルグルカミンが使用されている。
(式中、R1は、好ましくはC1−C4−アルキル、特に、メチルであり、R2は、好ましくは直鎖状のC7−C19−アルキル又は−アルケニル、特に、直鎖状のC11−C16−アルキル又は−アルケニルであり、そしてZは、好ましくは、1−デオキシドグルシチル、2−デオキシフルクチチル、1−デオキシマルチチル、1−デオキシラクチチル、1−デオキシガラクチチル、1−デオキシマンニチル又は1−デオキシマルトトリオチチルである。実施例は、アンモニウムラウリル-サルフェート、アンモニウムラウリルトリエチレングリコールサルフェート及びラウリル−N−メチルグルカミンを含有する毛髪用シャンプー組成物を開示している。
(a)成分(A)として、少なくとも90重量%がC8−アシル基又はC10−アシル基を有するN−メチル−N−アシルグルカミン、
(b)成分(B)として、一種又は二種のアニオン性の界面活性剤、
(c)成分(C)として、ベタイン系−界面活性剤、
(d)場合によって、成分(D)として更なる界面活性剤、
(e)成分(E)として、水、
(f)場合によって、成分(F)として、保存料、香料、着色料及び保湿剤のような更なる添加剤、
を含有する組成物である。
(a)0.01〜5.0重量%、好ましくは、0.1〜3.0重量%の成分(A)、
(b)1.0〜20.0重量%、好ましくは、5.0〜15重量%の成分(B)、
(c)0.1〜10.0重量%、好ましくは、1.0〜10.0重量%の成分(C)、
(d)0〜5.0重量%、好ましくは、0〜3.0重量%の成分(D)、
(e)55.0〜98.89重量%、好ましくは、75〜95重量%の成分(E)、
(f)0〜5.0重量%、好ましくは、0〜2.0重量%の成分(F)、
を含有する。
−アルキルフェノールの、ポリエチレン−、ポリプロピレン−及びポリブチレンオキシド縮合物。これらの化合物は、C6−〜C20−アルキル基を有するアルキルフェノールの、アルケンオキシドとの縮合生成物を含み、線状又は分岐状であることができる。これらの界面活性剤は、アルキルフェノールアルコキシレート、例えば、アルキルフェノールエトキシレートと呼ばれる。
−脂肪族アルコールと1〜25モルのエチレンオキシドとの縮合生成物。この脂肪族アルコールのアルキル鎖又はアルケニル鎖は、線状又は分岐状、第一級又は第二級であることができ、そして、全部で8〜22個の炭素原子を有する。特に好ましくは、この縮合生成物は、C10−〜C20−アルコールと、そのアルコール1モル当たり2〜18モルのエチレンオキシドとからの生成物である。アルコールエトキシレートは、エチレンオキシドの狭い同族体分布(“狭い範囲のエトキシレート”)又はエチレンオキシドの広い同族体分布(“広い範囲のエトキシレート”)を有することができる。市場から入手可能なこの種の非イオン性の界面活性剤の例は、Tergitol(登録商標) 15−S−9(線状の第二級のC11−C15−アルコールと9モルのエチレンオキシドとの縮合生成物)、Tergitol(登録商標) 24−L−NMW(線状の第一級のC12−C14−アルコールと6モルのエチレンオキシドとの、狭い分子量分布の場合の縮合生成物)である。同様に、この製品のクラスは、Clariantの登録商標であるGenapol(登録商標) PFを包含する。
−プロピレンオキシドとプロピレングリコールとの縮合によって得られる疎水性のベースを有するエチレンオキシドからの縮合生成物。この化合物の疎水性の部分は、好ましくは、1500〜1800の分子量を有する。この疎水性の部分に対するエチレンオキシドの付加により、水溶性が向上する。この生成物は、縮合生成物の全重量の約50%のポリオキシエチレン含有量までの液体であり、約40モルまでのエチレンオキシドとの縮合物に相当する。市場から入手可能なこの生成物の例は、BASFの登録商標Pluronic(登録商標)及びClariantの登録商標Genapol(登録商標)の製品である。
−エチレンオキシドと、プロピレンオキシド及びエチレンジアミンの反応生成物との縮合生成物。この化合物の疎水性の部分は、エチレンジアミンと、過剰のプロピレンオキシドとの反応生成物からなり、一般に2500〜3000の分子量を有する。この疎水性の部分に、40〜80重量%のポリオキシエチレンの含有量まで、そして5000〜11000の分子量までエチレンオキシドが付加される。市場から入手可能なこの種の化合物の例は、BASFの登録商標Tetronic(登録商標)及びClariantの登録商標Genapol(登録商標) PNの製品である。
例1及び2並びに比較例1〜4
以下に開示されるN−アシル−N−メチルグルカミンを、欧州特許第0 550 637号(特許文献3又は4)に従って、対応する脂肪酸メチルエステル及びN−メチルグルカミンから、溶媒としての1,2−プロピレングリコールの存在下で製造し、活性物質及び1,2−プロピレングリコールからなる固体物質として得た(全て重量%で与えられる)。
Claims (8)
- 界面活性剤水溶液中におけるN−メチル−N−アシルグルカミンの低温安定剤としての使用であって、その際、N−メチル−N−アシルグルカミンの少なくとも90重量%がC8−アシル−基又はC10−アシル基を有する、上記の使用。
- 前記界面活性剤水溶液が、アニオン性の界面活性剤としてアルキルサルフェート及び/又はアルキルエーテルサルフェート及びベタイン系−界面活性剤を含有することを特徴とする、請求項1に記載の使用。
- 前記界面活性剤水溶液が、線状のC8−C20−アルキルサルフェート及び/又は線状のC8−C20−アルキルエーテルサルフェートを含有することを特徴とする、請求項1又は2に記載の使用。
- 前記界面活性剤水溶液が、ラウリルサルフェート及び/又はラウリルエーテルサルフェートを含有することを特徴とする、請求項3に記載の使用。
- 前記界面活性剤水溶液が、アシルアミドプロピルベタイン又はアルキルベタインを含有することを特徴とする、請求項1〜4のいずれか一つに記載の使用。
- (a)成分(A)として、少なくとも90重量%がC8−アシル基又はC10−アシル基を有するN−メチル−N−アシルグルカミン、
(b)成分(B)として、一種又は二種のアニオン性の界面活性剤、
(c)成分(C)として、一種又は二種のベタイン系−界面活性剤、
(d)場合によって、成分(D)として更なる界面活性剤、
(e)成分(E)として、水、
(f)場合によって、成分(F)として、更なる添加剤、
を含有する組成物。 - (a)0.01〜5.0重量%の成分(A)、
(b)1.0〜20.0重量%の成分(B)、
(c)0.1〜10.0重量%の成分(C)、
(d)0〜5.0重量%の成分(D)、
(e)55.0〜98.89重量%の成分(E)、
(f)0〜5.0重量%の成分(F)、
を含有する組成物。 - 毛髪用シャンプー、シャワーソープ、ハンドソープ及び洗顔料の形態の請求項6又は7に記載の組成物。
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PCT/EP2013/061046 WO2013178670A2 (de) | 2012-05-30 | 2013-05-29 | Verwendung von n-methyl-n-acylglucaminen als kältestabilisatoren in tensidlösungen |
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BR112014029752A2 (pt) | 2017-06-27 |
ES2617535T3 (es) | 2017-06-19 |
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