JP2014515044A5 - - Google Patents
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- Publication number
- JP2014515044A5 JP2014515044A5 JP2014500241A JP2014500241A JP2014515044A5 JP 2014515044 A5 JP2014515044 A5 JP 2014515044A5 JP 2014500241 A JP2014500241 A JP 2014500241A JP 2014500241 A JP2014500241 A JP 2014500241A JP 2014515044 A5 JP2014515044 A5 JP 2014515044A5
- Authority
- JP
- Japan
- Prior art keywords
- phosphorus
- polyol
- flame retardant
- containing flame
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 50
- 229910052698 phosphorus Inorganic materials 0.000 claims description 50
- 239000011574 phosphorus Substances 0.000 claims description 50
- 229920005862 polyol Polymers 0.000 claims description 45
- 150000003077 polyols Chemical class 0.000 claims description 45
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 38
- 239000003063 flame retardant Substances 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 15
- -1 alkylene radical Chemical class 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 8
- 239000004814 polyurethane Substances 0.000 claims description 8
- 229920002635 polyurethane Polymers 0.000 claims description 8
- 239000000047 product Substances 0.000 claims description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 239000011541 reaction mixture Substances 0.000 claims description 7
- 150000001412 amines Chemical group 0.000 claims description 6
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 6
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 5
- 229930006000 Sucrose Natural products 0.000 claims description 5
- 229920000768 polyamine Polymers 0.000 claims description 5
- 239000005720 sucrose Substances 0.000 claims description 5
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000004971 nitroalkyl group Chemical group 0.000 claims description 4
- 229920001451 polypropylene glycol Polymers 0.000 claims description 4
- 239000000600 sorbitol Substances 0.000 claims description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- VZMUCIBBVMLEKC-UHFFFAOYSA-N 2-chloro-5,5-dimethyl-1,3,2$l^{5}-dioxaphosphinane 2-oxide Chemical compound CC1(C)COP(Cl)(=O)OC1 VZMUCIBBVMLEKC-UHFFFAOYSA-N 0.000 claims description 2
- RAOZVFGTRXLBTA-UHFFFAOYSA-N 2-chloro-5,5-dimethyl-1,3,2-dioxaphosphinane Chemical compound CC1(C)COP(Cl)OC1 RAOZVFGTRXLBTA-UHFFFAOYSA-N 0.000 claims description 2
- TXHWYSOQHNMOOU-UHFFFAOYSA-N chloro(diethoxy)phosphane Chemical compound CCOP(Cl)OCC TXHWYSOQHNMOOU-UHFFFAOYSA-N 0.000 claims description 2
- LGTLXDJOAJDFLR-UHFFFAOYSA-N diethyl chlorophosphate Chemical compound CCOP(Cl)(=O)OCC LGTLXDJOAJDFLR-UHFFFAOYSA-N 0.000 claims description 2
- 239000012948 isocyanate Substances 0.000 claims description 2
- 150000002513 isocyanates Chemical class 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 125000006353 oxyethylene group Chemical group 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- HHDUMDVQUCBCEY-UHFFFAOYSA-N 4-[10,15,20-tris(4-carboxyphenyl)-21,23-dihydroporphyrin-5-yl]benzoic acid Chemical compound OC(=O)c1ccc(cc1)-c1c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc([nH]2)c(-c2ccc(cc2)C(O)=O)c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc1[nH]2 HHDUMDVQUCBCEY-UHFFFAOYSA-N 0.000 description 2
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical group COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 description 2
- 229920005830 Polyurethane Foam Polymers 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 150000001414 amino alcohols Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2011/072072 WO2012126179A1 (en) | 2011-03-23 | 2011-03-23 | Phosphorous-containing flame retardants for polyurethane foams |
| CNPCT/CN2011/072072 | 2011-03-23 | ||
| PCT/CN2012/072802 WO2012126380A1 (en) | 2011-03-23 | 2012-03-22 | Phosphorous-containing flame retardants for polyurethane foams |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2014515044A JP2014515044A (ja) | 2014-06-26 |
| JP2014515044A5 true JP2014515044A5 (https=) | 2016-03-24 |
Family
ID=46878610
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014500227A Pending JP2014508841A (ja) | 2011-03-23 | 2011-03-23 | ポリウレタンフォームのためのリン含有難燃剤 |
| JP2014500241A Pending JP2014515044A (ja) | 2011-03-23 | 2012-03-22 | ポリウレタンフォーム用リン含有難燃剤 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014500227A Pending JP2014508841A (ja) | 2011-03-23 | 2011-03-23 | ポリウレタンフォームのためのリン含有難燃剤 |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US20140018509A1 (https=) |
| EP (2) | EP2688898A4 (https=) |
| JP (2) | JP2014508841A (https=) |
| CN (1) | CN103534263B (https=) |
| AU (2) | AU2011362906A1 (https=) |
| BR (2) | BR112013022385A2 (https=) |
| CA (2) | CA2830446A1 (https=) |
| MX (2) | MX2013010824A (https=) |
| RU (2) | RU2013147165A (https=) |
| WO (2) | WO2012126179A1 (https=) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103443186A (zh) * | 2011-03-23 | 2013-12-11 | 陶氏环球技术有限责任公司 | 用于聚氨酯泡沫体的含磷阻燃剂 |
| WO2012126179A1 (en) * | 2011-03-23 | 2012-09-27 | Dow Global Technologies Llc | Phosphorous-containing flame retardants for polyurethane foams |
| US9550856B2 (en) | 2011-12-27 | 2017-01-24 | Dow Global Technologies Llc | Phosphorous based polyaddition / polyurethane-urea polyols |
| WO2014170316A1 (en) * | 2013-04-16 | 2014-10-23 | Basf Se | Phosphorous containing flame retardants |
| AU2014318649B2 (en) | 2013-09-13 | 2017-09-07 | Dow Global Technologies Llc | Thixotropic polyol compositions containing dispersed urethane-modified polyisocyanurates |
| CN103641971B (zh) * | 2013-12-16 | 2015-09-09 | 上海华峰超纤材料股份有限公司 | 含氨基甲酸酯结构的磷氮系阻燃剂及其制备方法 |
| KR20180104020A (ko) * | 2016-01-18 | 2018-09-19 | 바스프 에스이 | 다공성 재료의 제조 방법 |
| ES3063896T3 (en) | 2016-10-25 | 2026-04-21 | Ele Corp | Low-viscosity phosphate polyols |
| US10421910B2 (en) | 2017-08-16 | 2019-09-24 | International Business Machines Corporation | Sorbitol, glucaric acid, and gluconic acid based flame-retardants |
| US11059723B2 (en) * | 2018-07-18 | 2021-07-13 | International Business Machines Corporation | Renewable flame-retardant compounds derived from muconic acid |
| TW202020037A (zh) | 2018-08-29 | 2020-06-01 | 美商陶氏全球科技有限責任公司 | 用於改良剛性－韌性平衡之聚矽氧增強之乙烯／α－烯烴互聚物 |
| CN113549222B (zh) * | 2021-08-04 | 2022-05-13 | 中国科学技术大学 | 一种基于磷硅氮协效阻燃的超支化阻燃剂及其制备方法和应用 |
| US20250236700A1 (en) * | 2021-11-25 | 2025-07-24 | Dow Global Technologies Llc | Polyurethane compositions and viscoelastic polyurethane foams having reduced surface defect prepared with same |
| KR20250114131A (ko) * | 2022-12-16 | 2025-07-28 | 다우 글로벌 테크놀로지스 엘엘씨 | 고강성 폴리우레탄 발포체 조성물 |
Family Cites Families (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3294873A (en) * | 1961-09-12 | 1966-12-27 | Fmc Corp | Phosphorylated polyether polyols |
| NL129043C (https=) | 1964-08-14 | |||
| US3382236A (en) * | 1965-07-23 | 1968-05-07 | Weston Chemical Corp | Oxypropylated sucrose phosphites |
| US3369059A (en) * | 1965-07-27 | 1968-02-13 | Weston Chemical Corp | Monomeric polyphosphites with ether linkages |
| JPS4820535B1 (https=) * | 1969-06-09 | 1973-06-21 | ||
| US3725510A (en) * | 1970-02-05 | 1973-04-03 | Borg Warner | Phosphite-phosphates |
| US3758646A (en) | 1970-07-16 | 1973-09-11 | Borg Warner | Halogen containing phosphorus monools |
| JPS4923241Y1 (https=) | 1970-09-07 | 1974-06-22 | ||
| JPS492560B1 (https=) * | 1970-12-28 | 1974-01-21 | ||
| US3839504A (en) | 1971-08-04 | 1974-10-01 | Uniroyal Inc | Reaction of phosphorus trihalides with pentaerythritol and polymeric phosphite products thereof |
| JPS5037192B2 (https=) * | 1972-06-26 | 1975-12-01 | ||
| JPS5035537B2 (https=) * | 1972-06-26 | 1975-11-17 | ||
| FR2271229B1 (https=) * | 1974-05-13 | 1978-01-27 | Poudres & Explosifs Ste Nale | |
| US4049617A (en) * | 1976-01-19 | 1977-09-20 | Velsicol Chemical Corporation | Reactive flame retardants |
| US4070336A (en) * | 1976-09-03 | 1978-01-24 | Monsanto Company | Hydrogen phosphonates and polymer compositions containing them as flame retardants |
| JPS5552314A (en) * | 1978-10-13 | 1980-04-16 | Takeda Chem Ind Ltd | Manufacture of flame-retardant urethane-modified isocyanurate foam |
| US4394491A (en) | 1980-10-08 | 1983-07-19 | The Dow Chemical Company | Addition polymerizable adduct of a polymeric monoahl and an unsaturated isocyanate |
| JPS58108224A (ja) * | 1981-12-21 | 1983-06-28 | Hitachi Chem Co Ltd | アルキド樹脂の製造法 |
| JPS58126896A (ja) * | 1982-01-23 | 1983-07-28 | Ajinomoto Co Inc | アラニルプロリン誘導体およびこれを含有する降圧剤 |
| AT387577B (de) * | 1984-09-26 | 1989-02-10 | Eszakmagyar Vegyimuevek | Verfahren zur herstellung von n-alkyl/en/-n-/o,o- disubstituierten thiophosphoryl/-n'n'disubstituierten-glycinamiden und diese verbindungen enthaltende akarizide, insektizide und fungizide mittel |
| DE3504646A1 (de) * | 1985-02-12 | 1986-08-14 | Basf Ag, 6700 Ludwigshafen | Halogenfreie, selbstverloeschende thermoplastische formmasse |
| US4855345A (en) * | 1986-06-19 | 1989-08-08 | Ciba-Geigy Corporation | Stabilizers for organic polymers |
| US4885327A (en) * | 1987-11-18 | 1989-12-05 | Southwest Research Institute | Swelled polymeric decontamination composition |
| DE3811005A1 (de) * | 1988-03-31 | 1989-10-19 | Bayer Ag | Thionophosphor(phosphon)saeureamidester |
| DE3919195A1 (de) * | 1989-06-13 | 1990-12-20 | Bayer Ag | (di) (thio)phosphor(phosphon)saeure (amid)ester |
| EP0514332B1 (de) * | 1991-05-16 | 1996-04-17 | Ciba-Geigy Ag | Bisphosphite |
| JPH06345788A (ja) * | 1993-06-14 | 1994-12-20 | Nippon Alkyl Alum Kk | 不斉触媒及びそれを用いた光学活性第２級アルコールの製造方法 |
| JP3077786B2 (ja) * | 1993-12-03 | 2000-08-14 | 大八化学工業株式会社 | ポリウレタン用難燃剤 |
| DE4342621A1 (de) * | 1993-12-14 | 1995-06-22 | Bayer Ag | Phosphorsäure-Derivate |
| DE4342973A1 (de) * | 1993-12-16 | 1995-06-22 | Hoechst Ag | Flammwidrige Polyurethane |
| CN1043896C (zh) * | 1993-12-31 | 1999-06-30 | 清华大学 | 胺类在水体系中直接磷酰化合成氨基磷酸盐及其混合物的方法 |
| US5556894A (en) | 1994-11-04 | 1996-09-17 | Basf Corporation | Flame resistant rigid polyurethane foams containing phosphorus and a halogen |
| US5698664A (en) * | 1995-04-26 | 1997-12-16 | The Penn State Research Foundation | Synthesis of polyphosphazenes with controlled molecular weight and polydispersity |
| JPH0923241A (ja) | 1995-07-05 | 1997-01-21 | Fujitsu Ltd | 非同期型データの通信制御方法 |
| GB2321460B (en) | 1996-09-25 | 2000-09-13 | Ciba Sc Holding Ag | Monomeric and oligomeric bisphosphites as stabilisers for polymers such as PVC and as additives for lubricants, hydraulic fluids and metal processing fluids |
| WO2000035999A1 (en) | 1998-12-18 | 2000-06-22 | The Dow Chemical Company | Polyurethane based foam containing exfoliating graphite and the process for the preparation thereof |
| US6211259B1 (en) * | 1999-02-01 | 2001-04-03 | Aristech Acrylics Llc | Low volatile reinforcing system |
| GB0108061D0 (en) * | 2001-03-30 | 2001-05-23 | Baxenden Chem | Low monomer one component foam |
| US20060035989A1 (en) * | 2002-11-04 | 2006-02-16 | Noriaki Tokuyasu | Composition for flame-retardant flexible polyurethane foam |
| JP2007520572A (ja) * | 2003-08-14 | 2007-07-26 | チェイル インダストリーズ インコーポレイテッド | 難燃性ゴム強化ポリスチレン樹脂組成物 |
| WO2005082916A1 (en) * | 2004-02-26 | 2005-09-09 | Bayer Cropscience S.A. | 5-phosphorylaminopyrazole derivatives and their use as pesticides |
| WO2008067026A2 (en) * | 2006-09-29 | 2008-06-05 | Michigan Technological University | Purification of synthetic oligomers |
| US20100063169A1 (en) | 2007-01-04 | 2010-03-11 | Jeffrey Stowell | Phosphoramide ester flame retardant and resins containing same |
| CN101463086B (zh) * | 2009-01-09 | 2012-06-27 | 华南农业大学 | 二乙氧基硫代磷酸酯类有机磷农药抗体及其制备方法和应用 |
| CN101624403B (zh) * | 2009-08-10 | 2011-11-23 | 浙江工业大学 | 磷氮型季铵盐及其制备方法和应用 |
| WO2012126179A1 (en) * | 2011-03-23 | 2012-09-27 | Dow Global Technologies Llc | Phosphorous-containing flame retardants for polyurethane foams |
-
2011
- 2011-03-23 WO PCT/CN2011/072072 patent/WO2012126179A1/en not_active Ceased
- 2011-03-23 EP EP11861881.8A patent/EP2688898A4/en not_active Withdrawn
- 2011-03-23 US US14/001,902 patent/US20140018509A1/en not_active Abandoned
- 2011-03-23 CA CA 2830446 patent/CA2830446A1/en not_active Abandoned
- 2011-03-23 AU AU2011362906A patent/AU2011362906A1/en not_active Abandoned
- 2011-03-23 JP JP2014500227A patent/JP2014508841A/ja active Pending
- 2011-03-23 CN CN201180069503.9A patent/CN103534263B/zh active Active
- 2011-03-23 MX MX2013010824A patent/MX2013010824A/es unknown
- 2011-03-23 RU RU2013147165/04A patent/RU2013147165A/ru not_active Application Discontinuation
- 2011-03-23 BR BR112013022385A patent/BR112013022385A2/pt not_active IP Right Cessation
-
2012
- 2012-03-22 RU RU2013147161/05A patent/RU2595687C2/ru active
- 2012-03-22 US US14/001,903 patent/US9023925B2/en active Active
- 2012-03-22 MX MX2013010835A patent/MX362285B/es active IP Right Grant
- 2012-03-22 WO PCT/CN2012/072802 patent/WO2012126380A1/en not_active Ceased
- 2012-03-22 JP JP2014500241A patent/JP2014515044A/ja active Pending
- 2012-03-22 BR BR112013022426-6A patent/BR112013022426B1/pt not_active IP Right Cessation
- 2012-03-22 EP EP12761119.2A patent/EP2688953B1/en active Active
- 2012-03-22 AU AU2012231542A patent/AU2012231542B2/en not_active Ceased
- 2012-03-22 CA CA2830445A patent/CA2830445C/en active Active
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