JP2015231980A - 多官能酸無水物及び熱硬化性樹脂組成物 - Google Patents
多官能酸無水物及び熱硬化性樹脂組成物 Download PDFInfo
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- JP2015231980A JP2015231980A JP2015040922A JP2015040922A JP2015231980A JP 2015231980 A JP2015231980 A JP 2015231980A JP 2015040922 A JP2015040922 A JP 2015040922A JP 2015040922 A JP2015040922 A JP 2015040922A JP 2015231980 A JP2015231980 A JP 2015231980A
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- acid anhydride
- polyhydric alcohol
- polyfunctional acid
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- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
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- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 5
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- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- NXPPAOGUKPJVDI-UHFFFAOYSA-N naphthalene-1,2-diol Chemical class C1=CC=CC2=C(O)C(O)=CC=C21 NXPPAOGUKPJVDI-UHFFFAOYSA-N 0.000 description 1
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
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- 239000000454 talc Substances 0.000 description 1
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- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 description 1
- LVEOKSIILWWVEO-UHFFFAOYSA-N tetradecyl 3-(3-oxo-3-tetradecoxypropyl)sulfanylpropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCC LVEOKSIILWWVEO-UHFFFAOYSA-N 0.000 description 1
- BRKFQVAOMSWFDU-UHFFFAOYSA-M tetraphenylphosphanium;bromide Chemical compound [Br-].C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 BRKFQVAOMSWFDU-UHFFFAOYSA-M 0.000 description 1
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- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
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- MDCWDBMBZLORER-UHFFFAOYSA-N triphenyl borate Chemical compound C=1C=CC=CC=1OB(OC=1C=CC=CC=1)OC1=CC=CC=C1 MDCWDBMBZLORER-UHFFFAOYSA-N 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
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- Reinforced Plastic Materials (AREA)
- Furan Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
透明性、耐熱性、強靭性、耐着色性に優れた硬化物を与える樹脂組成物を得ること、特に光学部品に適した特性を有するものを得ること。
【解決手段】
一分子中に少なくとも3つの水酸基を含有する多価アルコール(A)と無水トリメリット酸ハライド及び核水添無水トリメリット酸ハライドとを反応させて得られる多官能酸無水物、多価アルコール(A)にアルキレンオキサイド、環状エーテル、及び環状エステルからなる群より選ばれる1以上とを反応させて得られる多価アルコール(B)と無水トリメリット酸ハライド及び核水添無水トリメリット酸ハライドと反応させて得られる多官能酸無水物、及びそれら多官能酸無水物と一分子中に少なくとも1つのエポキシ基を有する化合物を含む熱硬化性樹脂組成物。
【選択図】なし
Description
粒子(C−1)が無機粒子である前記熱硬化性樹脂組成物に関する。
繊維(C−2)がガラス繊維である前記熱硬化性樹脂組成物に関する。
繊維(C−2)がガラス繊維を紡糸し、さらに織製してなるガラスクロスである前記熱硬化性樹脂組成物に関する。
撹拌機、還流冷却管、撹拌装置を備えたフラスコに、窒素パージを施しながら、TMAC38.2g(182mmol)とHTAC39.4g(182mmol)に、THFを120g加えて均一溶液にした。この溶液を攪拌しながら5℃まで冷却後、TMP14.8g(110mmol)にピリジン37.3g(472mmol)とTHF180gを加えて均一にした溶液を、液温を10℃以下に保ちながら徐々に滴下した。滴下終了後、室温で1時間攪拌し、次いで50℃まで昇温し、反応を8時間継続した。続いて、反応液を20℃まで冷却し、不溶解分であるピリジン塩酸塩をろ去した後、ろ液を濃縮した。濃縮物を酢酸エチル400mlに溶解させ、100mlの水で3回洗浄した後、無水硫酸マグネシウムで乾燥した。無水硫酸マグネシウムをろ去した後、ろ液を濃縮した。得られた濃縮物を40mlの酢酸エチルに溶かし、トルエンで再結晶し、生成物を54.7g(収率76.3%)得た。
この生成物は、1H-NMRから目的の化合物であることを確認した。図1に1H-NMRのチャートを示す。
1H-NMR(ジメチルスルホキサイド−d6,δppm):0.79−1.00(m,3H),1.20−2.73(m,15.5H),3.05−3.57(m,3H),3.93−4.58(m,6H),8.13−8.53(m,4.5H)
撹拌機、還流冷却管、撹拌装置を備えたフラスコに、窒素パージを施しながら、TMAC38.2g(182mmol)とHTAC39.4g(182mmol)に、アセトンを120g加えて均一溶液にした。この溶液を攪拌しながら5℃まで冷却後、ジペンタエリスリトール14.0g(55mmol)にピリジン33.6g(475mmol)とアセトン180gを加えて均一にした溶液を、液温を10℃以下に保ちながら徐々に滴下した。滴下終了後、実施例1−1と同様にして生成物を65.1g(収率79.1%)得た。
撹拌機、還流冷却管、撹拌装置を備えたフラスコに、窒素パージを施しながら、TMAC38.2g(182mmol)とHTAC39.4g(182mmol)に、THFを120g加えて均一溶液にした。この溶液を攪拌しながら5℃まで冷却後、ジペンタエリスリトール6モルエチレンオキサイド付加物28.5g(55mmol)にピリジン33.6g(475mmol)とTHF180gを加えて均一にした溶液を、液温を10℃以下に保ちながら徐々に滴下した。滴下終了後、実施例1−1と同様にして生成物を68.9g(収率71.2%)得た。
撹拌機、還流冷却管、撹拌装置を備えたフラスコに、窒素パージを施しながら、ジペンタエリスリトール25.4g(100mmol)にカプロラクトン45.7g(400mmol)を加え、180℃12時間撹拌し、ジペンタエリスリトール4モルカプロラクトン付加物71.1gを得た。続いて撹拌機、還流冷却管、撹拌装置を備えた別のフラスコを用意し、窒素パージを施しながら、TMAC38.2g(182mmol)とHTAC39.4g(182mmol)に、THFを120g加えて均一溶液にした。この溶液を攪拌しながら5℃まで冷却後、ジペンタエリスリトール4モルカプロラクトン付加物39.1g(55mmol)にピリジン33.6g(475mmol)とTHF180gを加えて均一にした溶液を、液温を10℃以下に保ちながら徐々に滴下した。滴下終了後、実施例1−1と同様にして生成物を79.2g(収率73.3%)得た。
撹拌機、還流冷却管、撹拌装置を備えたフラスコに、窒素パージを施しながら、TMAC15.3g(72.6mmol)とHTAC62.9g(290.4mmol)に、THFを120g加えて均一溶液にした。この溶液を攪拌しながら5℃まで冷却後、TMP14.8g(110mmol)にピリジン37.3g(472mmol)とTHF180gを加えて均一にした溶液を、液温を10℃以下に保ちながら徐々に滴下した。滴下終了後、実施例1−1と同様にして生成物を54.1g(収率75.4%)得た。
撹拌機、還流冷却管、撹拌装置を備えたフラスコに、窒素パージを施しながら、TMAC49.7g(236mmol)とHTAC27.5g(127.1mmol)に、THFを120g加えて均一溶液にした。この溶液を攪拌しながら5℃まで冷却後、TMP14.8g(110mmol)にピリジン37.3g(472mmol)とTHF180gを加えて均一にした溶液を、液温を10℃以下に保ちながら徐々に滴下した。滴下終了後、実施例1−1と同様にして生成物を54.0g(収率76.2%)得た。
撹拌機、還流冷却管、撹拌装置を備えたフラスコに、窒素パージを施しながら、TMAC3.82g(18.2mmol)とHTAC74.7g(344.9mmol)に、THFを120g加えて均一溶液にした。この溶液を攪拌しながら5℃まで冷却後、TMP14.8g(110mmol)にピリジン37.3g(472mmol)とTHF180gを加えて均一にした溶液を、液温を10℃以下に保ちながら徐々に滴下した。滴下終了後、実施例1−1と同様にして生成物を54.4g(収率75.6%)得た。
撹拌機、還流冷却管、撹拌装置を備えたフラスコに、窒素パージを施しながら、TMAC61.2g(290.4mmol)とHTAC15.7g(72.6mmol)に、THFを120g加えて均一溶液にした。この溶液を攪拌しながら5℃まで冷却後、TMP14.8g(110mmol)にピリジン37.3g(472mmol)とTHF180gを加えて均一にした溶液を、液温を10℃以下に保ちながら徐々に滴下した。滴下終了後、実施例1−1と同様にして生成物を52.7g(収率74.7%)得た。
撹拌機、還流冷却管、撹拌装置を備えたフラスコに、窒素パージを施しながら、TMAC51.0g(242mmol)とHTAC52.4g(242mmol)に、THFを120g加えて均一溶液にした。この溶液を攪拌しながら5℃まで冷却後、ペンタエリスリトール4モルエチレンオキサイド付加物34.3g(110mmol)にピリジン49.8g(629mmol)とTHF180gを加えて均一にした溶液を、液温を10℃以下に保ちながら徐々に滴下した。滴下終了後、実施例1−1と同様にして生成物を71.9g(収率75.2%)得た。
実施例1−1で得た多官能酸無水物を35g、脂肪族型エポキシ樹脂EHPE−3150((株)ダイセル製、エポキシ当量181)を10g、芳香族型エポキシ樹脂として(4(4(1,1−ビス(p−ヒドロキシフェニル)−エチル)α,α−ジメチルベンジル)フェノール)型エポキシ樹脂(エポキシ当量206、全塩素量550ppm)を27g、同じくRE−310S(日本化薬(株)製:液状ビスフェノールAエポキシ樹脂、エポキシ当量185、全塩素量500ppm)を23g、その他の成分としてオクタン酸亜鉛を0.3g、希釈溶剤であるMEKを41gあわせたものを70℃に加温、混合し、固形分が70質量%である本発明の樹脂組成物の希釈組成物を得た。
多官能酸無水物を実施例1−2で得たもの34g、MEKを40gとした他は実施例2−1と同様にして、固形分が70質量%である本発明の樹脂組成物の希釈組成物を得た。
多官能酸無水物を実施例1−3で得たもの41g、MEKを43gとした他は実施例2−1と同様にして、固形分が70質量%である本発明の樹脂組成物の希釈組成物を得た。
多官能酸無水物を実施例1−4で得たもの46g、MEKを46gとした他は実施例2−1と同様にして、固形分が70質量%である本発明の樹脂組成物の希釈組成物を得た。
多官能酸無水物を実施例1−5で得たもの35gとした他は実施例2−1と同様にして、固形分が70質量%である本発明の樹脂組成物の希釈組成物を得た。
多官能酸無水物を実施例1−6で得たもの35gとした他は実施例2−1と同様にして、固形分が70質量%である本発明の樹脂組成物の希釈組成物を得た。
多官能酸無水物を実施例1−7で得たもの35gとした他は実施例2−1と同様にして、固形分が70質量%である本発明の樹脂組成物の希釈組成物を得た。
多官能酸無水物を実施例1−8で得たもの35gとした他は実施例2−1と同様にして、固形分が70質量%である本発明の樹脂組成物の希釈組成物を得た。
多官能酸無水物を実施例1−9で得たもの40g、MEKを43gとした他は実施例2−1と同様にして、固形分が70質量%である本発明の樹脂組成物の希釈組成物を得た。
4-メチルヘキサヒドロ無水フタル酸を17g、MEKを33gとした他は実施例2−1と同様にして、固形分が70質量%である比較用樹脂組成物を得た。
1,2,4,5−シクロヘキサンテトラカルボン酸二無水物を17g、希釈溶剤をアセトン33gとした他は実施例2−1と同様にして、固形分が70質量%である比較用樹脂組成物の希釈組成物を得た。
ガラス基板上に耐熱離型テープで40mm×25mm×1mmの型を作製し、本発明の硬化性樹脂組成物及び比較例の硬化性樹脂組成物をそれぞれ厚さ約800μmにまで注型し、80℃にて50分間乾燥した。乾燥途中で真空脱泡を1回行い、泡を除去した。その後室温まで冷却し、状態を確認したところ、本発明の硬化性樹脂組成物は室温で固体であった。
続いて140℃乾燥機にて3時間硬化し、本発明の硬化物を得た。得られた硬化物についてそれぞれガラス転移点、強靭性、耐着色性を測定した。
(1)ガラス転移温度(Tg):硬化した樹脂組成物のTg点を粘弾性測定システム(DMS−6000:セイコー電子工業(株)製)において、引っ張りモード、周波数1Hzにて測定した。判定基準は以下の通りである。
◎:Tgが200℃以上
○:Tgが190℃以上199℃以下
△:Tgが185℃以上189℃以下
×:Tgが184℃以下
(2)強靭性:硬化した樹脂組成物の硬化膜の両端を手で固定し、中央部を押したときの硬化膜の状態を観察した。判定基準は以下の通りである。
◎:強く押してもひびが入らず、割れない。
○:弱く押してもひびが入らず、割れないが、強く押すとひびが入る。
△:弱く押すとひびが入り、強く押すと割れる。
×:弱く押すと割れる。
(3)耐着色性:硬化した樹脂組成物の硬化膜の初期の黄色度(YI)と230℃20分間放置後の黄色度(YI)を分光光度計(U−3900H:(株)日立ハイテクノロジーズ製(黄色度はJIS K7105/JIS K7373)にて測定し、その差(黄変度:ΔYI)を求めた。判定基準は以下の通りである。
◎:ΔYIが0.4以下
○:ΔYIが0.5以上0.7以下
△:ΔYIが0.8以上1.0以下
×:ΔYIが1.1以上
(4)信頼性:ライン/スペース=50/50ミクロンのくし型電極を構成させたポリイミド基板上に、シルクスクリーン法を用いて、厚さおおよそ25ミクロンの塗膜を作成した。120℃・85%相対湿度の高温槽中に入れて100Vの電圧を印加し、その抵抗値の推移を比較した。試験開始から抵抗値が1メガオームを下回った時点の時間を計測した。判定基準は以下の通りである。
◎:抵抗値が1メガオームを下回った時点が200時間以上
○:抵抗値が1メガオームを下回った時点が150時間以上199時間以下
△:抵抗値が1メガオームを下回った時点が100時間以上149時間以下
×:抵抗値が1メガオームを下回った時点が99時間以下
実施例 樹脂組成物 Tg(℃) 強靭性 黄変度(ΔYI) 信頼性
実施例3−1 実施例2−1 ○ ○ ○ ◎
実施例3−2 実施例2−2 ◎ ○ ○ ◎
実施例3−3 実施例2−3 ○ ◎ ○ ◎
実施例3−4 実施例2−4 ○ ◎ ○ ◎
実施例3−5 実施例2−5 ○ ○ ◎ ◎
実施例3−6 実施例2−6 ◎ ○ ○ ◎
実施例3−7 実施例2−7 △ ○ ◎ ◎
実施例3−8 実施例2−8 ◎ ○ △ ◎
実施例3−9 実施例2−9 ○ ◎ ○ ◎
比較例3−1 比較例2−1 ◎ △ × ◎
比較例3−2 比較例2−2 × × ◎ ×
比較例3−3 比較例2−3 △ × ◎ △
実施例1−4で得た多官能酸無水物を34g、エポキシ樹脂として3,4−エポキシシクロヘキシルメチル−3,4−エポキシシクロヘキシルカルボキシレート(ダウ・ケミカル製 UVR−6105)を33g、硬化剤としてヘキサデシルトリメチルアンモニウムヒドロキシド(東京化成工業(株)製 25%メタノール溶液)を0.09g、希釈溶剤であるMEKを20gとした樹脂組成物を得た。
多官能酸無水物を実施例1−6で得たもの34gとした他は実施例4−1と同様にして、樹脂組成物を得た。
多官能酸無水物を実施例1−8で得たもの34gとした他は実施例4−1と同様にして、樹脂組成物を得た。
多官能酸無水物を比較例1−1で得たもの34g、UVR−6105を39gとした他は実施例4−1と同様にして、比較用樹脂組成物を得た。
実施例4−1において多官能酸無水物を4-メチルヘキサヒドロ無水フタル酸17g、UVR−6105を20g、ヘキサデシルトリメチルアンモニウムヒドロキシドを0.06g、MEKを10gとした比較用樹脂組成物を得た。
実施例4及び比較例4で得られた樹脂組成物を真空脱泡60分間実施後、発光波長465nmを持つ発光素子を搭載した表面実装型LED(SMD型5mmφ 規定電流30mA)のリードフレームを金型に配置しトランスファ成形プロセスで樹脂を金型に流し込み加熱加圧し硬化させることで、点灯試験用LEDを得た。点灯試験は、規定電流である30mAの2倍の電流での点灯試験を行った。詳細な条件は下記に示した。測定項目としては、200時間点灯前後の照度を積分球を使用して測定し、試験用LEDの照度の保持率を算出した。結果を表2に示す。
発光波長:中心発光波長、465nm
駆動方式:定電流方式、60mA(発光素子規定電流は30mA)直列で3個同時に点灯
駆動環境:85℃、85%湿熱機内での点灯
評価:200時間後の照度保持率
判定基準は以下の通りである。
○:照度保持率が70%以上
△:照度保持率が65%以上69%以下
×:照度保持率が65%以下
実施例 組成物 照度保持率
実施例5−1 実施例4−1 ○
実施例5−2 実施例4−2 ○
実施例5−3 実施例4−3 ○
比較例5−1 比較例4−1 ×
比較例5−2 比較例4−2 △
実施例2−4、実施例2−6、実施例2−8、比較例2−1、比較例2−2で得られた樹脂組成物をE−ガラスからなるガラスクロス(IPCスペック106相当)に含浸した後100℃のオーブンで10分間乾燥させ、厚さ50μmのプリプレグを得た。
ITOによる導電加工を施したポリエチレンナフタレート(PEN)シートにポリ−3−ヘキシルチオフェン(プレックスコアOS P3HT、アルドリッチシグマ製)の薄膜を作製した。次いでこの基板を真空蒸着装置内に設置して、装置内の真空度が2×10−3Pa以下になるまで排気した。抵抗加熱蒸着法によって、C60を30nmの厚さに、2,9−ジメチル−4,7−ジフェニル−1,10−フェナントロリンを10nm蒸着した。さらにシャドウマスクを介してアルミニウムを100nm の厚さに蒸着して陰極を形成し、直径2mmの丸型有機太陽電池素子を作製した。
放射照度:100mW/cm2
駆動環境:−20℃15分→25℃5分→100℃15分→25℃5分のヒートサイクルを20回繰り返す。
評価:試験後の光電変換効率保持率
判定基準は以下の通りである。
◎:光電変換効率保持率が80%以上
○:光電変換効率保持率が70%以上79%以下
△:光電変換効率保持率が60%以上69%以下
×:光電変換効率保持率が59%以下
実施例 組成物 光電変換効率保持率
実施例7−1 実施例6−1 ◎
実施例7−2 実施例6−2 ◎
実施例7−3 実施例6−3 ◎
実施例7−4 実施例6−4 ◎
実施例7−5 実施例6−5 ◎
比較例7−1 比較例6−1 ×
比較例7−2 比較例6−2 ×
実施例3−1、3−3、3−4の硬化物について透明性の評価を行った。透明性評価は目視で着色を確認した。
実施例 樹脂組成物 繊維(C−2) 屈折率 透明性
実施例8−1 実施例3−1 ガラスクロス 1.561 透明
比較例8−1 実施例3−3 ガラスクロス 1.553 淡黄色
比較例8−2 実施例3−4 ガラスクロス 1.569 紫色
Claims (8)
- 請求項1に記載の多価アルコール(A)にアルキレンオキサイド、環状エーテル、及び環状エステルからなる群より選ばれる1以上を反応させて得られる多価アルコール(B)に無水トリメリット酸ハライド及び核水添無水トリメリット酸ハライドを反応させて得られる多官能酸無水物。
- 請求項1に記載の多価アルコール(A)または請求項2に記載の多価アルコール(B)のR1、R2が炭素数1〜4のヒドロキシアルキルである多価アルコールと無水トリメリット酸ハライド及び核水添無水トリメリット酸ハライドと反応させて得られる多官能酸無水物。
- 請求項1ないし請求項3のいずれか一項に記載の多官能酸無水物を含む封止材料。
- 一分子中に少なくとも1つのエポキシ基を有する化合物と請求項1ないし3のいずれか一項に記載の多官能酸無水物を含む熱硬化性樹脂組成物。
- 請求項5に記載の熱硬化性樹脂組成物を半硬化状態で形状を付与したプリプレグ。
- 請求項5に記載の熱硬化性樹脂組成物からなる封止材料。
- 請求項5に記載の熱硬化性樹脂組成物を硬化せしめた硬化物。
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CN201510140862.9A CN105085870A (zh) | 2014-05-13 | 2015-03-27 | 密封材料以及预浸体 |
TW104110360A TW201542617A (zh) | 2014-05-13 | 2015-03-31 | 密封材料以及預浸體 |
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